Neoproterozoic Subduction Research Articles

Reassessing early to mid-Neoproterozoic (∼885–720 Ma) tectonic evolution of the southwestern Jiangnan Orogen: A detrital zircon perspective

The Neoproterozoic Jiangnan Orogen (JNO) marks the consolidation of the South China Block, sparking ongoing debates on its early to mid-Neoproterozoic tectonic evolution. In this study, we have gathered detrital zircon data from the southwestern JNO, presenting new detrital zircon U-Pb ages alongside trace element data from the mid-Neoproterozoic Banxi Group and Sinian System within this region. Our objective is to illuminate the early to mid-Neoproterozoic tectonic evolution within the southwestern JNO through a comprehensive detrital zircon analysis. The obtained dating results derived from detrital zircons reveal maximum depositional ages of ∼733 Ma and ∼713 Ma for Mobin Formation (Banxi Group) and Jiangkou Formation (Sinian System) sedimentary rocks, suggesting a proximal source, possibly originating from magmatic rocks within the southwestern JNO. Within the paleo-geographic context, it is plausible that these samples were deposited within the deep-water expanse of the Nanhua Rift Basin. Trace element analysis of detrital zircons within the southwestern JNO highlights distinctive fluctuations, delineating three crucial time points (∼885 Ma, ∼835 Ma, and ∼810 Ma): the beginning of early Neoproterozoic subduction of the South China Ocean towards the Yangtze Block beneath the southwestern JNO, the subduction slab rollback, and the Nanhua rifting initiation. The discernible shifts in detrital zircon age distributions within these sedimentary rocks serve as robust validation for the proposed model and crustal reworking. We then propose that the southwestern JNO was in a lull of magmatism before ∼885 Ma, then transitioned to a convergent setting around 885–835 Ma, subsequently subduction slab rollback after ∼835 Ma. The time of final assembly of the Yangtze and Cathaysia blocks in the southwestern JNO is no later than ∼810 Ma. This transformative period (∼810–720 Ma) witnessed the development of a rift basin concurrently with the accumulation of deep-water deposits within the southwestern JNO.

In situ U-Pb isotopic dating method on titanite, and application to determine REE-Fe-Cu mineralization age of the Sin Quyen deposit, Lao Cai province

Titanite (CaTiSiO5) is an important common accessory mineral in hydrothermal deposits, with appreciable amounts of U and Th incorporated into their structures for age dating. Titanite crystals are usually larger than zircon and monazite and may have zoning in texture and geochemistry which represent different parageneses likely related to multiple hydrothermal or mineralization events. In line with the development of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) that has high sensitivity and spatial resolution, in-situ U-Pb isotopic dating method on titanite has become a powerful tool to investigate the ages of different zones from a mineral. Titanite typically accommodates a significant amount of Rare Earth Elements (REEs) and High Field Strength Elements (HFSEs) and the titanite generated from different origins exhibits distinct trace element geochemistry. Therefore, the trace element geochemistry of titanite can serve as an indicator of its formation environment. Titanite occurred in different mineralization stages of the Sin Quyen deposit, making it a suitable mineral for investigating the timing of mineralization. In this paper, we present the U-Pb age of titanite from different stages of the Sin Quyen deposit used to constrain the timing and origin of such events. The hydrothermal titanites are dated by in situ LA-ICP-MS technique and have U-Pb ages of 873±12 Ma and 844±12 Ma which indicate two mineralization/hydrothermal events at the same time, respectively. These ages from the Sin Quyen deposit are well correlated with regional tectono-thermal events during the long-lived Neoproterozoic subduction in the western Yangtze Block.

Geochronology, geochemistry, and Sr–Nd–C–O isotopic composition of the Qieganbulake carbonatites at the northeastern margin of the Tarim Craton, northwest China

