Negative Temperature Difference Research Articles

Enhancement of power density and hydrogen productivity of the reverse electrodialysis process by optimizing the temperature gradient between the working solutions

Reverse electrodialysis (RED) is an emerging technology that converts the salinity gradient energy (SGE) embedded in two solutions of different concentrations into electricity or hydrogen productivity. Given that two solutions containing SGE in nature are often at different temperatures, this study experimentally investigated the effects of the temperature and salinity ratio of the working solutions on the performance of RED systems. The results show that the power density and hydrogen productivity of RED systems could be markedly improved by adjusting the imposed temperature difference on the basis of the salinity gradient. The degree of improvement mainly depends on the magnitude and direction of the temperature difference between the high- and low-concentration solutions. The enhancement effect was more pronounced under a negative temperature difference (NTD) than under a positive temperature difference (PTD). Additionally, the improvement in system performance owing to the temperature difference was not affected by the endothermic or exothermic effects of different solutes in the water. At a NTD of 25℃ and a concentration of 0.1 M aqueous NaOH as the electrode solution, a RED system based on LiBr solution with a salinity ratio of 4.5 M/0.02 M as the working solution achieved a maximum power density of 0.754 ± 0.006 W∙m−2 and the highest hydrogen productivity of 1.128 ± 0.019 mol∙m−2∙h−1, which was 15.1% and 5.5% higher than the hydrogen productivity under LiCl and NaCl solution conditions, respectively. These results show the great potential of LiBr solution in the field of RED hydrogen productivity.

Ion current rectification coupled with asymmetric temperature and surface charge in ultrashort conical nanopores

Ion current rectification (ICR) is one of the electrodynamic properties in asymmetric nanochannels, which has been utilized to develop biosensors, heavy metal ion detection, and ion diodes. Previous studies on ICR mainly focused on long nanopores (length >500 nm), and relatively few studies on ion rectification performance in short nanopores. Here, we use a finite element numerical solution to simulate the effect of coupling asymmetric temperature and surface charge distribution on the ion rectification performance of ultrashort conical nanopores (length = 100 nm). The results show that the ion rectification performance is significantly improved when the inner and outer surfaces of the nanopore are charged non-uniformly, which is more than three times that when the inner surface of the nanopore is charged non-uniformly or the outer surface is charged non-uniformly. In addition, the positive temperature difference enhances the ion enrichment and dissipation and improves the ion rectification performance of nanopores. On the contrary, negative temperature difference inhibits ion enrichment and dissipation in pores, which is not conducive to improving ion rectification performance. Abnormal behavior is observed for nanopores non-uniform charged only on the outer wall surface, where the negative temperature gradient enhances the accumulation and dissipation of ions within the pores, thereby increasing the rectification ratio. In addition, in order to more clearly understand the ion transport behavior in the ultrashort nanopore under asymmetric temperature conditions, we further investigated the influence of the tip radius of the nanopore, the solution volume concentration, and the charge type of each surface charge distribution on the ion current rectification performance. The results reveal the ion transport mechanism of ultrashort conical nanopores and provide practical guidance for designing and optimizing nanofluidic devices.

Modulated turbulent convection: a benchmark model for large scale natural flows driven by diurnal heating

Our life is strongly affected by turbulent convective flows, driven by time-dependent thermal forcing, especially diurnal heating of the Earth’s surface by the Sun. In a laboratory experiment, we investigate their analogues: We study complex and extraordinary properties of turbulent buoyancy driven flows generated due to periodic modulation of the temperature of the plates of a Rayleigh–Bénard cell, with amplitudes both smaller and larger than either the positive or negative mean temperature difference between the top and bottom. We probe the turbulent flow of our working fluid – cryogenic helium gas – using temperature sensors placed in the cell interior and embedded in its plates. We discuss spatial and temporal structure of the heat flow, generalize validity of Nusselt versus Rayleigh number scaling Nu ∝\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\propto$$\\end{document} Raγ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$^\\gamma$$\\end{document} with γ≈1/3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\gamma \\approx {1/3}$$\\end{document} at very high Ra for modulated convection and argue that this system represents a benchmark model which helps us understand the energy budget of ocean currents or weather formation on Earth subject to diurnal Sun heating as well as similar natural flows on Earth-like planets.

