Incorporation Of Nanosilica Research Articles

Enhancement of Recycled Aggregate Concrete Properties Through the Incorporation of Nanosilica and Natural Fibers

This study introduces an innovative approach to enhancing recycled aggregate concrete (RAC) by incorporating nanosilica (NS) and natural fibers (NF), specifically sisal fiber (SF) and palm fiber (PF). This novel combination aims to overcome the inherent limitations of RAC, such as reduced strength and durability, while promoting sustainability in construction. The research focuses on evaluating the mechanical properties of RAC, including compressive and flexural strengths, through the integration of NS and NF. Our findings reveal that NS significantly improves the microstructure of RAC by enhancing the interface transition zone (ITZ) and filling nanovoids, resulting in a denser and more durable concrete matrix. Specifically, the addition of 3% NS increased the compressive strength of RAC by up to 22.5% and the flexural strength by up to 25.6% at a 100% replacement ratio of recycled aggregate. The addition of NF, treated to withstand the alkaline environment of concrete, further strengthens the RAC by providing a bridging effect that enhances flexural strength by up to 46.7%. This work not only advances the performance of recycled concrete but also aligns with the broader goal of environmental sustainability by utilizing waste materials and reducing the carbon footprint of concrete production. The findings have the potential to influence future construction practices, encouraging the adoption of more durable and eco-friendly building materials.

Comparative Study of Interfacial and Conventional Techniques for Nanosilica Incorporation in Natural Rubber Latex-Based Composites with Varied TEOS Content

This study investigates the preparation of natural rubber latex (NRL) composites with varying nanosilica contents of 5, 15, 30, and 45 phr, using both interfacial and conventional mixing techniques. Analysis focused on viscosity, plasticity, morphology, and FTIR spectra to evaluate the impact of these methods on composite properties. The interfacial techniquemaintained lower viscosity values, indicating better latex stability, and achieved higher silica yields and conversion rates (94 - 99%) at elevated TEOS contents. Plasticity analysis revealed that the interfacial method produced more uniform and stable plasticity values, suggesting improved resistance to oxidation and enhanced mechanical properties. SEM and FTIR analyses confirmed superior dispersion with the interfacial technique, especially at higher silica contents. These findings highlight the efficacy of the interfacial technique in optimizing the properties of NRL composites, making it a promising approach for advanced material applications. HIGHLIGHTS Analysis of interfacial and conventional mixing techniques reveals their impact on NRL composite properties, demonstrating the interfacial method's superior stability, silica dispersion, and enhanced mechanical properties. The interfacial method maintains lower, stable viscosity, prevents latex destabilization, achieves higher silica yields, and ensures economic and sustainable production of high-quality composites. SEM and FTIR analyses confirm better silica dispersion and morphology with the interfacial method, enhancing composite performance, durability, and informing industrial applications and future research directions. GRAPHICAL ABSTRACT

Mechanical properties and hydration mechanism of nano-silica modified alkali-activated thermally activated recycled cement

The recycling and reuse of waste concrete are crucial for reducing environmental pollution, minimizing resource waste, and lowering carbon emissions. However, current efforts to improve the performance of recycled cement (RC) using the synergistic effects of alkali activation and thermal activation have been suboptimal. Therefore, this study explores the influence of nano-silica (NS) incorporation on the mechanical properties and hydration mechanism of alkali-activated and thermally activated RC. The research focuses on cement mortar with a thermal activation temperature of 750°C, an RC replacement rate of 30%, and an alkali content of 6%. Various analytical techniques, including thermogravimetric analysis (TG-DTG), X-ray diffraction (XRD), and scanning electron microscopy (SEM), were used to evaluate the impact of different NS dosages (1%, 2%, 3%, and 5%) on the mechanical properties and hydration characteristics of nano-modified alkali-activated and thermally activated RC mortar. The study reveals the mechanism by which NS enhances the microstructure of alkali-activated and thermally activated RC. The experimental results show that as the NS content increases, the compressive and flexural strengths of RC initially increase and then decrease. The optimal strength was achieved with a 2% NS content, with a 31.5% increase in compressive strength compared to RC without NS. At this dosage, RC exhibited a higher hydration rate during the acceleration period of hydration. Additionally, the initial hydration heat release rate of RC increased with rising NS content. While NS incorporation did not alter the phase composition of RC, it activated the pozzolanic effect of RC, causing free active substances such as CaO and gypsum in the components to dissolve and react to form Aft at the start of the hydration reaction. The unsaturated bonds (≡Si-O- and ≡Si-) on the surface of NS absorbed Ca2⁺ and OH⁻ from the RC, promoting the hydration of C2S and C3S. However, excessive NS content (greater than 3%) led to a decline in RC strength and the formation of more cracks. This is primarily due to the excess NS particles not contributing to an increase in effective nucleation sites, causing agglomeration, an increase in large pores, and a reduction in transition and gel pores, which negatively affected the microstructure and thus reduced the mechanical properties of the RC. Our findings enhance the understanding of the role of nanomaterials in alkali-activated RC and provide valuable insights for further research into high-performance recycled cement materials.

