Geochronology, geochemistry, and Sr–Nd–C–O isotopic composition of the Qieganbulake carbonatites at the northeastern margin of the Tarim Craton, northwest China

Abstract

Carbonatites are the predominant source of rare earth element (REE) resources globally, but their origins and petrogenesis remain unclear. Currently, >600 carbonatites have been found worldwide, but only a few (<14%) of these carbonatites contain REE deposits. Some carbonatites are rich in REEs but do not host high-grade REE deposits. The Qieganbulake carbonatites at the northeastern margin of the Tarim Craton, China, are ideal for investigating why some carbonatites do not host REE mineralization. We undertook a detailed petrographic, geochronological, and isotopic study of the Qieganbulake carbonatites. In previous studies, a carbonatite at Qieganbulake was dated to ca. 811 Ma. However, in this study, ages of ca. 926 Ma were obtained for phlogopite and baddeleyite in carbonatite dykes rather than pyroxenites or phlogopitelites-bearing carbonatite complex. Such ages of ca. 926 Ma are consistent with a previously published apatite U–Pb age. 40Ar/39Ar dating of phlogopite yielded a plateau age of 928 ± 17 Ma and secondary ion mass spectrometry U–Pb dating of baddeleyite yielded a concordia age of 926 ± 8 Ma, implying the carbonatite was emplaced at ca. 926 Ma. Laser ablation–inductively coupled plasma–mass spectrometry U–Pb dating of monazite yielded a 206Pb/238U intercept age of 811 ± 27 Ma, indicating that the main REE mineralization stage was coeval with later carbonatite emplacement at ca. 811 Ma. The studied Qieganbulake calcio-carbonatite samples are REE-rich (864–1495 ppm) and consist of calcite (62.18–93.92 vol%), apatite (1.10–24.82 vol%), dolomite (0.37–10.48 vol%), and lesser amounts of phlogopite, olivine, monazite, magnetite, and vermiculite. The calcite, apatite, and monazite (<1 vol%) have REE contents of 757–1111 ppm, 5127–11,556 ppm, and 45.35–59.88 wt%, respectively, and account for the high REE contents of the carbonatites (883–1539 ppm). The small amount of monazite in this carbonatite suggests it is a prospective rather than a confirmed ore deposit. Petrographic studies, oxygen values of 5.74 and 7.51 ‰ and characteristics of trace element for apatites with less monazite around suggest they have magmatic origin with less alteration. The 926 Ma Qieganbulake carbonatite has high Sr isotope ratios (0.70580–0.70639) and negative εNd(t) values (−7.6 to −11.8), indicative of an enriched mantle source. δ13CPDB and δ18OVSMOW values of the carbonatites vary from –3.3‰ to –4.1‰ and 9.7‰ to 12.0‰, respectively, indicative of a contribution from recycled crustal C that was probably derived from a subducted oceanic slab. Above characteristics of carbonatite with ∼926 Ma are different with those of carbonatite occurred at ∼811 Ma, suggesting two carbonatite emplacements in Qieganbulake. Based on our results and the regional geology, we infer that the 926 Ma Qieganbulake carbonatite was derived by partial melting of a subcontinental lithospheric mantle source that had been metasomatized by early Neoproterozoic subduction during circum-Rodinia subduction in the northern Tarim Craton. Early crystallization of apatite sequestered the REEs, resulting in limited REE mineralization. In addition, the limited hydrothermal alteration and ligands available, such as F− and SO42−, hindered REE transportation and precipitation.