Temperature analysis and prediction for road-rail steel truss cable-stayed bridges based on the structural health monitoring

A growing number of road-rail steel truss bridges have been built worldwide in recent years. Due to the complex cross-sectional structure and increasing span length, these main girders are prone to developing uneven temperature fields and significant local thermal effects, which can lead to excessive temperature stresses and structural damage. An accurate assessment of the temperature distribution in road-rail steel truss girders is critical as it aids in the thermal response analysis of the bridge and the structural safety evaluation. The paper analyses the temperature distribution of the road-rail steel truss girder base on the light conditions and the structure of the main girder. A modified method for calculating the effective temperature (ET) and temperature difference (TD) is also proposed. Comparing with the conventional regional weighted averaging method, the modified method improves the accuracy of ET calculation by 20 %. A prediction method based on the long short-term memory (LSTM) network is proposed, which estimates ET and TD for road-rail steel truss girders based on the environment around the bridge. The deep learning-based method improves accuracy by 40 % compared with the conventional linear regression method for ET prediction. Meanwhile, the proposed method alleviates the current lack of prediction methods for TD of road-rail steel truss girders. A detailed analysis of the temperature of a road-rail steel truss bridge is also presented based on the structural health monitoring (SHM) system. A negative vertical temperature difference was observed in the fringe truss. The maximum transverse temperature difference (TTD) was much greater than the maximum vertical temperature difference (VTD). The above features deserve extra attention from bridge designers.

Synergy effects of pH and thermal localization on membrane-based salinity gradient energy harvesting

Salinity gradient power generation receives increasing attention due to its availability in nature. However, membrane surface charge is not fixed value in isolation but strongly dependent of various conditions. Here, a coupled ion transport model is proposed to study the synergy effects of pH and thermal localization on membrane-based salinity gradient energy conversion. The research illustrates that the surface charge is regulated by solution environment, membrane properties and thermal conditions. Specially, the surface charge sign can be even reversed at certain case that induces distinct ion transports behaviors. Consequently, Al2O3 membrane achieves the better energy conversion performance at low pH with negative temperature difference. While SiO2 membrane obtains the best output performance at high pH with negative temperature difference. Such is ascribed to pH-regulated surface charge and thermal up-diffusion enhancement. The maximum output power of 10 pW with efficiency of 16 % is achieved for individual membrane channel. As a proof of concept, it shows significant deviations between the single and coupling model on power generation. The findings of this study can help for better understanding the coupling mechanisms of solution, membrane and thermal conditions during the energy conversions, thereby providing a reasonable design route for membrane-based energy devices.

Assessment of Accuracy of Moderate-Resolution Imaging Spectroradiometer Sea Surface Temperature at High Latitudes Using Saildrone Data

The infrared (IR) satellite remote sensing of sea surface skin temperature (SSTskin) is challenging in the northern high-latitude region, especially in the Arctic because of its extreme environmental conditions, and thus the accuracy of SSTskin retrievals is questionable. Several Saildrone uncrewed surface vehicles were deployed at the Pacific side of the Arctic in 2019, and two of them, SD-1036 and SD-1037, were equipped with a pair of IR pyrometers on the deck, whose measurements have been shown to be useful in the derivation of SSTskin with sufficient accuracy for scientific applications, providing an opportunity to validate satellite SSTskin retrievals. This study aims to assess the accuracy of MODIS-retrieved SSTskin from both Aqua and Terra satellites by comparisons with collocated Saildrone-derived SSTskin data. The mean difference in SSTskin from the SD-1036 and SD-1037 measurements is ~0.4 K, largely resulting from differences in the atmospheric conditions experienced by the two Saildrones. The performance of MODIS on Aqua and Terra in retrieving SSTskin is comparable. Negative brightness temperature (BT) differences between 11 μm and 12 μm channels are identified as being physically based, but are removed from the analyses as they present anomalous conditions for which the atmospheric correction algorithm is not suited. Overall, the MODIS SSTskin retrievals show negative mean biases, −0.234 K for Aqua and −0.295 K for Terra. The variations in the retrieval inaccuracies show an association with diurnal warming events in the upper ocean from long periods of sunlight in the Arctic. Also contributing to inaccuracies in the retrieval is the surface emissivity effect in BT differences characterized by the Emissivity-introduced BT difference (EΔBT) index. This study demonstrates the characteristics of MODIS-retrieved SSTskin in the Arctic, at least at the Pacific side, and underscores that more in situ SSTskin data at high latitudes are needed for further error identification and algorithm development of IR SSTskin.