Research on mechanical properties and microscopic mechanism of multi-based geopolymer concrete under combined action of pre-curing and nano-silica

In order to study the combined action of curing conditions and nano-silica (NS) on geopolymer concrete (GPC), the multi-based geopolymer concrete (FSSGC) was prepared with fly ash (FA), slag (SG) and steel fiber (SF), the experiments were carried out in three stages. Firstly, the mechanical properties of FSSGC was tested by monofactor analysis, with pre-curing temperature (20, 40, 60, 80, and 100 °C) and pre-curing time (6, 12, 18, 24, 30, and 36 h) as parameters. The compressive strength and splitting tensile strength initially increased and then decreased with the increase of parameters, and there was an optimal value for subsequent experimental research (80 °C and 18 h). Secondly, the effects of NS content (0, 0.5, 1.0, 1.5, and 2.0 wt%) on the mechanical properties of FSSGC under different curing conditions were analyzed. The results indicated that the mechanical properties of the FSSGC exhibited a trend of initially increasing and then decreasing with the increase of NS content, with the optimal mechanical performance observed under the combined action of high-temperature pre-curing conditions and the incorporation of NS (1.0 wt%). Thirdly, X-ray diffraction, scanning electron microscopy, image analysis, and microhardness tests had been conducted, and the results were consistent with the mechanical properties. The pre-curing temperature affected the rate of geopolymerization, while the pre-curing time influenced the degree of geopolymerization by maintaining this rate. The small particle size and high Young's modulus of the NS effectively filled pores and inhibited the propagation of microcracks. High-temperature pre-curing enhanced the nucleation effect and pozzolanic effect of NS, resulting in a combined action that formed a denser microstructure in the matrix and interfacial transition zone (ITZ).

Investigation on Flexural Behavior of HFRC with Partial Replacement of Nano Silica and Slag Cement

This investigation directs to understand the flexural behavior of Hybrid Fiber Reinforced Concrete (HFRC) with incorporation of Nano silica and Portland slag cement. The mechanical properties of Concrete for the grade M50 is enhanced by combining different fibers such as glass, polypropylene, and steel. Specifically, we explore the replacement of these fibers for the cement at ratios of 2%, 3%, 4%, 5% and 6%. Findings indicate that it significantly improved flexibility, as well as micromechanical support. To assess the performance of the HFRC, Specimens are cast to undergo compression, Flexure and Spilt tensile using hybrid materials with a water-cement ratio of 0.40 and made to undergo normal water curing for a period of 7, 14, and 28 days. Our comprehensive analysis reveals that the inclusion of 5% fibers along with 5% of Nano silica as a partial replacement to fine aggregate exhibits superior ductility and flexural strength compared to other fiber ratios. The addition of latex admixture enhances the flexural strength of HFRC. Comparing the flexural behavior of HFRC to conventional concrete under applied loads the remarkable load-bearing capabilities of HFRC beams under flexural conditions are highlighted furthermore emphasizing the advantages of this innovative material for use in construction applications. The results were tabulated and comparative results were presented.