Carbonatites are the predominant source of rare earth element (REE) resources globally, but their origins and petrogenesis remain unclear. Currently, >600 carbonatites have been found worldwide, but only a few (<14%) of these carbonatites contain REE deposits. Some carbonatites are rich in REEs but do not host high-grade REE deposits. The Qieganbulake carbonatites at the northeastern margin of the Tarim Craton, China, are ideal for investigating why some carbonatites do not host REE mineralization. We undertook a detailed petrographic, geochronological, and isotopic study of the Qieganbulake carbonatites. In previous studies, a carbonatite at Qieganbulake was dated to ca. 811 Ma. However, in this study, ages of ca. 926 Ma were obtained for phlogopite and baddeleyite in carbonatite dykes rather than pyroxenites or phlogopitelites-bearing carbonatite complex. Such ages of ca. 926 Ma are consistent with a previously published apatite U–Pb age. 40Ar/39Ar dating of phlogopite yielded a plateau age of 928 ± 17 Ma and secondary ion mass spectrometry U–Pb dating of baddeleyite yielded a concordia age of 926 ± 8 Ma, implying the carbonatite was emplaced at ca. 926 Ma. Laser ablation–inductively coupled plasma–mass spectrometry U–Pb dating of monazite yielded a 206Pb/238U intercept age of 811 ± 27 Ma, indicating that the main REE mineralization stage was coeval with later carbonatite emplacement at ca. 811 Ma. The studied Qieganbulake calcio-carbonatite samples are REE-rich (864–1495 ppm) and consist of calcite (62.18–93.92 vol%), apatite (1.10–24.82 vol%), dolomite (0.37–10.48 vol%), and lesser amounts of phlogopite, olivine, monazite, magnetite, and vermiculite. The calcite, apatite, and monazite (<1 vol%) have REE contents of 757–1111 ppm, 5127–11,556 ppm, and 45.35–59.88 wt%, respectively, and account for the high REE contents of the carbonatites (883–1539 ppm). The small amount of monazite in this carbonatite suggests it is a prospective rather than a confirmed ore deposit. Petrographic studies, oxygen values of 5.74 and 7.51 ‰ and characteristics of trace element for apatites with less monazite around suggest they have magmatic origin with less alteration. The 926 Ma Qieganbulake carbonatite has high Sr isotope ratios (0.70580–0.70639) and negative εNd(t) values (−7.6 to −11.8), indicative of an enriched mantle source. δ13CPDB and δ18OVSMOW values of the carbonatites vary from –3.3‰ to –4.1‰ and 9.7‰ to 12.0‰, respectively, indicative of a contribution from recycled crustal C that was probably derived from a subducted oceanic slab. Above characteristics of carbonatite with ∼926 Ma are different with those of carbonatite occurred at ∼811 Ma, suggesting two carbonatite emplacements in Qieganbulake. Based on our results and the regional geology, we infer that the 926 Ma Qieganbulake carbonatite was derived by partial melting of a subcontinental lithospheric mantle source that had been metasomatized by early Neoproterozoic subduction during circum-Rodinia subduction in the northern Tarim Craton. Early crystallization of apatite sequestered the REEs, resulting in limited REE mineralization. In addition, the limited hydrothermal alteration and ligands available, such as F− and SO42−, hindered REE transportation and precipitation.

Tracing a Neoproterozoic subduction to collision magmatism in the eastern Pernambuco–Alagoas domain, northeastern Brazil

The Pernambuco–Alagoas (PEAL) Domain, southern Borborema Province, northeastern Brazil, bears the most voluminous Cryogenian–Ediacaran granitic rocks in this province, which was formed during the convergence of the São Francisco Craton and the Borborem Province, during the western Gondwana amalgamation. New geochemical and isotopic data along those from the literature, for one of the largest intrusions, the Correntes composite batholith, at the southern part of this domain, indicate that the granitic rocks are intermediate to acid, oxidized, metaluminous to peraluminous, magnesian, and are high-K calc alkalic to shoshonitic with I-type signature. They are enriched in large-ion lithophile elements, exhibit lightly negative Eu in rare-earth element patterns and negative Ta–Nb, P, and Ti anomalies in spidergrams. Average initial 87Sr/86Sr is 0.7055 and rocks present values of whole-rock εNd (0.6 Ga) that fall into two groups. The pre-to syn-collisional, 635–628 Ma plutons present εNd (0.6 Ga) values from +1.3 to −2.5, with Nd model ages varying from 1.29 to 0.92 Ga, while the late-to post-collisional, 602–580 Ma, plutons show more negative values (−8.2 to −9.5), and older Nd model ages from 1.95 to 1.81 Ga. This Nd-isotope pattern is also observed in other plutons of the southern PEAL Domain and indicates a change in the lower crust source rock with time, with larger contributions of crustal components in the late-to post-collisional rocks. The chemical and isotopic characteristics of the studied granitic rocks and other granitic batholiths in the southern PEAL Domain are compatible with modern magmatic arcs of continental active margins. We propose that in earlier stages of convergence, melting has further affected the younger (Stenian –Tonian), likely less refractory rocks associated with abundance of volatiles, whose segregation would have differentiated to form the oldest plutons. Slow cooling allowed the accumulation of heat from mantle-derived magma in the pre-collisional period, which, together with radiogenic heat from thickened crust, led to partial melting of older crustal rocks, and the formation of magmas whose segregation and differentiation of the melt would originate the younger plutons in this part of the PEAL Domain. Older plutons formed during a Cryogenian-Ediacaran flare-up event that occurred in the southern PEAL Domain.

Neoproterozoic tectonic transition from subduction to back-arc extension along the western Yangtze Block, South China: Petrological evidence of Nb-enriched basalts and arc-type intrusive rocks

