AbstractThe commercial carbon‐based supercapacitor with high power ability (~5 kW kg−1) is still unable to fulfill the superhigh power requirement of specific power‐type equipments (>20 kW kg−1), such as rail transit facilities, electromagnetic and laser equipment. To unravel the structure‐activity relationship and electrochemical behavior of power‐type densifying carbon is a key to overcome the contradiction of the suitable mesoporous ratio and highly‐densifying features toward the superhigh power requirement. Here, we built the hierarchically‐densifying mesoporous apocynum carbon (HDMC) with optimized mesoporous ratio by hierarchical activation method. More importantly, both the isothermal desorption/adsorption and high‐pressure mercury intrusion porosimetry methods were employed to synergistically uncover the microscopic surface carbon network stacking mechanism and the macroscopic carbon skeleton densification assembly mechanism. The highly‐densifying skeleton features and high mesoporous ratio properties were proved to be co‐existed in HDMC, which is in favour of rapidly ion/electron transferring toward electrochemically‐improving power behavior of HDMC. A combination of high tap density (0.387 g cm−3) and ideal microporous‐mesoporous system (23.1 % proportion of mesoporous) have taken this HDMC to provide a super‐high power density (33.5 kW kg−1) and a high volume power density (9.37 kW L−1) for HDMC‐based supercapacitor, more than those of commercial YP‐50F (14.9 kW kg−1 @ 4.63 kW L−1). Therefore, this work provides a synergistic strategy to incorporate the properties of mesoporous and densifying, and reveals its electrochemical behavior toward the further application of power‐type supercapacitors.
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