Hybrid Effect of Metakaolin and Nano-Silica on Mechanical and Durability Parameters of Mortar

The incorporation of pozzolanic materials such as nano silica and metakaolin in cementitious materials has gained significant attention in recent years due to their potential to improve the mechanical and durability properties of cement-based composites. This thesis investigates the hybrid effect of nano silica and metakaolin on the mechanical and durability properties of cement mortar. The research work involved the preparation of cement mortar specimens with varying proportions of nano silica and metakaolin, which were then subjected to a series of mechanical and durability tests. The mechanical tests included compressive strength, while the durability tests included water absorption and elevated temperature test. The study showed that the addition of both nano silica and metakaolin to cement mortar resulted in a significant improvement in the mechanical properties of the mortar. Additionally, the hybrid effect of nano silica and metakaolin resulted in enhanced durability of the cement mortar, with a significant reduction in water absorption and improved temperature resistance. The findings of this study will have significant implications for the development of sustainable and durable cementitious materials. The use of pozzolanic materials such as nano silica and metakaolin can reduce the consumption of cement and the associated carbon footprint while also improving the durability and long-term performance of cement-based composites. Overall, this study suggests that the incorporation of nano silica and metakaolin can lead to significant improvements in the mechanical and durability properties of cement mortar, making it a promising material for use in various construction applications.

The influence of nano-silica composite superabsorbent polymer on the autogenous shrinkage of mortar

To address the diminished shrinkage reduction capacity due to high ion sensitivity of superabsorbent polymers (SAP) within cement-based materials, this study employs solution polymerization where acrylic acid and acrylamide are copolymerized with nano-silica at varying concentrations to synthesize innovative SAPs. The investigation encompasses the structural groups, microscopic morphology, liquid absorption characteristics of these SAPs, and their effect on mortar's autogenous shrinkage. The results indicate that nano-silica can be encapsulated within polyacrylate-acrylamide network via physical adsorption and chemical grafting. The incorporation of nano-silica enhances the water absorption and retention capacities of SAPs in alkaline environments. Nano-silica composite SAPs absorb sufficient internal curing water and prolong the subsequent moisture gradient-driven water release process, continuously releasing water within matrix to maintain internal humidity, thereby further enhancing the shrinkage reduction effect on mortar. Based on Scanning Electron Microscopy (SEM) observations of SAPs morphologies within mortar and X-ray Computed Tomography (X-CT) monitoring of internal curing water distribution, it is revealed that nano-silica undergoes pozzolanic reactions, forming a tightly connected domain with matrix. This facilitates continuous water release to the surrounding through capillary action, thus maintaining capillary pore liquid levels. Consequently, it effectively mitigating shrinkage stress and deformation, leading to an enhancement in shrinkage reduction effects.

Synergistic effect of nano silica and metakaolin on mechanical and microstructural properties of concrete: An approach of response surface methodology

Nano and micro materials are both effective individually in enhancing the mechanical and microstructural properties of concrete. The combination illustrates an iconic shift in material engineering to produce concrete with distinctive characteristics. In this work, the combined effect of Nano Silica (NS) and Metakaolin (MK) on the mechanical and microstructure properties were examined by conducting compressive strength, split tensile strength, and Field Emission Scanning Election Microscope (FE-SEM) with Energy-dispersive X-ray (EDX) analysis, X-ray Diffraction (XRD) spectroscopy, Fourier Transform Infra-Red (FTIR) spectroscopy, respectively. The concrete matrix was investigated by varying the concentration of NS and MK with different Water-Binder Ratio (WBR). Further, the Response Surface Methodology (RSM) technique was used to identify the complex interaction between NS (1–3 %) and MK (5–20 %) at different WBR (0.35, 0.40 and 0.45). The synergistic effect between NS and MK resulted in enhanced compressive and split tensile strengths of the concrete. The optimum mix proportion of the concrete was found to be 2 % NS and 12.5 % MK at a WBR of 0.4. The compressive strength enhancements for the optimum mix proportion were 35.75 %, 34.4 %, 33.1 %, and 32.5 %, while the split tensile strength enhancements were 26.56 %, 25.92 %, 20.95 %, and 17.8 %, respectively on the 7th, 28th, 56th, and 90th day. The RSM technique developed for all the mixes has been statistically validated to have less than 5 % of mean error. Moreover, the microstructural analysis revealed early hydration, formation of additional Calcium Silicate Hydrate (C-S-H) products, and presence of dense microstructure resulting in improved microstructural properties. The incorporation of NS and MK in the concrete changes the concrete’s configuration at the nano and micro levels, thus paving the way for the development of novel and sustainable construction materials.

