Municipal Solid Waste Compost Application Research Articles

Effects of municipal solid waste compost and sewage sludge on chemical and spectroscopic properties of humic acids from a sandy Haplic Podzol and a clay loam Calcic Vertisol in Portugal

The effects of amendment with municipal solid waste compost (MSWC) and anaerobically digested sewage sludge (SS) on the compositional and structural features of soil humic acids (HAs) were investigated. For this purpose, HAs were isolated from MSWC, SS, and two different Portuguese soils, a sandy Haplic Podzol and a clay loam Calcic Vertisol, which were either unamended or amended with MSWC or SS at a rate of 60 t ha(-1). The isolated HAs were analyzed for elemental and acidic functional group composition, and by ultraviolet/visible, Fourier transform infrared (FT IR), and fluorescence spectroscopies. The application of MSWC and especially SS to soils determined an increase of C, N, H, and S contents and E4/E6 ratios (i.e., ratios of absorbances at 465 and 665 nm), and a decrease of O, COOH, and phenolic OH contents and C/N, C/H, and O/C ratios of soil HAs. The FT IR and fluorescence results showed that the organic amendments, especially SS, caused an increase of the aliphatic character and a decrease of the degrees of aromatic polycondensation, polymerization, and humification of amended soil HAs. Both MSWC and SS affected more markedly the clayey soil HAs than the sandy soil HAs, possibly due to less extended mineralization processes and the protective action of clay minerals on amended soil HAs.

Bacterial community diversity assessment in municipal solid waste compost amended soil using DGGE and ARISA fingerprinting methods

Bacterial community structure and diversity of Tunisian agricultural soil treated with different amounts of municipal solid waste compost (MSWC) and other fertilizers were studied using DGGE and ARISA fingerprinting methods. Sequence analysis of dominant DGGE bands revealed the presence of three major clusters, Cytophaga/Flexibacter/Bacteroides (CFB) group, Proteobacteria and Acidobacteria group. Using ARISA profiles, dominant populations were assigned to low and high GC Gram positive bacteria, Cyanobacteria, Spirochetes and Cytophagales. The two methods revealed the absence of significant bacterial community shifts related to the different MSWC applications. Moreover, indigenous bacterial population of the used loam-clayey soil was observed to limit proliferation and survival of Proteobacteria, initially dominant in MSWC and farmyard manure. Effectiveness of the two methods for soil bacterial community studying was shown. While DGGE was more accurate for bacterial identification, ARISA was more practical for handling and rapid estimation of dominant bacteria.

Effect of enriched municipal solid waste compost application on soil available macronutrients in the rice field

A study was conducted in the Department of Environmental Sciences, Tamil Nadu Agricultural University, Coimbatore, India, to transform the normal compost into bioactive compost, which has multiple benefits to the crop system. The key players in this transformation process were Azotobacter sp., Pseudomonas sp., Phosphobacteria sp. and the waste materials like poultry litter and spent wash. This enrichment process increases both the quality and nutrient content of the municipal solid waste compost significantly. A study was carried out to evaluate the effect of application of different levels of enriched municipal solid waste compost on the availability of the macronutrient content to the rice field soil. The effect of enriched compost on soil available nutrients was significant. The soil ammonium nitrogen and soil nitrate nitrogen content was found to be high in the plots where the enriched compost was applied along with inorganic fertilizer with the values of 38.87 mg kg−1 and 32.87 mg kg−1, respectively. In addition, the availability decreased towards crop growth. The soil available P and K were also increased with enriched compost application to about 22.46 kg ha−1 and 647 kg ha−1 compared with control values of 19.44 kg ha−1 and 518 kg ha−1, respectively. Both phosphorus and potassium content decreased towards advancement of crop growth.