Identifying the tectonic transition process from persistent slab subduction to back-arc extension is vital for the systematical study of arc magmatic evolution in a temporal perspective. Although Neoproterozoic subduction setting along the western Yangtze Block has been widely documented, the detailed tectonic transition from subduction to back-arc extension was not systematically constrained. The coexistence of Nb-enriched rocks and normal arc-type rocks can generally provide unique insights into back-arc extension background under subduction setting. Herein we therefore present combined data of petrology, mineralogy, zircon U-Pb geochronology, whole-rock major and trace elements, and Sr-Nd isotopes as well as zircon Lu-Hf isotopes for the Neoproterozoic Nb-enriched basalts and arc-type intrusive rocks (i.e., gabbros and diorites) from the Luding area along the western Yangtze Block (South China), to characterize back-arc extension setting of Neoproterozoic continental magmatic arc. Zircon U-Pb ages suggest that the Nb-enriched basalts and arc-type gabbros-diorites formed coevally at ca. 780 Ma. The Nb-enriched basalts have much clinopyroxene phases and display higher TiO2, P2O5, Nb, Nb/La, and Nb/U values than normal arc volcanics. They are weakly enriched in Rb and Ba, and slightly depleted in Nb, Ta, Zr, and Hf, and show decoupled Nd-Hf isotopes with highly positive whole-rocks εNd(t) (+5.79 ∼ +7.39) and relatively low zircon εHf(t) (+1.09 ∼ +9.05) values, indicating an origination of subduction slab melts-metasomatized mantle wedge source, resembling with the genesis of those typical Nb-enriched mafic rocks in a back-arc setting. Compared with Nb-enriched basalts, the arc-type gabbros and diorites contain more hornblende minerals, and are characterized by variably high MgO (3.10–5.71 wt%) contents and Mg# values (51.5–57.2), and enriched LREEs and LILEs (e.g., Rb, Ba, Sr, and K) as well as depleted Nb, Ta, and Ti. Considering their relatively depleted and coupled Nd-Hf isotopes, these arc-type gabbros and diorites were formed by partial melting of hydrous mantle wedge modified by subduction fluids. The co-occurrence of Nb-enriched basalts and arc-type gabbros-diorites studied here therefore reveal Neoproterozoic back-arc extension background under the subduction setting. Combined with ca. 810–780 Ma mafic rocks showing Nb-enriched signatures and ca. 860–740 Ma normal arc-type mafic-intermediate rocks in the western Yangtze Block, we support that Neoproterozoic geodynamic transition from continuing subduction to back-arc extension initially occurred at ca. 820–810 Ma. The Neoproterozoic back-arc extension is thus significant for geochemical changes of subduction-related metasomatized agents and arc magmatic types.

Three-dimensional magnetotelluric imaging of the Eastern Qinhang Belt between the Yangtze Block and Cathaysia Block: Implications for lithospheric architecture and associated metallogenesis

The Eastern Qinhang Belt represents the suture zone between the Yangtze and Cathaysia Blocks and controls the world-class Dexing porphyry copper (Cu) deposits. A three-dimensional three-dimensional structural interpretation based on magnetotelluric array data covering the Eastern Qinhang Belt was determined to provide new information on the lithospheric architecture of this mineral system. The regional electrical structure of the Eastern Qinhang Belt is consistent with the pattern of the Appalachian-style multi-terrane Wilson cycle, with the main electrical gradients corresponding to pre-existing lithospheric faults. It is possible that the central domain between the Huaiyu Terrane and Western Cathaysia Block preserved the slivers of the mafic lower crust generated by the modification of Neoproterozoic subduction. Partial melting of this juvenile mafic lower crust was triggered by the extension from the rollback of the Paleo-Pacific Plate during the Mid-Jurassic. The Northeast Jiangxi Fault represents the conduit for the rise of ore-bearing magmas capable of producing porphyry Cu mineralization.

A linkage between early Silurian Nb-REE enriched alkaline magmatism and Neoproterozoic subduction metasomatized mantle in South Qinling, Central China

A linkage between early Silurian Nb-REE enriched alkaline magmatism and Neoproterozoic subduction metasomatized mantle in South Qinling, Central China

Neoproterozoic (750–711 Ma) Tectonics of the South Qinling Belt, Central China: New Insights from Geochemical, Zircon U‐Pb Geochronological, and Sr‐Nd Isotopic Data from the Niushan Complex

AbstractThe Xiejiaba and Fuqiangbei plutons form part of the newly identified Neoproterozoic Niushan complex, which is located in the southern South Qinling belt (SQB). The plutons are compositionally similar, were emplaced at 750–711 Ma, and provide insights into Neoproterozoic tectonism within the South Qinling belt. The Xiejiaba pluton contains diorite, quartz diorite, granodiorite, and granite phases, all of which are sub‐alkaline and have variable major element compositions with negative correlations between SiO2and MgO, TFe2O3, Al2O3, CaO, TiO2and P2O5. These rocks are enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) and have negative Nb, Ta, P and Ti anomalies, all of which are indicative of arc‐type magmatism. The Fuqiangbei pluton contains granitoids that are compositionally similar to the rocks in the Xiejiaba pluton. Samples from these plutons have similarɛNd(t) values (1.24–5.99) but very variable (87Sr/86Sr)ivalues (0.7010–0.7054). Combining these data with the geochemical data for these rocks suggests that the magmas that formed the Niushan complex were derived from the crust–mantle boundary. This, combined with the results of previous research, suggests that the transition from low pressure‐low temperature to low pressure‐high temperature conditions within a subduction zone caused melting during a period of late subduction and backarc extension. This constrain the timing of subduction within the South Qinling belt and the northern Yangtze Block (YB) to 750–711 Ma, with this Neoproterozoic subduction associated with an ocean to the north overprinting an existing continental rift‐type tectonic setting within the northern margin of the Yangtze Block and the South Qinling belt.