Numerical study of airflow pattern and bioaerosol dispersion during door motion in a negative pressure isolation ward

Negative pressure isolation wards are typically equipped with buffer rooms to prevent the spread of infectious bioaerosols into clean areas and facilitate timely removal. The opening and closing process of sliding doors is very common in wards. Since the air exchange characteristics of the doorway affect the risk of infection and the efficiency of particle removal within the buffer room, the boundary transformation method and dynamic numerical simulations are used to study the airflow patterns and particle diffusion during door motion. The corresponding cases for different pressure differences, temperature differences, and door motion modes are compared. The results indicate that under different temperature differences, the particles can be dispersed uniformly in a short time (about 23s), and there is no phenomenon of particle aggregation. Compared to the initial pressure difference, adjusting the initial temperature difference has a more pronounced effect on air infiltration and particle concentration trends. The peak particle concentrations within the buffer zone under negative temperature differences are on average 19.9 % higher compared to the positive temperature differences. However, particle concentrations at negative initial temperature differences decay more rapidly. It is found that by reducing the duration of full door opening from 6s to 2s, the time for particles to be completely removed can be reduced by 30.6 %. This study provides useful information for evaluating the risk of infection and developing operational modes of the buffer room.

Supercritical heat transfer of CO2 in horizontal tube emphasizing pseudo-boiling and stratification effects

Here, we investigate supercritical heat transfer of CO2 in a 10.0 mm diameter horizontal tube, covering pressures, mass fluxes and heat fluxes in the ranges of (7.531∼20.513) MPa, (496.7∼1346.2) kg/m2s, and (97.4∼400.3) kW/m2, respectively. It is surprising to find the non-monotonic increase of wall temperatures along the flow direction. Besides, either positive or negative wall temperature differences, ΔT, exist between bottom tube and top tube. The three-regime-model is introduced to explore the mechanisms that trigger the above abnormal findings. The stratified-wavy flow involves a liquid-like (LL) core and a vapor-like (VL) layer on the tube wall. The wavy interface is formed by the two separated phases of LL and VL. The oscillation of wall temperatures is explained by the thermal conduction in the solid wall interacted with the stratified-wavy flow in the tube. Once wall temperatures increase, the local heat flux decreases to decrease the evaporation momentum force, reducing the VL layer thickness to ensure the heat transfer recovery. A regime map clarifies the positive and negative temperature difference runs, and the maximum wall temperature differences are well correlated based on the LL phase Reynolds number, ReLL,ave. In the two-phase-like (TPL) regime, the measured heat transfer coefficients significantly deviate from the predictions based on the single-phase fluid assumption. The strong deviation of hbot/htop from 1 indicates both important effects of pseudo-boiling and stratification in horizontal tubes, where hbot and htop are the heat transfer coefficients at the bottom generatrix and the top generatrix, respectively. Based on this work, the pseudo-boiling theory is recommended to deal with the supercritical heat transfer.