Effect of Enriched Municipal Solid Waste Compost Application on Growth, Plant Nutrient Uptake and Yield of Rice

Effect of Enriched Municipal Solid Waste Compost Application on Growth, Plant Nutrient Uptake and Yield of Rice

Effects of municipal solid waste compost application on the microbial biomass of cultivated and non-cultivated soil in a semi-arid zone

The aim of this study was to assess whether soil microbial biomass could be used as an indicator of environmental changes following the application of organic residue (compost of municipal solid waste and farmyard manure) or mineral fertilizers (N and P) into cultivated or uncultivated loam-clayey soil, for three consecutive years. The carbon and nitrogen of the microbial biomass (B(C) and B(N) were studied using the fumigation-extraction method. For the two cultivated and uncultivated plots, B(N) and B(C) were more important in the superficial profile (0-20 cm) than in the deep one (20-40 cm). In the uncultivated soil, we observed a good linear relation between B(C) and B(N) at the level of upper soil horizon during the wet season with r coefficients of 0.95, 0.71 and 0.80 for the consecutive years 2000, 2001 and 2002, respectively. Microbial biomasses C and N increased during the rainy season and decreased during the dry season. Microbial biomass C and N showed the higher content with compost and farmyard manure at 40 tonnes ha(-1). Moreover, the results showed that at the beginning of the experiment, the microbial biomass was higher in the ploughed wheat-cultivated plot than in the uncultivated one. Microbial biomass C and N in the cultivated plot amended with compost at 40 tonnes ha(-1) were significantly different in comparison with the soil microbial biomass amended with farmyard manure. The combining of chemical fertilizer with the organic fertilizer, such as compost at 40 or 80 tonnes ha(-1) and farmyard manure, increased the microbial biomasses C and N after 1 and 2 years. In the cultivated or uncultivated plots the results revealed that the best application rate of the compost was 40 tonnes ha(-1) and when the compost rate was increased from 40 to 80 tonnes ha(-1) both B(C) and B(N) decreased significantly.

L-asparaginase and L-glutaminase activities in submerged rice soil amended with municipal solid waste compost and decomposed cow manure

The field study was conducted to evaluate the effect of municipal solid waste compost (MSWC) as a soil amendment on L-asparaginase (LA) and L-glutaminase (LG) activities. Experiments were conducted during the wet seasons of 1997, 1998 and 1999 on rice grown under a submerged condition, at the Agriculture Experimental Farm, Calcutta University at Baruipur, West Bengal, India. The treatments consisted of control, no input; MSWC, at 60 Kg N ha− 1; well-decomposed cow manure (DCM), at 60 Kg N ha− 1; MSWC (30 Kg N ha− 1) + Urea (U) (30 Kg N ha− 1); DCM (30 Kg N ha− 1) + U (30 Kg N ha− 1) and Fertilizer, (at 60:30:30 NPK kg ha− 1) through urea, single superphosphate and muriate of potash respectively). LA and LG activities alone and their ratio with organic-C (ratio index value, RIV), straw and grain yield were higher in DCM than MSWC-treated soils, due to higher amount of biogenic organic materials like water-soluble organic carbon, carbohydrate and mineralizable nitrogen in the former. The studied parameters were higher when urea was integrated with DCM or MSWC, compared to their single applications. The heavy metals in MSWC did not detrimentally influence the above-measured activities of soil. In the event of long term MSWC application, changes in soil quality parameters should be monitored regularly, since heavy metals once entering into soil persist over a long period.

Alternative sugar beet production using shallow tillage and municipal solid waste fertiliser

