Muscovite Research Articles

Deformation along the roof of a fossil subduction interface in the transition zone below seismogenic coupling: The Austroalpine case and new insights from the Malenco Massif (Central Alps)

Abstract A network of fossil subduction plate interfaces preserved in the Central Alps (Val Malenco, N Italy) is herein used as a proxy to study deformation processes related to subduction and subsequent underplating of continental slices (in particular the Margna and Sella nappes) at depths reported to in the former brittle-ductile transition. Field observations, microfabrics, and mapping revealed a network of shear zones comprising mostly mylonites and schists but also rare foliated cataclasites. These shear zones are either located at the contacts of the two nappes or within the boundaries of the Sella unit. Microprobe results point to two different white mica generations, with higher-pressure (Si-rich) phengites rimming lower-pressure (Si-poor) phengites. Garnet is locally observed overgrowing resorbed pre-Alpine cores. Pressure-temperature estimates based on pseudosection modeling point to peak burial deformation conditions of ∼0.9 GPa and 350–400 °C, at ∼30 km depth. Rb/Sr geochronology on marbles deformed during the Alpine event yields an age of 48.9 ± 0.9 Ma, whereas due to incomplete recrystallization, a wide range of both Rb/Sr and 40Ar/39Ar apparent ages is obtained from deformed orthogneisses and micaschists embracing 87–44 Ma. Based on our pressure-temperature, structural and geochronological observations, the studied shear zones last equilibrated at depths downdip of the seismogenic zone in an active subduction zone setting. We integrate these new results in the frame of previous studies on other segments of the same Alpine paleosubduction interface, and we propose that this system of shear zones represents deformation conditions along the subduction interface(s) in the transition zone below the seismogenic zone during active subduction.

Boron isotope record of peak metamorphic ultrahigh-pressure and retrograde fluid\u2013rock interaction in white mica (Lago di Cignana, Western Alps)

This study presents boron (B) concentration and isotope data for white mica from (ultra)high-pressure (UHP), subduction-related metamorphic rocks from Lago di Cignana (Western Alps, Italy). These rocks are of specific geological interest, because they comprise the most deeply subducted rocks of oceanic origin worldwide. Boron geochemistry can track fluid–rock interaction during their metamorphic evolution and provide important insights into mass transfer processes in subduction zones. The highest B contents (up to 345 μg/g B) occur in peak metamorphic phengite from a garnet–phengite quartzite. The B isotopic composition is variable (δ11B = − 10.3 to − 3.6%) and correlates positively with B concentrations. Based on similar textures and major element mica composition, neither textural differences, prograde growth zoning, diffusion nor a retrograde overprint can explain this correlation. Modelling shows that B devolatilization during metamorphism can explain the general trend, but fails to account for the wide compositional and isotopic variability in a single, well-equilibrated sample. We, therefore, argue that this trend represents fluid–rock interaction during peak metamorphic conditions. This interpretation is supported by fluid–rock interaction modelling of boron leaching and boron addition that can successfully reproduce the observed spread in δ11B and [B]. Taking into account the local availability of serpentinites as potential source rocks of the fluids, the temperatures reached during peak metamorphism that allow for serpentine dehydration, and the high positive δ11B values (δ11B = 20 ± 5) modelled for the fluids, an influx of serpentinite-derived fluid appears likely. Paragonite in lawsonite pseudomorphs in an eclogite and phengite from a retrogressed metabasite have B contents between 12 and 68 μg/g and δ11B values that cluster around 0% (δ11B = − 5.0 to + 3.5). White mica in both samples is related to distinct stages of retrograde metamorphism during exhumation of the rocks. The variable B geochemistry can be successfully modelled as fluid–rock interaction with low-to-moderate (< 3) fluid/rock ratios, where mica equilibrates with a fluid into which B preferentially partitions, causing leaching of B from the rock. The metamorphic rocks from Lago di Cignana show variable retention of B in white mica during subduction-related metamorphism and exhumation. The variability in the B geochemical signature in white mica is significant and enhances our understanding of metamorphic processes and their role in element transfer in subduction zones.