Temperature gradient of composite PK girder based on monitoring and long-term simulation

Bridge structures exposed to the environment are inevitably affected by the thermal load which is closely related to the type of section. In this study, the temperature field of a composite Pasco-Kennewick (PK) section girder was monitored in situ for the first time. Meanwhile, a refined finite-element model (FEM) of the temperature field was established and verified with measured temperatures. The temperature distribution and variation characteristics were analyzed using measured temperatures. On this basis, the simplified profiles of vertical temperature gradient (VTG) and transverse temperature gradient (TTG) were proposed. The representative values of temperature differences with a 100-year return period were predicted by extreme value analysis (EVA) with the samples of temperature differences obtained through 23-year numerical simulation. Finally, comparisons were made between the temperature gradients of composite PK section and the recommendations in current specifications. The results show that the vertical temperature distributions and variations on different webs have apparent differences. Meanwhile, remarkable transverse temperature differences exist on the top plate and bottom plate. Five VTGs and four TTGs are proposed with totally different simplified profiles. The representative values of positive temperature differences in TTGs are larger than those in VTGs, as well as the absolute values of negative temperature differences. The proposed temperature gradients are significantly distinct from the recommendations in current specifications. These temperature gradients are expected to improve the stipulation about the temperature action of bridges.

Effect of membrane thermal conductivity on ion current rectification in conical nanochannels under asymmetric temperature

Nowadays, there have been extensively theoretical studies on the phenomenon of ion current rectification (ICR) induced by the asymmetric electrical double layer (EDL). As a key factor influencing the behavior of ion transport, temperature is given high priority by researchers. The thermal conductivity of the material commonly employed to prepare nanopores is 2–3 times higher than that of liquid solutions, which may affect ion transport within the nanochannel. However, it is often neglected in previous studies. Thus, we investigate the effect of membrane thermal conductivity on the ICR in conical nanochannels under asymmetric temperature. Based on the PNP-NS theoretical model, the ion current, the rectification ratio, as well as the temperature and ion concentration distributions along the nanochannel are calculated. It is found that the thermal conductivity of the solid membrane noticeably affects the temperature distribution across the nanochannel, altering the ion transport behavior. Larger membrane thermal conductivity tends to homogenize the temperature distribution in the nanochannel, leading to a decline of ionic thermal down-diffusion by a positive temperature difference and ionic thermal up-diffusion by a negative temperature difference, with the former promoting and the latter inhibiting ion current. As a result, the rectification ratio decreases under the positive temperature difference and increases under the negative temperature difference as the thermal conductivity of the membrane increases. These studies will be instructive for the design of nanofluidic diodes and biosensors.

Analysis of the Temperature Field Effect on the Thermal Stress of the Main Tower of Long-Span Suspension Bridges

To investigate the temperature field variation of the main tower of large-span suspension bridges, the Nanjing Xinshengwei Yangtze River Bridge was selected as the objective of the present study. The finite element model of the main tower was developed, and the analysis of the effect of the temperature field on the structure of the main tower was carried out. The calculation parameters of the temperature field of the main tower were determined, and the influence of the solar radiation temperature of the main tower within 24 h was investigated. Differences in the temperatures inside and outside the wall of the tower column were analyzed, and the thermal stress of the tower wall under the most unfavorable temperature difference was calculated. Results show that under the positive temperature difference, the area of tensile stress is mainly concentrated on the inner wall, the maximum value is located at the corner of the intersection of the tower wall, and the range of tensile stress is mainly diffused along the vertical wall. Under the action of negative temperature difference, the area of tensile stress is mainly concentrated in the outer tower wall, the maximum value is located in the upper part of the western outer tower wall, and the range of tensile stress is mainly diffused along the center of the tower wall to both sides. The maximum tensile stresses in the inner and outer tower wall are 2.8 MPa and 1.3 MPa, respectively, which meets the standard value of 2.85 MPa for the tensile strength of C60 concrete specified in the Chinese national standard.

