National Metrology Institutes Research Articles

Case studies for the MATHMET Quality Management System at VSL, the Dutch National Metrology Institute

The European Metrology Network MATHMET is a network in which a large number of European national metrology institutes combine their forces in the area of mathematics and statistics applied to metrological problems. One underlying principle of such a cooperation is to have a common understanding of the ‘quality’ of software, data and guidelines. To this purpose a flexible, lightweight Quality Management System (QMS), also referred to as Quality Assessment Tools (QAT), is under development by the EMN. In this contribution the application of the QMS to several use cases of different nature by VSL is presented. The benefits and usefulness of the current version of the QMS are discussed from the particular viewpoint of a particular employee of VSL, and an outlook for possible future extensions and usage of the QMS is given.

Primary microvibration standards down to 10−3 m s−2 at low frequency

The reliability of microvibration measurements is important in some applications, such as infrastructure health monitoring. Thus, it is necessary to develop a vibration standard based on ISO16063-11 for microvibrations. In this study, the low-frequency standard vibration calibration system in the National Metrology Institute of Japan was upgraded to be compatible with small input vibrations down to an amplitude of 10−3 m s−2. A low-noise reference vibration measurement system and a precise signal processing method were integrated to reduce the background noise contribution, which is a dominant uncertainty source in the field of microvibration calibration. The developed system could calibrate the sensitivity of a low-noise accelerometer down to 10−3 m s−2, between 0.1 Hz and 100 Hz. This paper reports the calibration demonstration using a servo accelerometer and the evaluated uncertainty budget. The estimated calibration uncertainty was 0.1% for a normal calibration process with an excitation of 10 m s−2, and it was 2.1% for a microvibration calibration process with an excitation of 10−3 m s−2.

Reference material development for detection of human respiratory syncytial virus using digital PCR.

Nucleic acid testing is a powerful tool for the detection of various pathogens. Respiratory syncytial virus (RSV) is a major cause of acute respiratory infection, especially in young children and infants. To improve the confidence and reliability of nucleic acid testing results for RSV, reference materials (RMs) of both type A and B of RSV were developed by the National Institute of Metrology, China, code numbers NIM-RM 4057 and 4058. The reference material was composed of in vitro transcribed RNA containing the nucleocapsid (N) gene, matrix (M) gene, and partial polymerase (L) gene of RSV. A duplex reverse transcription digital PCR method was established with limit of blank (LoB), limit of detection (LoD) and limit of quantification (LoQ) of 2, 5, and 23 copies per reaction for RSV-A and 4, 8, and 20 copies per reaction for RSV-B. The certified value and expanded uncertainty (U, k = 2) of the two RMs were determined to be (6.1 ± 1.4) × 104 copies/μL for RSV-A and (5.3 ± 1.2) × 104 copies/μL for RSV-B. The developed RMs can be used as standards to evaluate the performance of RSV detection assays.

Binary Organic Solar Cells with 19.2% Efficiency Enabled by Solid Additive.

Morphology optimization is critical for achieving high efficiency and stable bulk-heterojunction (BHJ) organic solar cells (OSCs). Herein, we propose the use of 3,5-dichlorobromobenzene (DCBB) with high volatility and low cost to manipulate evolution of the BHJ morphology and improve the operability and photostability of OSCs. Systematic simulations reveal the charge distribution of DCBB and its non-covalent interaction with the active layer materials. The addition of DCBB can effectively tune the aggregation of PBQx-TF:eC9-2Cl during film formation, resulting in a favorable phase separation and a reinforced molecular packing. As a result, we obtain a power conversion efficiency (PCE) of 19.2% (certified as 19.0% by the National Institute of Metrology) for DCBB-processed PBQx-TF:eC9-2Cl-based OSCs, which is the highest reported value for binary OSCs. Importantly, the DCBB-processed devices exhibit superior photostability and have thus considerable application potential in the printing of large-area devices, demonstrating outstanding universality in various BHJ systems. Our study provides a facile approach to control the BHJ morphology and enhance the photovoltaic performance of OSCs. This article is protected by copyright. All rights reserved.

