In a recent paper, a new method of calculating the doublets and triplets gate utilisation factors f 2 and f 3 for passive neutron multiplicity counters has been developed resulting in the MCF computer code. In this paper we arrange the basic multiplicity equations and generate nuclear data parameter combinations to enable f 2, f 3, f 2/ f 3 and f 2 2/ f 3 to be derived from measurements taken using a calibrated 252Cf source and multiplicity shift-register electronics. The two approaches have been compared with reference to Harwell Instruments Ltd. N95 neutron coincidence counting measurement chamber operated both with and without an internal cadmium liner. The Monte Carlo code MCNP™ was used to calculate neutron capture time distributions and these were fed into the MCF code to produce theoretical gate utilisation factors to compare with the experimental data. Pre-delays of 2 and 4 μs and coincidence gate widths between 16 and 240 μs were investigated. The predicted values agreed with those measured within 1.5% and 5% for the f 2 and f 3 results, respectively. These results confirm the power of the new theoretical treatment in accurately predicting gate utilisation factors in an absolute sense and with confidence at the design stage. Relative predictions can be made with greater accuracy.