Seasonal sea breeze variation analysis based on multi‐year near‐surface observations in Jakarta, Indonesia

AbstractIn this study, multi‐year near‐surface observations were conducted at two sites in Jakarta, Indonesia to analyse seasonal sea breeze variation. Seasonal length was defined using observed zonal wind components, the rainy season was defined as December–March, and the dry season was defined as May–September. We found that the sea breeze in Jakarta started earlier, propagated more rapidly, and lasted for a shorter period of time during the rainy than dry season. Variation in the air temperature difference between urban and coastal areas of Jakarta was the major factor driving sea breeze seasonal variation. During the rainy season, night‐time cloud downwelling decreased this air temperature difference, causing earlier sea breeze onset and more rapid sea breeze propagation due to a weaker land breeze. By contrast, during the dry season, intense night‐time radiative cooling inland caused a strong negative temperature difference that produced a stronger land breeze, thus, slowing sea breeze propagation. Seasonal differences in urban surface heating and urban heat island circulation may also affect sea breeze onset and propagation speed. Discrepancies in thermal properties between urban core and coastal areas of Jakarta also prolonged positive temperature differences after sunset, thus extending the sea breeze duration in the dry season.

Simulation Study on Sunshine Temperature Field of a Concrete Box Girder of the Cable-Stayed Bridge

This paper investigates the distribution of the sunshine temperature field in bridge structures. To implement thermodynamic boundary conditions on the structure under the influence of sunshine, this study utilized the FILM and DFLUX subroutines provided by ABAQUS. Based on this method, the sunshine temperature field of the concrete box girder of a cable-stayed bridge was analyzed. The results showed that the simulated temperature values were in good agreement with the measured values. The temperature difference between the internal and external surfaces of the box girder under the influence of sunshine was significant, with the maximum negative temperature difference appearing around 6:00 a.m. and the maximum positive temperature difference appearing around 2:00 p.m. The temperature gradient of the box girder section calculated by the method presented a C-shaped distribution pattern, which differs from the double-line distribution pattern specified in the current “General Specifications for Design of Highway Bridges and Culverts” in China (JTG D60-2015). Furthermore, a sensitivity analysis of thermal parameters using the proposed simulation method for the sunshine temperature field of the concrete box girder was conducted, and the results indicated that the solar radiation absorption coefficient had a significant impact on the temperature field. A 30% increase or decrease in the solar radiation absorption coefficient caused the maximum temperature change on the surface of the structure to exceed 10 °C. This paper provides an accurate simulation of the sunshine temperature field of the concrete box girder of a cable-stayed bridge, and the research results are significant for controlling bridge alignment and stress state during the construction period, ensuring the reasonable initial operating state of the bridge, and enhancing the sustainability of the structure.

Energy harvesting from charged conical nanopore with salinity and temperature gradient

• An energy harvesting system from charged conical nanopore with coupled salinity and temperature gradient is proposed. • An interesting completive mechanism between the concentration gradient and temperature gradient effect was found, which determined the output performance. • The enhancement of negative temperature difference on output power is more significant compared with positive temperature difference. • The research results provide useful information for the design and optimization of energy devices. Renewable energy has been received more attention with the increasingly serious energy crisis. In this paper, an energy harvesting system from charged conical nanopore with coupled salinity and temperature gradient is proposed. The results show that the obtained maximum power increases first and then decreases as the concentration difference increases. Particularly, the enhancement of negative temperature difference (NTD) on maximum output power and the corresponding energy conversion efficiency is more significant compared with positive temperature difference (PTD) due to the simultaneous increase of short circuit current and open circuit voltage. Besides, the maximum output power is larger when the low concentration reservoir is connected to the tip end of the conical nanopore. The obtained maximum optimal value is about 0.22 pW. In the further investigation of a temperature gradient, we found that the short circuit current, open circuit voltage, and maximum output power show the approximately linear thermal response characteristics as the temperature difference is increased. Besides, an interesting competive mechanism between the concentration gradient effect and temperature gradient effect is found, which determines the prior conical nanopore orientation. The related research results provide useful information for the design and optimization of energy devices.

