With the implementation of the “3060” carbon neutrality policy, the cancellation of external insulation has led to the increasingly serious deposition of heavy components in petroleum storage tanks. However, there are few studies on the flocculation and deposition behavior of industrial complex crude oil systems during the entire storage period in tanks. This study used an equivalent crude oil tank system to systematically investigate the flocculation and deposition behavior of industrial crude oil systems during storage. Static settling experiments were conducted for the entire storage period (32 days) to measure changes in oil parameters such as density, wax appearance temperature (WAT), gel point, and particle size at different heights in the tank. In addition, a full-component molecular system for crude oil was constructed, and molecular dynamics (MD) simulation was used to reveal the flocculation and aggregation mechanisms of heavy components in crude oil systems for the first time. The result showed that the maximum density difference between the upper and lower of the test tank is 14 kg/m3 and the marked stable time of sedimentation is 163 h. The maximum increment of the WAT appears at the bottom of the tank with the value increasing from 38.17 °C to 45.75 °C. The microscopic observations are consistent with the changes in macroscopic parameters. The wax is very prone to aggregation and wax crystals show a face-to-face sticking state. As for asphaltenes, the degree of aggregation is weaker than that of wax molecules, and the aggregation state mainly shows two manners: T-shape sticking and face-to-face sticking. This study can provide the theoretical basis for tackling the tank bottom sediment.
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