Investigation on the properties of sustainable alkali-activated GGBS mortar with nano silica and dredged marine sand: Mechanical, microstructural and durability aspects

In recent years, alkali-activated mortar (AAM) has emerged as a promising alternative to ordinary Portland cement (OPC) due to concerns regarding the environmental impact resulting from cement production, which releases carbon dioxide and degrades the quality of the environment. To address these concerns, researchers have explored the addition of supplementary binder materials to enhance cement properties and mitigate pollution. The effectiveness of these binder materials depends heavily on their chemical composition and fineness. Notably, ground granulated blast furnace slag (GGBS) enhances the strength and durability of the cement. In response to the scarcity of river sand (RS), dredged marine sand (DMS) has gained popularity as a potential substitute within the civil engineering field. Furthermore, the integration of nanomaterials has shown promising improvements in the mechanical and microstructural properties of mortar. Therefore, this study aims to investigate the properties of mortar by incorporating nano silica (NS) within the range of 1% to 7%, varying the molarity from 2 M to 8 M, and substituting RS with DMS. The tests carried out encompass a range of evaluations, including compressive strength, flexural strength, SEM-EDS, XRD, UPV, RCPT, and carbonation analysis, to comprehensively assess the properties of the mortar. The study reveals that the AAM demonstrates optimal performance when 50% of RS is replaced by DMS in the absence of NS. Once this optimal point is determined, further analyses are conducted at this value while varying the concentrations of NS from 1–7%. The experimental results indicate that replacing 50% of RS with DMS and incorporating 6% NS leads to maximum compressive strength (49.2 MPa) and flexural strength (9.36 MPa) in the assessed properties. Furthermore, the incorporation of NS in GGBS-based AAM mixes enhances durability by improving resistance against chloride penetration, reducing water absorption, and minimizing carbonation diffusion. Additionally, the microstructural and mineralogical characterization of GGBS-NS-based AAM specimens demonstrates the formation of C-S-H and C-A-S-H gels as the end products of the reactions.

One-part sodium carbonate-activated slag/r-MgO based mixes: Influence of nano-silica incorporation on compressive strength and microstructural development

In this study, environment-friendly one-part alkali-activated slag-based mixes were prepared by using solid sodium carbonate as the alkali activator and incorporating reactive MgO (r-MgO) as the additive. Substitution of r-MgO in reference mixes was carried out at various levels, up to 15%, to enhance the reaction mechanism and strength development. The strength development was measured up to 56 days and analyzed microstructurally using Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric, and scanning electron microscopy analyses. Additionally, the influence of incorporating nano-silica in the binary mixes on strength development and microstructure was investigated. It was observed that the reaction mechanism could be improved by incorporating a low amount of reactive MgO, leading to expedited setting time and significant increases at both early age and final compressive strength values. Nano-silica incorporation was found to be effective in improving compressive strength at all ages, resulting in the formation of a higher matrix phase as demonstrated by microstructure tests. The highest compressive strength was attained in the nano-silica and r-MgO incorporating ternary mixes, reaching 25.9 MPa on the 3rd day and 47.2 MPa on the 28th day after production. Furthermore, the environmental impacts of the produced mixes were assessed. This study highlights the feasibility of one-part sodium carbonate-activated slag-based materials, especially with r-MgO inclusion, and underscores the role of nano-silica incorporation in enhancing strength properties.

Evaluation of mechanical strength, gamma-ray shielding characteristics, and ITZ microstructural properties of heavyweight concrete using nano-silica (SiO2) and barite aggregates

This research assessed the mechanical performance, gamma-ray shielding, and interfacial transition zone (ITZ) microstructural properties of concrete mixes that incorporate barite coarse aggregates and nanosilica. To achieve this goal, several concrete mixes containing normal coarse aggregate (NC), barite aggregate (BC), and nano-silica/barite aggregates (NSBC) were fabricated. Several properties such as workability, mechanical strength, electrical resistivity (ER), ultrasonic pulse velocity (UPV), chloride migration (RCPT), and gamma shielding were comparatively assessed for these concrete mixtures. In addition, analytical characterizations viz., x-ray diffraction (XRD), Fourier transform infrared (FTIR), scanning electronic microscopy (SEM), and energy dispersive x-ray (EDX) were employed to study the ITZ microstructure at mortar/aggregate interface of concrete mixtures. The results showed that barite concrete incorporating nanosilica (NSBC) exhibited higher density and improved mechanical properties compared to both normal concrete (NC) and barite concrete (BC). Specifically, concrete mixture containing barite aggregate and 3% nanosilica (3NSBC) content exhibited improved impermeability and reduced concrete porosity. The gamma-ray shielding properties for 3NSBC were superior among all concrete mixtures. After 28 days, 3NSBC exhibits higher compressive strength (18.26% and 14.76%) and greater shielding capacity (12.82% and 6.66%) compared to NC and BC, respectively. The analytical characterizations results have demonstrated that nanosilica helps prevent the accumulation of calcium hydroxide in the ITZ by utilizing it to form calcium silicate hydrate. This leads to the development of a more compact and denser microstructure in the ITZ of nano-silica-based barite concrete (NSBC). Furthermore, it was revealed that, the incorporation of nanosilica exceeding 3% led to agglomeration, resulting in a weaker ITZ within the concrete leading to overall reduction in concrete properties.

