Municipal Wells Research Articles

Characterization of groundwater dynamics and contamination in an unconfined aquifer using isotope techniques to evaluate domestic supply in an urban area

In the urban area of Rio Cuarto groundwater is used for domestic supply. The objective of the current research was to investigate the water dynamics and nitrate contamination in an unconfined aquifer system of Rio Cuarto River basin. Stable isotopes of water (δ18O and δ2H) and nitrate (δ15N–NO3 and δ18O–NO3) were used and combined with conventional chemical techniques and mixing modelling approaches to determine the recharge areas and identify the main origin of nitrate pollution. More enriched water isotope values were recorded in Rio Cuarto city than in the piedmont and mountains indicating local recharge for well batteries 2 and 3. The well battery 1 and the infiltration gallery showed more negative isotopic values, demonstrating a strong influence by the recharge from the piedmont sector (impoverished groundwater). The δ15N–NO3 values and the Bayesian modeling showed that the dominant nitrate contamination source in the urban area is the on-site sanitation systems whereas in the peri-urban area nitrate contamination originates mostly from animal wastes. Both sources supply the aquifer with anthropogenic organic matter (>50%). The highest δ15N–NO3 values were correlated with low dissolved oxygen values, indicating the occurrence of denitrification processes in some places. High NO3 ions in the rural sector were attributed to the application of fertilizers and consequent nitrification processes. The samples from Rio Cuarto river located upstream of the Rio Cuarto City and close to the infiltration gallery showed the highest input from fertilizers (~40%), due to surrounding agricultural fields. The municipal well batteries showed good water quality (freshwater of low to extremely low nitrate concentration) which is linked to the high hydraulic conductivity of the aquifer that increases its capacity to dilute the contaminants. These results will be useful for local water administrators to improve water management.

Hydraulic tomography analysis of municipal-well operation data with geology-based groundwater models

The sustainable management of groundwater resources is essential to municipalities worldwide due to increasing water demand. Planning for the optimized use of groundwater resources requires reliable estimation of hydraulic parameters such as hydraulic conductivity (K) and specific storage (Ss). However, estimation of hydraulic parameters can be difficult with dedicated pumping tests while municipal wells are in operation. In this study, the K and Ss of a highly heterogeneous, multi-aquifer/aquitard system are estimated through the inverse modeling of water-level data from observation wells collected during municipal well operations. In particular, four different geological models are calibrated by coupling HydroGeoSphere (HGS) with the parameter estimation code PEST. The joint analysis of water-level records resulting from fluctuating pumping and injection operations amounts to a hydraulic tomography (HT) analysis. The four geological models are well calibrated and yield reliable estimates that are consistent with previously studies. Overall, this research reveals that: (1) the HT analysis of municipal well records is feasible and yields reliable K and Ss estimates for individual geological units where drawdown records are available; (2) these estimates are obtained at the scale of intended use, unlike small-scale estimates typically obtained through other characterization methods; (3) the HT analysis can be conducted using existing data, which leads to substantial cost savings; and (4) data collected during municipal well operations can be used in the development of new groundwater models or in the calibration of existing groundwater models, thus they are valuable and should be archived.

Trendline and Monthly Variations of Nitrate in Water Supply Wells in Upper Egypt

Safe drinking water is among the most important environmental as well as health challenges facing Egypt. Groundwater from the aquifer of the Nile valley in Upper Egypt accounts for about 40% of the overall source of drinking water. Nearly, all rural residents rely on groundwater as the source of drinking water. Irrigation water is the main source of groundwater recharge in Nile Valley. Moreover, nitrate fertilizer utilization in Egypt has risen significantly due to the requirement for further agricultural production. Nitrate levels higher than the permissible limit (45 mg/L) for drinking water have been related to health issues. To determine the effect of agrochemical nitrate on the health of pumping water, municipal water wellfields established in Upper Egypt have been examined. Pumped water from those municipal wells (60 m depth and 2000 m3/day gross pumping rate) was evaluated from 2000 to 2018 to accomplish this objective. Monthly analysis of the quality of groundwater, in particular nitrate, has been conducted. Sulfate and nitrate concentrations as well as other consistency metrics were assessed. Water sampling findings show that the water already comes under the drinking-water limits. Nevertheless, increased nitrate and sulfate values are found beyond naturally existing levels in the aquifer. Consequently, to determine the possible future likelihood of nitrate contamination in such municipal wells, the trendline of nitrate level has been used. The observations suggest that the intensive utilization of nitrogen fertilizer in Upper Egypt in the last 30 years would endanger the quality of the groundwater supply. Resultantly, the usage of nitrogen fertilizers in Upper Egypt must be regulated and continuous groundwater monitoring must be implemented.