Discovery of a &gt;1,000 km Cambrian Eclogite‐Bearing High‐Pressure Metamorphic Belt in the Central Asian Orogenic Belt: Implications for the Final Closure of the Pan‐Rodinian Ocean

AbstractThe immense Central Asian Orogenic Belt (CAOB) records the transition from the Pan‐Rodinian Mirovoi Ocean to the Paleo‐Asian Ocean, but the final closure of the Mirovoi Ocean remains unexplored. Here we document two new eclogite occurrences, located between CAOB microcontinents and the Ediacaran–Cambrian island arc in Mongolia. Pseudosection modeling and geothermobarometry constrain peak conditions of ∼560°C and ∼2.2 GPa for the Urgamal eclogite and ∼715°C and ∼2.0 GPa for the Tsengel eclogite. Zircon U‐Pb dating results suggest the Urgamal eclogite‐facies metamorphism occurred at ∼522 Ma, and the granite gneiss enclosing the eclogite yielded ∼811 Ma crystallization age and ∼519 Ma metamorphic age. Detrital zircon age spectra of the paragneisses associated with the eclogite suggest a probable provenance from the adjacent Zavkhan microcontinent and the Neoproterozoic arc superimposed on the microcontinent. The Tsengel eclogite has a protolith age of ∼853 Ma and an eclogite‐facies metamorphic age of ∼522 Ma, and the associated migmatite gneiss record a ∼520 Ma migmatization event. The rock associations and geochemical affinities indicate that their protoliths represent mafic rocks formed in a continental rift setting and the Early Neoproterozoic subduction–accretion complex, respectively. Their similar tectonic position and metamorphic age suggest that these rocks are part of a single &gt;1,000 km long Cambrian high‐pressure metamorphic belt. The rocks record closure of the Mirovoi Ocean within the CAOB and constrain this crucial event to ∼520 Ma along the western margin of the microcontinents in Mongolia.

Geochronology and geochemistry of the granitoids in the Diancangshan-Ailaoshan fold belt: Implications on the Neoproterozoic subduction and crustal melting along the southwestern Yangtze Block, South China

The Neoproterozoic magmatic and tectonic history of the South China Craton (SCC) is critical for the reconstruction of Rodinia break-up and subsequent Gondwana assembly. Nonetheless, the tectonic attribution of the Neoproterozoic igneous rocks in the southwestern Yangtze is contentious, and the mechanism for crustal anatexis remains unclear. Here, we report mineralogical, whole-rock geochemical and Sr-Nd isotope data, and zircon U-Pb-Hf-O isotope data from the newly found Neoproterozoic trondhjemites and granites in the Diancangshan-Ailaoshan (DCS-ALS) fold belt along the southwestern Yangtze. Both the trondhjemites (ca. 771–762 Ma) and granites (ca. 767 Ma) have high SiO2 and low MgO contents. The trondhjemites have relatively high CaO, Na2O and Sr contents, but low K2O contents and Rb/Sr ratios, and show positive to slightly negative Eu anomalies and heavy rare earth elements (HREEs) depletions, resulting in high Sr/Y and La/Yb ratios. In contrast, the granites have lower CaO, Na2O, and Sr contents, but higher K2O and Rb/Sr, and display negative Eu anomalies and flat HREEs patterns. The trondhjemites have negative εNd(t) (-4.12 to −3.85), positive to negative εHf(t) (-2.50 to + 5.28) and low δ18O (4.37 ‰–7.27 ‰) values. In comparison, the granites have positive εNd(t) (0.09 to 0.26), εHf(t) (+1.24 to + 9.86) and higher δ18O (6.50 ‰–7.24 ‰) values. The distinct elemental and isotopic compositions between the trondhjemite and granite samples reflect two different types of crustal anataxis within different crustal levels. The trondhjemites were formed by water-fluxed melting of the juvenile mafic lower continental arc crust (with addition of ancient Yangtze basement). The granites were derived from dehydration melting of juvenile felsic middle crust. Our results imply that the trondhjemites and granites were formed in a continental arc setting. The melting processes revealed here should be applicable to decipher the widespread Neoproterozoic crustal melting along the southwestern Yangtze, which was most likely fluid-controlled via subduction-induced asthenosphere upwelling. Combined with available regional geological data, we suggest that a long-lived Neoproterozoic (∼880–730 Ma) subduction zone may have extended from the Panxi-Hanna region in the northern/western Yangtze Block to the DCS-ALS fold belt in the southwestern Yangtze. Thus, the SCC may have located on the northwestern margin of Rodinia.

