Neodymium Isotope Research Articles

Lithopetrographic and geochemical features of the Saalian tills in the Szczerców outcrop (Poland) in various deformation settings

Abstract This paper presents the results of new studies of Saalian tills, from the Ławki and Rogowiec formations, filling the Kleszczów Graben. The study area is located in the Szczerców outcrop, Bełchatów Lignite Opencast Mine, central Poland. Laboratory studies included macrofossil analysis of the deposits, as well as petrographic and geochemical (neodymium isotope ratio) measurements. The studies were carried out in 2014–2016 and resulted in both establishing the sedimentary Saalian complex and constructing geological cross-sections and a synthetic lithostratigraphic profile. Development of sediments in this part of the Kleszczów Graben in the Pleistocene was largely influenced by tectonic factors (Chabielice fault, Dębina Salt Dome) and glacitectonic processes (Wartanian Glaciation). The Saalian tills (T4 – Ławki and T7 – Rogowiec lithotypes) are between the Holsteinian sand with macroremnants of trees and the Eemian gyttja and peat. Petrographic coefficients for lithotype T4 (Ławki Formation) are 1.33–1.06–1.01 and 0.12 and for lithotype T7 (Rogowiec Formation) are 1.29–1.23–1.04 and 0.12. Investigations of the Nd isotopic compositions of the studied samples reinforce our interpretations of till deformation and tentative lithostratigraphic correlations. Neodymium isotope ratios “P” (−14.4 ± 0.7) and “D” (−12.4 ± 0.3) ε Nd values (2σ) correspond to mean signatures of Saalian glacigenic moraine sediment. This proves that ε Nd values less than −12.4 reflect the southern Fennoscandian Ice Sheet sediment provenance, but ε Nd values greater than −12.4 indicate the western European origin.

Neodymium Isotope Geochemistry of a Subterranean Estuary

Neodymium Isotope Geochemistry of a Subterranean Estuary

Paleoenvironmental implications of Sr and Nd isotopes variability over the past 48 ka from the southern Sea of Japan

Millennial scale variations of terrigenous provenance in marine realm are closely related to regional environment and climate changes. Therefore, a wealth of information of past environment and climate can be constrained via fingerprinting sediment provenance. The Sea of Japan is a unique marginal sea in the North Pacific due to its high sill and distinct thermohaline circulation. The modern hydrography in the Sea of Japan is mainly affected by the East Asian Monsoon and Tsushima Warm Current, one branch of the Kuroshio Current. The Sea of Japan communicates with neighboring seas through four shallow and narrow straits, indicating great effects of global eustatic sea level change on its environment over glacial-interglacial cycles. Here we examine the terrigenous provenance in fine-grained fraction (<63 μm) of core KCES1, located near one end of the Tsushima Strait of the Sea of Japan over the last 48 ka, using radiogenic isotopes of strontium (Sr) and neodymium (Nd). Our data suggest that the terrigenous provenance in core KCES1 was mainly derived from the Yangtze River after 7 ka and a mixture of Yangtze and Yellow Rivers during the last glacial and deglacial periods. Notably, pronounced negative excursions of εNd values at HS1 were attributed to minor additions of unradiogenic Nd contribution from China-Korea cratonic hinterland. A binary mixing model further reveals that >85% terrigenous material is derived from the Yangtze and Yellow Rivers over the last 48 ka. Moreover, abrupt variations in sediment provenance occurred at ~18 ka and ~ 7 ka, which coincide with variations in oceanic surface circulation and deep ventilation recorded in the Sea of Japan. We suggest that paleo-Tsushima Warm Current invaded into the Sea of Japan with reopening of the Tsushima Strait at HS1 and the Tsushima Warm Current substantially entered the Sea of Japan after 7 ka due to intensified Kuroshio Current and rising eustatic sea level. The inflow of Tsushima Warm Current gives rise to a range of changes in surface hydrography, deep ventilation, ecological communities and productivity and sediment texture. The combination of fluxes of paleo-rivers and the intensity of Kuroshio Current, which are closely tied to the eustatic sea level and the East Asian Monsoon, plays a key role in controlling the variations in sediment provenance in the Ulleung Basin. Our study provides unique insight into the tight coupling between changes in sediment provenance and oceanic environment over the last 48 ka in the Sea of Japan.