Temperature distribution simulation and thermal properties investigation of hollow slab beam based on meteorological data

Natural environment has a great impact on the performance of bridge structures, such as the ambient temperature, solar radiation, climate extremes and so on. Due to the lack of regional pertinence in the provisions of the existing specifications on the temperature load standard, and the lack of verification of its adaptability of hollow slab beam bridge in the reconstruction and expansion project, it is necessary to study the temperature load of the beam based on the temperature data of the area where the bridge site is located. Based on the measured meteorological data, the cross-section temperature distribution characteristics of the hollow slab beam and the temperature load effect were investigated. The vertical temperature load model of the short and medium-span hollow slab beam was proposed according to the simplified temperature curve. Firstly, based on the annual measured meteorological data, the plane model was established to analyze the temperature distribution characteristics of the hollow slab beam. Secondly, according to the temperature field distribution of the beam cross-section, the solid model of 16 m hollow slab beam was established to analyze the distribution of the temperature load effect. Finally, based on the preliminarily proposed temperature curve, vertical temperature load models were proposed by introducing the theory of extreme value extrapolation. The studies have shown that the temperature of the hollow slab beam is approximately horizontal distributed, and temperature extreme value appear at the location of the beam web. The roof and floor of the hollow slab beam are compressed and the webs are tensioned in the positive temperature difference state, the stress condition is opposite under the negative temperature difference state. The positive and negative temperature load models can meet the extrapolation requirements of the bridge design reference period. This study innovatively proposed a temperature load model based on the temperature curve corresponding to the most unfavorable effect of the beam. The extrapolation idea in the derivation of vehicle load model is introduced as well. And a temperature load model suitable for the extension of hollow slab bridges in Guangdong is established in this study.

Analysis of Measured Temperature Field of Unpaved Steel Box Girder

This work used the measured data during the whole test period to study the law of temperature change in the steel rail beams, and the distribution characteristics of the sunshine temperature field, in straddle-type monorail tourist transportation systems, employing a field-test and a numerical simulation. The curve form of the temperature gradient was determined by a comparative analysis of the existing domestic and foreign norms. Finally, the generalized extreme value distribution model was used to predict the extreme value of the representative value of the temperature difference, and the value of the temperature base, for different return periods, and the complete temperature gradient model were determined. Results: During the whole test period, the maximum vertical positive temperature difference of the steel box girder was 15.21 °C, and the negative temperature difference was −5.07 °C. In addition, the effect of the ambient temperature, considering solar radiation, was found to be an important factor affecting the distribution of the vertical temperature difference. The analysis determined that the positive and negative temperature difference curves in the unpaved steel box girder were multi-segment polylines and linear straight lines, respectively. The extreme value predicts that the representative temperature differences between T1 and T2 of the 450 mm beam during the 50-year return period were 17.2 °C and 4.58 °C, respectively, and T1 and T2 under the 100-year return period were 17.38 °C and 4.62 °C, respectively.

Statistical Analysis of the Vertical Temperature Gradient of the Web Plate of Steel Box Girder Bridges in Cold Regions

To understand the actual vertical temperature gradient mode of steel box girder webs in cold regions, nearly 1.5 million data measured for over a year by a comprehensive temperature collection system of a steel box girder bridge in a cold region were used to verify the typicality of the temperature screening samples, and a cluster analysis was performed to verify the statistical symmetry of temperature at the symmetry points of webs on both sides of the bridge. One years' worth of daily temperature difference data were used to investigate the vertical temperature difference distribution on the web and to determine the probability distribution curve form. After selecting the extreme temperature difference samples, the standard vertical temperature difference of the web was calculated, and the actual vertical temperature gradient model of the steel box girder web was established. Results show that the probability distribution model of temperature at the symmetrical points of webs on both sides of the steel box girder was symmetric. The vertical temperature differences of the web demonstrated significant seasonal changes. The probability distribution of the positive and negative temperature differences can be described based on the sum of two Weibull distribution functions. The temperature gradients at all levels in the proposed vertical temperature gradient model were generally greater than the values indicated in the relevant specifications.

