The composite wear resistant cladding of nickel-based powder matrix and 10% SiC powder as reinforced was developed through microwave hybrid heating on martenisitic stainless steel (SS-420) substrate. The development of the clad has been carried out by using a domestic microwave applicator of frequency 2.45 GHz and 900 W power level. The microstructural and mechanical characterizations of the developed clad were carried out by using scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction, and Vicker’s microhardness analysis. Results revealed that clads of approximately 1.25 mm thickness were developed with significantly low porosity (∼1.10%). The scanning electron microscopic results show that the microstructure of clad exhibits typical cellular-like structure. The metallurgical bonding between clad and substrate surface was obtained with partial dilution. The complex carbides of chromium and silicides of chromium, iron, and nickel phases were identified in the clad region by XRD study, which may enhance the Vicker’s microhardness of the clads significantly. The average Vicker’s microhardness of the developed clad was in the range of 652 ± 90 HV.