Evaluation of the acid degradation properties of colloidal nanosilica‐based cement pastes

AbstractThe present study examined the effects of colloidal nanosilica on the performance of cement paste samples exposed to nitric acid for a continuous period of 28 days. Compressive strength and weight losses in paste samples as a result of this attack were determined to be 66% and 27%. The inclusion of nanosilica up to 6% by weight reduced these sample losses by densifying the microstructure with its pore filling and pozzolanic effects. The addition of nanosilica decreased the flow of cement paste by 30%, but improved compressive and flexural strengths at the end of 28 days by up to 45% and 118%. The acid attack on the cement sample resulted in the formation of a degraded layer surrounding the unaltered core material. X‐ray tomography images showed this zone formation, and the scanning electron microscopy images revealed the degraded microstructure. The results of the x‐ray diffraction and nanoindentation tests confirmed the complete decalcification of the main cement hydrates, including calcium silicate hydrate and portlandite, as a result of acid attack. The results obtained suggest that the incorporation of nanosilica strengthens the microstructure of the cement matrix, thus improving the service life of structural concrete operating in chemical environments.

Influence of nanosilica and polypropylene fibers on the permeability, compressive and flexural strength of pervious concrete

The article examines the importance of pervious concrete in construction, emphasizing the need to balance the required permeability with necessary strength. The incorporation of nanosilica and polypropylene fibers into pervious concrete was evaluated, considering compressive and flexural strength, void percentage, and permeability. The methodology included an experimental mix design and specific tests. The results showed significant improvements in the properties of pervious concrete. For instance, compressive strength increased from 128.01 kg/cm² in the standard concrete to 216.08 kg/cm² with the addition of 0.12% polypropylene and 1% nanosilica. Similarly, flexural strength exhibited substantial increases, from 18.76 kg/cm² in the standard to 34.11 kg/cm² and 43.42 kg/cm² with the respective dosages. Regarding permeability, the coefficient decreased from 2.60 cm/s in the standard concrete to 2.50 cm/s with the addition of 0.12% polypropylene and 1% nanosilica. In summary, the research supports the effectiveness of these additives in enhancing the performance of pervious concrete, with improvements of up to 68.8% in compressive strength and 131.4% in flexural strength.

Comparative Analysis of Pre and Post Mix Methods for Nano Silica Incorporation in Concrete: A Study on Mechanical Property Enhancement

Comparative Analysis of Pre and Post Mix Methods for Nano Silica Incorporation in Concrete: A Study on Mechanical Property Enhancement

Effect of particle size of NanoSiO2 on cement-based stabilization/solidification of municipal solid waste incineration fly ash

As a part of by-product generated during the incineration, the municipal solid waste incineration fly ash (MFA) is a secondary pollutant. The ordinary Portland cement (OPC)-based stabilization/solidification (S/S) is a prevalent and robust technique for the treatment of MFA, which can not only effectively dispose the MFA, but also decrease the demand of OPC and reduce the greenhouse gas emissions. However, when MFA was directly utilized to partly replace the cement with a replacement ratio of 15%, the MFA-OPC based composites exhibited inferior mechanical properties. The nano silica (NS) was considered to be introduced to compensate for the strength loss caused by the MFA. In this research, the NS with varying dosages and particle sizes were integrated into the MFA-OPC composites and in total seven groups of the composites were prepared. The mechanical properties of the composites were examined and the results indicated that the composites containing 2 wt% 100 nm NS presented relatively superior mechanical properties. The incorporation of NS could increase the compressive strength of MFA-OPC composites by 37.5% at later age. Then, thermodynamic modelling and the micro-structural analysis including hydration heat, XRD, TG, MIP and SEM were coupling applied to probe into the NS modification mechanism. Experimental results indicated that the addition of NS enhanced the strength of OPC containing MFA at both early and later ages via pozzolanic reaction, hydration acceleration and micro filling effects. Overall considering the macro performance improvement and microstructure modification effect, the 2 wt% NS with particle size of 100 nm was recommended to be utilized. Therefore, this study expands the emerging application of NS and demonstrates that NS-augmented binders can ensure low-carbon and high-performance S/S of hazardous materials.