Production of a reference material for seawater pHT measurements by a National Metrology Institute

Measurements of seawater pH on the total scale, noted pHT, contribute to the assessment of ocean acidification and its impact on the marine environment if a sufficient data quality is achieved. In order to achieve this, reference materials known as TRIS buffers (equimolal buffer of 2-Amino-2-(hydroxymethyl)-1,3-propanediol (TRIS) and TRIS hydrochloride (TRIS.HCl) in artificial seawater of salinity 35) have been developed and commercialised in the last decades. This paper describes, for the first time, the production of this reference material according to the ISO guide 35 and ISO standard 17034 guidelines that includes a thorough uncertainty budget evaluation carried out following the Guide to the expression of Uncertainty in Measurement (GUM). Characterization with Harned Cells at three temperatures as well as homogeneity and long-term stability assessments were performed and taken into account in the final uncertainty budget. The global standard uncertainty budget of the produced reference material for seawater pHT measurements is of 0.0025, 0.0024 and 0.0022 at, respectively, 15 °C, 25 °C and 30 °C for a shelf life of six months. The level of uncertainty obtained meets the requirements of the “climate” quality objective requested by the Global Ocean Acidification Observing Network (GOA-ON) for the monitoring of ocean acidification.

Intercomparison of bidirectional reflectance distribution function measurements at in- and out-of-plane geometries.

In recent years, there has been a growing interest in the measurements of the bidirectional reflectance distribution function (BRDF) in industry and research and development. However, there is currently no dedicated key comparison to demonstrate the scale conformity. To date, scale conformity has been proved only for classical in-plane geometries, in comparisons between different national metrology institutes (NMIs) and designated institutes (DIs). This study aims at expanding that with nonclassical geometries, including, for the first time, to the best of our knowledge, two out-of-plane geometries. A total of four NMIs and two DIs participated in a scale comparison of the BRDF measurements of three achromatic samples at 550 nm in five measurement geometries. The realization of the scale of BRDF is a well-understood procedure, as explained in this paper, but the comparison of the measured values presents slight inconsistencies in some geometries, most likely due to the underestimation of measurement uncertainties. This underestimation was revealed and indirectly quantified using the Mandel-Paule method, which provides the interlaboratory uncertainty. The results from the presented comparison allow the present state of the BRDF scale realization to be evaluated, not only for classical in-plane geometries, but also for out-of-plane geometries.

Mathematical modelling of metrological traceability chains

Metrological traceability is a property of the measurement result and requires an established multi-level calibration hierarchy. The metrological traceability chain is established through the calibration hierarchy and is used to establish the metrological traceability of the measurement result. Approaches to the establishment of metrological traceability chains are based mainly on graphic images.
 Special international guidelines and European recommendations on the measurement uncertainty are used to evaluate the measurement uncertainty during the calibration of measuring instruments. The measurement uncertainty necessarily increases along the calibration sequence and is different for different levels of the metrological traceability chain. The measurement uncertainty depends on measurement standards or measuring instruments used during calibration.
 A mathematical model of the metrological traceability chain for different levels of the calibration hierarchy is proposed. This model includes, as components, such basic metrological characteristics for a certain level of the chain as the measurement range, measurement uncertainty, measuring instrument or measurement standard. As additional parameters for the metrological traceability chain, it is proposed to use data from the calibration certificate of the corresponding measuring instrument or measurement standard used at a certain level of the chain.
 Recommendations regarding practical application of the developed mathematical model of the metrological traceability chain, which can be used for chains of any measurements, are proposed. They can be used to establish the required metrological characteristics for a certain level of the metrological traceability chain. Such a model and recommendations for its practical application can be used in national metrology institutes and calibration laboratories.

Comprehensive understanding of fluorination-performance relationship: The best-performed A-D-A-type acceptors

Acceptor-donor-acceptor (A-D-A)-type nonfullerene acceptors (NFAs) have contributed to an efficiency breakthrough in organic solar cells (OSCs). However, the absence of an in-depth understanding of how to achieve high charge generation probability while guaranteeing low energy loss by molecular design has caused the stagnation of power conversion efficiency (PCE) in A-D-A-type acceptors. The fluorination strategy, as an effective approach to regulating molecular photoelectric and aggregation properties, can significantly affect device performance in OSCs. However, a comprehensive understanding of the relationship between fluorination and photovoltaic performance has been scarcely investigated thus far. Herein, a series of A-D-A-type acceptors, named ZITI-N-nF (n = 2, 4, 6, 8, representing the number of fluorine atoms), were designed and synthesized to reveal the underlying work mechanism of OSCs with low energy loss and efficient charge generation via fine-tuning of the charge-transfer state. The results indicate that ZITI-N-6F-based devices exhibit impressive charge generation probability with low energy loss (Eloss) because of the reduced nonradiative recombination, thus leading to a high PCE of 16.11% in binary OSCs and a PCE of 17.09% in ternary OSCs. Notably, a PCE of 16.6% was verified by the National Institute of Metrology, China, which is the highest certified PCE among OSCs based on A-D-A-type NFAs.

