Niobium Alloys Research Articles

Study on the Oxidation Behavior of TiB2-CeO2-Modified (Nb,Mo,Cr,W)Si2 Coating on the Surface of Niobium Alloy

A novel TiB2-CeO2-modified (Nb,Mo,Cr,W)Si2 coating was prepared on a Nb-5W-2Mo-1Zr alloy substrate using two-step slurry sintering and halide-activated pack cementation to address the limitations of a single NbSi2 coating in meeting the service requirements of niobium alloys at elevated temperatures. At 1700 °C, the static oxidation life of the coating exceeded 20 h, thus indicating excellent high-temperature oxidation resistance. This was due to the formation of a TiO2-SiO2-Cr2O3 composite oxide film on the coating surface, which, due to low oxygen permeability, effectively prevented the inward infiltration of oxygen. Additionally, the dense structure of the composite coating further enhanced this protective effect. The composite coating was able to withstand over 1600 thermal shock cycles from room temperature to 1700 °C, and its excellent thermal shock performance could be attributed to the formation of MoSi2, CrSi2, and WSi2 from elements such as Mo, Cr, and W, which were added during modification. In addition to adjusting the difference in thermal expansion coefficients between the layers of composite coatings to reduce the thermal stress generated by thermal shock cycles, the formation of silicide compounds also improved the overall fracture toughness of the coating and thereby improved its thermal shock resistance.

Shear bond strength between dental adhesive systems and an experimental niobium-based implant material

This study aimed to investigate adhesive shear bond strength (SBS) on an ultrafine-grained niobium alloy (UFG-Nb) that is a potential dental implant material. SBS of three adhesive systems combined with three composites to UFG-Nb was compared to corresponding SBS to Ti-6Al-4V and to zirconia. Specimens of the substrates UFG-Nb, Ti-6Al-4V and zirconia with plane surfaces were sandblasted with Al2O3, cleaned and dried. Three adhesive systems (Futurabond U, Futurabond M + , Futurabond M + DCA; all VOCO GmbH, Cuxhaven, Germany) were applied each on specimens of each substrate and light cured. One composite (BifixSE, BifixQM, GrandioSO; all VOCO GmbH) was applied and light cured resulting in 27 groups (n = 10) for all substrate-adhesive-composite-combinations. SBS was measured after 24 h of storage. To simulate aging equally prepared specimens underwent 5000 thermocycles before SBS measurement. There was no significant difference in SBS within the non-aged groups. Among the artificially aged groups, GrandioSO-groups showed a greater variance of SBS than the other composites. All significant differences of corresponding UFG-Nb-, Ti-6Al-4V- and zirconia-groups with same adhesive-composite-combination (ACC) were observed between UFG-Nb and zirconia or Ti-6Al-4V and zirconia but never between the two metallic substrates. The similarity between these materials might show in their adhesive bonding behavior. As there were no differences comparing corresponding groups prior to and after artificial aging, it can be concluded that aging does not affect SBS to UFG-Nb, Ti-6Al-4V and zirconia using the tested ACCs. Adhesive bonding of established ACCs to UFG-Nb is possible resulting in SBS comparable to those on Ti-6Al-4V and zirconia surfaces.Graphical

Plasma-assisted particle deposition manufacturing: Multi-functional integrated superhigh temperature thermal protection coating on niobium alloy

Plasma-assisted particle deposition manufacturing: Multi-functional integrated superhigh temperature thermal protection coating on niobium alloy

Analysis of High and Low Temperature Performance of Titanium Zirconium Molybdenum Alloy and High Temperature Alloy Brazed Joint

