This study shows that it is possible to achieve a very large supercontinuum spectral broadening with a peak power hundreds of times lower than in previous publications. We can achieve by using a square lattice toluene-core photonic crystal fiber. With the heterogeneity in the diameter of air holes, our new design allows simultaneous optimization of characteristic quantities to ensure flat near-zero dispersion, small effective mode area, and low attenuation for efficient spectral broadening. Supercontinuum generation (SC) of proposed PCFs has been numerically simulated and studied under different pump source parameters. The first fiber with a lattice constant of 1.0 μm and filling factor of 0.65 operates in all-normal dispersion. It generates broadband of 1.045 μm by a pump pulse with a central wavelength of 1.3 μm, 40 fs duration, and energy of 18 pJ (corresponding peak power of 0.45 kW). Besides, two octave-spanning of the SC spectrum in the wavelength range of 0.775–4.3 μm are formed in the second fiber with an input pulse whose optical properties are 1.55 μm wavelength, 100 fs duration, and energy of 55 pJ (0.45 kW of the peak power). The lattice constant of second fiber is 2.0 μm and the filling factor is 0.3. They would be good candidates for all-fiber SC sources operating with low-power pump lasers. This would be a as cost-effective alternatives to glass core fibers.