The application of conventional agricultural practices, e.g. deep soil tillage and repeated, plentiful mineral fertilisation, can lead to a progressive deterioration of soil fertility, especially in Mediterranean environments characterised by scanty rains and high summer temperatures. As a consequence, to maintain high levels of both crop productivity and soil organic matter and to improve some soil properties, a reduction of agricultural inputs and a greater supply of organic material are needed. In the light of these considerations, we carried out a two-year field experiment in Southern Italy to determine the effects of reduced soil tillage and municipal solid waste compost application on growth parameters, production and quality of sugar beet crops, and on both soil chemical characteristics and mineral nitrogen deficit. Two soil tillage depths were compared: conventional tillage, till 40–45 cm and shallow tillage, at 15–20 cm. Within each soil tillage, the following N-fertilising strategies were tested: (1) mineral fertilisation, with 100 kg N ha−1; (2) organic fertilisation with municipal solid waste compost at 100 kg N ha−1; (3) mixed fertilisation, with 50% of organic N as municipal solid waste compost, and 50% of mineral N; and (4) slow-release organic-mineral N fertiliser, at 100 kg N ha−1. All these treatments were compared with a lower level of mineral fertiliser at 50 kg N ha−1, and with an unfertilised control. Our findings show first the absence of a significant difference in root and sucrose yields between reduced tillage and deep tillage; as shown by roots (36.02 t ha−1) and sucrose (3.41 t ha−1) yields for reduced tillage and 35.76 and 3.51 t ha−1, respectively, for the deepest tillage. Secondly, among the N treatments, the mixed organic-mineral N fertilisation gave productions statistically not different from mineral N fertilisation; as shown by root yields (36.38 versus 36.40 t ha−1) and sucrose yields (3.56 versus 3.65 t ha−1). Third, the mixed organic-mineral N induced a reduction of 13.2% in α-amino N content by comparison with the mineral treatment of 100 kg N ha−1. Fourth, our results showed that the applications of the municipal solid waste compost increased the extracted and the humified organic carbon by +27.7 and +25.4%, compared with the mineral fertiliser, and did not raise the content of heavy metals. These findings highlighted that in Southern Italy it is sustainable to adopt alternative sugar beet production, safeguarding crops’ quantitative and qualitative performance, decreasing the production costs and using the natural resources better.

Nitrogen Utilization, Yield, Quality and Soil Properties In a Sugarbeet Crop Amended With Municipal Solid Waste Compost

The aim of this research was to study different ways of nitrogen (N) fertilization and soil tillage management to ensure high yield, quality and correct usage of the available resources. Therefore, a two-year field experiment (2001 and 2003) was carried out on a sugarbeet crop grown in a Mediterranean environment to evaluate the effects of two soil tillage depths (10-15 and 40-45 cm) and of a municipal solid waste (MSW) compost application, compared to mineral N fertilization. The following fertilization treatments were compared: MSW compost at 100 kg N ha−1 (Ncom); mineral N fertilizer at 50 kg ha−1 (N50) and at 100 kg ha−1 (N100); MSW compost combined with mineral N fertilizer (Nmix) (50 kg ha−1 as organic N plus 50 kg ha−1 as mineral N); slow release organic-mineral fertilizer (Nslow) and an unfertilized control (Contr). In each trial year, growth parameters, plant and soil N indicators, yield, quality, N uptake and N efficiency, soil chemical characteristics and N mineral deficit in the soil were determined. The findings of this research highlighted that MSW compost was an important N source for sugarbeet, especially when MSW compost was combined with mineral N fertilizer. In fact, the Nmix treatment did not determine any significant reduction in root (32.5 vs. 36.4 t ha−1 of N100) and sucrose yields (3.56 and 3.65 ha−1). Furthermore, it presented a significantly lower amount of one of the most important qualitative parameters, the alfa amino N (1.74 and 1.97 meq 100 g−1 of N100), and ensured the least soil N deficit in 2003. The application of MSW compost significantly increased the extracted organic carbon in both 2001 (37% of increase for compost treatment in respect to unfertilized control) and 2003 (24%). Higher values were also recorded for total organic carbon in 2001 (20% of increase) and for humified organic carbon in 2001 (27%) and in 2003 (16%), whereas its application did not increase the total content of heavy metals. Finally, among plants and soil N indicators tested, the petiole nitrate content was the only one significantly and positively correlated with root and sucrose yields, indicating that it was an effective tool to monitor N supply.

Fluorescence characterization of metal ion–humic acid interactions in soils amended with composted municipal solid wastes

Fluorescence spectroscopy has been used to probe the structural properties and Cu(II), Zn(II), Cd(II), and Pb(II)-binding behavior of humic acid (HA)-like fractions isolated from a municipal solid waste compost (MSWC) and HAs from unamended and MSWC-amended soils. The main feature of the fluorescence spectra, in the form of emission-excitation matrix (EEM) plots, was a broad peak with the maximum centered at an excitation/emission wavelength pair that was much shorter (340/437 nm) for MSWC-HA than for unamended and MSWC-amended soil HAs (455/513 and 455/512 nm, respectively). Fluorescence intensity for MSWC-amended soil HA was less than that for unamended soil HA. These results were indicative of more aromatic ring polycondensation and humification of soil HAs, and of partial incorporation of simple and low-humified components of MSWC-HA into native soil HA, as a result of MSWC amendment. Titrations of HAs with Cu(II), Zn(II), Cd(II), and Pb(II) ions at pH 6 and ionic strength 0.1 mol L(-1) resulted in a marked decrease of the fluorescence intensities of untreated HAs. By successfully fitting a single-site fluorescence-quenching model to titration data, the metal ion complexing capacities of each HA and the stability constants of metal ion-HA complexes were obtained. The binding capacities and stability constants of MSWC-HA were smaller than those of the unamended soil HA. Application of MSWC to soil slightly reduced the metal-ion-binding capacities and affinities of soil HAs.

