Na2O CaO K2O FeO MgO Al2O3 SiO2 H2O Research Articles

Evolution of Contact Metamorphic Rocks in the Zhoukoudian Area: Evidence from Phase Equilibrium Modelling

The Yanshan intraplate tectonic belt is a tectonic-active area in the central part of the North China Craton that has undergone long-term orogenic evolution. Detailed studies on magmatic activity and metamorphism of this belt are significant for restoring its orogenic thermal evolution process. The Fangshan pluton in the Zhoukoudian area within this tectonic belt is a product of the late Mesozoic Yanshan event. However, there is a lack of detailed research on the metamorphic evolution history of the ancient terrane surrounding the Fangshan pluton subjected to contact thermal metamorphism. To further constrain the metamorphic P–T evolution of contact metamorphism associated with the Fangshan pluton, we collected rock samples in the andalusite–biotite contact metamorphic zone of the Fangshan pluton, and conducted petrographic investigations, geochemical and mineral composition analysis, and phase equilibrium modeling. The phase equilibrium modeling in the MnO–Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O system indicates that the peak mineral assemblages of andalusite–biotite schists are pl + q + mu + bi + and ± kfs + ilm + mt, formed at 550 to 610 °C, 1 to 3.5 kbar, and the peak mineral assemblage of garnet–andalusite–cordierite–biotite schists is gt + pl + q + bi + and + cord + ilm + mt, formed at 580 to 620 °C, 1.5 to 2.1 kbar. Therefore, we believe that the rocks in the andalusite biotite contact metamorphic zone of the Fangshan pluton underwent low pressure and medium temperature metamorphism, with the peak metamorphic conditions of about 550–610 °C, <3.5 kbar. The results show that the rocks in contact with the thermal metamorphic zone were rapidly heated by the heat released by the Fangshan pluton, and after reaching the peak metamorphic temperature, they were cooled down simultaneously with the cooling of the rock mass, defined in a nearly isobaric P–T trajectory.

Thermodynamic constraints on the composition of orogenically thickened lower crust

Orogenically thickened lower crust is the key site of crustal differentiation, crustal deformation, and Moho modification. However, the composition of thickened lower crust is still highly debated. Here, we calculate a set of pseudosections with mafic lower crust compositions in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 (NCKFMASHTO) system. Our modeling results show that the maximum thickness of the mafic lower crust increases with the Moho temperature (TMoho). In addition, the lithologies of stable mafic crust are characterized by medium-pressure (MP) to high-pressure (HP) granulites at 40–50 km, HP granulites and garnet-omphacite granulites at 50–60 km, and garnet-omphacite granulites at 60–70 km. Under the Pamir geothermal conditions, mafic rocks with high SiO2 (>50.2 wt%), XMg (>0.70), XCa (>0.49), or low XAl (<0.11) could be stable at 70 km; however, only ~10% of global mafic granulite xenoliths lie within this compositional range. Further modeling indicates that if TMoho reaches 900–1000 °C, neither the lower crust nor the upper mantle has significant strength relative to the upper crust, and that only ~5–37% of mafic materials are gravitationally stable at 70 km. This implies that the base of doubly thickened (70 km) crust is dominated by intermediate-felsic rocks, consistent with the low Vp and Vp/Vs values seismically observed in young orogenic crustal roots. Thus, most mafic materials at >70 km could delaminate into the deep mantle. Our results provide insights on the formation of extremely thick crust with a predominantly intermediate-felsic base and the crustal thickness variation in continental collision zones.

Geochemistry and mineral chemistry of pelitic gneiss of Ikare area, southwestern Nigeria

This study conducts Electron Probe Microanalysis (EPMA), X-ray Fluorescence (XRF) and Laser Ablation Inductively Coupled Plasma Spectrometry (LA-ICP-MS) analysis on the pelitic gneiss of the Basement complex of Nigeria. Phase equilibrium modeling was undertaken in the MnO–Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 (MnNCKFMASHTO) chemical system using THERMOCALC. The rock comprises of sillimanite + biotite + garnet + K-feldspar + quartz + ilmenite + plagioclase ± cordierite. Garnet has inclusions of sillimanite, biotite, and quartz. There is a very close association between biotite and sillimanite. Fibrolitic and prismatic sillimanite are both present. Fibrolitic sillimanite surrounding biotite could have possibly formed through melt-residue back reactions involving crystallization of melt. Garnet has almandine higher than 60 % and pyrope less than 33 %. Plagioclase feldspar has anorthite content between 29 and 39 %, comprising of both oligoclase and andesine. Microtextures such as cordierite corona round garnet, symplectite and kinked biotite were observed. The textural association indicates that cordierite was formed at the expense of garnet and sillimanite; garnet + sillimanite + plagioclase => cordierite + melt/fluid. Metamorphic peak conditions of 770–840 °C and 5.5–7 kbar were obtained for the mineral assemblage garnet-biotite-sillimanite-K-feldspar-quartz indicating medium-pressure granulite facies metamorphism.

