Near-infrared Diffuse Reflectance Research Articles

A strategy to reduce the effect of organic matter on fluorescence intensity for improving the detection accuracy of polycyclic aromatic hydrocarbons in soil

Fluorescence spectroscopy has been used for rapid detection of PAHs in soil, but soil organic matter (SOM) produces strong interference to the fluorescence intensity of PAHs, which restricts the application of fluorescence spectroscopy for rapid detection of PAHs in soil. A correction method of reducing the interference of SOM on PAHs fluorescence intensity was proposed combining fluorescence and near-infrared (NIR) spectroscopy. Six soil samples with different concentrations of humic acid (HA) at a given phenanthrene concentration (5 mg/g) were prepared and scanned for obtaining the fluorescence and NIR diffuse reflectance spectra. The spectral data showed that the fluorescence intensity and NIR diffuse reflectance had an approximate trend with the change of HA concentration. It was found that the NIR diffuse reflection at 4672 cm−1 as a calibration factor could effectively reduce the interference of HA on the fluorescence intensity of phenanthrene. Subsequently, a standard curve for the quantitative analysis of phenanthrene in soil was established based on the fluorescence intensity before and after calibration. For the unknown samples, the predicted average relative errors of the standard curves before and after calibration were 27.46 % and 9.00 %, respectively. The results showed that the proposed correction method could reduce the interference of HA on the quantitative analysis of PAHs, and provide a reference for eliminating the interference constraint of fluorescence spectroscopy technique for rapid real-time detection of PAHs in soil.

Effect of spectrum measurement position on detection of Klason lignin content of snow pears by a portable NIR spectrometer

AbstractSnow pears are an important and widespread agricultural product that can relieve respiratory symptoms, constipation, and alcoholism. Lignin content (LC) has a direct and negative role on the fruit texture and taste of snow pears. Here, we studied the effect on the near‐infrared (NIR) spectroscopy determination of the LC in snow pears due to the position at which spectral measurements were obtained. NIR diffuse reflection spectra were collected from nine measurement positions on each sample by a portable NIR spectrometer. Partial least squares regression (PLSR) was used to develop spectrum compensation models of the LC for three local spectrum models, an average spectrum model, and a global spectrum model. The results indicated that the prediction accuracy of the LC was affected by the spectral measurement position. Compared with the local spectrum models and the global spectrum model, the average spectrum model had good prediction results. Next, synergy interval partial least squares, bootstrapping soft shrinkage, competitive adaptive reweighted sampling, genetic algorithm, and an improved variable stability and frequency analysis algorithm (VSFAA) method were used to select the most effective variables to build the PLSR model. The average spectrum calibration model established using the 10 effective variables selected by VSFAA reduced the influence of the variation of the spectral measurement position for LC prediction and achieved more promising results, with the correlation coefficient of calibration and prediction of 0.842 and 0.824, respectively. The root mean square error of cross‐validation and prediction were 0.736 and 0.694, respectively. The overall results showed that the average spectrum model based on the nine spectral measurement positions reduced the sensitivity to the variation of spectral measurement position for predicting the LC and combined the VSFAA variable selection algorithm to improve the accuracy and provide a robust model for prediction of LC in snow pears. Compared with the local spectrum position models and the global spectrum position model, the average spectrum position model combining the nine measurement positions (three stem‐calyx longitudes intersected three latitudes (stem, equator, calyx)) produced good prediction results and reduced the sensitivity to the variation of the spectral measurement position. The effective wavelengths (SNV‐VSFAA‐PLSR)‐average spectrum position model achieved good results, reducing the influence of the variation of the spectral measurement position for LC prediction, and the effective wavelengths selected from the average spectrum position model were helpful for offsetting the influence of the variation of spectral measurement position on the PLSR models based on the spectrum from the equatorial positions alone.

Non-Destructive Discrimination of Sunflower Seeds with Different Internal Mildew Grades by Fusion of Near-Infrared Diffuse Reflectance and Transmittance Spectra Combined with 1D-CNN.