Abstract Using niobium as the intermediate layer and gold nickel (Au82-Ni) filler metal, TZM alloy and high-temperature alloy GH3128 were brazed. The brazed specimens were subjected to 400 cycles of high and low temperature cycling tests at temperatures ranging from 650 °C ∼ 680 °C (high temperature) to -196 °C (low temperature) for 10 minutes seperately. Then the microstructure variation before and after the experiment were observed and the shear strength of the specimens were tested at room temperature for 50 cycles of 400 high and low temperature testing.. The results show that the microstructure of the transition zone at the brazing interface after brazing is uniform and dense, with good wettability with the substrate and no defects such as cracks. The solder and substrate undergo diffusion reactions, and the molybdenum alloy, niobium, and niobium, high-temperature alloy had each form diffusion layers, formed intermetallic compounds on the brazing surface. After high and low temperature cycling, cracks exist in the braze seam between molybdenum alloy and niobium alloy. The cracking mode should be thermal fatigue based on the fracture morphology and phase analysis. The reasons of interface cracking are that due to different thermal expansion coefficients, low mutual solid solubility, and the formation of a large number of different types of intermetallic compounds, Mo and Nb materials have poor brazing compatibility and lower interface strength. Under cold and hot cycling conditions, brittle intermetallic compounds are prone to form crack source areas. As the number of cycles increases, the cracks gradually expand, ultimately leading to product leakage. In addition, the shear strength of brazed joints shows a decreasing trend with the increase of high and low temperature cycles in 400 high and low temperature tests.

Pulsating Heat Pipe Performance Modeling with Liquid Metal Coolants Under Hypersonic Aerothermal Heating

Hypersonic heating loads concentrate at leading-edge compression areas to create excessively high local temperatures and thermally driven stresses. The fast and reliable thermal dispersion of heat pipes with significantly high thermal conductance can alleviate these localized thermal stiffness problems. The pulsating heat pipe (PHP) holds numerous advantages when compared to capillary, constant-conductance heat pipes for hypersonic thermal management applications, primarily because they lack a wicking structure. This paper numerically investigates thermal performances of a four-turn C103 niobium alloy PHP operating with lithium, potassium, sodium, and a eutectic sodium–potassium alloy (NaK-78) when exposed to heating conditions relevant to the hypersonic environment, investigating flight Mach numbers ranging from 6 to 8 and dynamic pressures ranging from 40 to 44 kPa. The robust thermofluidic properties of liquid metals, along with the powerful fluid pulsation induced in the PHP, can provide significant thermal transport from hot stagnant regions of the leading edge to the cooler trailing surfaces. Potassium showed superior thermal performance when compared to other liquid metal coolants under the presently tested conditions, with overall PHP thermal conductance as high as 34 W/K predicted for Mach 8 flight conditions. In contrast, sodium was associated with startup difficulties in the PHP; this paper attributes this to its significantly larger thermal conductivity, which can limit the vapor pressure difference over the liquid slug lengths. These predictions indicate an overall latent heat transfer dominance of around 70–95% in liquid metal PHPs.

Отримання жароміцного гомогенного сплаву методом пресування та спікання суміші порошків (Nb-21Ti-5Al-10Cr-7Mo) ат. %

Multicomponent high temperature strength alloys of the Nb-Ti-Al system, alloyed with Cr, Zr, Mo and Si, with a specific gravity of 6.3 - 7.4 g/cm3, have proven extremely promising in aviation and space technology. However, their physical and chemical features are associated with the high activity of the components, with a significant difference in melting temperatures (from Tmel. Mo – 2617 °C to Tmel. Al – 660 °C) and different specific gravity (from 10.2 g/cm3- Mo up to 2.7 g/cm3- Al), is a big problem for their production. The long crystallization interval of cast alloys of this system, thermophysical features of their crystallization, determine the possibility of formation of dendritic structures, the development of dendritic liquation and segregation of low- or high-temperature intermetallics and eutectics, the tendency to the formation of crystallization cracks, which reduces the operational characteristics of cast alloys. In this regard, it became necessary to investigate the possibilities of obtaining an alloy by the method of powder metallurgy. The purpose of this work was to obtain a homogeneous alloy, to study changes in the grain structure, phase transformations and mechanical properties of the material at various stages of processing in the process of obtaining a homogeneous alloy structure by powder metallurgy methods. The need to protect powder components from oxidation, formation of nitrides, carbides during technological operations at temperatures above 200 °C (high-purity argon) has been established. The optimal duration of intensive grinding of a mixture of powders and granules of raw materials has been worked out, which makes it possible to control the uniformity of the size of the particles of the mixture components, porosity and homogeneity of the alloy. The optimal duration of grinding is 30 minutes, during which the most homogeneous mixture in terms of particle size is formed. The optimal annealing mode was established, which ensures the achievement of homogenization of the alloy, phase transformations at the boundaries of the contact of component particles, and changes in grain sizes. Microstructural and X-ray structural analysis of the samples was carried out, their microhardness and grain dispersion were determined. Keyword: high-temperature strength niobium alloys, physical and chemical features, powder metallurgy, homogeneity, microstructure, mechanical properties, phase composition.

