Effect of particle size of NanoSiO2 on cement-based stabilization/solidification of municipal solid waste incineration fly ash

Abstract

As a part of by-product generated during the incineration, the municipal solid waste incineration fly ash (MFA) is a secondary pollutant. The ordinary Portland cement (OPC)-based stabilization/solidification (S/S) is a prevalent and robust technique for the treatment of MFA, which can not only effectively dispose the MFA, but also decrease the demand of OPC and reduce the greenhouse gas emissions. However, when MFA was directly utilized to partly replace the cement with a replacement ratio of 15%, the MFA-OPC based composites exhibited inferior mechanical properties. The nano silica (NS) was considered to be introduced to compensate for the strength loss caused by the MFA. In this research, the NS with varying dosages and particle sizes were integrated into the MFA-OPC composites and in total seven groups of the composites were prepared. The mechanical properties of the composites were examined and the results indicated that the composites containing 2 wt% 100 nm NS presented relatively superior mechanical properties. The incorporation of NS could increase the compressive strength of MFA-OPC composites by 37.5% at later age. Then, thermodynamic modelling and the micro-structural analysis including hydration heat, XRD, TG, MIP and SEM were coupling applied to probe into the NS modification mechanism. Experimental results indicated that the addition of NS enhanced the strength of OPC containing MFA at both early and later ages via pozzolanic reaction, hydration acceleration and micro filling effects. Overall considering the macro performance improvement and microstructure modification effect, the 2 wt% NS with particle size of 100 nm was recommended to be utilized. Therefore, this study expands the emerging application of NS and demonstrates that NS-augmented binders can ensure low-carbon and high-performance S/S of hazardous materials.