On the way to SI traceable primary transfer standards for amount of substance measurements in inorganic chemical analysis

During its 25 years of existence, the Inorganic Analysis Working Group of the Consultative Committee for Amount of Substance: Metrology in Chemistry and Biology (CCQM IAWG) has achieved much in establishing comparability of measurement results. Impressive work has been done on comparison exercises related to real-world problems in fields such as ecology, food, or health. In more recent attempts, measurements and comparisons were focused on calibration solutions which are the basis of most inorganic chemical measurements. This contribution deals with the question of how to achieve full and transparent SI traceability for the values carried by such solutions. Within this framework, the use of classical primary methods (CPMs) is compared to the use of a primary difference method (PDM). PDM is a method with a dual character, namely a metrological method with a primary character, based on the bundling of many measurement methods for individual impurities, which lead to materials with certified content of the main component. As in classical methods, where small corrections for interferences are accepted, in PDM, many small corrections are bundled. In contrast to classical methods, the PDM is universally applicable to all elements in principle. Both approaches can be used to certify the purity (expressed as mass fraction of the main element) of a high-purity material. This is where the metrological need of National Metrology Institutes (NMIs) for analytical methods meet the challenges of analytical methods. In terms of methods, glow discharge mass spectrometry (GMDS) with sufficient uncertainties for sufficiently small impurity contents is particularly noteworthy for the certification of primary transfer standards (PTS), and isotope dilution mass spectrometry (IDMS), which particularly benefits from PTS (back-spikes) with small uncertainties, is particularly noteworthy for the application. The corresponding relative uncertainty which can be achieved using the PDM is very low (< 10−4). Acting as PTS, they represent the link between the material aspect of the primary calibration solutions and the immaterial world of the International System of Units (SI). The underlying concepts are discussed, the current status of implementation is summarised, and a roadmap of the necessary future activities in inorganic analytical chemistry is sketched. It has to be noted that smaller measurement uncertainties of the purity of high-purity materials not only have a positive effect on chemical measurements, but also trigger new developments and findings in other disciplines such as thermometry or materials science.Graphical Primary Transfer Standards (PTSs) are the link between the immaterial world of the International System of Units (SI) and the material aspects of the primary calibration solutions.

Experimental and Monte Carlo-based determination of magnetic field correction factors in high-energy photon fields for two ionization chambers.