MSW Compost Application on Tomato Crops in Mediterranean Conditions: Effects on Agronomic Performance and Nitrogen Utilization

A two-year field experiment (2001 and 2003) was carried out in a Mediterranean environment to study the effects of municipal solid waste (MSW) compost application compared with mineral nitrogen (N) fertilization on the agronomic performance and N utilization of a tomato crop, in rotation with durum wheat. The research was conducted in the south of Italy where five N treatments and two soil tillage depths (40-45 cm and 10-15 cm) were compared. The N treatments were: MSW compost at 140 kg ha−1 (Ncom); mineral N fertilizer at 140 kg ha−1 (Nmin); MSW compost combined with mineral N fertilizer (Nmix) (70 kg ha−1 as organic N plus 70 kg ha−1 as mineral N); mineral N fertilizer at 70 kg ha−1 combined with two applications of foliar fertilizer (Nfito) (3 kg ha−1 as hydrolyzed proteins), and an untreated control (Contr). During cropping cycles, growth parameters and plant N status (SPAD readings and petiole nitrate content) were determined; at harvest the marketable, overripe, green fruit, total yield, yield components, quality performance, total and fruit N uptake, and N efficiency were recorded. In addition, at the beginning and at the end of the two-year experiment, soil chemical characteristics and mineral N was measured, allowing for the calculation of the mineral N deficit in the soil. The results of this research indicate that the application of MSW compost to tomato plants can serve as a N source in Mediterranean conditions, especially when MSW compost is combined with mineral N fertilizer and deeper soil tillage is applied. In fact, deeper soil tillage increased total yield 7.0 t ha−1 compared to surface tillage, whereas soil amended with MSW compost increased total yield compared to the untreated control by approximately 6.4% when used alone and 11.1% when combined with mineral N fertilizer. Nitrogen utilization parameters and Harvest Index varied significantly across years and N treatments. Petiole nitrate content and SPAD readings did not vary between Nmin and Nmix treatments, but they were significantly different from the untreated control. This indicates that plant N status was an effective tool to monitor N supply. After the two-year experiment, the Nmix treatment was statistically not significant in total yield (86.1 and 88.2 t ha−1, respectively), marketable yield (66.9 and 67.7 t ha−1) and quality compared to the Nmin treatment. Furthermore, the Nmix treatment ensured the least N deficit in the soil, indicating that MSW applications were effectively used as alternative organic supplements. Finally, the results indicated a positive effect of MSW application on organic carbon content in the soil and did not show any significant increase of the heavy metals at the end of the two-year experiment.

Effect of municipal solid waste compost on phosphorous content of rice straw and grain under submerged condition

The effect of municipal solid waste compost (MSWC) on the phosphorous content of submerged rice was studied. Experiments were conducted during the three consecutive wet seasons from 1997 – 1999 on rice grown under submergence, at the Experimental Farm of Calcutta University, West Bengal, India. A sequential extraction method was used to determine the various phosphorous fractions in MSWC and cow dung manure (CDM), traditional manure for comparison. Phosphorous (P) was significantly bound to the organic matter and Fe and Al oxides in MSWC and CDM. P content in rice grain was higher than straw. P bound with organic matter in MSWC best correlated with straw P (r = + 0.99**) and grain P (r = + 0.99**) contents. The P bound with Fe, Al and Ca in MSWC was highly correlated with P content of grain (r = + 0.99**, + 0.93* and + 0.97** respectively) and straw (r = + 0.98**, + 0.95** and + 0.99** respectively). The saloid bound P (readily available P) of MSWC was also correlated significantly with straw (r = + 0.94*) and grain P ( + 0.91*). The P content of rice grain ( + 0.99**) and straw ( + 0.99**) was best correlated Fe-P followed by Al bound P in CDM. Single application of MSWC or CDM resulted in lower P content of rice grain and straw but the increase was spectacular when MSWC and CDM was applied in conjunction with fertilizer. The increase in P availability to the plants by the application of MSWC might be due to blocking of absorption sites and/or releasing soluble P with time.