Neodymium isotope composition of Palaeoproterozoic Birimian shales from the Wa‐Lawra Belt, north‐west Ghana: Constraints on provenance

An Nd‐isotopic study was carried out on Palaeoproterozoic Birimian shales from the Wa‐Lawra volcanic belt, located in the southeastern margin of the West African Craton. The objective of this study was to assess the nature and average crustal residence ages of the source areas, and deduce the provenance of these shales. Nd‐model ages range from 2.12 to 2.58 Ga, which are within the range of Nd‐model ages reported for the Birimian volcanic rocks, suggesting that the Birimian volcanic rocks are the main sources of detritus for the Birimian shales. The εNd values of the Birimian shales, calculated at an age of 2.1 Ga, which represents the time of the deposition of the Birimian shales, ranges from −1.65 to +3.01. The range of observed εNd values (i.e., −1.65 to +3.01) suggest that the Birimian shales were predominantly derived from the juvenile Palaeoproterozoic crust, with minor contribution of older crustal material. εNd(T) versus Th/Sc, and ƒSm/Nd versus εNd(T) systematics indicate that the provenance can be explained by mixing between Palaeoproterozoic volcanic arc rocks and variable amounts of Archean continental crustal rocks. Provenance modelling shows that the Birimian shales received at least 80% detritus from a juvenile Birimian volcanic arc. The mean Archean component is 8%, suggesting that the continental crust of the Wa‐Lawra Belt is clearly dominated by material derived directly from the mantle.

Variations in deep water masses along the western margin of South Africa, spanning the last two glacial terminations

The neodymium isotope composition (εNd) of planktic foraminifera and the relative abundances and δ13C of the benthic foraminiferal species C. wuellerstorfi from two gravity cores, retrieved from the western margin of South Africa, provide a late Quaternary (MIS 6 to MIS 1) record of the variations in North Atlantic Deep Water (NADW) and Southern Component Water (SCW). The εNd records from cores at water depths of 3522 m and 3631 m reveal a strong influence of SCW (Lower Circumpolar Deep Water (LCDW) and Antarctic Bottom Water (AABW)) during the peak glacial periods of MIS 6 (εNd = −8.75 to −7.35) and MIS 2 (εNd = −8.44 to −7.27). The strength of the SCW influence decreases while that of the NADW increases during glacial terminations (GT) II (εNd = −10.61 to −9.99) and GT I (εNd = −10.75 to −9.67). More radiogenic εNd values along the flow path of NADW are interpreted to indicate the weakening of NADW penetration southward, as a result of decreasing deep water formation in the North Atlantic during peak glacial periods. The relative abundance and δ13C of C. wuellerstorfi are greater during glacial terminations and interglacials than during peak glacial periods, which is consistent with the less radiogenic εNd values following GT II and GT I. These results suggest that C. wuellerstorfi abundances can be a useful indicator of deep water masses when combined with εNd and δ13C records.

Nd isotope record of ocean closure archived in limestones of the Devonian–Carboniferous carbonate platform, Greater Karatau, southern Kazakhstan

The neodymium isotope composition of micritic limestones from the Devonian–Carboniferous carbonate platform of the Greater Karatau (southern Kazakhstan) was investigated to test the ability of calcite micrite to archive Nd isotope signatures of seawater. The carbonate fraction that displays seawater-like rare earth element (REE + Y) signatures is often more radiogenic than the dispersed terrigenous material in the samples. Hence, its Nd isotope composition is interpreted to correspond to the seawater from which the micrite was precipitated. The seawater on the Karatau platform exhibited an extremely wide range of ε Nd (t) values from –9.3 to +4.3 (the most radiogenic value measured for past seawater to date) and very uniform Sm/Nd ratios, from 0.19 to 0.22, lying within the range characteristic for modern oceanic water. The temporal trend in ε Nd (t) values is interpreted to document the final closure of the Uralian–Turkestan Ocean. It shows that the subduction along Kazakhstan's active margin had already started at the beginning of the Tournaisian ( c . 355 Ma), at least 23 Myr earlier than previously thought. The application of Nd isotope time series on biostratigraphically dated carbonates opens a new direction for geotectonic studies. This approach has the potential to provide useful constraints for the precise dating of the duration of geotectonic and volcanic events. Supplementary material: Nd isotope and REE concentration data, summary of stratigraphic and lithological data, field photographs and additional geochemical plots are available at: https://doi.org/10.6084/m9.figshare.c.5110163