Internally mildewed sunflower seeds, which cannot be recognized and discarded based on their appearance, pose a serious risk to human health. Thus, there is a need for a rapid non-destructive mildew grade discrimination method. Currently, few reports are available regarding this process. In this study, a method based on the combination of the near-infrared diffuse reflectance and near-infrared diffuse transmission (NIRr-NIRt) fusion spectra and a one-dimension convolutional neural network (1D-CNN) is proposed. The NIRr-NIRt fusion spectra can provide more complementary and comprehensive information, and therefore better discrimination accuracy, than a single spectrum. The first derivative (FD) preprocessing method could further improve the discrimination effect. By comparison against three conventional machine learning algorithms (artificial neural network (ANN), support vector machine (SVM), and K-nearest neighbor (KNN)), the 1D-CNN model based on the fusion spectra was found to perform the best. The mean prediction accuracy was 2.01%, 5.97%, and 10.55% higher than that of the ANN, SVM, and KNN models, respectively. These results indicate that the CNN model was able to precisely classify the mildew grades with a prediction accuracy of 97.60% and 94.04% for the training and test set, respectively. Thus, this study provides a non-destructive and rapid method for classifying the mildew grade of sunflower seeds with the potential to be applied in the quality control of sunflower seeds.

Near-Infrared Absorption Coefficients in Kidney Stone Minerals and Their Relation to Crystal Structure

To quantitatively understand laser ablation of kidney stones by near-infrared (NIR) lasers, accurate measurements of physical properties related to heating and mechanical failure are needed. While light scattering varies among individual stones, absorption coefficients for the materials that form the bulk of each kidney stone are measurable when scattering is controlled. We developed methods to grow single crystals with lengths and widths >20 μm for the minerals that form kidney stones: calcium oxalate monohydrate, calcium oxalate dihydrate, calcium hydrogen phosphate dihydrate, hydroxyapatite, anhydrous uric acid, and magnesium ammonium phosphate hexahydrate. These single crystals were used with an infrared microscope to measure their NIR absorption coefficients from 1.67 to 2.5 μm. The strong correlation between single crystal NIR spectra and diffuse reflectance NIR spectra indicates little anisotropy in absorption. Most minerals absorbed more strongly at 1.94 μm than 2.12 μm, the wavelengths of thulium fiber and holmium:YAG surgical lasers, respectively. For water bearing minerals, we attribute absorption mainly to water combination modes and assign NIR absorption peaks to specific water molecules and the OH bonds thereof where possible. Reported absorption coefficients can be used to quantitatively compare both laboratory investigations of ablation and surgical experience to physical properties for the first time.

Insights into the Effects of Study Area Size and Soil Sampling Density in the Prediction of Soil Organic Carbon by Vis-NIR Diffuse Reflectance Spectroscopy in Two Forest Areas