Late Permian plume and Neoproterozoic subduction-modified mantle interaction: Insights from geochronology and Sr-Nd-O isotopes of mafic dikes of the western Emeishan large igneous province

Geochronological investigations of mafic dikes along the southwestern margin of the Emeishan large igneous province (ELIP) in the South China block display a restricted range of U-Pb zircon, baddeleyite, and apatite isotopic ages ranging from 263 to 257 Ma, which overlaps with that of previously studied ELIP basalts and mafic intrusions. The dikes are divided into high-Ti and low-Ti groups, whereby the latter is further divided into two subgroups (low-Ti group-1 and -2). The high-Ti group rocks (Ti/Y &gt; 500) are characterized by ocean island basalt-like trace element patterns with mantle-like zircon δ¹⁸O of 5.0 ± 0.10‰ and slightly enriched ε_Nd(t) values of −1.0 to +1.0. The low-Ti group-1 rocks (Ti/Y &lt; 500) have trace element patterns similar to those of the high-Ti group, yet generally with weak negative Nb-Ta anomalies, lower (Sm/Yb)_N ratios, elevated zircon δ¹⁸O (6.6 ± 0.33 ‰), and highly variable ε_Nd(t) values (−3.9 to +3.2). The low-Ti group-2 rocks (Ti/Y &lt; 500) are characterized by pronounced negative Nb-Ta anomalies, more negative ε_Nd(t) (−8.4 to −6.6) values, and higher initial ⁸⁷Sr/⁸⁶Sr ratios than those of the other two groups. The compositional variations of the high-Ti group and the low-Ti group-1 rocks, in conjunction with the negative correlation between the ε_Nd(t) values and the (Th/Nb)_N ratios, suggest that the two groups were generated from an isotopically heterogeneous mantle plume at different depths, and experienced varying degrees of crustal contamination (but &lt; 20 wt.%). The high-Ti group rocks are considered to have originated from a deeper garnet-stable source, and the low-Ti group-1 rocks from a shallower source. Mixing calculations indicate that the highly enriched Sr-Nd isotopes of the low-Ti group-2 rocks cannot be explained by crustal contamination. A subduction-modified mantle source is required to account for the arc-like geochemical characteristics of this group. This is consistent with the spatial overlap of the low-Ti group-2 rocks and previously studied geochemically similar samples with rocks from the Neoproterozoic subduction zone along the western margin of the South China block. Furthermore, a fertilized mantle is also consistent with the variable δ¹⁸O values of various mafic-ultramafic rocks of the western and central ELIP due to the involvement of recycled oceanic crustal materials. Our results are in accordance with the model that the western ELIP late Permian magmatism was generated by the interaction of two distinct sources, that is, an isotopically heterogenous mantle plume and a Neoproterozoic subduction-modified, Nd isotope-enriched lithospheric mantle with distinct heterogenous oxygen isotope characteristics.

Metasomatized mantle lithosphere and altered ocean crust as a fluid source for orogenic gold deposits

Whether auriferous hydrothermal fluid is generated during crustal metamorphism or by subcrustal processes to form orogenic gold deposits is hotly debated. Noble gas isotope and halogen abundance ratios can provide important constraints to help resolve this controversy. The Danba gold deposit is a rare example of a Jurassic age hypozonal orogenic gold deposit on the western margin of the Yangtze Craton, China. It is characterized by thick barren quartz veins with fractures infilled by thin auriferous quartz veinlets. The syn-gold quartz veinlets are associated with plagioclase and pyrrhotite and are distinguished from the barren quartz vein hosts on the basis of cathodoluminescence, trace-element content and Raman spectroscopy and microthermometry of fluid inclusions. The dominant fluid inclusions in the gold-bearing quartz and plagioclase are H2O–CH4 with vapor fill of ∼ 15–45 vol% and high pressure-corrected trapping temperatures of ∼ 500 °C, low salinities (<4 wt% NaCl equiv.) and high Mg/Fe ratios. Crushing syn-gold quartz and plagioclase released fluid inclusions with 40Ar/36Ar ratios of between 490 and 710, molar Br/Cl ratios of (0.3–0.7) × 10−3 and molar I/Cl ratios of (18–60) × 10−6. Crushing syn-gold pyrrhotite released fluid inclusions with 3He/4He ratios of 0.21–0.38 Ra (Ra = air value, 1.39 × 10−6) that are higher than typical crustal values of < 0.1 Ra, and 40Ar/36Ar of 330–640 that are similar to the gold-related quartz-hosted inclusions. The combined noble gas and halogen data do not favor an auriferous fluid derived from K- and U-rich Proterozoic granitic basement, which is expected to have radiogenic 40Ar/36Ar and 3He/4He ratios. Instead, the data are more consistent with a fluid source from underlying mantle lithosphere containing a high proportion of altered ocean crust (AOC). The auriferous fluid that formed the Danba gold deposit is thus considered to have been derived from a source comprising both metasomatized mantle lithosphere that had been fertilized in a Neoproterozoic subduction event and a portion of relict AOC beneath the western margin of the Yangtze Craton. In contrast with syn-gold fluid inclusions, those in pre-gold barren quartz are H2O–CO2 dominated. Crushing pre-gold quartz released fluid inclusions with 40Ar/36Ar ratios of 2410–5450, Br/Cl ratios of (1.2–1.5) × 10−3 and I/Cl ratios of (60–80) × 10−6 that are distinctly different to the gold-ore stage. The higher 40Ar/36Ar ratios of the pre-gold fluids are consistent with a source for the barren host quartz veins from prograde greenschist- to amphibolite-facies metamorphism of the Proterozoic granitic basement.