Bioactive surface modification of Ti–Nb alloy by alkaline treatment in potassium hydroxide solution

Abstract The aim of this work is to compare the responsive behaviour of titanium, niobium and titanium–niobium alloy during alkaline treatment in forming alkaline titanate layer and their resultant bioactive properties. Titanium and niobium powder mixture with composition in the beta region was pressed at 550 MPa and sintered at 1,200 °C for 2 h. The alloy was soaked in potassium hydroxide aqueous solution at 60 °C for 24 h with different concentrations of 0.5 M and 5 M. The effect of post sintering-heat treatment was investigated by annealing the treated alloy at 600 °C for 2 h. X-ray diffraction analysis and Fourier transform infrared spectroscopy analysis were used to evaluate the chemical composition and the functional group of material on the treated alloy surface respectively. Immersion in Hanks solution for 1 day resulted in traces of calcium and phosphate on alloy surfaces treated in different concentrations of alkali as well as post-heat treatment. The cell viability evaluation using MTT (3-[4,5-dimethylthiazol-2-yl]-2,5 diphenyl tetrazolium bromide) assay on the new beta-Ti alloy with potassium-based titanate layer demonstrated potassium hydroxide treatment with a 5 M concentration after post-heat treatment significantly improved cell proliferation, which is a prerequisite for bone mineral apatite deposition.

Enhanced an eutectic carbide reinforced niobium alloy by optimizing Mo and W alloying elements

Niobium alloys play an indispensable role in aerospace technology. However, traditional niobium alloys has unsatisfactory or high-temperature strength or limited room-temperature. This work introduces Nb2MoxWyC0.25 alloys with strength-plasticity balance by optimizing refractory alloy elements and eutectic carbides drawing on the design concepts of eutectic high-entropy alloys. The influence of Mo and W contents on the microstructure and mechanical properties of the alloys was studied. The Nb2MoxWyC0.25 alloy contain body-centered cubic (BCC) primary phase and eutectic structures composed of BCC and carbide phases with semi-coherent interfaces. Appropriate additions of Mo and W refine the grain size of the primary BCC phase and cause the carbide phase to evolve from Nb2C to NbC. The Nb2Mo0.5W0.5C0.25 hypoeutectic niobium alloy composed of BCC and Nb2C phases with a relatively small lattice mismatch has a room-temperature yield strength of 1.27 ± 0.04 GPa, compressive strength of 2.03 ± 0.06 GPa, and a fracture strain of 17.8 ± 2.2 %. Solid solution strengthening in the BCC phase and second-phase strengthening of the carbide phase simultaneously enhance the alloy. The fine grain strengthening, reduced crack origination at low mismatch interface, and the crack tip by soft BCC at the phase interface improve the plasticity simultaneously. This paper provides a method to improve the room-temperature plasticity and strength of refractory niobium alloys, laying the foundation for the industrial application of refractory niobium alloys.