Spatial Characteristics of Groundwater Chemistry in Unzen, Nagasaki, Japan

Nitrate pollution in groundwater is a serious problem in Shimabara Peninsula, Nagasaki, Japan. A better understanding of the hydrogeochemical evolution of groundwater in vulnerable aquifers is important for health and environment. In this study, groundwater samples were collected at 12 residential and 57 municipal water supply wells and springs in July and August 2018. Nitrate (NO3−N) concentration at eight sampling sites (12%) exceeded Japanese drinking water standard for NO3 + NO2−N (10 mg L−1). The highest nitrate concentration was 19.9 mg L−1. Polluted groundwater is distributed in northeastern, northwestern, and southwestern areas, where land is used for intensive agriculture. Correlation analysis suggests that nitrate sources are agricultural fertilizers and livestock waste. Dominant groundwater chemistry is (Ca+Mg)−HCO3 or (Ca+Mg)−(SO4+NO3) type. Groundwater with higher nitrate concentration is of (Ca+Mg)−(SO4+NO3) type, indicating nitrate pollution affecting water chemistry. Principal component analysis extracted two important factors controlling water chemistry. The first principal component explained dissolved ions through water–rock interaction and agricultural activities. The second principal component explained cation exchange and dominant agricultural effects from fertilizers. Hierarchical cluster analysis classified groundwater into four groups. One of these is related to the dissolution of major ions. The other three represent nitrate pollution.

Groundwater Quality of Aquifers Overlying the Oxnard Oil Field, Ventura County, California

Groundwater samples collected from irrigation, monitoring, and municipal supply wells near the Oxnard Oil Field were analyzed for chemical and isotopic tracers to evaluate if thermogenic gas or water from hydrocarbon-bearing formations have mixed with surrounding groundwater. New and historical data show no evidence of water from hydrocarbon-bearing formations in groundwater overlying the field. However, thermogenic gas mixed with microbial methane was detected in 5 wells at concentrations ranging from 0.011–9.1 mg/L. The presence of these gases at concentrations <10 mg/L do not indicate degraded water quality posing a known health risk. Analysis of carbon isotopes (δ13C-CH4) and hydrogen isotopes (δ2H-CH4) of methane and ratios of methane to heavier hydrocarbon gases were used to differentiate sources of methane between a) microbial, b) thermogenic or c) mixed sources. Results indicate that microbial-sourced methane is widespread in the study area, and concentrations overlap with those from thermogenic sources. The highest concentrations of thermogenic gas were observed in proximity to relatively high density of oil wells, large injection volumes of water disposal and cyclic steam, shallow oil development, and hydrocarbon shows in sediments overlying the producing oil reservoirs. Depths of water wells containing thermogenic gas were within approximately 200 m of the top of the Vaca Tar Sand production zone (approximately 600 m below land surface). Due to the limited sampling density, the source and pathways of thermogenic gas detected in groundwater could not be conclusively determined. Thermogenic gas detected in the absence of co-occurring water from hydrocarbon-bearing formations may result from natural gas migration over geologic time from the Vaca Tar Sand or deeper formations, hydrocarbon shows in sediments overlying producing zones, and/or gas leaking from oil-field infrastructure. Denser sampling of groundwater, potential end-members, and pressure monitoring could help better distinguish pathways of thermogenic gases.