Study of giant dipole resonances for neodymium isotopes with an exciton model

The partial photonuclear [Formula: see text], pn) and [Formula: see text] and the total photonuclear cross-sections (the giant dipole resonance (GDR)) have been investigated theoretically for neodymium isotopes, namely [Formula: see text]Nd, using framework of the EMPIRE 3.2.2 code. The energy, width and cross-section parameters of the GDR used in our calculations have been investigated in this paper depending on the deformation parameters of nuclei. The calculated results have been compared with the experimental data and with those calculated using Lorentzian fitting parameters. Our calculations show a good agreement for all isotopes under study and give better results than the results calculated with Lorentzian parameters. Furthermore, the neutron number dependence of the total and partial photonuclear cross-sections has also been discussed. The results appear that the EMPIRE code used is a perfect tool for reproducing the splitting in the GDR for deformed [Formula: see text]Nd isotope in two distinct dipole modes which are perfectly consistent with the experimental results. It has also been shown that the present parameters are suitable parameters for reproducing the GDR for spherical, or nearly spherical, and the deformed ([Formula: see text]Nd) neodymium isotopes. The parameters have been indicating the small deformation in [Formula: see text]Nd, which cannot be shown by the Lorentzian fitting parameters.

Intermediate and deep ocean current circulation in the Mozambique Channel: New insights from ferromanganese crust Nd isotopes

The Mozambique Channel plays a key role in the exchange of water masses between the Indian and Atlantic Oceans, which include the North Atlantic Deep Water (NADW) inflow from the south and the North Indian Deep Water (NIDW), an aged form of the NADW spreading poleward from the northern and equatorial Indian Ocean basin. Several authors assume that the Davie Ridge acts as a topographic barrier to the northward advection of NADW, which would therefore be absent in the Comoros Basin. Other studies suggest that the NADW flows from the south of the Mozambique Channel to the Comoros Basin, indicating that the Davie Ridge may not currently constitute a blocking topographic barrier to deep water mass circulation. To address this question, we studied ferromanganese (Fe, Mn) crusts collected over 2000 km in the Mozambique Channel, from the Agulhas Plateau to the Glorieuses Islands. Neodymium (Nd) isotope compositions (εNd) of surface scrapings range between εNd = −10.1 above the Agulhas Plateau, which might reflect the NADW inflow, and more radiogenic values between εNd = −8.0 and −8.2 in the Glorieuses area, highlighting the NIDW influence. However, value of εNd = −9.4 measured north of the Davie Ridge cannot be explained by the sole influence of the NIDW and therefore highlights the advection of the NADW northeast of the Comoros Basin. We estimate that the contribution of the NADW through the channel is up to 68% in the Agulhas Plateau and 60% north of the Davie Ridge. These findings are consistent with previous hydrographic studies and suggest that the Davie Ridge does not currently act as topographic barrier to deep currents.