Интервью с актерами Театра Юных Москвичей

Интервью с актерами Театра Юных Москвичей

Linking tracks in mica crystals with phase transitions in a bistable lattice

Since the middle of the last century, scientific research has been conducted to explain the nature of the tracks visible to the naked eye in mica muscovite crystals. In the present work, an attempt to link the appearance of tracks with a phase transition in a bistable medium is made using classical molecular dynamics method. For this purpose, a two-dimensional triangular lattice simulating one row of potassium atoms in mica is considered. Interactions between atoms are described via pairwise Morse potential and a local potential, whose minima create a hexagonal lattice. In order to create a bistability in the system, a mismatch between the equilibrium distance of the triangular lattice and the period of the local potential is artificially introduced. The phase transitions arising from a monotonic increase or decrease of the depth of the local potential are described. It is revealed that at lower temperatures the domains of different phases can coexist, but at higher temperatures the domain with lower potential energy grows with heat release by reducing the high energy domain. It is speculated that the considered model, which provides the possibility of coexistence of two different phases, can be used to explain at qualitative level the nature of dark tracks visible with the naked eye in transparent crystals of mica muscovite.

Timing of Paleozoic Exhumation and Deformation of the High-Pressure Vestgӧtabreen Complex at the Motalafjella Nunatak, Svalbard

The Vestgӧtabreen Complex exposed in the Southwestern Caledonian Basement Province of Svalbard comprises two Caledonian high-pressure units. In situ white mica 40Ar/39Ar and monazite Th-U-total Pb geochronology has resolved the timing of the tectonic evolution of the complex. Cooling of the Upper Unit during exhumation occurred at 476 ± 2 Ma, shortly after eclogite-facies metamorphism. The two units were juxtaposed at 454 ± 6 Ma. This was followed by subaerial exposure and deposition of Bullbreen Group sediments. A 430–400 Ma late Caledonian phase of thrusting associated with major sinistral shearing throughout Svalbard deformed both the complex and the overlying sediments. This phase of thrusting is prominently recorded in the Lower Unit, and is associated with a pervasive greenschist-facies metamorphic overprint of high-pressure lithologies. A c. 365–344 Ma geochronological record may represent an Ellesmerian tectonothermal overprint. Altogether, the geochronological evolution of the Vestgӧtabreen Complex, with previous petrological and structural studies, suggests that it may be a correlative to the high-pressure Tsäkkok Lens in the Scandinavian Caledonides. It is suggested that the Vestgӧtabreen Complex escaped to the periphery of the orogen along the sinistral strike-slip shear zones prior to, or during the initial stages of continental collision between Baltica and Laurentia.

Melt-rock interaction between granitic pegmatites and hosting amphibolites from the Chiavenna Ophiolitic Unit (Tanno Pegmatitic Field, Central Alps, North Italy)

The Tanno pegmatitic field, placed southward of Chiavenna (Central Alps, Sondrio, Italy), develops a large number of subplanar dykes that crosscut the Chiavenna Unit, an ophiolitic complex mainly composed, in the study area, of amphibolite rocks. This study focuses on the contact between a pegmatitic dyke and the amphibolitic country rock. We distinguished four zones across the contact: I) inner amphibolite, II) contact amphibolite, III) contact pegmatite, IV) inner pegmatite. The inner amphibolite, not affected by melt-rock interaction, is composed of amphibole, phlogopite, ilmenite, titanite and rutile. Two amphibole generations occur, both of them showing a patchy compositional zoning. Amphibole I are Mg-hornblende, whereas Amphibole II have a pargasitic composition. The contact amphibolite shows an enrichment of mica belonging to the phlogopite-biotite series, titanite and the presence of fluorapatite and plagioclase (Ab45-60), that is absent in the inner amphibolite. Close to the contact, amphiboles display no zoning and gain an Mg-horneblenditic composition. The contact pegmatite has quartz, albitic plagioclase, garnet (almandine-spessartine series), muscovite, K-feldspar and fluorapatite. It shows a comb texture, with elongation of plagioclase crystals normal to the contact itself. Far from the contact, the inner pegmatite has an increasing grain-size and a less organized texture. In this zone several accessory phases occur, including gahnite, columbite-(Fe), monazite-(Ce), xenotime-(Y), uraninite and betafite. Whole rock analyses suggest that a chemical exchange, concerning both major elements and trace elements, occurred between the pegmatitic melt and the hosting amphibolite. A considerable increase of SiO2, Na2O and, to a lesser extent, of Al2O3 is observed from the amphibolite towards the pegmatite; K2O and CaO show a decrease at the same extent. The REE pattern in the pegmatite highlights an enrichment in HREE at the contact. Mineral chemistry confirms this trend with variations observable in plagioclase, gradually more albitic from the amphibolite to the pegmatite. Mineralogical characters and geochemical features allow to classify the Tanno pegmatite in the LCT (Lithium, Cesium, Tantalium) family. Based on the metamorphic peak conditions reported from the Lepontine Dome the ambient conditions during pegmatite intrusion were ca. 550°C and 5 kbar. The reduced thermal difference between pegmatite and wall rock explains the diffuse contact observed by X-ray micro-computed tomography. The collected data suggest a chemical interaction between melt and wall rock, according to the following reaction taking place in the amphibolite Amphibole I + Amphibole II + Ilmenite + Pegmatitic melt → Amphibole III + Plagioclase + Phlogopite + Titanite + Fluorapatite