Neoarchean ultrahigh-temperature sapphirine granulites from the Karimnagar Granulite Terrane, Southern India: Implications for hot orogen along the Eastern Dharwar Craton margin

We have uncovered evidence of Neoarchean ultrahigh-temperature (UHT) metamorphism in the Karimnagar Granulite Terrane (KGT), southern India, based on new petrological and mineralogical data of sapphirine-bearing and related granulites. We investigated their petrogenesis and implications of a hot orogen along the north-eastern margin of the Eastern Dharwar Craton (EDC). We found various reaction textures, such as spinel mantled by sapphirine and hydration of orthopyroxene, indicating a peak mineral assemblage of cordierite + sapphirine + spinel + orthopyroxene + biotite + rutile + K-feldspar. Phase-equilibria modelling in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3 system indicates peak metamorphic conditions of 905 °C–910 °C and 4.5–4.6 kbar. The peak stage was followed by a retrograde metamorphic stage represented by increasing modal abundance of biotite and consumption of rutile and spinel at ~730 °C and ~ 4 kbar, suggesting near-isobaric cooling. Using the chemical Th–U-Pbtotal isochron method, we dated monazites in textural association with sapphirines and cordierites in a sapphirine–spinel–orthopyroxene–cordierite granulite. The resulting Neoarchean age (2638 ± 44 Ma) probably represents the timing of peak UHT metamorphism. We infer that Neoarchean UHT metamorphism and post-peak near-isobaric cooling took place in the terrane during the terminal stage of complex accretion–collision tectonic processes related to amalgamation of microcontinents and/or magmatic arcs that occurred during 2.70–2.62 Ga, one of the major episodic crust-forming events in the EDC. Our findings and regional distribution of lithologies overturn the existing tectonic model of the KGT as a collisional suture zone between the EDC and the Bastar Craton. Moreover, we propose that the KGT is a discrete tectonic block composed of ~2.7–2.6-Ga granulites and younger granite representing the mid-crustal segment of the EDC, which was uplifted as a tilted tectonic block along the southern flank of the Kadam outlier.

Exsolution intergrowth of cpx-opx and pseudosection modelling of two-pyroxene mafic granulite from Daltonganj of Chhotanagpur Granite Gneiss Complex, Eastern India

In this study, we reconstruct for the first time the evolution of a two-pyroxene mafic granulite from the Daltonganj of Chhotanagpur Granite Gneiss Complex (CGGC). Transmission electron microscopy (TEM) revealed that some of the clinopyroxene have exsolution texture, where orthopyroxene occurs as thin lamellae within the porphyroblast of clinopyroxene. To tightly constrain the P-T conditions at which exsolution lamellae developed after the metamorphic peak, we have applied both conventional and multi-equilibrium thermobarometry, as well as forward thermodynamic modelling. Results from multi-equilibrium thermobarometry, using the software THERMOCALC, suggest peak conditions of the mafic granulite at average pressure-temperature (PTav) conditions of 6.7 ± 1.19 kbar/814 ± 60 °C. In contrast, exsolution bearing opx-cpx minerals crystallised at relatively lower temperature (772 ± 14 °C), determined by the conventional geothermometers. The peak to retrograde evolution of these mafic granulites is constrained through phase equilibrium modelling in the NCKFMASHTO (Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O) model system using the software Perple_X. Phase equilibria results of peak conditions (i.e. 6.0–6.78 kbar and 775–808 °C) are consistent with respect to those obtained through multi-equilibrium and conventional thermobarometry, while the retrograde path is defined down to ~4.5 kbar and ~540 °C. Our results have twofold implications: (i) they show how the integrating of different geothermobarometric methods is the best proxy to tightly constrain the evolution of high-grade metamorphic rocks, and (ii) they pavement to new constraints on the Paleoproterozoic to Neoproterozoic evolution of the CGGC.

The Conlara Metamorphic Complex: Lithology, provenance, metamorphic constraints on the metabasic rocks, and chime monazite dating