Bayesian Poroelastic Aquifer Characterization From InSAR Surface Deformation Data. Part I: Maximum A Posteriori Estimate

AbstractCharacterizing the properties of groundwater aquifers is essential for predicting aquifer response and managing groundwater resources. In this work, we develop a high‐dimensional scalable Bayesian inversion framework governed by a three‐dimensional quasi‐static linear poroelastic model to characterize lateral permeability variations in groundwater aquifers. We determine the maximum a posteriori (MAP) point of the posterior permeability distribution from centimeter‐level surface deformation measurements obtained from Interferometric Synthetic Aperture Radar (InSAR). The scalability of our method to high parameter dimension is achieved through the use of adjoint‐based derivatives, inexact Newton methods to determine the MAP point, and a Matérn class sparse prior precision operator. Together, these guarantee that the MAP point is found at a cost, measured in number of forward/adjoint poroelasticity solves, that is independent of the parameter dimension. We apply our methodology to a test case for a municipal well in Mesquite, Nevada, in which InSAR and GPS surface deformation data are available. We solve problems with up to320,824state variable degrees of freedom (DOFs) and16,896parameter DOFs. A consistent treatment of noise level is employed so that the aquifer characterization result does not depend on the pixel spacing of surface deformation data. Our results show that the use of InSAR data significantly improves characterization of lateral aquifer heterogeneity, and the InSAR‐based aquifer characterization recovers complex lateral displacement trends observed by independent daily GPS measurements.

Three-dimensional hydraulic tomography analysis of long-term municipal wellfield operations: Validation with synthetic flow and solute transport data

This study proposes the utilization of municipal well records as an alternative dataset for large-scale heterogeneity characterization of hydraulic conductivity (K) and specific storage (Ss) using hydraulic tomography (HT). To investigate the performance of HT and the feasibility of utilizing municipal well records, a three-dimensional aquifer/aquitard system is constructed and synthetic groundwater flow and solute transport experiments are conducted to generate data for inverse modeling and validation of results. In particular, we simultaneously calibrate four groundwater models with varying parameterization complexity using five datasets consisting of different time durations and periods. Calibration and validation results are qualitatively and quantitatively assessed to evaluate the performance of investigated models. The estimated K and Ss tomograms from different model cases are also validated through the simulation of independently conducted pumping tests and conservative solute transport. Our study reveals that: 1) the HT analysis of municipal well records is feasible and yields reliable heterogeneous K and Ss distributions where drawdown records are available; 2) accurate geological information is of critical importance when data density is low and should be incorporated for geostatistical inversions; 3) the estimated K and Ss tomograms from the geostatistical model with geological information are capable in providing robust predictions of both groundwater flow and solute transport. Overall, this synthetic study provides a general framework for large-scale heterogeneity characterization using HT through the interpretation of municipal well records, and provides guidance for applying this concept to field problems.

The application of multi-criteria (AHP-PROMETHEE) decision-making methods in selecting and prioritizing the green area irrigation resources

One of the underlying factors in the conservation and development of urban green spaces is the available water resources use for green areas in each region. The primary purpose of this study is to introduce the integration of a proper simulation method for runoff along with AHP-PROMETHEE decision-making method for water resources management in urban basins. The application of this approach was investigated in the city Buin Zahra of Qazvin Province of Iran. In the first step by using the analytic hierarchy process (AHP), the available water resources in the case study were weighted. In the second step, the water resources of the municipal and residential wells and water collected by precipitation and flooding were investigated to provide irrigation water. The Storm Water Management Model was applied to optimize water resources use from the flood as a solution to save potable water. The simulation was performed for precipitation with a return period of 5 and 10 years, for 6-h intervals. The simulation results were carried out for a total of 25 nodes, and the discharge was calculated, which is between 0.95 up to 1.2 cubic meters per second. The flow of the resulting discharge can feed the required water for green areas. Also, the available water resources in the case study were weighted by Expert Choice and were finally selected by using the Preference Ranking Organization Method for Enrichment Evaluation (PROMETHEE). The results indicated that residential wells had the priority in supplying irrigation water for green areas.

