Nanoantenna Effect Research Articles

Exciton-plasmon-photon conversion in silver nanowire: Polarization dependence

Polarization dependence of the exciton-plasmon-photon conversion in silver nanowire-quantum dots structure was investigated using a scanning confocal microscope system. We found that the fluorescence enhancement of the CdSe nanocrystals was correlated with the angle between the excitation light polarization and the silver nanowire direction. The polarization of the emission was also related with the nanowire direction. It was in majority in the direction parallel with nanowire due to the nano-antenna effect.

Plasmonic Nanofabrication by Long-Range Excitation Transfer via DNA Nanowire

Driven by the demand for ongoing integration and increased complexity of today's microelectronic circuits, smaller and smaller structures need to be fabricated with a high throughput. In contrast to serial nanofabrication techniques, based, e.g., on electron beam or scanning probe methods, optical methods allow a parallel approach and thus a high throughput. However, they rarely reach the desired resolution. One example is plasmon lithography, which is limited by the utilized plasmonic metal structures. Here we show a new approach extending plasmonic lithography with the potential for a highly parallel nanofabrication with a higher level of complexity based on nanoantenna effects combined with molecular nanowires. Thereby femtosecond laser pulse light is converted by Ag nanoparticles into a high plasmonic excitation guided along attached DNA structures. An underlying poly(methyl methacrylate) (PMMA) layer acting as an electron-sensitive resist is so structured along the former DNA position. This apparently DNA-guided effect leads to nanometer grooves reaching even micrometers away from the excited nanoparticle, representing a novel effect of long-range excitation transfer along DNA nanowires.

Terahertz sensing with carbon nanotube layers coated on silica fibers: Carrier transport versus nanoantenna effects

Carbon nanotube layers prepared as coatings on silica fibers are found to be suitable for terahertz detection in 0.5–7.3 THz range within temperatures of 4.2–70 K. In time-domain of terahertz excitation, two following constituents in the photoresponse are discriminated: the first one is attributed to the bolometric effect while the other one is related to the photoconductivity caused by the terahertz-induced hopping effect. In frequency domain, nonmonotonic behavior of the photoconductivity is associated with prevailing carbon nanotube-induced antenna effects in the electronic transport. The experimental observations are supported by theoretical estimates.

Noble Metal Nanocrystals: Plasmon Electron Transfer Photochemistry and Single-Molecule Raman Spectroscopy

The excited electronic states of noble metal Au and Ag nanocrystals are very different than those of molecules. Ag and Au nanocrystal optical transitions (plasmons) in the visible can be so intense that they significantly modify the local electromagnetic field. Also, coherent elastic Rayleigh light scattering is stronger than normal electronic absorption of photons for larger nanocrystals. These two facts make Au and Ag nanocrystals ideal nanoantennas, in that they focus incident light into the local neighborhood of subwavelength size. Surface-enhanced Raman scattering (SERS), in which the Raman scattering rate of nearby molecules increases by many orders of magnitude, is a consequence of this nanoantenna effect. Metallic nanocrystals also have no band gap; this makes them extraordinarily polarizable. Their electronic transitions sense the local environment. An extreme case is the interaction of two 30 nm Ag nanocrystals separated by a 1 nm gap. Their mutual polarization completely transforms the nature of the metallic excited electronic state. Single particles have an excited state uniformly distributed throughout the interior, while the nanocrystal dimer has its excited state localized on the metal surface in the junction. This creates an electromagnetic "hot spot" in the junction, enabling the observation of single-molecule SERS. The fact that surface molecules are typically chemisorbed and exchange electrons with the metal has interesting chemical consequences. First, the enhanced Raman intensities are controlled by quantum mechanical coupling of the molecular lowest unoccupied molecular orbital (LUMO) and highest occupied molecular orbital (HOMO) with the optically excited electrons in the metal. Second, charge-transfer photochemistry can result from metal plasmon excitation. In crystalline Ag nanocrystals the photochemistry quantum yield can be high because the nanocrystal surface dominates plasmon nonradiative relaxation. Colloidal Ag nanocrystals stabilized by sodium citrate build up a photovoltage under visible excitation, caused by irreversible "hot hole" photo-oxidation of adsorbed citrate anion. This creates a driving force for photochemical transformation of round 8 nm Ag seeds into 70 nm single-crystal disk prisms under room lights, in a novel type of light-driven Ostwald ripening.

Near-field, broadband optical spectroscopy of metamaterials

Near-field, broadband optical spectroscopy of metamaterials is reported. A compact, easy to assemble supercontinuum light source, coupled with a near-field scanning optical microscope and spectrometer provide the means to locally probe the spectral response of a nanorod metamaterial sample. Spectral maps of near-field transmittance are obtained for the spectral range from 500 to 950nm. In comparison to far-field measurement, the average of the near-field mappings shows a significant increase in transmittance. The uniqueness of the spectral maps and the increased transmittance indicates a strong nanoantenna effect between the sample and the plasmonic near-field aperture.

Enhanced transmission in near-field imaging of layered plasmonic structures

Near-field imaging of an engineered double layer structure in transmission mode has shown enhancement of light intensity through the structure. An array created by an optically thick double layer structure of a total thickness of 165 nm containing twin 50 nm Au layers was imaged using a near-field scanning optical microscope in illumination mode. The resulting transmission image shows an increased local transmission at the position of each particle in the array. This viewable enhancement is due to a nanoantenna effect that is created by a resonant plasmon oscillation between the two layers.