Geochemical characteristics and uranium mineralization exploration potential of late Miocene molasse sediments of NW Himalayan foreland basin Pakistan

This study has defined the provenance, tectonic settings, paleo-weathering, sediment-recycling, and sandstone-type uranium mineralization potential of late Miocene mid-Siwalik Dhok Pathan Formation from Surghar-Shingar Range of NW-Himalayan foreland Fold-and-Thrust-belt. Twenty-six sandstone samples were analyzed on XRF and ICP-MS to determine concentrations of different geochemical species. These Himalayan molasse sediments are moderately rich in quartz. The other framework gains include igno-metamorphic and sedimentary lithic fragments (second in abundance after quartz), feldspars, and dominance of ferroan phlogopite (biotite) over white mica. Garnet, epidot, amphibole, magnetite, tourmaline, rutile, zircon, monazite, and uranothorite are present as common accessory minerals. These sandstones are generally classified as lithic arenite, greywacke, and arkose on the basis of geochemistry. These molasse sediments have recorded the signatures of first-cycle detritus mainly contributed by felsic-igneous rocks in collision-arc tectonic settings. Chemical index of weathering and alteration (CIW and CIA) revealed slight/low weathering of source areas. The REE patterns and Eu/Eu* values are also supporting felsic-igneous provenance for the studied samples. The median high concentrations (ppm) of vanadium (V 79.57), thorium (Th 10.08) and uranium (U 33.05) in sandstone, positive correlation of U with Al2O3 (r = 0.22), deposition in strong anoxic environments are the characteristic features of uranium enrichment/accumulation processes in sandstone-type environments thus signifying good potential for uranium exploration.

Strain partitioning in host rock controls light rare earth element release from allanite-(Ce) in subduction zones

AbstractCombined microstructural, mineral chemical, X-ray maps and X-ray single-crystal diffraction analyses are used to reveal the behaviour of individual grains of magmatic allanite relicts hosted in variably deformed metagranitoids at Lago della Vecchia (inner part of the Sesia-Lanzo Zone, Western Alps, Europe), which experienced high-pressure and low-temperature metamorphism during the Alpine subduction. X-ray single-crystal diffraction shows that none of the allanite crystals, irrespective of the strain state of the host rock, record any evidence of plastic deformation (i.e. intracrystalline deformation), as indicated by the shape of the Bragg diffraction spots, the atomic site positions, and their displacement around the centre of gravity. On the contrary, strong plastic deformation affected matrix minerals, such as quartz, white mica and feldspar of the hosting rocks, during the development of the Alpine eclogitic- and blueschist-facies metamorphism. Despite the strain-free atomic structures of allanite, different patterns of chemical zoning, as a function of strain accumulated in the rock matrix, are observed. As allanite occurs in magmatic and metamorphic rocks and it is stable at high-pressure and low-temperature conditions, we infer that allanite could behave as one of the main carriers of light rare earth elements into the mantle wedge during subduction of continental crust. In particular, the release of light rare earth elements from allanite, under high-pressure conditions in subduction zones, is facilitated by high strain accumulated in the host rock.