Rare earth element and neodymium isotope tracing of sedimentary rock weathering

Chemical weathering plays an important role in sequestering atmospheric CO2, but its potential influence on global climate over geological timescales remains debated. To some extent, this uncertainty arises from the difficulty in separating the respective contribution of sedimentary and crystalline silicate rocks to past weathering rates in the geological record; two types of rocks having presumably different impact on the long-term carbon cycle. In this study, we investigate the use of rare earth element (REE) and neodymium isotopes (εNd) in leached iron oxide fractions of river sediments for tracing the origin of weathered rocks on continents. A new index, called ‘concavity index’ (CI), is defined for measuring the degree of mid-REE enrichment in geological samples, which enables the determination of the source of iron oxides in sediments, such as seawater-derived Fe-oxyhydroxide phases, ancient marine Fe oxides derived from the erosion of sedimentary rocks, and recent secondary oxides formed in soils via alteration of crystalline silicate rocks or pyrite oxidation. Using this index, we demonstrate that the εNd difference between paired Fe-oxide and detrital fractions in river sediments (defined here as ∆εNd Feox-Det) directly reflects the relative contribution of sedimentary versus crystalline silicate rocks during weathering. While rivers draining old cratons and volcanic provinces display near-zero ∆εNd Feox-Det values indicative of dominant silicate weathering (0.5 ± 1.1; n = 30), multi-lithological catchments hosting sedimentary formations yield systematically higher values (2.7 ± 1.2; n = 44), showing that sedimentary rock weathering can be traced by the occurrence of riverine Fe oxides having more radiogenic Nd isotope signatures compared to detrital fractions. This assumption is reinforced by the evidence that calculated ∆εNd Feox-Det values agree well with previous estimates for carbonate and silicate weathering rates in large river basins.Examining the influence of climate and tectonics on measured Nd isotopic compositions, we find that ∆εNd Feox-Det is strongly dependent on temperature in lowlands, following an Arrhenius-like relationship that reflects enhanced alteration of silicate rocks and formation of secondary Fe oxides in warmer climates. In contrast, in high-elevation catchments, ∆εNd Feox-Det defines striking correlation with maximum basin elevation, which we also interpret as reflecting the intensification of silicate weathering and associated Fe oxide formation as elevation decreases, due to the combined effects of thicker soils and warmer temperature.Overall, our new findings are consistent with previous assertions that the alteration of sedimentary rocks prevails in high-elevation environments, while silicate weathering dominates in floodplains. This novel approach combining REE and Nd isotopes opens new perspectives for disentangling the weathering signals of sedimentary and crystalline silicate rocks in the geologic record, which could be used in future studies to reassess the causal relationships between mountain uplift, erosion and climate throughout Earth's history.

Last glacial atmospheric CO2 decline due to widespread Pacific deep-water expansion

Ocean circulation critically affects the global climate and atmospheric carbon dioxide through redistribution of heat and carbon in the Earth system. Despite intensive research, the nature of past ocean circulation changes remains elusive. Here we present deep-water carbonate ion concentration reconstructions for widely distributed locations in the Atlantic Ocean, where low carbonate ion concentrations indicate carbon-rich waters. These data show a low-carbonate-ion water mass that extended northward up to about 20° S in the South Atlantic at 3–4 km depth during the Last Glacial Maximum. In combination with radiocarbon ages, neodymium isotopes and carbon isotopes, we conclude that this low-carbonate-ion signal reflects a widespread expansion of carbon-rich Pacific deep waters into the South Atlantic, revealing a glacial deep Atlantic circulation scheme different than commonly considered. Comparison of high-resolution carbonate ion records from different water depths in the South Atlantic indicates that this Pacific deep-water expansion developed from approximately 38,000 to 28,000 years ago. We infer that its associated carbon sequestration may have contributed critically to the contemporaneous decline in atmospheric carbon dioxide, thereby helping to initiate the glacial maximum.

Particle–Seawater Interaction of Neodymium in the North Atlantic

Dissolved neodymium (Nd) isotopes (expressed as εNd) have been widely used as a water mass tracer in paleoceanography. However, one aspect of the modern biogeochemical cycle of Nd that has been sparsely investigated is the interplay between dissolved and particulate phases in seawater. We here present the first regional data set on particulate Nd isotope compositions (εNdp) and concentrations ([Nd]p) from five stations in the western North Atlantic Ocean along the GEOTRACES GA02 transect, in conjunction with previously published dissolved Nd isotope compositions (εNdd) and concentrations ([Nd]d)1. Key observations and interpretations from our new particulate data set include the following: (1) Low fractional contributions of [Nd]p to the total Nd inventory per volume unit of seawater (∼5%), with significant increases of up to 45% in benthic boundary layers. (2) Increasing Nd concentrations in suspended particulate matter ([Nd]SPM) and fractions of lithogenic material with water depth, suggesting the removal of Nd poor phases. (3) Different provenances of particulates in the subpolar and subtropical gyres as evidenced by their Nd isotope fingerprints reaching from εNdp ≈ −20 near the Labrador Basin (old continental crust), over εNdp ≈ −4 between Iceland and Greenland (young mafic provenance), to values of εNdp ≈ −13 in the subtropics (similar to African dust signal). (4) Vertical heterogeneity of εNdp as well as large deviations from ambient seawater values in the subpolar gyre indicate advection of lithogenic particles in this area. (5) Vertically homogeneous εNdp values in the subtropical gyre, indistinguishable from εNdd values, are indicative of predominance of vertical particulate supply. The process of reversible scavenging only seems to influence particulate signatures below 3 km. Overall, we do not find evidence on enhanced particle dissolution, often invoked to explain the observed increase in dissolved Nd in the North Atlantic.