Preparation of fine-grained/ultrafine-grained Nb521 alloy with superior mechanical property by friction stir processing

High strength-ductility synergy is difficult to achieve in Nb alloys. Although high strength has been achieved through severe plastic deformation (SPD) technology, led to low ductility in alloys. In this work, FSP technology was applied to treat Nb–5W–2Mo–1Zr-0.1C (Nb521) alloys in preparation of fine-grained (FG)/ultrafine-grained (UFG) Nb521 with excellent strength and ductility. The microstructure evolution and mechanical property improvement mechanism were systematically studied for Nb521 alloy through various characterization pathways. The research results indicated that UFG Nb521 alloy with a grain size of 0.63 ± 0.41 μm can be prepared using low shoulder plunge depth FSP (LPD-FSP), which is the first report of UFG Nb521 alloy. The main reason for the formation of onion rings structure in SZ is the periodic wear of the stirring tool, and the onion rings structure does not cause mechanical damage. The texture formed by Nb521 alloy under different processing parameters is off-axis shear texture, which matches the ideal shear texture of D2 (112‾)[111] after rotation. In addition, this study also elaborated on the refinement mechanism of the second phase particles (Nb, Zr) C in Nb521 alloy during FSP. This study also indicated that the increase in yield strength of FSP samples at room temperature is mainly determined by grain refinement. These findings provided new ideas for the development of high-performance niobium alloys.

Enhancing the high-temperature oxidation resistance of C-103 niobium alloy via hybrid treatment combining nickel plating with molten-salt siliconising

ABSTRACT A multi-phase silicide protective coating was prepared by electroplating nickel on the surface of C-103 niobium alloy (89Nb–10Hf–1Ti), followed by molten-salt non-electrolytic siliconising to enhance the high-temperature oxidation resistance of the substrate. The phase composition, microscopic morphology and elemental analysis of the coating were analysed via X-ray diffraction, scanning electron microscope, energy-dispersive spectrometer and hardness distribution. Oxidation characteristics were evaluated by comparing the oxidation inhibition effect of the coating on niobium alloy substrate and that of coating prepared via molten-salt infiltration alone at a constant temperature of 1100°C for 9 h. Results show that a silicide infiltration coating containing about 200-μm-thick compound layer with Ni2Si, NiSi, Nb5Si3, NbSi2, Ni3Si2 and TiNiSi multi-phase composition and ∼10–15-μm-thick diffusion layer were dense with few defects. In the hybrid synthesis process, the upper electroplated nickel coating can promote and modify the growth of subsequent siliconised coating. The duplex prepared silicon infiltration coating can reduce the oxidation rate of niobium alloy substrate by about 1/10, indicating good high-temperature oxidation resistance. This is because the siliconised coating is considerably thick, has a dense blocking structure and generates Ni4Si7Ti4, thereby blocking oxygen.

Diffusion bonding of dissimilar materials for space applications via hot isostatic pressing

In this work, hot isostatic pressing diffusion bonding (HIP DB) behaviour of dissimilar materials such as niobium (Nb), platinum (Pt) and titanium alloy (Ti6Al4V) were assessed, especially for thrust combustion chamber used in rocket engines. In particular, the development of an oxidation-resistant layer for pure Nb using Pt was addressed. The diffusion layer analysed by scanning electron microscopy (SEM) shows a successful reaction between pure Nb and Pt with the generation of a 20 µm thick, fully dense reaction layer. Furthermore, the DB of pure Nb with Ti6Al4V was also investigated to evaluate the possibility of joining Nb and Ti6Al4V dissimilar materials for space applications. HIP-DBtrials presented in this work demonstrate the possibility of replacing the conventional R-512 E di-silicide coating with a Pt layer and the fusion welding of Nb and Ti6Al4V with solid state HIP-DBjoining to obtain a defect-free joint with a desirable microstructure at or near the interface.