Multistage gold mineralization events in the Archean Tati greenstone Belt, northeast Botswana: Constraints from integrative white mica Ar/Ar, garnet U-Pb and sulfides Pb/Pb geochronology

The Tati Greenstone Belt (TGB) in northeastern Botswana hosts numerous Au deposits (Shashe, Mupane and Signal Hill) associated with sulfides, garnet and white mica. In this study, integrative white mica Ar/Ar, garnet U-Pb and sulfides Pb/Pb dating techniques were combined with whole rock and sulfide Pb isotope characteristics to track the source(s) of gold and constrain the timeframes of gold mineralization events. All sulfides and arsenopyrite samples from the TGB yielded overlapping Pb/Pb errorchron ages of 2227 ± 66 Ma and 2220 ± 73 Ma, respectively, which coincide with the Shashe sulfides Pb/Pb errorchron age of 2250 ± 110 Ma. These relatively imprecise Pb/Pb dates suggest heterogeneity in the initial Pb isotope ratios of sulfides. At Mupane, whereas Au mineralization-associated hydrothermal almandine garnet yielded overlapping Tera-Wasserburg lower intercept 206Pb/238U age and a concordia age of 2119 ± 18 Ma (MSWD = 1.03) and of 2105 ± 24 Ma (MSWD of concordance = 1.10), respectively, sulfides produced an errorchron Pb/Pb age of 2873 ± 140 Ma, which despite the large error remains geologically meaningful as it coincides within error with the first Neoarchean Limpopo-Liberian Orogeny (2.70–2.65 Ga), granitoids intrusion emplacement (2.65–2.73 Ga) and deposition of banded iron formation (2.73 ± 0.15 Ga). Ore-related white mica from Signal Hill yielded an overlapping Ar/Ar plateau age of 1987 ± 24 Ma and a weighted mean Ar/Ar age of 1987 ± 13 Ma (n = 15, MSWD = 4.3), which coincide within error with the 2.05–1.95 Ga second Limpopo-Liberian tectonic cycle, herein considered to have possibly triggered the Au mineralization in this area. The obtained radiometric dates point to at least three well constrained gold mineralization events, with two of them possibly triggered by two different regional tectonic events. Lead isotope compositions of most of the sulfides overlap with those of spatially associated schists and granitoids, thus suggesting these units possibly represent Pb and by inference Au rock sources. The genetic model of the TGB Au deposits is consistent with many greenstone-hosted gold deposits worldwide, suggesting our results are not solely of local/regional interest, but can be used to characterize greenstone-hosted gold deposits worldwide.

Exhumation of eclogitic ophiolitic nappes in the W. Alps: New age data and implications for crustal wedge dynamics

The W. Alps high pressure ophiolitic terranes (Monviso and Rocciavre areas) are a natural laboratory to study processes such as nappe-stacking and crustal exhumation in the deep regions of subduction margins. We sampled each of the main shear zones, representing thrust contacts later reactivated as detachments, for petrological and Rb-Sr multi-mineral geochronological analyses. Three generations of white mica are commonly found in mylonitized metasediments with crystal cores formed during the high pressure event, a broad rim formed during decompression in the epidote blueschist facies and texturally late muscovite flakes locally lining the main foliation. Semi-brittle discrete shear zones commonly crosscut previous structures witnessing deformation at temperatures lower than 300°C during exhumation. In spite of this apparent structural heterogeneity, homogeneous deformation ages mostly ranging between 38 and 35 Ma were obtained for all the shear zones bounding these major ophiolitic bodies. Pseudosection modeling confirms that the bulk of the shearing occurred in the epidote blueschist facies around 400–450°C and 1.0–1.5 GPa. These findings suggest that the shear zones between high pressure ophiolitic nappes were being actively mylonitized during exhumation in the lower epidote blueschist facies (25–40 km depth) between 38 and 35 Ma while some of the units forming the internal crystalline massifs (e.g. the Dora Maira Ultra High-Pressure unit) were still buried at more than 100 km depth (3–4 GPa and 36-34 Ma, according to most recent peak burial estimates). The growth of a crustal-scale duplex in the W. Alps is seen here as a consequence of basal accretion events that followed the exhumation of eclogitized coherent crustal slices in a serpentinized subduction channel. We conclude that in the study area (i) the buoyancy-driven exhumation of subducted continental crust has not been the only and decisive trigger for the exhumation of eclogitized oceanic lithosphere and (ii) continental subduction imprint on crustal wedge dynamics may have not been as instrumental as previously thought.