\u2018Alexandrian\u2019 glass confirmed by hafnium isotopes

Archaeological glass contains information about the movement of goods and ancient economies, yet our understanding of critical aspects of the ancient glass industry is fragmentary. During Roman times, distinct glass types produced in coastal regions of Egypt and the Levant used evaporitic soda (natron) mixed with Nile-derived sands. In the Levant, furnaces for producing colourless Roman glass by addition of manganese have been uncovered, whereas the source of the desirable antimony-decolourised Roman glass remains an enigma. In the Edict of Diocletian, this colourless glass is listed as “Alexandrian” referring to Egypt, but its origin has been ambiguous. Previous studies have found overlapping strontium and neodymium isotope ratios for Levantine and Egyptian glass. Here, we confirm these findings and show for the first time, based on glasses from the ancient city of Gerasa, that hafnium (Hf) isotopes are different in Egyptian and Levantine natron glasses, and that Sb Roman glass is Egyptian. Our work illustrates the value of Hf isotopes in provenancing archaeological glass. We attribute the striking difference in Hf isotopes of Egyptian versus Levantine glasses to sorting of zircons in Nile sediments during longshore drift and aeolian transport along the south-eastern Mediterranean coast leaving behind a less juvenile fraction.

Evolution of the Global Overturning Circulation since the Last Glacial Maximum based on marine authigenic neodymium isotopes

The Global Overturning Circulation is linked to climate change on glacial-interglacial and multi-millennial timescales. The understanding of past climate-circulation links remains hindered by apparent conflicts among proxy measures of circulation. Here we reconstruct circulation changes since the Last Glacial Maximum (LGM) based on a global synthesis of authigenic neodymium isotope records (εNd). We propose the bottom-up framework of interpreting seawater and authigenic εNd considering not only conservative watermass mixing, but also the preformed properties and the non-conservative behavior of εNd, both subject to sedimentary influences. We extract the major spatial-temporal modes of authigenic εNd using Principal Component Analysis, and make a first-order circulation reconstruction with budget-constrained box model simulations. We show that during the LGM, the source region of North Atlantic overturning shifted southward, which led to more radiogenic preformed εNd of glacial Northern Source Water (NSW). Considering this preformed effect, we infer that glacial deep Atlantic had a similar proportion of NSW as today, although the overall strength of glacial circulation appears reduced from both North Atlantic and Southern Ocean sources, which increased the relative importance of non-conservative behavior of εNd and may have facilitated accumulation of respired carbon in the deep ocean. During the deglaciation, we find that Southern Ocean overturning increased, which offset suppressed North Atlantic overturning and resulted in a net stronger global abyssal circulation. Faster global scale deglacial circulation reduced the relative importance of non-conservative effects, resulting in Atlantic-Pacific convergence of abyssal εNd signatures. Variations of Southern Ocean overturning likely drove a significant fraction of deglacial changes in atmospheric CO2 and oceanic heat budget.

Sea-ice control on deglacial lower cell circulation changes recorded by Drake Passage deep-sea corals

The sequence of deep ocean circulation changes between the Last Glacial Maximum and the Holocene provides important insights for understanding deglacial climate change and the role of the deep ocean in the global carbon cycle. Although it is known that significant amounts of carbon were sequestered in a deep overturning cell during glacial periods and released during deglaciation, the driving mechanisms for these changes remain unresolved. Southern Ocean sea-ice has recently been proposed to play a critical role in setting the global deep ocean stratification and circulation, and hence carbon storage, but testing such conceptual and modelling studies requires data constraining past circulation changes. To this end, we present the first deglacial dataset of neodymium (Nd) isotopes measured on absolute-dated deep-sea corals from modern Lower Circumpolar Deep Water depths in the Drake Passage. Our record demonstrates deglacial variability of 2.5 εNd units, with radiogenic values of up to εNd=−5.9 during the Last Glacial Maximum providing evidence for a stratified glacial circulation mode with restricted incorporation of Nd from North Atlantic Deep Water in the lower cell. During the deglaciation, a renewed Atlantic influence in the deep Southern Ocean is recorded early in Heinrich Stadial 1, coincident with Antarctic sea-ice retreat, and is followed by a brief return to more Pacific-like values during the Antarctic Cold Reversal. These changes demonstrate a strong influence of Southern Ocean processes in setting deep ocean circulation and support the proposed sea-ice control on deep ocean structure. Furthermore, by constraining the Nd isotopic composition of Lower Circumpolar Deep Water in the Southern Ocean, our new data are important for interpreting deglacial circulation changes in other ocean basins and support a spatially asynchronous return of North Atlantic Deep Water to the deep southeast and southwest Atlantic Ocean.