Magnetotelluric signatures of Neoproterozoic subduction, and subsequent lithospheric reactivation and thinning beneath central South China

Broadband and long-period magnetotelluric (MT) soundings were collected along a 600-km-long EW-trending profile across the southwestern segment of the Jiangnan Orogenic Belt (JOB) to explore the possible remnants of ancient tectonic processes beneath the central South China Block (SCB). Beneath the JOB, the resistivity model reveals a west-dipping, trans-lithosphere conductor (<20 Ω ∙ m) embedded within the relatively thick (80–120 km) and highly resistive (>1000 Ω ∙ m) lithosphere, possibly associated with relics of the Neoproterozoic subduction zone between the Yangtze and Cathaysia blocks. The crustal portion of this conductor is interpreted as solid conducting materials (e.g., graphite, sulfide) that were emplaced into the crust during subduction and orogenesis, whereas its lithospheric mantle portion is more likely to be volatile-bearing minerals formed by subduction-related metasomatic processes. We attribute the greatly reduced asthenospheric resistivities (1~10 Ω ∙ m) below the JOB to low-degree melting of the early-formed metasomatized mantle. In contrast, the lithosphere of the Cathaysia Block is evidently thinned (60–100 km) and segmented by several subvertical, lithospheric-scale conductors (1~30 Ω ∙ m) that are likely associated with fossil fluid pathways along reactivated shear/fault zones. Notably, the thinnest lithosphere sits above a prominent low-resistivity (10 ~ 30 Ω ∙ m) anomaly in the asthenospheric mantle and is spatially coincident with the location of Late Jurassic basaltic outcrops. We interpret these features as signs of lithospheric extension and asthenospheric upwelling driven by roll-back of the Paleo-Pacific Plate during the Late Mesozoic. The results provide key constraints on subduction–accretion tectonics associated with the Neoproterozoic assembly of the SCB and the subsequent lithospheric evolution during the Phanerozoic.

The implication of two episodic Precambrian supercontinents convergence events from enriched mantle beneath the Yangtze Block: Constraints from the Zhangbaling mafic rocks

The Yangtze Block bears witness to a prolonged Precambrian evolutionary history and records the assembly of Precambrian supercontinents. Significantly, compared with the widely recognized ancient continental crustal growth and reconstruction, subduction-related mafic magmatism contains detailed possess of crust-mantle interaction in convergent plate boundaries. This paper reports Neoproterozoic mafic igneous rocks, represented by the 808–787 Ma amphibolites, from the Zhangbaling Uplift, northeastern sector of the Yangtze Block. Their prominent arc-affinity trace-element geochemical compositions with high concentration of LILE, the trough of Th, U, Zr and Hf in the spider diagram as well as natural δ18O values (5.3–6.5‰), indicate an interaction between the lithospheric mantle wedge peridotite and slab-derived fluids during early Neoproterozoic subduction event, and deficient in the involvement of felsic melts from crustal materials and sediments. Analyses of radioisotopes for amphibolites yield extremely low zircon εHf(t) (−25.3 to −3.6) and whole-rock εNd(t) (−17.1 to −10.4) values respectively, corresponding to an enriched mantle source. However, in consideration of the fact that the recycled slab-derived fluids is difficult to alter the isotopic composition (especially hafnium) of lithospheric mantle compared with its geochemical characteristics. Meanwhile, on the compilation of all Precambrian subduction-related magmatism in the Yangtze Block, it appears that the enriched isotopic signature in amphibolites is mainly inherited from the Paleoproterozoic (ca. 2.0 Ga) lithospheric mantle beneath the Yangtze Block, and extremely negative εHf(t) values (–25.3 to –18.4) further reflect prominent crust-mantle interaction correspond to the assembly of Columbia supercontinents. Therefore, the Zhangbaling mafic rocks witness the modification of lithospheric mantle by two episodic subduction events during Paleoproterozoic and Neoproterozoic respectively, which provide new evidence for the Yangtze Block to get involved in the reconstruction of Columbia and Rodinia supercontinents.

Intrusive Complexes of the Late Neoproterozoic Island Arc Structure of the Lake Zone (Mongolia): Isotope Systematics and Sources of Melts

Abstract –We present data on the geochemical and Sr–Nd isotope compositions of rocks and on the Lu–Hf isotope composition of magmatic and xenogenic zircons from granitoids and gabbroids of the late Neoproterozoic island arc structure of the Lake Zone. Plagiogranitoids, gabbroids, and quartz diorites (559–542 Ma) formed at the late Neoproterozoic subduction stage of magmatism, and two-feldspathic granites (~483 Ma) mark Cambrian–Ordovician accretion–collision processes. We have established that the volcanic rocks of the late Neoproterozoic island arc and/or its oceanic base, which formed from the depleted mantle, were the mafic source of plagiogranitoids. This is proved by the overlapping positive εNd values of plagiogranitoids and the host volcanic rocks and by the commensurate εHf values of magmatic zircons from the plagiogranitoids and depleted mantle. The lower εNd values of gabbro and quartz diorites from the Tavan Hayrhan and Shuthuyn plutons, the lower εHf values of zircons from these rocks, and the high (87Sr/86Sr)0 ratios and K2O, Rb, and Th contents point to the generation of these rocks from a less depleted mantle source, namely, mantle wedge peridotites. The isotope composition of the latter changed at the previous subduction stage under the impact of fluids and with the contribution of subducted sediments. The least radiogenic Hf isotope composition of magmatic and xenogenic zircons from Ordovician accretion–collisional two-feldspathic granites of the Ih Zamiin pluton suggests their formation through the melting of the late Neoproterozoic–Cambrian island arc crust with the contribution of more differentiated crustal sources enriched in Th, Nb, and LREE and characterized by low εNd values. The age of xenogenic zircons (≤716 Ma) in the studied granitoids and gabbroids and their similarity in Hf isotope composition to magmatic zircons from the same rocks confirm the formation of the late Neoproterozoic island arc of the Lake Zone in an intraoceanic setting far from ancient continental sources similar to the Dzavhan microcontinent.

