AbstractThe felting behavior of wool fibers is found to be correlated with their flocculation properties. The interaction between the fibers is suggested as the common factor responsible for this correlation. It is observed that in a felting medium there is attraction between natural wool fibers. Such attraction is observed to be greatly diminished, or absent, after the wool has been shrinkproffed by any one of several chemical modification treatments. Hydrophobic attraction and electrostatic repulsion are proposed as significant components of the interaction between fibers in aqueous media. These components are linked to the surface chemistry of natural and chemically modified wool. It is proposed that the hydrophobic nature of the fiber surface promotes the felting shrinkage of natural wool fabrics, that shrink‐resist chemical treatments of wool top make the fiber surface more hydrophilic and may increase the electrostatic repulsion between fibers, and that the influence of surfactants on felting depends on the adsorption energy of the surfactant at the fiber surface. These ideas are presented as a guide for the development of further shrink‐resist chemical modifications of wool.
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