Water mass mixing versus local weathering inputs along the Bay of Biscay: Evidence from dissolved hafnium and neodymium isotopes

We present dissolved neodymium and hafnium concentrations and isotope compositions of surface and deep-water masses from the Bay of Biscay. Neodymium isotope signatures in surface waters of the Bay of Biscay are mostly dominated by local weathering inputs from the surrounding continental margin. Subsurface Eastern North Atlantic Central Water (ENACW) shows a distinct Nd isotope signature (εNd ≅ −12) at the southwestern-most station and is significantly diluted by mixing with more radiogenic waters or shifted by inputs of relatively radiogenic particulate Nd on its way north along the European margin. Furthermore, the Nd isotope data clearly show a declining fraction of Mediterranean Sea Water (MSW) at intermediate depths on its way north indicating that only 40% to 60% of MSW still present in the mixture at the Galician margin arrive at the stations further north in the Bay of Biscay. An interannual variability of the flow path of MSW is identified when comparing the results of the Nd isotope compositions and salinity data of this study with those of earlier studies from the area.In agreement with Nd isotope and concentration analyses the Hf isotope composition of MSW is set by large-scale inputs of terrigenous material into the Mediterranean as can be deduced from elevated Hf concentrations still observable at the Galician margin. Hf isotope signatures of all water masses of the Bay of Biscay, moreover, are overprinted by local weathering inputs and do not reflect water mass mixing. However, combined dissolved Nd and Hf isotopes serve as indicators of local weathering influences on signatures expected from long distance water mass mixing.

Reconstruction of Ocean Circulation Based on Neodymium Isotopic Composition: Potential Limitations and Application to the Mid-Pleistocene Transition

Reconstruction of Ocean Circulation Based on Neodymium Isotopic Composition: Potential Limitations and Application to the Mid-Pleistocene Transition

Northern-sourced water dominated the Atlantic Ocean during the Last Glacial Maximum

Abstract Increased carbon sequestration in the ocean subsurface is commonly assumed to have been one of the main causes responsible for lower glacial atmospheric CO2 concentrations. Remineralized carbon must have been stored away from the atmosphere for thousands of years, yet the water mass structure accommodating such increased carbon storage continues to be debated. Here, we present new sediment-derived bottom-water neodymium isotope records that allow fingerprinting of water masses and provide a more complete picture of the Atlantic Meridional Overturning Circulation geometry during the Last Glacial Maximum. These results suggest that the vertical and meridional structure of the Atlantic water mass distribution only experienced minor changes since the last ice age. In particular, we find no compelling evidence supporting glacial southern-sourced water substantially expanding to shallower depths and farther into the Northern Hemisphere than today, which had been previously inferred from stable carbon isotope (δ13C) reconstructions. We argue that depleted δ13C values observed in the deep Northwest Atlantic do not necessarily indicate the presence of southern-sourced water. Instead, these values may represent a northern-sourced water mass with lower than modern preformed δ13C values that were further modified downstream by increased sequestration of remineralized carbon, facilitated by a more sluggish glacial deep circulation, corroborating previous evidence.

Neodymium isotope constraints on chemical weathering and past glacial activity in Svalbard