The Conlara Metamorphic Complex, the easternmost complex of the Sierra de San Luis, is a key unit to understand the relationship between the late Proterozoic-Early Cambrian Pampean and the Upper Cambrian-Middle Ordovician Famatinian orogenies of the Eastern Sierras Pampeanas. The Conlara Metamorphic Complex extends to the east to the foothills of the Sierra de Comechingones and to the west up the Río Guzmán shear zone. The main rock types of the CMC are metaclastic and metaigneous rocks that are intruded by Ordovician and Devonian granitoids. The metaclastic units comprise fine to medium-grained metagreywackes and scarce metapelites with lesser amounts of tourmaline schists and tourmalinites whereas the metaigneous rocks encompass basic and granitoids rocks. The former occur as rare amphibolite interlayered within the metasedimentary rocks. The granitic component corresponds to a series of orthogneisses and migmatites (stromatite and diatexite). The CMC is divided in four groups based on the dominant lithological associations: San Martin and La Cocha correspond mainly to schists and some gneisses and Santa Rosa and San Felipe encompass mainly paragneisses, migmatites and orthogneisses. The Conlara Metamoprphic Complex underwent a polyphase metamorphic evolution. The penetrative D2-S2 foliation was affected by upright, generally isoclinal, N-NE trending D3 folds that control the NNE outcrop patterns of the different groups. An earlier, relic S1 is preserved in microlithons. Discontinuous high-T shear zones within the schists and migmatites are related with D4 whereas some fine-grained discontinuous shear bands attest for a D5 deformation phase. Geochemistry of both non-migmatitic metaclastic units and amphibolites suggest that the Conlara Metamorphic Complex represents an arc related basin. Maximun depositional ages indicate a pre- 570 Ma deposition of the sediments. An ample interval between sedimentation and granite emplacement in the already metamorphic complex is indicated by the 497 ± 8 Ma age of El Peñon granite. D1-D2 history took place at 564 ± 21 Ma as indicated by one PbSL age calculated for the M2 garnet of La Cocha Group. D3 is constrained by the pervasively solid-state deformed Early Ordovician granitoids which exhibits folded xenoliths of the D1-D2 deformed metaclastic rocks. Pressure-temperature pseudosections were calculated for one amphibolite using the geologically realistic system MnNCKFMASHTO (MnO–Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3). Peak metamophic conditions (M2) indicate 6 kbar and 620 °C. Late chlorite on the rims and in cracks of garnet, along with titanite rims on ilmenite and matrix plagioclase breaking down to albite suggests that the P-T path moved back down. Monazite analyses yield isochron Th–U–Pb ages ranging from 446 to 418 Ma. The oldest age of 446 ± 5 Ma correspond to a migmatite from the Santa Rosa Group. Monazites in samples from the La Cocha and the San Martin group crystallized at decreasing temperatures, followed by the 418 ± 10 Ma low-Y2O3 monazites in one sample of the la Cocha Group that was also obtained from a migmatite, and would likely mark a later stage of a retrograde metamorphism New CHIME monazite ages presented here likely represent post-peak fluid assisted recrystallization that are similar to amphibole and muscovite cooling ages. Therefore the monazite ages may represent a re-equilibration of the monazite on the cooling path of the basement complex.

Zircon U–Pb geochronology and clockwise P–T evolution of garnet-bearing migmatites from the Qinling complex in the Weiziping area of the Qinling Orogen, Central China: Implications for thermal relaxation after crustal thickening

Zircon U–Pb dating and phase equilibrium modeling in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 system were carried out to garnet-bearing migmatites from the Qinling Complex in the Weiziping area of the Qinling Orogen, Central China, to constrain their metamorphic P–T path and elucidate the tectonic setting and geodynamic mechanism of Early to Middle Devonian high-temperature (HT) metamorphism in the North Qinling Belt. The mesosomes of the migmatites are composed of garnet-bearing biotite–hornblende–plagioclase and biotite–plagioclase gneisses, and the leucosomes can be divided into two types: wide leucosomes that were deformed, and narrow penetrative leucosomes. Laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) zircon U–Pb analyses yielded weighted mean 206Pb/238U ages of 398.8 ± 4.7, 394.6 ± 2.6, 399.5 ± 7.3, 372.5 ± 4.2, 370.8 ± 4.3, and 368.5 ± 4.2 Ma for metamorphic zircons within the sampled mesosomes, and a weighted mean age of 408.7 ± 5.7 Ma for igneous zircons within a deformed leucosome. Based on the published data and the results in this study, the timing of granulite-facies metamorphism is constrained to be ca. 409–395 Ma. The mesosome sample (garnet-bearing biotite–hornblende–plagioclase gneiss) has a peak mineral assemblage of garnet, biotite, plagioclase, hornblende, quartz, ilmenite, and melt, which equilibrated at P–T condition of 8.5–9.7 kbar at 745–820 °C as constrained by isopleths of XAn and XPy in a P–T pseudosection, suggesting that these gneisses underwent medium-pressure granulite-facies metamorphism. Conventional garnet–biotite–plagioclase–quartz (GBPQ) geothermobarometry yielded P–T conditions of 703 °C at 10 kbar and 685–748 °C at 7.1–8.9 kbar, which correspond to prograde and retrograde metamorphic stages, respectively. On the basis of these P–T results, the studied samples document a clockwise P–T path characterized by temperature increase and pressure decrease during the prograde stage, and temperature decrease and pressure decrease during the retrograde stage. Ti-in-zircon thermometry yielded a temperature range of 781–793 °C for metamorphic zircons from the mesosomes, further demonstrating that they underwent granulite-facies metamorphism at ca. 409–395 Ma. The prograde metamorphic stage characterized by temperature increase and pressure decrease suggests that thermal relaxation after crustal thickening has induced the partial melting and migmatization. Thus, the crustal thickening that may be caused by continental collision between the North China Block and the South China Block should occur no later than ca. 409 Ma.

Anatexis and metamorphic history of Permian pelitic granulites from the southern Chinese Altai: Constraints from petrology, melt inclusions and phase equilibria modelling