Trailblazing multi-material structure: Niobium alloy to tungsten–copper composite using wire-arc additive manufacturing

Integrating tungsten and niobium alloys into a single component offers synergistic benefits for fusion reactor applications. Additive manufacturing, particularly for components with complex geometries, further amplifies these advantages. This study examines the fabricability of a multi-material structure composed of a W–Cu composite and an Nb–Zr alloy using wire-arc additive manufacturing. The resulting W–Cu/Nb–Zr structure was free from significant defects like porosity or cracks, though the formation of hard intermetallic compounds was observed. Numerical analysis indicated considerable residual stress accumulation at the interface. During tensile testing, fractures occurred in the W–Cu composite near the interface, with the specimens exhibiting an ultimate tensile strength of 218 ± 3 MPa and an elongation of 5.7 ± 1 %.

Structural-phase state and properties of heat and wear resistant cast irons of Cr–Mn–Ni–Ti system additionally alloyed with Al and Nb

The paper presents the data on phase composition and structure forming for the alloys, on distribution of elements among the alloy structural components, on variation of wear resistance, scale resistance, growing stability and mechanical properties of cast iron of Cr–Mn–Ni–Ti–Al–Nb system depending on different aluminium and niobium content and thermal ac-cumulating capacity of a casting mould. Complex carbides (Nb, Ti)C are forming in white cast iron during niobium alloying. Quantitative metallographic analysis of (Nb, Ti)C carbides and (Cr, Fe, Mn)7C3 complex carbides was carried out on the samples with examined composition. Aluminium provides favourable influence on forming of the thin protective spinel-type films with minimal amount of defects; diffusion through such oxide film is very difficult. Joint alloying by aluminium and niobium leads to simultaneous increase of heat resistance and wear resistance. Wear resistance increased as a result of enlargement of the part of primary carbides (Nb, Ti)C with high hardness in the structure of cast iron. Composition of oxide films includes aluminium, which strengthens their protective properties and rises of the alloy scale resistance. It is found for the first time that niobium doping leads to secondary solidification during cooling in the casting mold. Dispersion particles of М7С3 carbides are forming in solid state, thereby no structure degradation occurs during testing at increased temperatures, and growing stability rises. On the basis of the complex of the conducted researches the rational composition of heat and wear resistant cast iron is offered at the following ratio of components, wt. %: 2.1–2.2 C; 4.5–5.0 Mn; 18.0–19.0 Cr; 1.0–1.2 Ni; 0.4–0.6 Ti, 2.0 Nb; 2.0 Al. Wear resistance increased 1.2 times compared to cast irons before the introduction of aluminum and niobium, and scale resistance – 2.4–4.5 times depending on the type of casting mold, the index of growth resistance is equal to zero for cast irons cast in dry SLM

A unified model of tensile and creep deformation for use in niobium alloy materials selection and design for high-temperature applications

There is renewed interest in refractory alloys that possess higher service temperatures than incumbent Ni-based superalloys (e.g., ⪆1100 °C). This study provides a review of the high-temperature constitutive responses of Nb-alloys measured over a wide range of temperatures (≈860 °C < T < ≈1760 °C) and strain rates (≈10–9 s-1< ε˙ < ≈10–1 s-1). Nevertheless, the extant data is sparse and informed materials selection decisions require constitutive expressions to interpolate and reliably extrapolate. The Larson-Miller parameter approach to describe creep-life provides a conservative estimate of material response at the highest temperatures and lowest strain rates, whereas the Sellars-Tegart model describes both steady-state creep and high-temperature tensile test data with a single, universal equation. A minimum flow stress based on the combination of these two models is proposed for design considerations to address the overprediction of strength that can arise from applying one or the other independently. This effort highlights the fact that refractory alloys exhibit strain rate sensitive flow strengths in the temperature range of interest for applications. The roles of alloying, thermomechanical processing, and impurity levels are discussed, and highlight the fact that these advanced Nb-alloys evidence Class 1 (Class A) solute drag controlled creep behavior, except the carbide precipitation strengthened alloy, D-43. In addition, the high-temperature strengths are confirmed to be strongly correlated with alloy melting point.