Neodymium (Nd) isotopes in leached authigenic components of marine sediments have been increasingly used as a tracer of past ocean-water masses. Despite the general assumption that the Nd isotopic composition of solutes released during chemical weathering fingerprints the source rocks on continents, preferential dissolution of easily dissolvable phases may result in significant deviations in Nd isotopic composition between the solutes and the source rocks, with potential implications for the utility of Nd isotopes in paleoenvironmental studies. Here, we present the Nd isotopic compositions of leached and detrital fractions separated from bedrock and marine sediment samples from the Svalbard archipelago. Our goal is to further understand the behaviour of Nd isotopes during chemical weathering in glacial catchments and evaluate how glacier fluctuations and associated weathering congruency may have affected the export of dissolved Nd isotope signatures to seawater.Our results confirm that terrestrial weathering on Svalbard causes considerable Nd isotopic decoupling between the leached and detrital fractions of fjord sediments (△εNd), resulting from the preferential dissolution of marine precipitates in glaciated catchments dominated by sedimentary rocks. We also show that the degree of Nd isotopic decoupling has fluctuated in response to climate variability on Svalbard during the Holocene, which is also as suggested by the occurrence of generally higher △εNd values during periods of glacier advances in sediment cores retrieved from two different fjords (Dicksonfjorden and Woodfjorden). We posit that the high △εNd values can be ascribed to incongruent chemical weathering of fresh rock flour produced by glacial abrasion. This finding suggests that the degree of Nd isotopic decoupling could be used as a new proxy for tracing glacial fluctuations and associated glacier-derived nutrient inputs to the marine realm.

Clay-fraction strontium and neodymium isotopes in the Indus Fan: implications for sediment transport and provenance

AbstractReconstructing the provenance of siliciclastic marine sediment is important for understanding sediment pathways and constraining palaeoclimate and erosion records. However, physical fractionation of different size fractions can occur during sediment transport, potentially biasing records derived from bulk sediment. In this study, records of radiogenic Sr and Nd isotopic composition and K/Al ratio of the separated clay fraction, as well as bulk grain size, are presented, measured from deep-sea sediments recovered from International Ocean Discovery Program (IODP) Sites U1456 and U1457 in the Arabian Sea. These new records are compared with published bulk sediment records to investigate the influence of sediment transport on these proxies and to constrain provenance evolution and its relationship to climate variability since middle Miocene time. Correlations between grain size and the bulk sediment isotopic composition confirm that transport processes are influencing the bulk sediment record. This relationship, although present, is not as strong in the clay-fraction isotopic records. Heterogeneity of bulk sediment likely drives differences between bulk and clay records, thought to be largely controlled by sediment transport processes. The isotopic records reveal variations in provenance that correlate with climatic change at 8–7 Ma, as well as an increase in overall provenance variability beginning at c. 3.5 Ma, likely linked to monsoon strength and glacial–interglacial cycles. The clay-fraction records highlight the potential value of measuring proxy records from multiple size fractions to help constrain provenance records as well as investigate sediment transport and/or weathering and erosion processes recorded in deep-sea sediment archives.

Labrador Sea bottom water provenance and REE exchange during the past 35,000 years

Deep waters of the Labrador Sea (LS) are important contributors to the Atlantic Meridional Overturning Circulation, but their water mass structure has been highly variable and sensitive to climatic changes on different time scales. The LS is also an area of intense exchange of rare earth elements (REE) between seawater and the underlying sediments, which complicates the reconstruction of past deep water provenance based on radiogenic neodymium (Nd) isotopes. Most notably, Northwest Atlantic Bottom Water exchanges Nd with Archaean age Laurentian detritus, resulting in a significant shift to less radiogenic Nd isotope signatures before it enters the North Atlantic to form the deep part of North Atlantic Deep Water. Here we show that the authigenic fractions of LS core top sediments carry Nd isotope signatures intermediate between bottom water and detritus and thus reflect pore waters that incorporate a mixture of both signatures.We furthermore find that detrital imprints on pore waters led to shifts of REE patterns in the authigenic fraction towards detrital signatures in the past during times of enhanced supply of glacially eroded material from Hudson Bay to the LS, as recorded by radiogenic lead isotopes. This allows an estimation of the intensity of past benthic REE exchange inside the LS.We exploit variations in the mid REE enrichment in the authigenic phase to propose a correction to one LS Nd isotope record for detrital imprints originating from pore water exchange. The corrected ϵNd signatures are argued to more accurately reflect those of past bottom waters. This correction results in past LS bottom water signatures of −16 ± 1 during MIS 2 and 3, considerably less radiogenic than today. This implies that no southern sourced waters advanced into the LS during the last 35 ka and instead supports continuous bottom water sourcing from the Nordic Seas. It thus seems likely that LS bottom waters supplied unradiogenic Nd to abyssal Glacial North Atlantic Bottom Water in the Northwest Atlantic, as was previously hypothesized.