Sustainable forest land management requires measuring and monitoring soil organic carbon. Visible and near-infrared diffuse reflectance spectroscopy (Vis-NIR, 350–2500 nm), although it has become an important method for predicting soil organic carbon (SOC), requires further studies and methods of analysis to realize its full potential. This study aimed to determine if the size of the study area and soil sampling density may affect the performance of Vis-NIR diffuse reflectance spectroscopy in the prediction of soil organic carbon. Two forest sites in the Calabria region (southern Italy), which differ in terms of area and soil sampling density, were used. The first one was Bonis catchment area (139 ha) with a cover consisting mainly of Calabrian pine, while the second was Mongiana forest area (33.2 ha) within the “Marchesale” Biogenetic Nature Reserve, which is covered by beech. The two study areas are relatively homogeneous regarding parent material and soil type, while they have very different soil sampling density. In particular, Bonis catchment has a lower sampling density (135 samples out of 139 ha) than Mongiana area (231 samples out of 33.2 ha). Three multivariate calibration methods (principal component regression (PCR), partial least square regression (PLSR), and support vector machine regression (SVMR)) were combined with different pretreatment techniques of diffuse reflectance spectra (absorbance, ABS, standard normal variate, SNV, and Savitzky–Golay filtering with first derivative (SG 1st D). All soil samples (0–20 cm) were analyzed in the laboratory for SOC concentration and for measurements of diffuse reflectance spectra in the Vis-NIR region. The set of samples from each study area was randomly divided into a calibration set (70%) and a validation set (30%). The assessment of the goodness for the different calibration models and the following SOC predictions using the validation sets was based on three parameters: the coefficient of determination (R2), the root mean square error (RMSE), and the interquartile range (RPIQ). The results showed that for the two study areas, different levels of goodness of the prediction models depended both on the type of pretreatment and the multivariate method used. Overall, the prediction models obtained with PLSR and SVMR performed better than those of PCR. The best performance was obtained with the SVMR method combined with ABS + SNV + SG 1st D pretreatment (R2 ≥ 0.77 and RPIQ > 2.30). However, there is no result that can absolutely provide definitive indications of either the effects of the study area size and soil sampling density in the prediction of SOC by vis-NIR spectroscopy, but this study fostered the need for future investigations in areas and datasets of different sizes from those in this study and including also different soil landscapes.

Simulated Spectral Strategy to Enhance Numerical Tobacco Blending Based on Near-Infrared (NIR) Diffuse Reflectance Spectroscopy and Calibration Transfer

Near-infrared diffuse reflectance spectroscopy, with the characteristics of simplicity, speed, and nondestructive analysis, has been frequently used in tobacco blending design and maintenance. Its main function is to identify the appropriate combination from hundreds of types of tobacco leaves to match the target formula. Due to the large number of combinations of tobacco leaves, preparing so many blended samples of tobacco powder with different proportions and measuring their spectra are time-consuming, laborious, and costly. Therefore, a novel strategy of simulated spectra based upon calibration transfer is proposed to substitute for the measured spectra without preparing these tobacco powder blended samples. Five and nine single-grade tobacco powder blending experimental results showed that the substitutive spectra for a massive tobacco powder blended samples may be obtained in a short time according to the established calibration transfer models between measured and simulated spectra of a small number of blended samples. Moreover, with the help of calibration models built on the same spectrometer, the desired properties including reducing sugar, total sugar, potassium, starch, and total nitrogen of these tobacco mixtures are quickly predicted. In addition, transfer based on canonical correlation analysis and independent component analysis were superior to other approaches, respectively. The strategy of simulated spectra partially may replace powder blending and spectral analysis and may be considered to be a valuable and effective tool for computer-aided numerical tobacco blending.

An Intelligent Near-Infrared Diffuse Reflectance Spectroscopy Scheme for the Non-Destructive Testing of the Sugar Content in Cherry Tomato Fruit

As a new non-destructive testing technology, near-infrared spectroscopy has broad application prospects in agriculture, food, and other fields. In this paper, an intelligent near-infrared diffuse reflectance spectroscopy scheme (INIS) for the non-destructive testing of the sugar contents in vegetables and fruits was proposed. The cherry tomato were taken as the research object. The applicable objects and features of the three main methods of near-infrared detection were compared. According to the advantages and disadvantages of the three near infrared (NIR) detection methods, the experiment was carried out. This experiment involved the near-infrared diffuse reflection detection method, and the back propagation (BP) network model was established to research the sugar content of the cherry tomatoes. We used smoothing and a principal component analysis (PCA) to extract the final spectrum from the experimental spectrum. Taking the preprocessed spectral data as the input of the network and the measured sugar content of the cherry tomatoes as the output, the 80-12-1 network model structure was established. The cross-validation coefficient of determination was 0.8328 and the mean absolute deviation was 0.5711. The results indicate that the BP neural network can quickly and effectively detect the sugar content in cherry tomatoes. This intelligent near-infrared diffuse reflectance spectroscopy (INIS) scheme can be extended and optimized for almost all sugar-containing fruits and vegetables in the future.