The integration of magnetic resonance tomography into clinical linear accelerators provides high-contrast, real-time imaging during treatment and facilitates online-adaptive workflows in radiation therapy treatments. The associated magnetic field also bends the trajectories of charged particles via the Lorentz force, which may alter the dose distribution in a patient or a phantom and affects the dose response of dosimetry detectors. To perform an experimental and Monte Carlo-based determination of correction factors , which correct the response of ion chambers in the presence of external magnetic fields in high-energy photonfields. The response variation of two different types of ion chambers (Sun Nuclear SNC125c and SNC600c) in strong external magnetic fields was investigated experimentally and by Monte Carlo simulations. The experimental data were acquired at the German National Metrology Institute, PTB, using a clinical linear accelerator with a nominal photon energy of 6 MV and an external electromagnet capable of generating magnetic flux densities of up to 1.5 T in opposite directions. The Monte Carlo simulation geometries corresponded to the experimental setup and additionally to the reference conditions of IAEA TRS-398. For the latter, the Monte Carlo simulations were performed with two different photon spectra: the 6 MV spectrum of the linear accelerator used for the experimental data acquisition and a 7MV spectrum of a commercial MRI-linear accelerator. In each simulation geometry, three different orientations of the external magnetic field, the beam direction and the chamber orientation were investigated. Good agreement was achieved between Monte Carlo simulations and measurements with the SNC125c and SNC600c ionization chambers, with a mean deviation of 0.3% and 0.6%, respectively. The magnitude of the correction factor strongly depends on the chamber volume and on the orientation of the chamber axis relative to the external magnetic field and the beam directions. It is greater for the SNC600c chamber with a volume of 0.6cm3 than for the SNC125c chamber with a volume of 0.1 cm3 . When the magnetic field direction and the chamber axis coincide, and they are perpendicular to the beam direction, the ion chambers exhibit a calculated overresponse of less than 0.7(6)% (SNC600c) and 0.3(4)% (SNC125c) at 1.5 T and less than 0.3(0)% (SNC600c) and 0.1(3)% (SNC125c) for 0.35 T for nominal beam energies of 6 MV and 7MV. This chamber orientation should be preferred, as may increase significantly in other chamber orientations. Due to the special geometry of the guard ring, no dead-volume effects have been observed in any orientation studied. The results show an intra-type variation of 0.17% and 0.07% standard uncertainty (k=1) for the SNC125c and SNC600c, respectively. Magnetic field correction factors for two different ion chambers and for typical clinical photon beam qualities were presented and compared with the few data existing in the literature. The correction factors may be applied in clinical reference dosimetry for existing MRI-linearaccelerators.

Development and application of absorbed dose primary standard for 60Co and high-energy photon beams using water calorimetry

Several new glass vessels, thermistor probes, and water phantoms have been designed and built at the National Institute of Metrology (China) to upgrade and develop the existing water calorimeter. The increased plane-parallel vessels have shorter thermal stability times and shallower positioning depths (∼1.3 cm) than the previous cylindrical vessels, which makes them suitable for electron beams. The sensitivity of the new probes is 10% greater than the previous ones. In this study, detailed experimental and theoretical investigations of various factors affecting the new water calorimeter are performed. The system uncertainty of the water calorimeter is reduced and the robustness of the determination of the absorbed-dose-to-water D w is improved using a variety of geometric detector vessels and two kinds of high-purity water systems saturated with high-purity gases. This new calorimeter is employed as a primary standard for determining the D w, has achieved a combined standard uncertainty of 0.24% for a 60Co beam, 0.27% for 6 MV and 10 MV photon beams and 0.30% for a 25 MV photon beam. The beam quality conversion factors kQ of ten cylindrical and three plane-parallel ionization chambers are measured using the new calorimeter to improve the reference dosimetry accuracy of high-energy clinical photon beams.

International Interlaboratory Comparison of Thermogravimetric Analysis of Graphene-Related Two-Dimensional Materials

Research on graphene-related two-dimensional (2D) materials (GR2Ms) in recent years is strongly moving from academia to industrial sectors with many new developed products and devices on the market. Characterization and quality control of the GR2Ms and their properties are critical for growing industrial translation, which requires the development of appropriate and reliable analytical methods. These challenges are recognized by International Organization for Standardization (ISO 229) and International Electrotechnical Commission (IEC 113) committees to facilitate the development of these methods and standards which are currently in progress. Toward these efforts, the aim of this study was to perform an international interlaboratory comparison (ILC), conducted under Versailles Project on Advanced Materials and Standards (VAMAS) Technical Working Area (TWA) 41 "Graphene and Related 2D Materials" to evaluate the performance (reproducibility and confidence) of the thermogravimetric analysis (TGA) method as a potential new method for chemical characterization of GR2Ms. Three different types of representative and industrially manufactured GR2Ms samples, namely, pristine few-layer graphene (FLG), graphene oxide (GO), and reduced graphene oxide (rGO), were used and supplied to ILC participants to complete the study. The TGA method performance was evaluated by a series of measurements of selected parameters of the chemical and physical properties of these GR2Ms including the number of mass loss steps, thermal stability, temperature of maximum mass change rate (Tp) for each decomposition step, and the mass contents (%) of moisture, oxygen groups, carbon, and impurities (organic and non-combustible residue). TGA measurements determining these parameters were performed using the provided optimized TGA protocol on the same GR2Ms by 12 participants across academia, industry stakeholders, and national metrology institutes. This paper presents these results with corresponding statistical analysis showing low standard deviation and statistical conformity across all participants that confirm that the TGA method can be satisfactorily used for characterization of these parameters and the chemical characterization and quality control of GR2Ms. The common measurement uncertainty for each parameter, key contribution factors were identified with explanations and recommendations for their elimination and improvements toward their implementation for the development of the ISO/IEC standard for chemical characterization of GR2Ms.