The Fuchuan Ophiolite in South China: Evidence for Modern‐Style Plate Tectonics During Rodinia Breakup

AbstractSubduction initiation processes, such as those evidenced in the Izu‐Bonin‐Mariana (IBM) forearc crust are a key feature of modern‐style plate tectonics. However, the evidence for this process in the Precambrian is limited, due to the scarcity of ophiolite suites and in particular a lack of typical complete ophiolitic sequences similar to those observed in Phanerozoic ophiolites. Mineral analyses of olivine, orthopyroxene, and chrome spinel from the harzburgite and two types of clinopyroxene from the cumulate gabbro of the Fuchuan ophiolite, South China suggest formation in a Neoproterozoic subduction system similar to the IBM. High temperature (1,000–1,200°C), low pressure along with a high degree of melt extraction (&gt;18%) have been recorded in the harzburgite. This evidence, in conjunction with magma evolution from forearc basalt to boninite to hydrous calc‐alkaline magmatism, recorded in the crustal section of the Fuchuan ophiolite indicates a transition from initial to mature subduction in a forearc setting. Statistical analysis of global ophiolites through time suggests that IBM‐like subduction systems may have successfully operated since at least the latest Neoproterozoic (ca. 1,000 Ma) and be pervasive on Earth from ca. 850 Ma. Additional evidence for Neoproterozoic ophiolites from India, Siberia, and Arabian‐Nubian Shield, which are also similar to the IBM forearc ophiolite, suggests that cold and deep subduction became much more common in the Neoproterozoic (ca. 850 Ma) around the periphery of the Rodinia supercontinent. This IBM‐like subduction system may have acted as the geodynamic trigger for the break‐up of Rodinia.

Early Neoproterozoic tectonic evolution of northern Yangtze Block: Insights from sedimentary sequences from the Dahongshan area

Precambrian sedimentary strata are widely distributed along the periphery of the Yangtze Block. However, the age, provenance and tectonic setting of the sedimentary successions on the northern margin still remain unclear, which exerted considerable influence on the understanding of Precambrian crustal evolution of the Yangtze Block. Here we report integrated detrital zircon U-Pb dates and Lu-Hf isotopes from the Dahongshan area to the northeast of the nuclei (i.e. the Kongling Complex) of the Yangtze Block. The youngest U-Pb dates of 995 Ma and 810 Ma of detrital zircon grains place constraints on the maximum depositional ages of the underlying Dagushi Group and the overlying Huashan Group, respectively. Both groups show pre-Mesoproterozoic age populations at ca. 2050 Ma and ca. 2700 Ma and corresponding εHf(t) values varying from –24.1 to + 2.3, consistent with counterparts of the Kongling Complex and Yangpo Complex in northern Yangtze Block. The εHf(t) values of Neoproterozoic (1000–800 Ma) detrital zircon grains in the Huashan Group show a decrease after ca. 880 Ma (from + 13.5 to –18.5), possibly indicating a transition from arc-continent collision to continental arc setting on the northern margin of the Yangtze Block. In combination with sedimentary characteristics and the new isotopic results, the Dagushi Group probably formed in a shallow marine basin setting and received dominant detritus from the Kongling and Yangpo complexes. In contrast, the Huashan Group received sediments recycled from the underlying Dagushi Group and contemporary igneous rocks in the Dahongshan and Kongling areas. The changes in provenance and tectonic setting recorded in the two sedimentary sequences suggest a tectonic transition from late Mesoproterozoic passive continental margin to Neoproterozoic subduction and accretion in response to the amalgamation of Rodinia supercontinent. On the basis of distinct location and history, Pre-Nanhua Neoproterozoic sedimentary sequences distributed in the periphery of Yangtze Block are dispersed into four separate domains. Through bivariate kernel density estimates and bootstrap resampling method, we have identified that these domains were characterized by asynchronous igneous impulse and heterogeneous character of igneous activity in early Neoproterozoic along with varying degrees of integration of crustal growth and reworking.