Investigation of ZrO2-toughened Yb2SiO5 environmental barrier coating on Nb alloy under water-vapor corrosion at 1500 °C

To protect niobium alloy against water-vapor corrosion at high temperatures, an innovative ZrO2-modified Yb2SiO5 environmental barrier coating was prepared via supersonic atmosphere plasma spraying. The service life of the modified coating (50 h) is 10 times higher than the pristine due to the higher fracture toughness (2.07 MPa∙m1/2) to inhibit cracking during frequent thermal cycles. With exposure prolonging, the in-situ formation of (Zr,Yb)O2 solid solution would weaken the fracture toughness of the coating by hindering the phase transformation of ZrO2 from cubic to monoclinic, while improving the corrosion resistance of the coating by enhancing atomic bonding strength.

Effect of Nb content on the mechanical properties of Nbx(MoTaW)(1-x) (x = 0.4, 0.55, and 0.7) refractory multicomponent alloys

The MoNbTaW refractory multicomponent alloy (RMCA) retains good yield strength up to 1873K, but limited plasticity and high density at room temperature impede its utility in practical applications. Thus, a unique alloy design approach based on composition modification was used to improve these properties. Among the four constituent elements of the MoNbTaW alloy, Nb has good plasticity and lower density; hence a series of alloys with varying Nb content, namely Nbx(MoTaW)(1-x) with x = 0.4, 0.55, and 0.7 (designated as Nb0.4, Nb0.55, and Nb0.7 in this manuscript), were processed using vacuum arc melting. X-ray diffraction results showed that all the alloys formed as single-phase with the body-centered cubic crystal structure. The microstructures of these RMCAs are dendritic in nature with segregation of elements that decreased with heat treatment. The hardness values showed a decrease as the Nb content increased. The compressive yield strength values are 1251, 1055, and 945 MPa, and those of fractured strain are 10, 22, and 33 % for Nb0.4(MoTaW)0.6, Nb0.55(MoTaW)0.45, and Nb0.7(MoTaW)0.3 respectively. The increase in plastic strain and toughness is due to the increment in the Nb concentration, which is directly interpreted as an enhancement in degree of plasticity. The average grain sizes of Nb0.4, Nb0.55, and Nb0.7 RMCAs are measured to be 86 μm, 106 μm and 145 μm respectively. It was observed that 36 % of the grains are above 100 μm for Nb0.4 alloy, whereas this fraction is increased to 49 % and 60 % for Nb0.55 and Nb0.7 alloys respectively, which indicates an increase in average grain size as well as fraction of coarser grains as the Nb content increases. Hence, the improvement in plasticity is attributed to the increase in the average grain size and broader grain distribution. Fracture surface analysis of all the compositions showed quasi-cleavage behavior. This study demonstrates that increasing the Nb concentration in the MoNbTaW RMCA enhances plasticity while decreasing density. In comparison to conventional niobium alloys like C103 and FS-85, the alloys of the present study had higher yield strength at the temperatures where the tests were carried out. The specific yield strength values of these alloys are found to be higher than commercially available Nb alloys.

High temperature oxidation behavior at 1250 °C: A new multilayer modified silicide coating design strategy on niobium alloys

Silicide coatings have proven to be promising for improving the high-temperature oxidation resistance of niobium alloy. However, the long-term protective property of single silicide coating remains a long-time endeavor due to the deficiency of oxygen-consuming phases, as well as the self-healing ability of the protective layer. Herein, a silicide-based composite coating is constructed on niobium alloy by incorporation of nano-SiC particles for enhancing the high-temperature oxidation resistance. Isothermal oxidation results at 1250 °C for 50 h indicate that NbSi2/Nb2O5-SiO2/SiC multilayer coated sample with a low mass gain of 2.49 mg/cm2 shows an improved oxidation resistance compared with NbSi2 coating (6.49 mg/cm2). The enhanced high-temperature antioxidant performance of NbSi2/Nb2O5-SiO2/SiC multilayer coating is mainly attributed to the formation of the protective SiO2 self-healing film and the high-temperature diffusion behavior of NbSi2/substrate.