Investigating the influence of nano-silica incorporation on mechanical characteristics of steel fiber-reinforced concrete to mitigate solid waste and environmental contamination

ABSTRACT Using nano-silica and steel micro-fibers in high-strength concrete has gained attention due to their potential to reduce solid waste and environmental pollution. In this study, the impact of nano-silica inclusions on the mechanical properties of steel fiber-reinforced concrete, referred to as “Micro-Concrete Reinforced with Steel Fibers Embedding Nano-Silica” (MRSFEN), was assessed. MRSFEN mixtures were prepared with 0%, 1%, and 2% nano-silica content and 0.5%, 1%, 2%, and 3% steel micro-fiber content. Tests showed a 17%-32% increase in compressive strength and a 12%-29% increase in tensile strength by adding 1%-2% nano-silica across all fiber contents. Incorporating 1%-3% steel micro-fibers resulted in 18–25 MPa higher compressive strength, 6–12 MPa higher tensile strength, and 10%-35% higher flexural strength relative to non-fiber concrete. However, workability reduced by 15%-30% with 3% fiber content. The combined use of nano-silica and steel micro-fibers enhanced strength and ductility, with the optimum composition identified as 1% nano-silica with 2% steel micro-fibers based on the mechanical performance. The results indicate the potential of tailored MRSFEN mixtures to improve the mechanical properties of steel fiber-reinforced concrete, with benefits in reducing solid waste and mitigating environmental contamination.

Exploring The Advancement Enabled By Nano-silica In Cement-based Materials: A Comprehensive Review

At present, the focus of current research lies predominantly in unraveling the fundamental science of cementitious materials at the nano and atomic levels. Simultaneously, researchers are working diligently to enhance the durability and sustainability of concrete, leading to a significant improvement in the mechanical properties of cementitious materials through the incorporation of nano-silica. This review paper aims to provide a comprehensive overview of the influence of nano-silica addition on the mechanical, durability and microstructural characteristics of paste, mortar and concrete. It also offers insight into the current developments in the application of nano-silica in these materials. Lastly, the paper discusses the potential future trends and implications of using nano-silica in cement-based materials.

Effects of nano-silica modification on early age hydration process in winter construction of tunnel engineering

Fast hardening and high early strength are crucial factors for concrete used in tunnel construction in cold regions. The incorporation of nano-silicate has been found to be an effective method for improving the properties of cement-based materials at an early age. Thus, the objective of this paper is to investigate the nano-modification effects of different nano-silica contents on the hydration process, mechanical properties, and hydration products of cement cured in a low-temperature environment. The effects of various nano-silica concentrations, including 1%, 2%, 3%, and a high dose of 6%, on the properties of the concrete were investigated. According to the test results, the optimal quantity of nano-silica plays a crucial role in determining the properties of concrete. The effects of nano-silica on the hydration of C3A were found to dominate the cement hydration process at an early age. The incorporation of nano-silica led to a significant improvement in the dissolution rate of anhydrite and the reaction rate of the C3A renewal, which may be responsible for the gain in early strength of concrete. However, an excessive amount of nano-silica could negatively affect the hydration process of the alite and C3A, as evidenced by the total heat generated during the silica and aluminate reactions. The XRD patterns further confirmed these results.