Оценка влияния температурных условий на естественную вентиляцию глубоких карьеров Арктической зоны

The Arctic zone of Russia is a territory where such minerals as gold and other precious metals are concentrated. Most often, the development of such deposits is carried out by an open method. The conditions hindering its use should be considered: the depth of distribution of permafrost and significant amplitude of changes in atmospheric air temperature during the year, month and day. The consequence of the alternation in depth of temperature zones may be the formation of recirculation zones in which harmful substances accumulate. Purpose of work. Study of the formation of velocity and temperature fields in a quarry under natural ventilation, taking into account the complex dynamics of atmospheric air temperature. Research methods. Systematization, generalization and analysis of theoretical and experimental studies in this area, including those carried out at the considered fields. Analysis of the results of mathematical modeling of aerodynamic processes in a quarry. Results. It is noted that to assess the peculiarities of formation of the mine atmosphere parameters it is sufficient to carry out only mathematical modeling of aerodynamic processes allowing to define the conditions of temperature inversions formation and dimensions of recirculation zones being potentially dangerous for accumulation of pollutants. The methodology of aerodynamic processes modeling taking into account the geometry of the pit space, temperature gradient, speed and direction of the wind flow is proposed. It is shown that at positive and negative temperature differences for the two investigated air media the development of recirculation movement zones of air masses that assure the accumulation of pollutants which in turn leads to reduced efficiency of natural ventilation in the pit, is characteristic. The conclusion has been made on the necessity to apply additional engineering measures during the period of inversion formation with negative temperature gradient in order to normalize the pit air parameters.

Thermal Effects on the Nonlinear Forced Responses of Hinged-Clamped Beam with Multimodal interaction

Nonlinear analysis of a forced geometrically nonlinear Hinged-Clamped beam involving three modes interactions with internal resonance and submitted to thermal and mechanical loadings is investigated. Based on the extended Hamilton’s principle, the PDEs governing the thermoelastic vibration of planar motion is derived. Galerkin’s orthogonalization method is used to reduce the governing PDEs of motion into a set of nonlinear non-autonomous ordinary differential equations. The system is solved for the three modes involved by the use of the multiple scales method for amplitudes and phases. For steady states responses, the Newton-Raphson shooting technique is used to solve the three systems of six parametric nonlinear algebraic equations obtained. Results are presented in terms of influences of temperature variations on the response amplitudes of different substructures when each of the modes is excited. It is observed for all substructures and independent of the mode excited a shift within the frequency axis of the temperature influenced amplitude response curves on either side of the temperature free-response curve. Moreover, it is found that thermal loads diversely influence the interacting substructures. Depending on the directly excited mode, higher oscillation amplitudes are found in some substructures under negative temperature difference, while it is observed in others under positive temperature change and in some others for temperature free-response curves.

Formation mechanism of heavy haze-fog associated with the interactions between different scales of atmospheric processes in China

Large-scale meteorological processes associated with aerosol pollution can be represented by two parameters: sensitive parameter θe with non-conservative changes and a decreasing mixing layer height (MLH), typically for 3–5 days. Pollution-associated micro-scale processes can be represented by atmospheric condensation rate function and atmospheric super-saturation S to measure the degrees of thermal stability and dynamic dispersion. This shows that the interactions between large- and micro-scale movements in lower atmosphere are critical for the formation of heavy haze-fog, which consists of three progressive processes. In the initial stage, with sufficiently large convective inhibition (CIN), air stratification stabilizes and reduces the MLH. During the micro-scale process, MLH reductions suddenly increase atmospheric super-saturation S, which accumulates additional aerosol by enhancing hygroscopic growth and accelerating secondary reactions. Secondly, from micro-to large-scale process, heat releases during the condensation processes, which is accelerated by an increase in super-saturation, thus, increasing the virtual temperature of ambient atmosphere and decreasing the virtual temperature of the polluted particulate matter. The negative virtual temperature difference δ (T′v−Tv) between the polluted particulate matter and environment further increases as the intensity of S increases with altitude, resulting in larger CIN and consequently more reductions in the MLH. Subsequently, a vicious cycle of increasing super-saturation starts, which again aggravates the haze-fog. This is the basic formation mechanism of heavy pollution under the boundary layer.