A probing system with a rotatable tip for 3D coordinate nanometrology

Performing coordinate nanometrology of arbitrarily shaped three-dimensional (3D) objects about a micrometer or less in size remains a challenge. In this paper we report a probing system with a rotatable tip for performing coordinate metrology on such objects. An atomically sharp tip is mounted on an active ball-and-socket microjoint, and the two are integrated into a conventional microcantilever probe. The ball-and-socket joint allows the tip to be pointed in any direction, and thereby enables access to any desired 3D feature, while the probe is employed to repeatedly touch the sample surface and extract its corresponding coordinates. The system has been demonstrated to access the surfaces of both horizontally and vertically oriented muscovite mica surfaces and to perform their coordinate nanometrology.

The absence of high-pressure metamorphism in the inverted Barrovian metamorphic sequences of the Arun area, eastern Nepal and its tectonic implication

The metamorphic pressure–temperature (P–T) conditions across the Main central thrust (MCT) in the Arun area have been investigated. The MCT marks the tectono-metamorphic boundary between the overlying high-grade High Himalaya crystalline sequences (HHCS) and the underlying low-grade Lesser Himalaya sequences (LHS). The metamorphic rocks regionally preserve an inverted Barrovian sequence (i.e., intermediate P/T type metamorphism) devoid of previously reported high-pressure metamorphism. The metamorphic grade increases upwards from 670–740 °C and 6.9–9.4 kbar in the MCT zone and lower HHCS to 760–835 °C and 10.0–11.1 kbar in the middle HHCS. Orthoamphibole gneisses in the middle HHCS yield prograde Barrovian-type metamorphism, such as staurolite inclusions in garnets, showing an intermediate P/T gradient. The differences in the tectonic setting and metamorphic evolution imply that the metamorphic units in the Arun area do not correspond to the other high-pressure units in eastern Himalaya. Zircon and monazite U–Pb ages from kyanite gneiss of the lower HHCS reveal the MCT activity, associated with fluid-present anatexis, at ca. 20–14 Ma. Furthermore, similar K–Ar white mica ages (ca. 13–7 Ma) in the hanging wall and footwall of the MCT could represent the timing of later deformation events in shear zones or cooling, possibly associated with exhumation accompanied by activities on younger, structurally lower thrust faults such as the lower MCT. The similar P–T conditions near the MCT in this area could result from recrystallization during syn-metamorphic thrusting, whereas the middle HHCS away from the MCT preserve the original Barrovian metamorphic sequences related to crustal thickening. This and previous studies imply that different P–T profiles near the MCT according to each transect observed in Nepal could be apparent and the cumulative result of polyphase metamorphism.

Effect of rock mineralogy on mortar expansion

Alkali-silica reaction (ASR) is among one of the most important damaging mechanisms in concrete, depending primarily on aggregates which contain reactive minerals. However, expansion in concrete may not directly relate to the reactive minerals. This study aims to investigate the influence of ASR and the expansion of mortar bars depending on aggregate type containing various components such as quartz, clay minerals (montmorillonite and kaolinite) and micas (muscovite and biotite). In this study, the accelerated mortar bar tests (AMBT) were performed in two conditions (mortar bars in the same and sole NaOH solutions). Petrographic thin section studies, X-ray diffraction (XRD) analysis (Rietveld method), scanning electron microscopy (SEM) and chemical analyses were carried out. This study showed that quartzite bars led to increase in expansion values of mortar bars in diabase-1 and andesite when these were in the same NaOH solution. However, three samples (basalt, quartzite and claystone) were found having ASR expansion based on the AMBT when the special molds were used for each sample. SEM study revealed that samples which exhibit highest expansions according to AMBT had a generally rough surface and acicular microstructures in or around the micro-cracks. Basalt and quartzite showed more variable in major oxides than those of other samples based on the chemical analyses, SEM studies and AMBT. This study revealed that the highest expansions were observed to source not only from reactive aggregates but also from alteration products (silicification, chloritization, sericitization and argillisation), phyllosilicates (muscovite, biotite and vermiculite) and clays (montmorillonite and kaolinite).