INFLUENCE OF WELDING PARAMETERS ON THE PERFORMANCE CHARACTERISTICS OF THE THERMOCATODES

Methods of controlling welding parameters, physical and physico-chemical transformations that occur during welding are considered in the work. The physico-chemical mechanism of welding is considered - the deformation of the crystal lattice, the transfer of metal on the contacting surfaces, the mixing of deformation products, diffusion, phase transformations, the appearance of new chemical compounds - intermetallics, oxides, carbides. Studies of the influence of the main parameters of friction welding on the formation of the structure of the welded joints of the investigated alloys have been carried out. The microstructures of welded joints OT4 + VN-2AE and VT6 + VN-2AE are given. The obtained dependence of the relative strength of the OT 4 + VN-2AE connection on the parameters of the welding process. The given microstructures were obtained by SEM from the surface of OT 4 + VN-2AE and VT6 samples, based on which it was determined that the destruction begins with the formation of microcracks in the contact zone on the side of the VN-2AE niobium alloy. It was determined that a layer saturated with oxygen is formed in the diffusion zone due to which the β-modification of Ni2O5 with a significant specific volume is formed, which causes high internal stresses and the formation of microcracks. The reason for the decrease in the mechanical properties of the welded joint OT 4 + ВН-2АЕ was established - the formation of a phase (Ti-Nb) with an orthorhombic lattice, the degree of curvature of which determines the degree of strengthening of the layer and depends on the niobium content. These data are confirmed by X-ray structural analysis. The analysis of the concentration curves of niobium and titanium shows that titanium does not diffuse into the narrow contact zone of the niobium alloy, and niobium forms a wide diffusion zone in the contact zone of the OT 4 alloy. It was established that niobium contributes to the increase in the solubility of aluminum in λ-titanium, which leads to increase in weldability plasticity and corrosion resistance. It was determined that the low mechanical properties of the welded joints of the VN-2AE alloy with the OT-4 and VT-6 titanium alloys are due to the same nature - the oxidation of the niobium alloy at the welding temperature. It was established that the weak link of the welded joint is the surface of the niobium alloy.

Construction of a Triboelectrochemical Setup with Controlled Environment for Biomaterial Testing with a Comparison of Cobalt–Chromium–Molybdenum and Titanium–Aluminium–Niobium Alloys

The present work is focused on the manufacturing of a special self‐developed tribocorrosion setup with a controlled incubated environment. The comparative studies between wrought Co27Cr6Mo and Ti6Al7Nb alloys are performed with the respective tribometer in Ringer's solution at 37 °C. It is found that the CoCrMo alloy demonstrated a noble open circuit potential not only in non‐wear condition but also under wear conditions, in comparison to Ti6Al7Nb. The mass loss rate examined at open circuit potential and at a constant potential of 0.2 V versus Ag|AgCl|3.5 m KCl also suggests a similar superiority of the CoCrMo alloy.

Optimizing Ferrotitanium Wire Injection Parameters for Improving Titanium Recovery in Ladle Furnace Steelmaking

Titanium or niobium alloying is done in microalloyed steels to improve the mechanical properties by grain refinement. Contrary to niobium, titanium addition gives additional advantages of 1) lower rolling load in the mill and 2) low ferroalloy cost. However, recovery of titanium, owing to its high affinity toward oxygen, is highly inconsistent and depends mainly on secondary steelmaking process parameters like dissolved oxygen content in steel, chemical composition of slag, addition method of alloy, fluid flow conditions of the bath during and after the addition of alloy and temperature of steel. Herein, process data have been analyzed and correlated to the chemical composition of steel and slag to understand the influence of various process parameters on titanium yield. Industrial plant trials have been conducted with a modified ferrotitanium (FeTi) addition practice. FeTi wire injection is done in seven heats with different wire injection speed and bottom argon purging rate. It has been found that 200 m min−1 of injection speed along with differential flow rate of argon from porous plugs with 35 and 6 Nm3 h−1, respectively, yields better recovery of titanium. The titanium recovery increases by 4% compared to the earlier practice of wire injection and argon purging.