Diminishing Depth to Water in Cambrian-Ordovician Arbuckle Group Disposal Wells in Kansas

Industrial and municipal wastewater and oilfield brines have been disposed of into the Cambrian-Ordovician Arbuckle Group for decades in Kansas and nearby states in the midcontinent United States. The industrial and municipal wastewater disposal wells (designated Class I disposal wells) are regulated by the Kansas Department of Health and Environment. The oilfield brines are disposed of in Class II disposal wells, which are regulated by the Kansas Corporation Commission. Annual testing of formation pressure and static fluid levels in Class I wells compose a body of data that is useful in monitoring movement of water and fill-up of Arbuckle disposal zones. In western Kansas, the depth to water in wells penetrating the Arbuckle can be several hundred to more than a thousand feet (305 m) below ground surface, but in parts of southern and southeastern Kansas, the depth to water locally can be less than 100 ft (31 m). Furthermore, most Class I wells indicate Arbuckle fluid levels in central and south-central Kansas are rising ~10 ft (~3 m) annually, suggesting that at current disposal rates, the Arbuckle may lose its capacity to accept wastewater under gravity flow in parts of the state in the next few decades, principally south-central and southeastern Kansas along the Oklahoma state line. At present in parts of six Kansas counties along the Oklahoma state line, low-density (~1.0 g/cc or slightly greater density) wastewater in a wellbore does not have a sufficient hydrostatic head by gravity alone to force its way into the more dense resident Arbuckle formation water.&#x0D; In general, Arbuckle formation water flows west to east in Kansas. Arbuckle disposal wells in Kansas collectively dispose of ~800,000,000 barrels (~127,000,000 m3) of wastewater per year, although some of this is recycled from Arbuckle oil production. Declines in oil price since mid-2014 have resulted in less oilfield disposal in the Arbuckle since 2015. The number of Class I wells recording annual fluid rises have also declined since 2015, as has the median of their annual change in static fluid level, but overall, more Class I wells are still recording fluid rises. There is a poor correlation between changes in fluid levels in Class I wells and the volume of fluid disposed in them annually, thereby indicating that more regional characteristics may control water movement in the Arbuckle. More monitoring wells are needed to better understand the movement of water in the deep subsurface and to anticipate any potential problems that may occur with reduced disposal capacity and possible migration of fluids through unplugged or improperly plugged older wells.

Health Risk Assessment of Groundwater Contamination Case Study: Gaza Strip

Gaza Governorates are suffering from shortage problems and poor quality of groundwater that is being pumped from 281 municipal wells. According to the latest data available at the Palestinian Water Authority (PWA), the water consumption can be distributed on municipal consumption 96.428 MCM and agricultural sector consumption 95.3 MCM. The annual recharge is less than the pumping rate with more than 90 MCM; resulting in declining water level, sea water intrusion and hence high chloride concentrations. Nitrate levels are increasing due to the improper systems of wastewater disposal, excess use of fertilizers and landfill leachate. The nitrate level exceeds the WHO limit in more than 90.6 % of Gaza Governorates municipal wells for the year 2018 (223 wells from a total of 245 wells. Due to the health impacts of nitrate, health risk assessment was conducted based upon the available quality data of 245 municipal wells. The risk assessment method adopted by the United States Environmental Protection Agency was utilized in this study. Three categories of receptors were assessed; infants, children and adults. The study revealed that the health risk values for adults is acceptable in 22 wells only while it is unacceptable in the other 223 wells. For children and small infants, the situation was riskier and the study outlined that none of the municipal wells in Gaza Governorates was suitable for drinking purposes for these two categories of people. The study recommended that actions should be taken to minimize the risk associated with drinking groundwater, looking for alternative water resources is to be seriously considered, community participation should be encouraged, people should know that their source of water is unsuitable and further studies that consider the impact of nitrate in groundwater on the public health in Gaza Strip should be performed.

Evaluating Bank-Filtration Occurrence in the Province of Quebec (Canada) with a GIS Approach

Due to the abundance of surface water in the province of Quebec, Canada, it is suspected that many groundwater wells are pumping a mixture of groundwater and surface water via induced bank filtration (IBF). The regulatory framework in Quebec provides comprehensive guidelines for the development and monitoring of surface water and groundwater drinking water production systems. However, the regulations do not specifically address hybrid groundwater-surface water production systems such as IBF sites. More knowledge on the use of IBF in the province is needed to adjust the regulations with respect to the particularities of these systems. In order to provide a first evaluation of municipal wells potentially using IBF and the corresponding population served by these wells, a Geographic Information Science framework (GISc) was used to implement an IBF spatial database and calculate the distance from each well to the nearest surface water body. GISc is based on open source GIS programs and openly available data, to facilitate the reproducibility of the work. From this provincial scale approach, we show that nearly one million people are supplied by groundwater from municipal wells located &lt;500 m from a surface water body, and half a million have a significant probability to be supplied by IBF wells. A more focused look at the watershed scale distribution of wells allows us to improve our interpretations by considering the aquifer type and other regional factors. This approach reveals strong spatial variability in the distribution of wells in proximity to surface water. Of the three selected regions, one has a high potential for IBF (Laurentides), one requires additional information do draw precise conclusions (Nicolet), and the third region (Vaudreuil-Soulanges) is unlikely to have widespread use of IBF. With this study, we demonstrate that extensive use of IBF is likely and that there is a need for improved understanding and management of these sites in order to properly protect the drinking water supply.