Стрелецкий сотник Микула –Московит, о котором узнала Европа

Стрелецкий сотник Микула –Московит, о котором узнала Европа

Mineralogy and mineral geochemistry of the Tuwu porphyry Cu deposit, Eastern Tianshan, NW China: implication for the ore-forming condition and Cu mineralization

The Tuwu deposit is one of the largest porphyry copper deposits in Eastern Tianshan, NW China. The widespread hydrothermal alteration is associated with porphyries and their wall-rocks in the porphyry deposit can be divided into potassic, chlorite–sericite, phyllic, and propylitic zones. In this study, we conducted a detailed study on the mineralogy of hydrothermal magnetite, mica, and epidote. Magnetite is closely related to the potassic alteration, and evolves from earlier disseminated magnetite (Mt-I) to the later magnetite–quartz ± biotite ± pyrite ± bornite ± chalcopyrite veins (Mt-II). The significant decrease in the Cr2O3 and V2O3 contents of magnetite from early to late period indicates the gradual increase of oxygen fugacity. The crystallization of magnetite supplies enough reduced sulfur that promotes the sulfide precipitation. The dominance of muscovite (Mc-I) in the early phyllic stage and the increasing of phengite muscovite (Mc-II) in the late phyllic stage suggest the evolution of hydrothermal fluid from a high-temperature and acidic environment to a low-temperature and less acidic environment. This process also results in the decrease of sulfide mineral deposition in the late phyllic stage. Epidote from propylitic zones at Tuwu has similar characteristic with the overprinting epidote in the Yandong porphyry Cu systems. Propylitic Ep-I have higher FeO content than Ep-II. The interaction of Fe-rich propylitic epidote with hydrothermal fluid enhanced both Ca2+ activity and pH value, and favored the precipitation of sulfides (e.g., chalcopyrite). In addition, the Fe-rich and less acidic fluids, which derived from the propylitic zones and flow though the sericitic rocks in the phyllic zones, also promote the deposition of Cu mineralization. Our results, combined with previous research on fluid inclusion, isotopes, and mass transfer, suggest that the changes in temperature, oxygen fugacity, and pH caused by the fluid–rock interaction played a critical role for the Cu mineralization at Tuwu.

The sapphirine-bearing rocks in contact with the Lherz peridotite body: New mineralogical data, age and interpretation

Sapphirine-bearing rocks are described in the Aulus Basin (Ariège, France) in a contact zone between the Lherz peridotitic body and Mesozoic metasediments which underwent the Pyrenean Cretaceous high-temperature, low-pressure metamorphic event (Monchoux, 1970, 1972a, 1972b). Sapphirine crystals occur in layered clastic deposits characterized by an uncommon suite of Al-Mg-rich minerals. A detailed petrographic study of sixteen samples representative of the diversity of the Lherz sapphirine-bearing rocks is presented. These rocks include breccias and microbreccias with various compositions. Some samples are composed of polymineralic clasts and isolated minerals that derive from regionally well-known protoliths such as ultramafic rocks, meta-ophites, “micaceous hornfels”, and very scarce Paleozoic basement rocks. Nevertheless, a large portion of the sapphirine-bearing clastic suite is composed of mono- and polymineralic debris that derive from unknown protolith(s). We define a "sapphirine-bearing mineral suite” (SBMS) composed of monomineralic debris including: sapphirine + enstatite + aluminous spinel + Mg-amphiboles + Ca-amphiboles + kornerupine + accessory minerals (apatite, diopside, rutile, serpentine, smectite, tourmaline, vermiculite and a white mica). We highlight the dominance of metamorphic Keuper clastic materials in the studied rocks and the presence of inclusions of anhydrite and F-, Cl-, Sr-rich apatite in minerals of the Al-Mg-rich suite. The brecciated texture and the presence of unequivocal sedimentary features suggest that the sapphirine-bearing rocks were mechanically disaggregated and then experienced winnowing in underwater conditions with poor mixing between the different sources. We measured U-Pb rutile age data in order to provide constraints on the age of (one of) the protolith(s) of those clastic deposits. The obtained age (98.6 + 1.2 Ma) is interpreted as the age of metamorphism of this protolith of the SBMS. Previous works interpreted the Lherz sapphirine-bearing rocks as crustal protoliths modified at depth along the contact with the ultramafic rocks of the Lherz body during their ascent towards shallower depths. These new data imply: (i) an Upper Triassic to Lower Jurassic origin for the main protolith of the sapphirine-bearing rocks; (ii) the metamorphism of this protolith along an active hot crust–mantle detachment during Cenomanian times with the involvement of metasomatic, brine-type fluids; and (iii) its brecciation during the exhumation of the material due to the evolution of the detachment, followed by subsequent sedimentary reworking of the metamorphic material.