Pelitic granulites from the southern Chinese Altai record a prominent Permian high–temperature reworking event. The lack of solid constraints on anatexis and metamorphic P–T path of these rocks has hindered our understanding of the thermo–tectonic history of Chinese Altai orogen. Here, we present a detailed field and petrological study of the pelitic granulites cropping out at Wuqiagou area, Fuyun county. They occur as lenses or interlayers hosted within biotite–plagioclase gneisses, with a rutile–bearing assemblage composed of garnet ± orthopyroxene + cordierite + biotite ± K–feldspar + plagioclase + quartz ± spinel ± sillimanite + ilmenite. These pelitic granulites preserve diagnostic features of anatexis, such as small patches of leucosomes at macroscopic scale, melt inclusions in garnet porphyroblasts and highly cuspate quartz at microscopic scale. Melt inclusions (up to ~40 μm) are now crystallized into a cryptocrystalline aggregate of feldspars, quartz and biotite (i.e. they are nanogranitoids). Phase equilibria modelling in the NCKFMASHTO (Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3) 10–compositional model system suggests a possible clockwise P–T path involving a post–peak isobaric cooling (IBC) process from 800 to 850 °C to near solidus conditions (700–720 °C) at 5.0–6.0 kbar. SIMS zircon UPb geochronology indicates that the granulite–facies metamorphism took place at 284.1 ± 2.6 Ma, which is coeval with spatially associated mantle–derived mafic intrusions. Therefore, we propose that the Permian granulite–facies metamorphic event occurred in a post–orogenic extensional tectonic setting, which was associated with the input of external heat, related to underplating and intruding of mantle–derived magmas possibly as a result of the Tarim mantle plume activity.

Retrieval of P–T–t–d paths in a syn-metamorphic shear zone: Implications for P-T calculations and the Permian–Triassic orogeny on the Korean Peninsula

Crustal-scale shear zones developed on the boundaries of the Precambrian Gyeonggi Massif (GM) can play key role on understanding collisional orogeny during the Late Paleozoic to Early Mesozoic in the Korean Peninsula. Garnet schist formed on the boundary between the GM and Okcheon Metamorphic Belt (OMB) experienced contractional (Dn) and extensional (Dn+1) shearing combined with a clockwise pressure–temperature–deformation (P–T–d) path. Two distinct mineral assemblages were found in the schists, (1) garnet (pre- and/or syn-Dn) + staurolite (syn-Dn and/or inter Dn and Dn+1, and syn-Dn+1) + andalusite (syn-Dn+1)-bearing and (2) garnet (pre- and/or syn-Dn) + epidote-bearing assemblages, depending on bulk-rock compositions. Various compositions (An10–40 in the former assemblage and An45–70 in the latter one) and texture of plagioclase resulted from bulk-rock compositions, heterogeneous strain and dissolution and precipitation during the multiple shearing. The P–T conditions estimated for the early contractional shearing (top-to-the-north reverse shear) are 560 °C–600 °C and 5.5–7.0 kbar based on the intersections between compositional isopleths for pre- and/or syn-Dn garnet and plagioclase (An30–40 & An45–55) calculated in the MnO–Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O and MnO–Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3 systems. Subsequent extensional shearing (top-to-the-south normal shear) was characterized by recrystallization of fine-grained syn-Dn+1 staurolite with growth of syn-Dn+1 andalusite porphyroblasts during cooling and decompression to 560 °C and 3.5 kbar. The contractional and extensional shearing probably occurred at the Permian and the Late Triassic to Early Jurassic, respectively, based on the previous geochronological data. Consequently, inferred P–T–t–d paths on the GM–OMB boundary probably suggest not only crustal thickening followed by thinning, but also multiple amalgamations of several terranes.

Neoarchean arc magmatism and Paleoproterozoic granulite‐facies metamorphism in the Bhavani Suture Zone, South India

The Bhavani Suture Zone in the Southern Granulite Terrane marks the zone of amalgamation of the Neoarchean Nilgiri Block and the northwestern Madurai Block in southern India. Here, we report detailed petrological, geochemical, and geochronological data on the Mettupalayam mafic–ultramafic complex within this suture zone with a view to evaluate the tectonothermal history of the Bhavani Suture Zone and adjoining crustal blocks. The metamorphosed complex includes charnockite, hornblende‐biotite gneiss, mafic granulite, amphibolite, garnet‐bearing mafic granulite, and dioritic gneiss along with metamorphosed banded iron formation. The mafic granulite and the dioritic gneiss occur as concordant layers of varying thickness within the hornblende‐biotite gneiss. The salient geochemical features of the mafic granulite and the dioritic gneiss including the enrichment of large‐ion lithophile elements and depletion of high‐field‐strength elements suggest a subduction‐related arc magmatic setting. However, the amphibolites show MORB‐related affinity, suggesting its formation from a N‐MORB‐related source and their accretion together with the overlying banded iron formation. The peak metamorphic conditions of the garnet‐bearing mafic granulite were estimated using conventional geothermobarometers as 800–820 °C/8.5–9.2 kbar, which we further confirm through phase equilibrium modelling in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3 (NCKFMASHTO) system. Magmatic zircons with high Th/U ratio from the amphibolite display a well‐defined discordia with an upper intercept age of 2,600 ± 38 Ma. Zircon grains from the dioritic gneiss show weighted mean 206Pb/207Pb age of 2,524 ± 6 Ma from concordant zircon spots and a comparable upper intercept age of 2,562 ± 34 Ma from discordant zircon spots, indicating protolith emplacement related to Neoarchean arc magmatism as inferred from our geochemical data. The thin overgrowth rims around the magmatic zircon grains in the amphibolite yielded an upper intercept age of 2,520 ± 20 Ma, which is comparable with the protolith crystallization age of the dioritic gneiss. Slightly younger weighted mean 207Pb/208Pb ages of 2,463 ± 27 Ma (from dioritic gneiss) and 2,422 ± 30 Ma (from amphibolite) are also obtained from the metamorphic zircon rims. These ages are correlated to the timing of high‐grade metamorphism associated with final collision of the Nilgiri Block and the northwestern Madurai Block. Similar Neoarchean–Paleoproterozoic magmatism and high‐grade metamorphism were reported from many localities south of the Dharwar Craton. Our study further confirms the previous tectonic model that envisages multiple subduction and collision of magmatic arcs and continental fragments towards the Dharwar Craton during the Archean–Paleoproterozoic transition.