An exploratory data analysis approach for assessing the sources and distribution of naturally occurring contaminants (F, Ba, Mn, As) in groundwater from southern Quebec (Canada)

The presence of naturally occurring contaminants in groundwater is a public health concern in rural areas of northeastern North America, where public and private wells are important sources of drinking water. In southern Quebec (Canada), inorganic groundwater chemistry data have been recently collected following standard procedures in several regional hydrogeological projects implemented by the government of Quebec. In this study, a groundwater chemistry database was compiled from 16 regional projects altogether covering an area of approximately 100,000 km2. The database includes information on water supply infrastructures, geological settings, hydrogeological conditions and inorganic water chemistry for 2369 water samples. Samples were mostly collected from private domestic wells, and to a lesser extent from municipal and observation wells. The data revealed that fluoride, barium, manganese and arsenic are the most common elements exceeding Canadian drinking water guidelines. Exploratory data analysis techniques were applied to selected subsets of data to gain insight into the sources and distribution of these hazardous groundwater contaminants. These exploratory methods include graphical data analysis (maps, Piper and empirical cumulative distribution function plots), multivariate compositional data analysis (clustering and correlation analysis) and geochemical modeling (saturation index calculations). The results suggest that fluoride, barium, manganese and arsenic are all derived from natural sources. Elevated fluoride concentrations are mainly associated with dilute Ca–Na–HCO3 bedrock groundwaters from granitic areas (Grenville Province), and more geochemically evolved Na–HCO3 to Na–HCO3–Cl bedrock groundwaters from shale areas (St. Lawrence Platform). High-F groundwaters are generally characterized by low Ca concentrations (<30 mg/L) and alkaline pH (pH > 8), suggesting that F is mainly controlled by fluorite (CaF2) precipitation and anion exchange with OH−. Barium is present at elevated concentrations in mineralized Ca–Na–HCO3, Na–HCO3 to Na–HCO3–Cl waters from bedrock aquifers of the St. Lawrence Lowlands. These groundwaters are mainly chemically evolved, strongly reducing waters occurring in confined aquifers and near major faults, which appear to correspond to discharge areas for deep regional flow. High Ba concentrations are generally associated with very low SO4 concentrations (< 5 mg/L) resulting from sulfate reduction, suggesting a solubility control of Ba through barite (BaSO4) precipitation. Most high manganese concentrations occur in less chemically evolved, near-neutral Ca–HCO3 groundwaters from both granular and bedrock aquifers, particularly those associated with metasedimentary and metavolcanic lithologies (Superior Province, St. Lawrence Platform and Appalachian Province). The results suggest that dissolved Mn concentrations are limited by the precipitation of Mn carbonates under alkaline conditions, but increase under reducing conditions owing to the dissolution of Fe–Mn oxyhydroxides. Elevated arsenic concentrations were mostly found in Ca-(Na–Mg)–HCO3 bedrock groundwaters of the Superior and Appalachian Provinces. As-rich groundwaters are associated with the presence of As-bearing sulfides in weakly metamorphosed sedimentary rocks (shale, slate, phyllite) and hydrothermally altered rocks. Most high As concentrations do not appear to be directly derived from sulfide oxidation, but rather from secondary sources, in particular through the reductive dissolution of As-rich Fe–Mn oxyhydroxides. This work shows that the combination of graphical, multivariate statistical and geochemical modeling techniques is a powerful approach to explore large hydrochemical datasets. It also reveals the benefits of using multivariate compositional data analysis instead of classical approaches based on raw data and log-ratios for groundwater chemistry data. Compositional data analysis techniques improved the detection of multivariate outliers, the cluster reliability in cluster analysis, and removed the spurious positive correlation between hydrochemical variables associated with total mineralization.