Effect Of Thermal Treatment Of Trepel At Temperature Range 800-1200˚C

AbstractTrepel is the local name for a mixture of diatomaceous earth and clay minerals. It represents a greyish, soft, very light, weakly cemented, fine biogenetic sedimentary rock. The studied material is taken from the vicinity of Bitola city (Republic of Macedonia). Here, trepel was treated up to three temperature intervals (800, 1000 and 1200C) for a period of 1 hour. The X-ray powder diffraction results indicate the presence of both an amorphous phase and the following crystalline phases: quartz, feldspars (plagioclase), mica (muscovite) and chlorites. The results of SEM analysis revealed skeletons of alga Diatomeae with nano-pores. By thermal treatment of the samples, a gradual change in color as well as higher bulk density and compressive strength was observed. The increase of the temperature, in addition, affected the mineralogical composition and increased the presence of the amorphous phase (aluminasilicate glassy phase). SEM results of the thermally investigated samples depicted morphological changes expressed by shrinkage of the pore diameters in comparison to the initial material. The major and minor constituents were established by chemical analysis revealing the following chemical composition of raw trepel: SiO2 (63.65 wt%), Al2O3 (11.76 wt%), Fe2O3 (5.93 wt%), MnO (0.13 wt%), TiO2 (0.63 wt%), CaO (1.42 wt%), MgO (2.22 wt%), P2O5 (0.11 wt%), K2O (1.63 wt%), Na2O (0.92 wt%), LOI (11.50 wt%).

Organothiol Monolayer Formation Directly on Muscovite Mica

AbstractOrganothiol monolayers on metal substrates (Au, Ag, Cu) and their use in a wide variety of applications have been extensively studied. Here, the growth of layers of organothiols directly onto muscovite mica is demonstrated using a simple procedure. Atomic force microscopy, surface X‐ray diffraction, and vibrational sum‐frequency generation IR spectroscopy studies revealed that organothiols with various functional endgroups could be self‐assembled into (water) stable and adaptable ultra‐flat organothiol monolayers over homogenous areas as large as 1 cm2. The strength of the mica–organothiol interactions could be tuned by exchanging the potassium surface ions for copper ions. Several of these organothiol monolayers were subsequently used as a template for calcite growth.

Organothiol Monolayer Formation Directly on Muscovite Mica.

Organothiol monolayers on metal substrates (Au, Ag, Cu) and their use in a wide variety of applications have been extensively studied. Here, the growth of layers of organothiols directly onto muscovite mica is demonstrated using a simple procedure. Atomic force microscopy, surface X‐ray diffraction, and vibrational sum‐frequency generation IR spectroscopy studies revealed that organothiols with various functional endgroups could be self‐assembled into (water) stable and adaptable ultra‐flat organothiol monolayers over homogenous areas as large as 1 cm2. The strength of the mica–organothiol interactions could be tuned by exchanging the potassium surface ions for copper ions. Several of these organothiol monolayers were subsequently used as a template for calcite growth.

Muscovite mica as a universal platform for flexible electronics

Muscovite mica as a universal platform for flexible electronics