Phase equilibrium modelling of the amphibolite to granulite facies transition in metabasic rocks (Ivrea Zone, NW Italy)

AbstractThe development of thermodynamic models for tonalitic melt and the updated clinopyroxene and amphibole models now allow the use of phase equilibrium modelling to estimate P–T conditions and melt production for anatectic mafic and intermediate rock types at high‐T conditions. The Permian mid‐lower crustal section of the Ivrea Zone preserves a metamorphic field gradient from mid amphibolite facies to granulite facies, and thus records the onset of partial melting in metabasic rocks. Interlayered metabasic and metapelitic rocks allows the direct comparison of P–T estimates and partial melting between both rock types with the same metamorphic evolution. Pseudosections for metabasic compositions calculated in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O (NCKFMASHTO) system are presented and compared with those of metapelitic rocks calculated with consistent end‐member data and a–x models. The results presented in this study show that P–T conditions obtained by phase equilibria modelling of both metabasic and metapelitic rocks give consistent results within uncertainties, allowing integration of results obtained for both rock types. In combination, the calculations for both metabasic and metapelitic rocks allows an updated and more precisely constrained metamorphic field gradient for Val Strona di Omegna to be defined. The new field gradient has a slightly lower dP/dT which is in better agreement with the onset of crustal thinning of the Adriatic margin during the Permian inferred in recent studies.

Origin, age, and significance of deep‐seated granulite‐facies migmatites in the Barrow zones of Scotland, Cairn Leuchan, Glen Muick area

AbstractPetrological modelling of granulite‐facies mafic and semipelitic migmatites from Cairn Leuchan, northeast Scotland, has provided new constraints on the pressure (P) and temperature (T) conditions of high‐grade metamorphism in the type‐locality Barrow zones. Phase diagrams constructed in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 system have constrained the P−T conditions of peak metamorphism in the Glen Muick region of the upper sillimanite zone (Sill+Kfs) to have been at least ∼840°C at ∼9 kbar (high‐P granulite facies). These conditions are ∼120°C and ∼3 kbar higher than those recorded by lower sillimanite zone (Sill+Ms) units located only a few kilometres away to the southeast at Glen Girnock, indicating the presence of a significant thermal and barometric high exposed within the Scottish Dalradian, and supporting previous suppositions of a potential tectonic break between the two regions. U–Pb zircon geochronology performed on these mafic migmatites produced ages of c. 540–470 Ma from grains with both igneous and metamorphic morphological characteristics. Their basaltic protoliths likely formed during a period of volcanism dated at c. 570 Ma, associated with passive‐margin extension prior to the onset of Iapetus Ocean closure, and high‐grade metamorphism and partial melting is interpreted to have taken place at c. 470 Ma, synchronous with sillimanite‐grade metamorphism recorded elsewhere in the Dalradian. These high‐grade Cairn Leuchan lithologies are interpreted as representing a fragment of Grampian Terrane lower crust that was exhumed via displacement along a steeply dipping tectonic discontinuity related to the Portsoy–Duchray Hill Lineament, and are not pre‐Caledonian Mesoproterozoic basement, as suggested by some previous studies. Veins within some mafic migmatites in the Cairn Leuchan area, composed almost entirely (&gt;80%) of garnet, with minor quartz, plagioclase, amphibole, and clinopyroxene, are interconnected with leucosomes and are interpreted to represent former garnet‐bearing melt segregations that have been locally drained of almost all melt. Thus, mafic components of the lower crust, currently underlying relatively lower grade metasediments exposed to the southeast, may represent a potential source rock for widely documented, post‐orogenic felsic plutons, sills, and dykes that occur throughout the Grampian Terrane.

Cordierite-bearing granulites from Ihosy, southern Madagascar: Petrology, geochronology and regional correlation of suture zones in Madagascar and India

Madagascar, a major fragment of Gondwana, is mainly composed of Precambrian basement rocks formed by Mesoarchean to Neoproterozoic tectono-thermal events and recording a Pan-African metamorphic overprint. The Ranotsara Shear Zone in southern Madagascar has been correlated with shear zones in southern India and eastern Africa in the reconstruction of the Gondwana supercontinent. Here we present detailed petrology, mineral chemistry, metamorphic P–T constraints using phase equilibrium modelling and zircon U-Pb geochronological data on high-grade metamorphic rocks from Ihosy within the Ranotsara Shear Zone. Garnet-cordierite gneiss from Ihosy experienced two stages of metamorphism. The peak mineral assemblage is interpreted as garnet + sillimanite + cordierite + quartz + plagioclase + K-feldspar + magnetite + spinel + ilmenite, which is overprinted by a retrograde mineral assemblage of biotite + garnet + cordierite + quartz + plagioclase + K-feldspar + magnetite + spinel + ilmenite. Phase equilibria modelling in the system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3 (NCKFMASHTO) indicates peak metamorphic conditions of 850–960 °C and 6.9–7.7 kbar, and retrograde P–T conditions of <740 °C and <4.8 kbar, that define a clockwise P–T path. Near-concordant ages of detrital zircon grains in the garnet-cordierite gneiss dominantly exhibit ages between 2030 Ma and 1784 Ma, indicating dominantly Paleoproterozoic sources. The lower intercept age of 514 ± 33 Ma probably indicates the timing of high-grade metamorphism, which coincides with the assembly of the Gondwana supercontinent. The comparable rock types, zircon ages and metamorphic P–T paths between the Ranotsara Shear Zone and the Achankovil Suture Zone in southern India support an interpretation that the Ranotsara Shear Zone is a continuation of the Achankovil Suture Zone.