Evaluation of the Groundwater Quality Using the Water Quality Index and Geostatistical Analysis in the Dier al-Balah Governorate, Gaza Strip, Palestine

Groundwater contamination is a major problem in the Gaza Strip. In this study we investigate the groundwater quality in the Dier al-Balah Governorate. Water samples were collected from 19 municipal wells in April 2009 and April 2014 and analyzed for physio-chemical parameters (pH, TDS, Ca2+, Mg2+, Na+, K+, Cl−, SO42–, HCO3− and NO3−). The aim of the research is to determine the groundwater quality and to produce groundwater quality maps using the water quality index (WQI) method and geostatistical analysis. The results show that all water samples are very saline due to the intrusion of Mediterranean seawater in the coastal aquifer. Differences in chemical composition between 2009 and 2014 indicate that about 1% more seawater was mixed with the groundwater in this period. The majority of the observed chemical parameters of all wells are well above the WHO water quality standards and all WQI values indicate that the water quality is problematic. The spatial variation of the WQI scores is modelled by a deterministic component expressing a linear dependence on the distance to the coastline and a stochastic residual described by an exponential variogram with a practical range of 3000 m. The mapping of the WQI scores and derived water quality classes is achieved through regression-kriging. The results indicate that the groundwater in a large area along the coastline is unsuitable for human consumption and comparison of the maps of 2009 and 2014 shows that this region further expanded by about 700 m inland in a period of 5 years. The results of this study are worrying, but they also contribute to a better understanding of the factors that determine the groundwater quality and can help authorities and stakeholders with sustainable development.

Role of Quaternary glacial-outburst megaflood paleochannel deposits in a basalt-dominated aquifer system in the West Plains area of eastern Washington, USA

Approximately 2 km2 of sand- and gravel-rich Pleistocene glacial-outburst megaflood sediment has accumulated in a series of five subparallel paleochannels that are an important component of a basalt-dominated aquifer system on the semiarid, ~450-km2 West Plains area. Located near Spokane, Washington (USA), the West Plains paleochannel deposits have been used for artificial storage and recovery wells and for planned and passive stormwater disposal in this rapidly growing area. Recent recognition of perfluorooctanoic acid contamination and excessive drawdowns have led to the closure of multiple municipal wells on the West Plains, highlighting the challenges of developing a sustainable groundwater supply in this complex aquifer system. Geologic and hydrogeologic data, from more than 1,400 water-well reports, surface exposures, existing groundwater geochemistry reports, and modeling, reveal the interconnections between the paleochannel deposits and surrounding basalt flows in three dimensions (3D). Initially incised into the Miocene Columbia River Basalt and excavated by Pleistocene glacial-outburst megaflooding, the West Plains paleochannels are projected in unprecedented 3D. This study’s modeled interactions between the more highly hydraulically conductive (100×) paleochannel sedimentary deposits and surrounding basalt beds provide insight into 14C ages and tritium values that had been measured previously. Sediment-filled closed depressions at the bases of the paleochannels, which are features likely formed by turbulent bursts (‘kolks’) during peak megaflood flows, are potentially promising groundwater storage sites. However, because of the relatively higher permeability of the unconfined paleochannel deposits, the closed depressions also are potential conduits for infiltration of contamination to deeper parts of the aquifer system.

Algal bioassays detect modeled loading of wastewater-derived nitrogen in coastal waters of O'AHU, HAWAI'I.

Previous studies indicate coastlines are at risk of wastewater contamination from injection wells, cesspools, and septic systems. In this study, common marine algae were used to ground-truth modeled loading of wastewater-derived N to coastlines of O'ahu, Hawai'i. Macroalgae were collected and/or deployed at 118 sites and analyzed for tissue δ15N and N %. Wastewater source locations were used to estimate wastewater-derived N in groundwater with the modeling software MT3DMS/MODFLOW. Algal bioassays identified six coastal regions subjected to elevated wastewater-derived N loading. In a case study, submarine groundwater discharge (estimated by 222Rn mass balance) was related to wastewater loading from onsite sewage disposal systems (OSDS) and municipal wastewater injection wells in Waimānalo. The highest 222Rn-derived SGD rate and N flux were 21.4m3/m/d and 62.6g/m/d, respectively. The results of this study suggest that OSDS and injection wells discharge substantial volumes of wastewater and N across broad regions of coastal O'ahu.