Dimensionality Reduction Statistical Models for Soil Attribute Prediction Based on Raw Spectral Data

To obtain a better performance when modeling soil spectral data for attribute prediction, researchers frequently resort to data pretreatment, aiming to reduce noise and highlight the spectral features. Even with the awareness of the existence of dimensionality reduction statistical approaches that can cope with data sparse dimensionality, few studies have explored its applicability in soil sensing. Therefore, this study’s objective was to assess the predictive performance of two dimensionality reduction statistical models that are not widespread in the proximal soil sensing community: principal components regression (PCR) and least absolute shrinkage and selection operator (lasso). Here, these two approaches were compared with multiple linear regressions (MLR). All of the modelling strategies were applied without employing pretreatment techniques for soil attribute determination using X-ray fluorescence spectroscopy (XRF) and visible and near-infrared diffuse reflectance spectroscopy (Vis-NIR) data. In addition, the achieved results were compared against the ones reported in the literature that applied pretreatment techniques. The study was carried out with 102 soil samples from two distinct fields. Predictive models were developed for nine chemical and physical soil attributes, using lasso, PCR and MLR. Both Vis-NIR and XRF raw spectral data presented a great performance for soil attribute prediction when modelled with PCR and the lasso method. In general, similar results were found comparing the root mean squared error (RMSE) and coefficient of determination (R2) from the literature that applied pretreatment techniques and this study. For example, considering base saturation (V%), for Vis-NIR combined with PCR, in this study, RMSE and R2 values of 10.60 and 0.79 were found compared with 10.38 and 0.80, respectively, in the literature. In addition, looking at potassium (K), XRF associated with lasso yielded an RMSE value of 0.60 and R2 of 0.92, and in the literature, RMSE and R2 of 0.53 and 0.95, respectively, were found. The major discrepancy was observed for phosphorus (P) and organic matter (OM) prediction applying PCR in the XRF data, which showed R2 of 0.33 (for P) and 0.52 (for OM) without using pretreatment techniques in this study, and R2 of 0.01 (for P) and 0.74 (for OM) when using preprocessing techniques in the literature. These results indicate that data pretreatment can be disposable for predicting some soil attributes when using Vis-NIR and XRF raw data modeled with dimensionality reduction statistical models. Despite this, there is no consensus on the best way to calibrate data, as this seems to be attribute and area specific.

Design and test of portable comprehensive quality non-destructive detector for grape bunches based on spectrum

Based on the analysis technology of visible/near infrared diffuse reflectance spectroscopy a portable and nondestructive detector was designed to test comprehensive quality of red globe grape bunches in growing period. The detector includes spectrum acquisition probe, spectrometer, lithium battery, halogen lamp light source, ARM board and peripheral circuit. Based on MFC development tool, the real-time analysis and processing software of the detector is written by C++ language. The optimal partial least squares regression (PLSR) detection model of multi-quality parameters was implanted into the hardware device. This paper selects the red globe grape bunches in the growth period as the research samples, collects the visible / near-infrared diffuse reflectance spectrum information, and then uses the established PLSR model to detect the Soluble solid content(SSC), Total acid (TA) and pH of the samples to generate comprehensive quality parameters. So as to realize the nondestructive testing of multiple quality and comprehensive quality parameter of red globe grape bunches in the growth period. In conclusion, the detector can realize real-time and non-destructive detecting of red globe grape bunches in growth period aiming at the multiple quality and comprehensive quality. Based on the analysis technology of visible/near infrared diffuse reflectance spectroscopy a portable and nondestructive detector was designed to test comprehensive quality of red globe grape bunches in the growth period. The detector included spectrum acquisition probe, spectrometer, lithium battery, halogen lamp light source, advanced RISC machines (ARM) board and peripheral circuit. Based on microsoft foundation classes (MFC) development tool, the real-time analysis and processing software of the detector was written by C++ language. The optimal partial least squares regression (PLSR) detection model of multi-quality parameters was implanted into the hardware device. This paper selected the red globe grapes bunches in the growth period as the research samples, collected the visible/near infrared diffuse reflectance spectrum information, and then used the established PLSR model to detect the soluble solid content (SSC), total acid (TA) and pH of the samples to generate comprehensive quality parameter. So as to realize the nondestructive detecting of comprehensive quality of red globe grapes bunches in the growth period. In conclusion, the detector could realize real-time and non-destructive detecting of red globe grapes bunches in growth period aiming at the comprehensive quality.