Detection of inferior myocardial infarction based on multi branch hybrid network

Background and ObjectivesEarly and accurate detection of inferior myocardial infarction (IMI) is important for reducing the risk of mortality from a heart attack. Although previous work has demonstrated IMI detection, the differences among patients have been ignored. Most models display excellent performance in the intra-patient scheme, but the inter-patient test results are not ideal. The present paper proposes a model based on densely connected convolutional and gated recursive unit (GRU) networks to enhance the generalization ability of the model. MethodsFirstly, the data of multi-lead beat in series is used with GRU, to obtain more inter-lead and intra-lead time correlation information. This correlation information is scientific and significant for IMI detection. Secondly, the proposed model retains both deep and shallow features of ECG through DenseNet, which include more detailed information of IMI. Finally, through the feature connection, the multi-dimensional features enrich the description of ECG signals, and help the network learn more essential characteristics of IMI, so as to enhance the generalization ability of the model. ResultsThe proposed method was verified by the PTB diagnostic database of the German National Metrology Institute. The generalization ability of the model was tested by intra-patient and inter-patient schemes. After 5-fold cross-validation, the average accuracy, sensitivity and specificity were 99.95%, 99.94% and 99.96% in the intra-patient scheme respectively. Furthermore, these parameters were 88.68%, 90.33% and 87.04% in the inter-patient scheme. ConclusionsThe experimental results show that the model displays good generalization ability, which has important clinical significance.

Evaluation of the long-term stability of arsenic species in certified reference materials: certification of arsenobetaine, As(V), and dimethylarsinic acid in NMIJ CRMs 7901-a, 7912-a, and 7913-a.

The long-term stabilities of arsenobetaine (AsB), arsenate (As(V)), and dimethylarsinic acid (DMA), which are arsenic (As) compounds in certified reference materials (CRMs), namely, NMIJ CRMs 7901-a, 7912-a, and 7913-a, were monitored. The CRMs were developed and certified by the National Metrology Institute of Japan (NMIJ) and the National Institute of Advanced Industrial Science and Technology (AIST) in 2009 to prepare a calibrant for the speciation analysis of As species. The CRMs were prepared from high-purity reagent powders as raw materials, and each reagent was dissolved in water or diluted acid. The certification of the CRMs for AsB, As(V), and DMA was conducted by NMIJ. The concentration of total As was determined by more than three independent analytical techniques. Then, the obtained As concentrations were converted into the concentration of each chemical species, and the mass fractions of each certified value were certificated. The long-term stability of As species in the CRMs under storage was performed by liquid chromatography-inductively coupled plasma-mass spectrometry, and this report presents data on long-term stability that occurred approximately 13years. The obtained monitoring results were evaluated using both measurement results with uncertainty and a statistical parameter method, complying with ISO Guide 35. According to the results, the long-term stability of all mass fractions was confirmed.

Value assignment and uncertainty evaluation for anion and single-element reference solutions incorporating historical information.

The National Institute of Standards and Technology, which is the national metrology institute of the USA, assigns certified values to the mass fractions of individual elements in single-element solutions, and to the mass fractions of anions in anion solutions, based on gravimetric preparations and instrumental methods of analysis. The instrumental method currently is high-performance inductively coupled plasma optical emission spectroscopy for the single-element solutions, and ion chromatography for the anion solutions. The uncertainty associated with each certified value comprises method-specific components, a component reflecting potential long-term instability that may affect the certified mass fraction during the useful lifetime of the solutions, and a component from between-method differences. Lately, the latter has been evaluated based only on the measurement results for the reference material being certified. The new procedure described in this contribution blends historical information about between-method differences for similar solutions produced previously, with the between-method difference observed when a new material is characterized. This blending procedure is justified because, with only rare exceptions, the same preparation and measurement methods have been used historically: in the course of almost 40 years for the preparation methods, and of 20 years for the instrumental methods. Also, the certified values of mass fraction, and the associated uncertainties, have been very similar, and the chemistry of the solutions also is closely comparable within each series of materials. If the new procedure will be applied to future SRM lots of single-element or anion solutions routinely, then it is expected that it will yield relative expanded uncertainties that are about 20 % smaller than the procedure for uncertainty evaluation currently in use, and that it will do so for the large majority of the solutions. However, more consequential than any reduction in uncertainty, is the improvement in the quality of the uncertainty evaluations that derives from incorporating the rich historical information about between-method differences and about the stability of the solutions over their expected lifetimes. The particular values listed for several existing SRMs are given merely as retrospective illustrations of the application of the new method, not to suggest that the certified values or their associated uncertainties should be revised.