Durability evaluation and environmental implications of blended cement with colloidal nano-silica for use in recycled fine aggregate concrete: Experimental and theoretical study

The incorporation of waste materials in concrete is currently a practical solution to solve certain environmental concerns. Because of the property degradation of the produced concrete owing to the addition of waste materials, using pozzolans in the concrete mix can help improve the mechanical performance of recycled concrete. Therefore, in this research, the mechanical specifications of recycled concrete were evaluated at different volume fractions of recycled fine aggregates (RFA) replacing natural fine aggregates (NFA). In addition, the impact of adding colloidal nano-silica particles on the performance of conventional and recycled concretes was investigated. Various parameters comprising compressive strength, pulse velocity, splitting tensile strength, flexural strength, elastic modulus, and water absorption were carefully examined. The attained experimental results reveal that the mechanical and physical characteristics of concrete degrade with increasing the volume fraction of RFA replacing NFA. Also, increasing the weight percentage of nano-silica replacing cement up to 6% in conventional concrete and that containing RFA improves the mechanical and physical properties, the optimum percentage of which was determined as 4.5%. Furthermore, relationships were recommended for predicting the compressive, splitting tensile, and flexural strengths as well as the elastic modulus of concrete mixes by including the RFA and nano-silica replacement levels, which are in acceptable accordance with the experiments in the present study and those available in the technical literature. Finally, to investigate the environmental effects of recycled concrete with different RFA substitution levels and colloidal nano-silica incorporation, the problem-based CML 2000 and the damage-based IMPACT2002 + methods were applied using SimaPro9 software. Thus, environmental parameters such as acidification, global warming potential (GWP), eutrophication, natural resources, ecosystem quality, and human health were inspected. Subsequently, the GWP results were compared and presented using the CML 2000 and the Intergovernmental Panel on Climate Change (IPCC) approaches. To verify the estimates, all the attained results were examined against those captured from the Building for Environmental and Economic Sustainability (BEES) method. Findings show that despite the implementation of different unit measurements in different methods, the environmental effects in the CML 2000 and BEES methodologies are almost the same, suggesting that nano-silica is a raw material with the greatest environmental impact. Additionally, based on the life cycle comparison results of manufacturing one cubic meter of concrete with different mix designs using the damage evaluation approach, IMPACT 2002+, concrete with the RF0NS6 mix design triggered the highest damage extent in natural resource, climate change, ecosystem, and human health categories, respectively. This study fills a significant research gap from an environmental perspective by comprehensively investigating the durability and mechanical specifications of concrete containing RFA and nano-silica pozzolan. The findings presented in this research provide valuable insights into the realm of sustainable construction practices, paving the way for novel advancements in concrete technology.

Hygrothermal effect on interfacial properties of CFRP-steel joint modified by nanosilica

The interface between the carbon fiber reinforced polymer (CFRP) reinforcement system and steel substrates may deteriorate in service environments. This study is concerned with the effect of moisture and temperature conditions on the interfacial performance of CFRP-steel joints using neat/modified adhesive. Tensile and shear tests were conducted on both unmodified adhesive specimens and those modified with nanosilica to assess the impact of nanoparticles. Water immersion tests were carried out on adhesive specimens with different nanosilica contents to determine the water absorption law of the adhesives at different immersion temperatures. The interfacial properties of CFRP-steel bonded joints were tested before and after hygrothermal aging. The results show that nanosilica significantly influences the mechanical properties of the adhesive, as well as CFRP-steel joints. In dry conditions, tensile and shear strengths, Young’s modulus and the elongation of adhesive are improved by increasing the nanosilica content up to about 1.4 wt%. A higher content of nanosilica reduces adhesive strength and modulus, while the elongation increases continuously with nanoparticles increasing to 7 wt%. The water absorption of the adhesive is significantly influenced by the content of nanosilica. More nanosilica particles lead to slower diffusion in adhesion and smaller saturated water absorption. A high immersion temperature speeds up the moisture diffusion, resulting in a larger moisture content and a more severe degradation in adhesive performance with the same immersion duration. Hygrothermal aging can be delayed by the addition of nanosilica with low content. The interfacial properties of CFRP-steel joints, including interfacial shear strength, load capacity and plasticity, are weakened by hygrothermal aging. Changing the main failure mode from cohesive failure to interfacial debonding may occur in CFRP-steel joints due to aging. The more severe deterioration is caused by longer immersion or a higher immersion temperature. However, the addition of nanosilica can enhance the durability of the aged joints in the long run by improving the water resistance, although peak shear stress decreases when the nanosilica content exceeds 1.4 wt%. The trilinear bond-slip model of reinforced adhesive joints may be reduced to a bilinear model by hygrothermal aging. The incorporation of nanosilica helps to mitigate the reduction in fracture energy due to water immersion at normal and high temperatures.