Application of Linear Additive Conditions for Near-Infrared Diffuse Reflectance Absorption Spectroscopy

Determining the homogeneity of material mixing in real time during product processing is critical for quality control. According to the Kubelka–Munk (K-M) function of diffuse reflectance absorption spectrum, absorbance (A) is approximately linear with the content of the components when the sample scattering coefficient (S) is in a certain range. The S is determined by the particle size of powder samples. Therefore, this study determined particle size ranges that satisfy linear additivity in near-infrared diffuse reflectance spectroscopy (NIRDRS). Thus, the proposed NIRDRS analysis technique can be used to determine the homogeneity of material mixes or analyze the percentages of the components in the mixture. In this study, vitamin B3 and vitamin C were used for preparing mixed samples with varying percentages. The experimental results revealed that linear additivity is satisfied when the powder particle size is in the range of less than 280, 280–450, and 450–900 μm. When the confidence level is 0.01, the actual mixed spectra are not significantly different from the “simulated mixed spectra” constructed by linear addition, with their relative deviations less than 1.08%. The absolute errors of the actual and analytic percentages were within 2.98% for each component in the mixtures. The above conclusions also hold for sorghum, which has a complex material composition. Statistical models cannot analyze the percentages of components in the mixture. In contrast, linear addition and direct calibration approach avoids the use of a large number of samples for statistical modeling and analyze the percentages of mixed samples. Meanwhile, it can be used to discriminate and analyze the material mixing uniformity by building a mechanistic model.

Assessment of Soil Characteristics Using a Three-Band Agricultural Digital Camera

Abstract Remote sensing techniques based on soil spectral characteristics are the key to future land management; however, they still require field measurement and an agrochemical laboratory for the calibration of the soil property model. Visible and near-infrared diffuse reflectance spectroscopy has proven to be a rapid and effective method. This study aimed to assess the suitability of multispectral data acquired with the agricultural digital camera in determining soil properties. This 3.2-Mpx camera captures images in three spectral bands – green, red and near-infrared. First, the reference data were collected, which consist of 151 samples that were later examined in the laboratory to specify the granulometric composition and to quantify some chemical elements. Second, additional soil properties such as cation exchange capacity, organic carbon and soil pH were measured. Finally, the agricultural digital camera photograph was taken for every soil sample. Reflectance values in three available spectra bands were used to calculate the spectra indices. The relationships between the collected data were calculated using the independent validation regression model such as Cubist and cross-validation model like partial least square in R Studio. Additionally, different types of data normalisation multiplicative scatter correction, standard normal variate, min–max normalisation, conversion into absorbance] were used. The results proved that the agricultural digital camera is suitable for soil property assessment of sand and silt, pH, K, Cu, Pb, Mn, F, cation exchange capacity and organic carbon content. Coefficient of determination varied from 0.563 (for K) to 0.986 (for soil organic carbon). Higher values were obtained with the Cubist regression model than with partial least squares.

