Petrology and age of Precambrian Aksu blueschist, NW China

Abstract

The first occurrence of blueschist in the Neoproterozoic signifies a transition in thermal regime from a warmer Archean–Proterozoic Earth to modern colder subduction characterized by blueschist facies or ultrahigh pressure metamorphism. To evaluate the thermal regime of the transition, we apply phase equilibrium modeling to the Aksu blueschist in northwestern China to constrain the pressure (P) and temperature (T) conditions of the peak mineral assemblages and to calculate the thermal regime recorded by the blueschist. Phase equilibrium modeling in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–O system indicates that the peak mineral assemblage (glaucophane/riebeckite + epidote + phengite + albite + quartz + chlorite) was developed at P–T conditions of 6.8–8.7 kbar and 320–410 °C for a stilpnomelane-bearing epidote blueschist (AK04) and of 6.5–8.0 kbar and 310–380 °C for an epidote blueschist (AK06). These P–T data define an apparent thermal gradient of ∼470 °C/GPa for the peak stage which is typical of the high-pressure intermediate type metamorphic facies series. In addition, we present new LA–ICP–MS U–Pb ages from detrital zircons from two blueschists (AK04 and AK06) and SHRIMP U–Pb ages from zircon from a cross-cutting post-metamorphic mafic dyke (AK134) to constrain the age of the metamorphism. The youngest concordant detrital zircon ages give a maximum depositional age for the blueschist protoliths of 806 ± 10 (AK04) and 803 ± 10 Ma (AK06), respectively, and the SHRIMP U–Pb ages of zircons from the mafic dyke yields a weighted mean age of 769 ± 19 Ma interpreted to date crystallization. These results constrain the age of Aksu blueschist facies metamorphism to between 769 ± 19 and c. 805 Ma.