Phase equilibrium modelling and SHRIMP zircon U–Pb dating of medium-pressure pelitic granulites in the Helanshan complex of the Khondalite Belt, North China Craton, and their tectonic implications

The Helanshan complex in the Khondalite Belt, North China Craton (NCC) is characterized by the occurrence of both medium-pressure (MP) and high-pressure (HP) pelitic granulites. This paper presents new results from phase equilibrium modelling and SHRIMP zircon U–Pb dating on the MP garnet-sillimanite granulites, in order to better understand the relationship between the MP and HP pelitic granulites, the tectonic implications of the MP pelitic granulites for the formation of the Khondalite Belt, and their geodynamic implications for the Paleoproterozoic orogenesis. Based on petrographic observations, the metamorphic evolution can be divided into four stages (M1–M4). The M1–M3 stages are suprasolidus as reflected by the migmatitic structure on the outcrop. The peak metamorphic stage (M1) is represented by the rim of garnet porphyroblasts along with inclusions of sillimanite + quartz ± biotite, and rutile relicts + plagioclase + K-feldspar in the matrix; the M2 is defined by the ilmenite that have partially replaced rutile; and the M3 is characterized by the replacement of garnet by cordierite. The subsolidus mineral assemblage is garnet + biotite + plagioclase + K-feldspar + sillimanite + cordierite + ilmenite + quartz (M4). Combined with the phase equilibrium modelling in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 chemical system, the MP pelitic granulites record a clockwise P–T path, which is characterized by near-isothermal decompression (ITD) from ∼10.1 kbar at ∼830 °C to ∼5.8 kbar at ∼800 °C and subsequent close-to-isobaric cooling (IBC). SHRIMP zircon U–Pb dating yielded a metamorphic age of 1931 ± 21 Ma, interpreted as the time of the retrograde cooling. Integrated with previously reported results, we propose that slab break-off subsequent to Yinshan-Ordos collision at ca. 1.95 Ga led to uplift of the MP and HP granulites in the Khondalite to the middle crustal level in an extensional regime as indicated by their ITD evolution, which was followed by slow cooling at ca. 1.93 Ga as evidenced by their nearly IBC evolution.

Petrology and age of Precambrian Aksu blueschist, NW China

The first occurrence of blueschist in the Neoproterozoic signifies a transition in thermal regime from a warmer Archean–Proterozoic Earth to modern colder subduction characterized by blueschist facies or ultrahigh pressure metamorphism. To evaluate the thermal regime of the transition, we apply phase equilibrium modeling to the Aksu blueschist in northwestern China to constrain the pressure (P) and temperature (T) conditions of the peak mineral assemblages and to calculate the thermal regime recorded by the blueschist. Phase equilibrium modeling in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–O system indicates that the peak mineral assemblage (glaucophane/riebeckite + epidote + phengite + albite + quartz + chlorite) was developed at P–T conditions of 6.8–8.7 kbar and 320–410 °C for a stilpnomelane-bearing epidote blueschist (AK04) and of 6.5–8.0 kbar and 310–380 °C for an epidote blueschist (AK06). These P–T data define an apparent thermal gradient of ∼470 °C/GPa for the peak stage which is typical of the high-pressure intermediate type metamorphic facies series. In addition, we present new LA–ICP–MS U–Pb ages from detrital zircons from two blueschists (AK04 and AK06) and SHRIMP U–Pb ages from zircon from a cross-cutting post-metamorphic mafic dyke (AK134) to constrain the age of the metamorphism. The youngest concordant detrital zircon ages give a maximum depositional age for the blueschist protoliths of 806 ± 10 (AK04) and 803 ± 10 Ma (AK06), respectively, and the SHRIMP U–Pb ages of zircons from the mafic dyke yields a weighted mean age of 769 ± 19 Ma interpreted to date crystallization. These results constrain the age of Aksu blueschist facies metamorphism to between 769 ± 19 and c. 805 Ma.