Synthesis and Characterisation of Mg2+ and Al3+ Co-Doped CoCr2O4 Inorganic Pigments With High Near-Infrared Reflectance

A new class of near-infrared (NIR) reflectance pigments based on Co1−xMgxCr2−yAlyO4 (x = 0–1 and y = 0–2) was synthesised using the Pechini-type sol-gel process. The developed powders were characterised by thermogravimetry and differential scanning calorimetry, X-ray diffraction (XRD), ultraviolet–visible near-infrared diffuse reflectance spectroscopy, and colour Commission Internationale del'Eclairage (CIE) 1976 (L*a*b*) colour scales. The XRD patterns revealed characteristic peaks of the spinel structure with good crystallinity. Substituting Mg2+ for Co2+ ions in the tetrahedral positions and Al3+ for Cr3+ ions in the octahedral positions of CoCr2O4 reduces the cost and changes the colour of the pigment (green to yellow and then blue). Moreover, the synthesised pigments exhibited high NIR solar reflectance in the 780–2,500 nm wavelength range. The thermal and chemical stability of the pigments was also studied. Our findings demonstrate the potential for applying these pigments in cool colourants.

Analysis of Human Exercise Health Monitoring Data of Smart Bracelet Based on Machine Learning.

The smart bracelet has become a hot-selling commodity, according to a daily consumption survey. Based on people's interest and concern for their health, the smart bracelet, as a design and application for achieving healthy weight loss monitoring, is quickly becoming a popular new favorite. This bracelet detects fat using the near-infrared diffuse reflection principle, with the goal of assisting people in controlling and maintaining a healthy weight. A large amount of data has been accumulated in all walks of life due to the development of the Internet network and data storage technology. As a result, the emergence of machine learning plays a critical role in the data analysis of human sports health monitoring of smart bracelets. Based on machine learning, this paper investigates the data analysis of human sports health monitoring smart bracelets. When the population index reaches 50 in the analysis of health monitoring data, the average accuracy of data mining is 86.8 percent, the average accuracy of the association rule algorithm is 85.9 percent, the average accuracy of the collaborative filtering algorithm is 84.3 percent, and the average accuracy of the machine learning algorithm is 90.1 percent in this paper. Among the four algorithms, the method presented in this paper is clearly the most effective, stable, and accurate. The system's stability and accuracy have been greatly improved by the addition of GPS-assisted and hand-up misjudgment algorithms. Because the smart bracelet is inexpensive, easy to wear, and consistent with consumer psychology, it is becoming increasingly popular to use it to monitor the human body's sports health.

Proximal sensor data fusion for tropical soil property prediction: Soil fertility properties

Proximal sensors have proven capable of predicting multiple soil properties under different conditions. However, doubts remain about which sensor is preferable for delivering optimal prediction models and which preprocessing methods produce the most accurate results. Portable X-ray fluorescence (pXRF) spectrometry and visible near-infrared (Vis-NIR) diffuse reflectance spectroscopy have been widely used, while the NixProTM color sensor has been explored more recently. This study evaluated the use of pXRF, Vis-NIR, and NixProTM data to predict soil organic matter content (SOM), pH, base saturation (BS), the sum of bases (SB), cation exchange capacity (CEC) at pH = 7 and effective CEC (eCEC), via each sensor in isolation, and via combined sensors data. Moreover, factors interfering in the prediction models' accuracy (data preprocessing methods, soil horizon, soil class, parent material) were used as auxiliary variables. 604 soil samples were collected in Brazil, encompassing ten soil orders and 19 parent materials. Numerical and categorical prediction models (7,980) were created for six soil properties using a random forest algorithm, totaling 7980 models, delivering almost 24,000 results., Coefficient of determination (R2), root mean square error (RMSE), mean absolute error (MAE), and residual prediction deviation (RPD) were used for validation of numerical predictions., Overall accuracy and kappa coefficient were calcualted for categorical predictions. Although the combination of sensors provided most of the best predictions, pXRF in isolation achieved accuracies close to the three sensors combined. NixProTM offered superior contributions to SOM and CEC predictions, but pXRF and Vis-NIR were responsible for the best results of most studied variables. On average, by adding pXRF to Vis-NIR data, predictive accuracy improved 32%; while adding Vis-NIR to pXRF data increased accuracy by ca. 6%. Soil-order-specific models improved predictions for Ultisols compared to general models (without soil order distinction), reaching R2 > 0.90. Soil parent material and horizon did not improve models significantly. Categorical predictions improved the accuracy for some properties, reaching an overall accuracy of 100% and kappa index of 1.0 for pH in A horizons of Ultisols via pXRF + Vis-NIR data. Proximal sensor data with no auxiliary variables provided almost all the best results. The fusion of proximal sensors can provide better predictions, but pXRF alone can deliver satisfactory results in most cases for the six soil properties.