An integrated multi-techniques approach for hydrogeochemical evaluation of ion exchange processes and identification of water types based on statistical analysis: Application to the Gaza coastal aquifer, Gaza Strip, Palestine

Several approaches for ion exchange process (IEP) evaluation and water type identification have widely been developed during the last several decades. However, a lack of clear methodology to characterise IEP and water type remains a problem. In this paper, a novel hybrid approach is proposed to understand this deficiency, determine IEP accurately, identify hydrogeochemical facies precisely that characterise each hydrogeochemical signature of aquifer salinization and freshening, discriminate between humid and arid areas and investigate Ca2+/Mg2+ enrichment processes which may be accompanied with IEP and would have not explained using other conventional methods. This new method, termed IEP-SF-HA-WT, combines three techniques: hierarchical cluster analysis “HCA”, new hydrochemical analysis, and correlation analysis. It is applied on ten physicochemical variables for 214 municipal wells belonging to Gaza coastal aquifer system, Gaza Strip, Palestine to test its reliability and imputation ability.The results demonstrate that the new hybrid method performs well in discrimination between areas of reverse and direct IEP. It shows the dominance of IEP and the wide impact of reverse IEP as a result of the wide -ranging influence of seawater intrusion, saltwater up-coning and sewage inputs. .Similarly, it illuminates the impact of direct IEP and carbonate dissolution on the groundwater of the northern area. It reveals the predominance of Na–Cl (65.4%), Ca/Mg–HCO3/NO3 (15.9%), Na–HCO3 (8.4%), Ca/Mg–Cl (8%) and the existence of a unique Ca/Mg–NO3/HCO3 type (3.3%) in the northern area as a result of the influence of fertilizer inputs in this area. Moreover, it elucidates the humidity of the northern area due to rainfall recharge, irrigation return flow, and partially treated sewage infiltration. Therefore, the implication of this multi-beneficial approach can be widely used for precise and detailed hydrogeochemical evaluation of groundwater in the Gaza coastal aquifer system as well as for other similar aquifer systems elsewhere around the world.

Integrated Deep Soil N and Groundwater Isotope Investigation of N Sources Captured by Municipal Wells

AbstractIdentification of major nitrate sources that adversely impact groundwater quality in municipal well capture zones in areas of emerging nitrate contamination is essential to minimize leaching and prevent exceedance of the nitrate drinking water standard. Vertical profiles of nitrate leachate in deep soils provide an estimate of the amount of nitrate in transit beneath irrigated, row‐cropped fields; depths of peak leachate; and the approximate rate of downward movement. Profiles of pore‐water soil‐nitrate concentrations in thick 60‐feet (~18 m), fine‐textured soils near Hastings, Nebraska clearly indicate that considerably more nitrate leached beneath furrow‐irrigated than center‐pivot irrigated fields. Peak leaching appeared to correlate with recorded periods of poor weather conditions during some growing seasons and may best be controlled by “spoon feeding” fertilizer to the crop through the sprinkler irrigation system at times of nutrient need. The presence of trace levels of atrazine and deethylatrazine to 60 feet (18 m) in core samples indicates that larger, more complex anthropogenic molecules also leach through the fine‐textured soils. The light δ15NNO3 values in the surficial groundwater beneath fertilized and irrigated cropland indicate that ammonium fertilizer is a major N source and suggest that the natural soil‐N contribution is negligible. δ15NNO3 values were most enriched in irrigation wells located within municipal well capture zones downgradient of a large feedlot. Dual isotope method (DIM) δ15NNO3 and δ18ONO3 values suggest that the Hastings’ municipal wells farther downgradient are contaminated with a mixture of nitrate from manure and commercial ammonium‐based fertilizer. DIM values indicate an absence of denitrification, which has implications for long‐term management of the water resources.