Prolonged anatexis of Paleoproterozoic metasedimentary basement: First evidence from the Yinchuan Basin and new constraints on the evolution of the Khondalite Belt, North China Craton

Discerning the history of burial, residence at depth and exhumation of high grade metamorphic rocks from an orogen is essential to understanding crustal differentiation and orogenesis. Such high grade rocks are inferred to exist beneath the Yinchuan Basin, which is overlain by a thick covering of younger sediments, and is located at the inferred southwest boundary of the Paleoproterozoic Khondalite Belt in the northwestern North China Craton. The metamorphic basement sampled from a recently completed deep borehole in the Yinchuan Basin is migmatitic and contains an assemblage of garnet, biotite, sillimanite, plagioclase, quartz, minor K-feldspar and local occurrences of muscovite. Phase equilibrium modelling in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O system constrains the peak P–T conditions of anatexis to 6–10kbar at 760–810°C, followed by final crystallization at 4.5–5.5kbar and 690–710°C. Ti-in-zircon thermometry for the narrow metamorphic zircon rims provides a temperature range of 687–753°C, demonstrating formation during retrogression to the solidus. NanoSIMS U–Pb analyses on the metamorphic overgrowths of zircon grains yields an upper intercept age of 1895±36Ma. Chronological and chemical analyses of monazite indicate irregular bright gray domains with relatively high Th and low Y and HREE contents developed during prograde metamorphism (1962±8Ma). Conversely, dark domains with low Th and high Y and HREE overgrew during retrograde cooling (1892±14Ma) that was synchronous with the development of metamorphic zircon rims. LA-ICP-MS U–Pb analyses of detrital zircons reveal that the metamorphic basement beneath the Yinchuan Basin has a sedimentary protolith of Paleoproterozoic age. The results directly confirm the existence of Paleoproterozoic basement beneath the Yinchuan Basin, and the well-constrained P–T–t path supports the involvement of the basement (as part of the western Khondalite Belt) in burial and exhumation processes during the 1.96–1.89Ga period, during which anatexis occurred for ∼70Ma.

High‐grade metamorphism and partial melting of basic and intermediate rocks

AbstractRocks of basic and intermediate bulk composition occur in orogenic terranes from all geological time periods and are thought to represent significant petrological components of the middle and lower continental crust. However, the former lack of appropriate thermodynamic models for silicate melt, amphibole and clinopyroxene that can be applied to such lithologies at high temperature has inhibited effective phase equilibrium modelling of their petrological evolution during amphibolite‐ and granulite facies metamorphism. In this work, we present phase diagrams calculated in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2(NCKFMASHTO) compositional system for a range of natural basic and intermediate bulk compositions for conditions of 2–12 kbar and 600–1050 ∘C using newly parameterized activity–composition relationships detailed in a companion paper by Green et al. in this issue. Particular attention is given to mid‐ocean ridge basalt (MORB) and diorite protolith bulk compositions. Calculated subsolidus mineral assemblages in all basic and intermediate rock types are modally dominated by hornblende and plagioclase, with variable proportions of epidote, clinopyroxene, garnet, biotite, muscovite, quartz, titanite or ilmenite present at different pressures. The H2O‐saturated (wet) solidus has a negativeP−Tslope and occurs between ∼620–690∘C at mid‐ to lower‐crustal pressures of 5–10 kbar. The lowest‐Tmelts generated close to the wet solidus are calculated to have granitic major‐element oxide compositions. Melting at higher temperature is attributed primarily to multivariate hydrate‐breakdown reactions involving biotite and/or hornblende. Partial melt compositions calculated at 800–1050∘C for MORB show good correlation with analysed compositions of experimental glasses produced via hydrate‐breakdown melting of natural and synthetic basic protoliths, with Niggli norms indicating that they would crystallize to trondhjemite or tonalite. Diorite is shown to be significantly more fertile than MORB and is calculated to produce high‐Tmelts (&gt;800 ∘C) of granodioritic composition. Subsolidus and suprasolidus mineral assemblages show no significant variation between different members of the basalt family, although theP−Tconditions at which orthopyroxene stabilizes, thus defining the prograde amphibolite–granulite transition, is strongly dependent on bulk‐rock oxidation state and water content. The petrological effects of open‐ and closed‐system processes on the mineral assemblages produced during prograde metamorphism and preserved during retrograde metamorphism are also examined via a case‐study analysis of a natural Archean amphibolite from the Lewisian Complex, northwest Scotland.

Differential Evolution of High‐Pressure and Ultrahigh‐Pressure Metapelites from Habutengsu, Chinese Western Tianshan: Phase Equilibria Modelling and 40Ar/39Ar Geochronology

AbstractMetapelite is one of the predominant rock types in the high‐pressure–ultrahigh‐pressure (HP–UHP) metamorphic belt of western Tianshan, NW China; however, the spatial and temporal variations of this belt during metamorphism are poorly understood. In this study, we present comparative petrological studies and 40Ar/39Ar geochronology of HP and UHP pelitic schist exposed along the Habutengsu valley. The schist mainly comprises quartz, white mica, garnet, albite and bluish amphibole. In the MnO–Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (MnNCKFMASH) system, P–T pseudosections were constructed using THERMOCALC 333 for two representative pelitic schists. The results demonstrate that there was a break in the peak metamorphic pressures in the Habutengsu area. The northern schist has experienced UHP metamorphism, consistent with the presence of coesite in the same section, while the southern one formed at lower pressures that stabilized the quartz. This result supports the previous finding of a metamorphic gradient through the HP–UHP metamorphic belt of the Chinese western Tianshan by the authors. Additionally, phengite in the northern schist was modelled as having a Si content of 3.55–3.70 (a.p.f.u.) at the peak stage, a value much higher than that of oriented matrix phengite (Si content 3.32–3.38 a.p.f.u.). This indicates that the phengite flakes in the UHP schist were subjected to recrystallization during exhumation, which is consistent with the presence of phengite aggregates surrounding garnet porphyroblast. The 40Ar/39Ar age spectra of white mica (dominantly phengite) from the two schists exhibit similar plateau ages of ca. 315 Ma, which is interpreted as the timing of a tectonometamorphic event that occurred during the exhumation of the HP–UHP metamorphic belt of the Chinese western Tianshan.