Nondestructive determination of SSC in an apple by using a portable near-infrared spectroscopy system

The soluble solids content (SSC) is an important factor in the internal quality detection of apples. It is essential to have reliable and high-speed measurement of the SSC. However, almost all traditional equipment is inconvenient and expensive. We designed a handheld nondestructive SSC detector based on near-infrared (NIR) spectroscopy, which is composed of a portable NIR spectrometer, cloud server, smartphone app, and prediction model of SSC. We preprocessed the spectrum with multiplicative scatter correction (MSC), standard normal variable transformation (SNV), and Savitzky-Golay (S-G) smoothing algorithms. Besides, the linear weight reduction of the particle swarm optimization algorithm is carried out, and we establish the model of an extreme learning machine optimized with the improved particle swarm optimization (IPSO-ELM) algorithm. The R2, root mean square error of prediction (RMSEP), and residual prediction deviation (RPD) of the model are 0.993, 0.0155, and 11.6, respectively, which are better than the traditional model obviously. In addition, the number of wavelengths reduced from 228 to 70 as the model is simplified with the uninformative variable elimination (UVE) method. The time of training is reduced by 29.30% compared with the original spectrum. It can be verified that the IPSO-ELM model has good prediction performance, and the NIR diffuse reflectance spectroscopy is a reliable nondestructive measurement of SSC in apples.

Nondestructive Characterization of Citrus Fruit by near-Infrared Diffuse Reflectance Spectroscopy (NIRDRS) with Principal Component Analysis (PCA) and Fisher Linear Discriminant Analysis (FLDA)

The nondestructive characterization of citrus varieties (Egyptian sweet orange, Lane Late navel orange, Australian orange, and Blood orange) was developed based on near-infrared diffuse reflectance spectroscopy (NIRDRS) together with principal component analysis (PCA) and Fisher linear discriminant analysis (FLDA). An experiment for the penetration of NIRDRS into the peel was designed and the effects of different spectral acquisition points were investigated. Pretreatments were used to eliminate the spectral interferences. As an unsupervised pattern recognition method, PCA was used to establish the characterization models. Furthermore, supervised pattern recognition based on PCA and FLDA was employed to enhance the accuracy. The results of the penetration experiments show that near-infrared light enters the citrus peel and is able to characterize the internal composition. Even with the optimized spectral pretreatment, accurate characterization of citrus varieties was not achieved by PCA. However, the accurate characterization of citrus varieties was provided by PCA-FLDA. The accuracies of four spectral acquisition points are 95%, while the characterization accuracies of six spectral acquisition points are 100% combined with optimized spectral pretreatment. Therefore, NIRDRS with PCA-FLDA is suitable for the rapid and nondestructive characterization of citrus varieties.

Etruscan Fine Ware Pottery: Near-Infrared (NIR) Spectroscopy as a Tool for the Investigation of Clay Firing Temperature and Atmosphere

Fine ware pottery from the Etruscan town of Tarquinia, whose necropolis in inscribed in the list of UNESCO sites, was studied by means of near-infrared (NIR) diffuse reflection spectroscopy. The aim was to investigate the correlation between the firing conditions of the illitic-calcareous local clay, in terms of temperature and atmosphere, and the physical properties of the ceramic paste, usually exploited by the archaeologists for a classification of pottery sherds. For comparison, analytical data related to the mineralogical composition of the samples were obtained by X-ray diffraction and Fourier-transform infrared (FTIR) spectroscopy. Spectroscopic data were elaborated by methods of multivariate analysis.