Influence of rainy season and land use on drinking water quality in a karst landscape, State of Yucatán, Mexico

To understand the impacts of dry and wet seasons and land use on water quality in a karst system, twenty-one deep municipal wells were sampled synoptically across the State of Yucatán. Surrounding land uses comprised urban, crop, and livestock as defined by the National Institute of Statistics and Geography of Mexico. Measurements included pH, temperature, specific conductance, Ca2+, Mg2+, Na+, K+, Cl−, SO42−, alkalinity, NO3−, and fecal coliforms. Data were reduced using various geochemical, statistical, and spatial analytical methods and compared to a similar study on cenotes (sinkhole). Results show that 1) groundwater is diluted during the rainy season, but not for all parameters; 2) the geochemical structure of the water is obscured during the wet season; 3) the change in values for most parameters differs from that in the cenotes, however for both, fecal coliforms are higher in the wet season; 4) the relationship of land use to water quantity is unclear, however some influence of agriculture and urban were observed, and 5) water quality is at risk in both dry (NO3−) and wet (fecal coliforms) seasons. It is hypothesized that these results may be explained by changes in dominant flow paths between dry (matrix, fracture flow) and wet (conduit flow) seasons. In addition, results suggest that rock-water interactions, hydrology, and land cover maybe more important in understanding the influence on water quality than land use. Clearly, understanding the impact of both land use and season on groundwater quality in any karst environment is challenging. Further work should include using different methods for defining land use need to be explored and a more diverse set of water quality measurements need to be made.

Security of deep groundwater against arsenic contamination in the Bengal Aquifer System: a numerical modeling study in southeast Bangladesh

Across the floodplains of southern Bangladesh deep (> 150 m belowground level, bgl) groundwater within the Bengal Aquifer System (BAS) has become widely used for domestic water supply as a de facto mitigation response to the presence of excessive arsenic (As), exceeding the World Health Organization standard of 10 µg L− 1, in shallow groundwater. Over the past 10 years, many hand-pumped tube wells and high-capacity municipal water-supply wells have been installed at this depth and at deeper regions of the BAS, which are almost uniformly free of excessive As. Concern for the security of the deep groundwater resource against possible invasion of As and saline water from shallow depths emphasizes the need for comparative assessments of groundwater abstraction strategies to guide water resource managers and policy makers. To this end, particle-tracking post-processing has been applied within a numerical groundwater flow model for an area of over 10,000 km2 in southeastern Bangladesh, one of the regions where the As issue is most acute. Criteria for describing the security of deep groundwater abstraction strategies over a 100-year time frame have been applied to the model outcomes for a range of scenarios. Our analyses suggest that deep groundwater will remain secure against invasion of As across the entire region if it is restricted to domestic use, even under domestic demand projected for 2050. Our approach can be applied in other regions and in similar Asian mega-deltas where As contamination of groundwater is recognized as a grave concern for sustainable water resources development.

Lead and strontium isotopes as tracers to investigate the potential sources of lead in soil and groundwater: A case study of the Hun River alluvial fan

Lead (Pb) isotopes and strontium (Sr) isotopes are good combined multiple geochemical tracers to differentiate lead pollution in soil and groundwater due to the characteristic “fingerprints” of Pb isotopes and fractionation of Sr isotopes. Soil, surface water, groundwater, and river sediment samples were investigated for Pb and Sr content and the isotopic ratio was used to determine the potential sources of Pb in soil and groundwater of the Hun River alluvial fan, Liaoning, China. Lead from anthropogenic sources was of high solubility and could translocate, and it was relatively stable after deposition in the soil. Therefore, lead speciation and the isotopic ratio of the acid extraction fraction and the residual fraction in the soil and river sediments were also measured to obtain more information regarding the anthropogenic pollution. The results indicate that most Pb in the soil was of geogenic origin, in particular, ore chemical weathering along the Hun River, while the topsoil was significantly affected by leaded gasoline and coal combustion, sewage irrigation, and other human activities. The geogenic origin of Pb in groundwater was from the carbonate rock aquifer and ore upstream. Shallow groundwater was affected by contaminated surface water through the interaction of groundwater and rivers. The influence of vehicle exhausts and coal combustion on groundwater from municipal wells can be ignored.