P–T–t evolution of pelitic gneiss from the basement underlying the Northwestern Ordos Basin, North China Craton, and the tectonic implications

Using petrography, phase equilibria modeling and in situ (U–Th)–Pb monazite geochronology, we show that pelitic gneiss from close to the bottom of the Qitan1 borehole in the northwest of the Ordos Basin records a four stage metamorphic evolution. The M1–M3 stages, which were suprasolidus, are represented by: rutile relicts in the matrix and biotite+K-feldspar+plagioclase+sillimanite+quartz inclusions in the cores of garnet porphyroblasts (M1); inclusion-free mantles on garnet with ilmenite (partially replacing rutile) and biotite+K-feldspar+plagioclase+sillimanite+quartz in the matrix (M2); and, the appearance of cordierite in the assemblage biotite+K-feldspar+plagioclase+sillimanite+ilmenite+quartz (M3). The final subsolidus mineral assemblage is garnet+biotite+K-feldspar+plagioclase+sillimanite+cordierite+ilmenite+quartz (M4). The P–T conditions for the mineral assemblage evolution (M1→M4) are constrained by a P–T pseudosection constructed in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 chemical system. The P–T–t path is clockwise involving slight heating during near isothermal decompression from ∼8.8kbar at ∼769°C to 5.5kbar at 785°C followed by close-to-isobaric cooling across the solidus. Two cores of monazite and three unzoned grains that have similar populations of dates yield robust ages of 1.96–1.94Ga, interpreted to date the timing of late prograde-to-peak metamorphism (M1–M2). In addition, one rim and two unzoned monazite grains with similar populations of dates yield robust ages of 1.90–1.88Ga, interpreted to date the timing of post decompression slow cooling across the solidus (M3→M4). On the basis of these results, the pelitic gneiss is interpreted to have formed by crustal thickening (M1) during collision between the Yinshan and Ordos Terranes, the latter with the Khondalite Belt protoliths along its northern margin (present co-ordinates). This collision culminated at ca. 1.95Ga and was followed by decompression (M2–M3) and slow cooling (M4) to ca. 1.89Ga during post-collisional extension. The similarity between the P–T–t path determined in this study and those from HP/MP granulites in the Khondalite belt confirms that they experienced a common tectono-metamorphic history. The P–T–t path records an evolution from an apparent thermal gradient of ∼75°C/kbar at peak pressure to ∼150°C/kbar after decompression. Together with the occurrence of mid-Paleoproterozoic magmatism in the basement of the Ordos Basin, these features indicate that the Ordos Terrane was the upper plate at a convergent margin with the Khondalite Belt representing the forearc sediments along its northern edge. Collision with the Yinshan Terrane, part of the subducting plate, led to shallow slab breakoff and the development of a two-sided hot collision and formation of a wide plateau-like hot orogen, similar to those in the numerical models of Sizova et al. (2014).

Multiple metamorphic episodes recorded in the Paleozoic Pyeongan Supergroup on the northeastern margin of the Yeongnam massif, South Korea: Implications for the Songrim (Indosinian) orogeny

Metasedimentary rocks of the Pyeongan Supergroup, which occur as roof pendants on the northeastern margin of the Yeongnam massif, South Korea, preserve a record of the impact of the Late Permian–Triassic Songrim (Indosinian) orogeny in the eastern Eurasia margin. Metamorphic results of this paper have revealed that the metasedimentary rocks were affected by three metamorphic events during the Middle Permian to Middle Mesozoic. Representative mineral assemblages from three metamorphic zones I, II and III are Cld+And±Ky±St, Grt+St+Ky+Bt±And, and And+Sill+Bt±Grt±St, respectively. Kyanite and sillimanite paramorphs after andalusite occur in zones I and III, respectively. Metamorphic P–T conditions and paths were determined from conventional geothermobarometers and compositional isopleths of chloritoid, staurolite, and garnet on P–T pseudosections in the MnO–Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (MnNCKFMASH) and KFMASH–T (TiO2)–O (Fe2O3) systems. In the study area, the Pyeongan Supergroup experienced medium pressure regional metamorphism (M1 and M2) belonging to greenschist to amphibolite facies followed by thermal metamorphism (M3). The M1 metamorphism occurred at 450–500°C and 2–4kbar and produced the kyanite paramorph after andalusite. The M2 metamorphism occurred at 520–600°C and 4–6kbar, and was associated with the growth of garnet, staurolite, and kyanite. The later thermal metamorphism occurred at ca. 580°C and ca. 4kbar, and was caused by intrusion of Jurassic granitoids. The medium pressure regional metamorphism (M1 and M2) have occurred around 270Ma during the Songrim orogeny based on the SHRIMP U–Pb zircon ages.