Characterization of the LED filament lamp for luminous intensity calibration

Light-emitting diode (LED) is now the main type of light source in global lighting marketing. However, traditional photometry with the incandescent standard lamp is not sufficient to implement high-level LED photometric measurement, since a considerable spectral mismatch error may exist if the photometer has a large general V(λ) mismatch index . The LED standard lamp is proposed to be the complementary transfer standard for photometry to reduce this measurement uncertainty. National Institute of Metrology, China (NIM) has previously reported a type of LED filament lamp for total luminous flux. In this article, NIM demonstrates another type of LED filament lamp for luminous intensity calibration. The LED filaments are sealed in a T90 cylinder glass bulb as emitters, and have a spectrum similar to the reference white LED spectrum considered in Commission on Illumination technical committee 2–90. The LED lamp uses the E27 screw base as the connector, and is compatible with the traditional alignment approaches. The warm-up time is less than 12 min. The output change of a group of 12 lamps, over nearly two years of storage and 1 h operation every day during the whole long-term test, is found to be ±0.2% or less for most of the lamps. The ageing effect of one lamp over a continuous 6500 h of burning is estimated to be −0.014% per 100 h, and it is significantly lower than 1% per 100 h, the typical drift rate of the traditional incandescent luminous intensity lamp. In the aspect of the coincidence with inverse square law, the LED lamp has a similar performance to the WI41/G lamp, the traditional luminous intensity lamp.

Development of a glucose reference material in human serum for clinical assay standardization

BackgroundBlood glucose is an important monosaccharide functioning as the main source of energy for the human body. The accurate measurement of blood glucose is crucial for the screening, diagnosis, and monitoring of diabetes and diabetes-associated diseases. To assure the reliability and traceability of blood glucose measurements, we developed a reference material (RM) for use in human serum at two different concentrations, which were certified by the National Institute of Metrology (NIM) as GBW(E)091040 and GBW(E)091043. MethodsRaw serum samples were collected from residual samples after clinical testing, filtered, and repackaged under mild stirring. The homogeneity and stability of the samples were examined according to ISO Guide 35: 2017. Commutability was evaluated in compliance with CLSI EP30-A. Value assignment was carried out in six certified reference laboratories using the JCTLM-listed reference method for serum glucose. Moreover, the RMs was further applied in a trueness verification program. ResultsThe developed RMs was homogeneous and commutable enough for clinical use. They were also stable for 24 h at 2–8 ℃ or 20–25 ℃ and for at least 4 years at − 70 ℃. The certified values were 5.20 ± 0.18 mmol/L and 8.18 ± 0.19 mmol/L (k = 2) for GBW(E)091040 and GBW(E)091043, respectively. The pass rates were evaluated by bias, coefficient of variation (CV), and total error (TE) for 66 clinical laboratories in the trueness verification program were 57.6%, 98.5%, and 89.4% of GBW(E)091040, and 51.5%, 98.5%, and 90.9% of GBW(E)091043, respectively. ConclusionThe developed RM could be used for the standardization of reference and clinical systems with satisfactory performance and traceable values, providing strong support for the accurate measurement of blood glucose.