Accurate nondestructive prediction of soluble solids content in citrus by near‐infrared diffuse reflectance spectroscopy with characteristic variable selection

This study employs a near-infrared diffuse reflectance spectroscopy (NIRDRS) system to accurate nondestructive determine citrus soluble solids content (SSC). The penetration experiment results showed that the interference of thick peel is large and NIRDRS light has the ability to penetrate the peel to a certain extent. Partial least squares with different characteristic variable selection methods were used to establish the quantitative model of SSC. The results demonstrated that characteristic variable selection methods can select targeted characteristic variables and improve the accuracy with few variables. Monte Carlo-uninformative variable elimination method was selected as the optimal prediction performance. In the best prediction model, the correlation coefficient and root mean square error of prediction of the prediction set are 0.854 and 0.7%Brix, respectively, while the variable number decreases to 440 from 1557. Furthermore, the models using the average spectra of four points on the equator are the most appropriate. Novelty impact statement The penetrating ability of near-infrared diffuse reflectance spectroscopy (NIRDRS) light to thick peel and the prediction of internal quality of citrus is still unsatisfactory with traditional partial least squares (PLS) algorithm due to the interference of thick peel. In this study, a nondestructive method for the analysis of soluble solids content (SSC) in citrus was established by NIRDRS with characteristic variable selection algorithms. The results demonstrated that NIRDRS light has the ability to penetrate the peel to a certain extent, while characteristic variable selection methods can select targeted characteristic variables and improve the accuracy of quantitative analysis models with fewer variables.

On-Line Monitoring of the Tobacco Leaf Composition during Flue-Curing by Near-Infrared Spectroscopy and Deep Transfer Learning

The yield, quality, and output value of tobacco leaves are strongly affected by the flue-curing conditions. To effectively control the flue-curing and guarantee quality, it is necessary to quantify the chemical composition of tobacco leaves and provide timely feedback during this process. Therefore, the practicability of on-line monitoring of moisture, starch, protein, and soluble sugars for tobacco leaves by near-infrared (NIR) spectroscopy and deep transfer learning was explored. The results showed that the use of an NIR spectrometer equipped with a fiber-optic probe with a deep learning algorithm accurately predicted the content of these components during the curing process. The convolutional neural networks model showed greater potential for on-line monitoring than partial least squares and support vector machines. Furthermore, a network-based deep transfer learning strategy was crafted to include seasonal and temperature variability to accurately predict samples from a new harvest season in a curing barn. The overall studies indicated the efficacy of NIR diffuse reflectance spectroscopy as a rapid and nondestructive method for on-line and simultaneous determination of moisture, starch, protein, and soluble sugars in the flue-curing process to assist in making decisions.

Variation of properties of two contrasting Oxisols enhanced by pXRF and Vis-NIR

Oxisols are generally deep, weathered-leached soils that present morphologically homogeneous profiles. Despite their apparent homogeneity, different parent materials and pedogenetic processes grant these soils diverse chemical and mineralogical attributes. Proximal sensors might help to detect the variability of soil attributes along such old and deep profiles. The objective of this study was to investigate the physical, chemical and mineralogical variability of Oxisol profiles originated from different parent materials with aid of visible and near-infrared diffuse reflectance spectroscopy (Vis-NIR DRS) and portable X-ray fluorescence (pXRF) spectrometry, in order to evaluate if these proximal sensors can complement the analysis of these deep and weathered tropical soils. Two Oxisol profiles were selected: Anionic Acrudox (AA) and Typic Hapludox (TH). One hundred samples were collected in each profile down to 2 m of depth, following a grid of 10 × 10 cm, for pXRF, Vis-NIR and XRD analyses. Vis-NIR DRS spectra provided key mineralogical information in agreement with X-ray diffraction results, showing differential occurrence of kaolinite, hematite, maghemite and gibbsite/kaolinite ratio in these profiles. PXRF detected high chemical variability across the profiles and allowed to map the spatial chemical distribution of both soils. Proximal sensors provided an inexpensive and efficient way to help complement the identification of meaningful variability across Oxisol profiles that remained even after the long formation process of these very weathered tropical soils.