Magmatic controls on the mineralization potential of a porphyry Cu system: The case of Jurassic Tongshan skarn Cu deposit in the Qin–Hang Belt, South China

The Qin–Hang suture belt in South China formed during the Neoproterozoic amalgamation between the Cathaysia and Yangtze blocks. There are several Jurassic porphyry–skarn Cu deposits in this region, and the factors controlling the mineralization potential remain unclear. This study reports geochemical data for the Tongshan skarn deposit and zircon trace element data for five porphyry- or skarn-type Cu deposits in this region, in order to identify geochemical indexes for the mineralization potential of the ore-related intrusions. A garnet U–Pb age (170 Ma) for the Tongshan skarn indicates that Cu mineralization occurred in the Middle Jurassic, which is consistent with the zircon U–Pb ages (173 Ma–171 Ma) of the host granodiorite porphyries. Granodiorite porphyry samples from the Tongshan deposit have moderately high SiO2 contents (64.4–65.0 wt%), low MgO contents (1.39–1.47 wt%), and high (La/Yb)N ratios (14.7–16.8), typical of low-Mg adakitic rocks. The whole-rock geochemistry, bulk Earth-like εNd (t) values (–1.5 to –1.6) and positive zircon εHf(t) values (+2.7 to +6.0), corresponding to two-stage Hf model ages of 1014–832 Ma, suggest the porphyries were derived from thickened juvenile lower crust initially generated during Neoproterozoic amalgamation. In addition, the porphyry samples have arc-like geochemical characteristics (Nb–Ta–Ti depletion), low Th/Yb ratios (average = 4.7), high Ba/Th ratios (average = 346), zircon Eu/Eu* values (average = 0.71) and 10000×(Eu/Eu*)/Y values (average = 6.80), and moderate zircon Ce/Ce* values (average = 705) and Ce/Nd ratios (average = 17.1). These features demonstrate that the parental magmas of the porphyries were formed by melting of a mantle wedge.That had been metasomatized by moderately oxidized slab-derived fluid near a Neoproterozoic subduction zone. Previous studies suggest porphyries from large to giant deposit (e.g., Dexing and Yinshan) have similar two-stage Hf model ages and were derived from Neoproterozoic juvenile crust. But these porphyries have higher whole–rock Th/Yb ratios and zircon Ce/Ce* and Ce/Nd values than those of intrusions from medium-sized deposits (e.g., Tongshan, Chuankeng and Jiande). This indicates that the magma source of the former may have been distant from the trench in the Neoproterozoic, and formed by melting of a mantle wedge that had been metasomatized by highly oxidized slab-derived melt. Our results and previously published data indicate that the Neoproterozoic two-stage Hf model ages of the intrusions are positive indicators of Jurassic Cu mineralization, and granitoids with relatively high Th/Yb ratios and zircon Ce/Ce* and Ce/Nd values likely have more potential to form large to giant Cu deposits.

New identification and significance of Early Cretaceous mafic rocks in the interior South China Block

Early Cretaceous mafic rocks are first reported in the northern Guangxi region from the western Qin-Hang belt in the interior South China Block. A systematic investigation of zircon U–Pb dating, whole-rock geochemistry, Sm–Nd isotopes and zircon Hf–O isotopes for these mafic rocks reveals their petrogenesis and the mantle composition as well as a new window to reconstruct lithospheric evolution in interior South China Block during Late Mesozoic. Zircon U–Pb dating yielded ages of 131 ± 2 Ma to 136 ± 2 Ma for diabase and gabbro from Baotan area, indicating the first data for Early Cretaceous mafic magmatism in the western Qing-Hang belt. These mafic rocks show calc-alkaline compositions, arc-like trace element distribution patterns, low zircon εHf(t) of − 9.45 to − 6.17 and high δ18O values of + 5.72 to + 8.09‰, as well as low whole-rock εNd(t) values of − 14.27 to − 9.53. These data suggest that the studied mafic rocks are derived from an ancient lithospheric mantle source that was metasomatized during Neoproterozoic subduction. Thus, the occurrence of these mafic rocks indicates a reactivation of Neoproterozoic subducted materials during an extension setting at Late Mesozoic in the western Qin-Hang belt, an old suture zone that amalgamates the Yangtze and Cathaysia blocks.

Desiccation drives the growth of crystalline graphite in the cold mantle wedge: Evidence from the Achankovil Suture Zone, southern India

Carbon is constantly released from subducting slabs back to the atmosphere in the form of gases such as CO2 and CH4. This constitutes a source of greenhouse gases that can regulate atmospheric chemistry over geological timescales. However, the carbon carried by hydrothermal fluids released from slabs may be locked along their ascending paths for variably long periods of time. The processes involved in this chromatographic pathway remain unclear. Here we report the co‐occurrence of graphite and phlogopite in highly metasomatized rocks derived from the mantle wedge of a Late Neoproterozoic subduction zone in the Achankovil Suture Zone in southern India. Petrographic, isotopic, and fluid inclusion evidence suggests these rocks formed in an environment soaked in C‐bearing fluids derived from the subducting slabs. We propose that desiccation of slab‐derived fluids in contact with a dry mantle wedge is the main driver for this phenomenon, while redox change only plays a marginal role. Our work provides a perspective on the diversity of non‐traditional carbon graphitization pathways in the lithosphere. It shows that refractory forms of elemental carbon of abiotic origin may be ubiquitous in the cold mantle wedge.