Calibration and Validation of a Transfer Radiometer Applied to a Radiometric Benchmark Transfer Chain

A transfer radiometer (TR) applied to an on-orbit radiometric benchmark transfer chain has been developed, which can achieve the high-precision transformation of power and radiance responsivity and transmit the radiance responsivity traced to the cryogenic radiometer to remote sensors, such as an imaging spectrometer, so that the on-orbit remote sensors can achieve the high accuracy calibration of 10−3 magnitude. Radiance comparison experiments between the TR and the radiance standard of the National Institute of Metrology (NIM) were carried out to demonstrate the absolute accuracy of the TR radiance measurement. At 780.0 nm and 851.9 nm, the relative measurement uncertainties of the TR filter-free channel were 0.24% (k = 1). Additionally, the radiance measurement results of the TR were consistent with those of the NIM radiance meter, and the radiance measurement results’ relative differences between the TR and the NIM radiance meter were approximately 0.04% at 780.0 nm and 851.9 nm. The relative measurement uncertainties of TR 780.4 nm and 851.8 nm filter channels were 0.89% (k = 1) and 0.84% (k = 1), respectively. Additionally, the radiance measurement results of the TR 780.4 nm and 851.8 nm filter channels were consistent with the radiances of the integrating sphere source calibrated by the NIM at 780.4 nm and 851.8 nm; the relative differences between the radiances measured by the two TR filter channels and the radiances of the integrating sphere source itself were better than 0.56%. This proved that the TR could measure the monochromatic source radiance with a measurement uncertainty of 0.24% and measure the broadband source radiance with a measurement uncertainty better than 0.89%. The TR can be applied to the radiometric benchmark transfer chain to improve the measurement precision of on-orbit remote-sensing instruments.

A GPS-Referenced Wavelength Standard for High-Precision Displacement Interferometry at λ = 633 nm.

Since the turn of the millennium, the development and commercial availability of optical frequency combs has led to a steadily increase of worldwide installed frequency combs and a growing interest in using them for industrial-related metrology applications. Especially, GPS-referenced frequency combs often serve as a "self-calibrating" length standard for laser wavelength calibration in many national metrology institutes with uncertainties better than u = 1 × 10-11. In this contribution, the application of a He-Ne laser source permanently disciplined to a GPS-referenced frequency comb for the interferometric measurements in a nanopositioning machine with a measuring volume of 200 mm × 200 mm × 25 mm (NPMM-200) is discussed. For this purpose, the frequency stability of the GPS-referenced comb is characterized by heterodyning with a diode laser referenced to an ultrastable cavity. Based on this comparison, an uncertainty of u = 9.2 × 10-12 (τ = 8 s, k = 2) for the GPS-referenced comb has been obtained. By stabilizing a tunable He-Ne source to a single comb line, the long-term frequency stability of the comb is transferred onto our gas lasers increasing their long-term stability by three orders of magnitude. Second, short-term fluctuations-related length measurement errors were reduced to a value that falls below the nominal resolving capabilities of our interferometers (ΔL/L = 2.9 × 10-11). Both measures make the influence of frequency distortions on the interferometric length measurement within the NPMM-200 negligible. Furthermore, this approach establishes a permanent link of interferometric length measurements to an atomic clock.

Dissemination of the Acoustic Pascal: The Role and Experiences of a National Metrology Institute.

Hydrophones are pivotal measurement devices ensuring medical ultrasound acoustic exposures comply with the relevant national and international safety criteria. These devices have enabled the spatial and temporal distribution of key safety parameters to be determined in an objective and standardized way. Generally based on piezoelectric principles of operation, to convert generated voltage waveforms to acoustic pressure, they require calibration in terms of receive sensitivity, expressed in units of [Formula: see text]Pa-1. Reliable hydrophone calibration with associated uncertainties plays a key role in underpinning a measurement framework that ensures exposure measurements are comparable and traceable to internationally agreed units, irrespective of where they are carried out globally. For well over three decades, the U.K. National Physical Laboratory (NPL) has provided calibrations to the user community covering the frequency range 0.1-60 MHz, traceable to a primary realization of the acoustic pascal through optical interferometry. Typical uncertainties for sensitivity are 6%-22% (for a coverage factor k = 2), degrading with frequency. The article specifically focuses on the dissemination of the acoustic pascal through NPL's calibration services that are based on a comparison with secondary standard hydrophones previously calibrated using the NPL primary standard. The work demonstrates the stability of the employed dissemination protocols by presenting representative calibration histories on a selection of commercially available hydrophones. Results reaffirm the guidance provided within international standards for regular calibration of a hydrophone in order to underpin measurement confidence. The process by which internationally agreed realizations of the acoustic pascal are compared and validated through key comparisons (KCs) is also described.