Microbial biomass and enzyme activities in submerged rice soil amended with municipal solid waste compost and decomposed cow manure

We studied the suitability of municipal solid waste compost (MSWC) application to submerged rice paddies in the perspective of metal pollution hazards associated with such materials. Experiments were conducted during the wet seasons of 1997, 1998 and 1999 on rice grown under submerged condition, at the Agriculture Experimental Farm, Calcutta University at Baruipur, West Bengal, India. The treatments consisted of control, no input; MSWC, at 60 kg N ha −1; well decomposed cow manure (DCM), at 60 kg N ha −1; MSWC (30 kg N ha −1) + Urea (30 kg N ha −1); DCM (30 kg N ha −1) + U (30 kg N ha −1) and Fertilizer, (at 60:30:30 NPK kg ha −1 through urea, single superphosphate and muriate of potash respectively). Soil microbial biomass-C (MBC), MBC as percentage of organic-C (ratio index value, RIV), urease and acid phosphatase activities were higher in DCM than MSWC-treated soils, due to higher amount of biogenic organic materials like water soluble organic carbon, carbohydrate and mineralizable nitrogen in the former. The studied parameters were higher when urea was integrated with DCM or MSWC, compared to their single applications. Soil MBC, urease and acid phosphatase activities periodically declined up to 60 day after transplanting (DAT) and then increased after crop harvest. The heavy metals in MSWC did not detrimentally influence MBC, urease and acid phosphatase activities of soil. In the event of long term MSWC application, changes in soil quality parameters should be monitored regularly, since heavy metals once entering into soil persist over a long period.

Reduction of agronomic inputs in sunflower (Helianthus annuus L.)

SUMMARY A two-year field study was carried out in a Mediterranean environment (Foggia, Southern Italy) to assess the effects of two soil tillage depths (conventional and minimum tillage) and three strategies of nitrogen (N) fertilization (organic, mixed, mineral) on the growth, biometric parameters, yielding and qualitative characteristics of sunflower cropped with durum wheat in a twoyear rotation. The fertilizer treatments applied were: 100com, with Municipal Solid Waste (MSW) compost; 100mix, with organic N (MSW compost) and mineral N; 100slow, with a slow release organic-mineral fertilizer; 100min and 50min, with mineral N; unfertilized control (Contr). The results obtained during the trial period have shown that the minimum soil tillage, MSW compost fertilization (as 100com and 100mix) and conservative practices were able to give good quantitative and qualitative responses. Furthermore, no increase of heavy metals has been found in the plots treated with MSW compost application.

Soil and Plant Response to MSW Compost Applications on Lowbush Blueberry Fields in 2000 and 2001

SUMMARY Field experiments were initiated in May 1999 to investigate the application of municipal solid waste (MSW) compost to low-bush blueberry (Vaccinium angustifolium Ait.) fields. Three sites were selected: Debert, NS (Truro sandy loam) and two sites near Musquodoboit, NS (both Rawdon gravely loamy sands). Treatments at each site consisted of a randomized complete block design with six treatments (Control [no fertilizer], NK fertilizer, NPK fertilizer, and three rates of MSW compost) blocked four times. Compost treatments provided the equivalent of 100, 200, and 400 kg ha−1 of total N, respectively. The experimental objectives were to evaluate soil and plant response to the compost and to determine whether the organic amendment could be used as an alternative to chemical fertilizers. Yield, soil fertility, and plant nutrients were evaluated in blueberry leaf tissue and fruit over two years. The MSW compost had a strong (K) and a mild effect (P, Ca, Mg, S, Cu, Zn) on extractable soil nutrients, while a...

Source-separated municipal solid waste compost application to Swiss chard and basil.

A growth room experiment was conducted to evaluate the bioavailability of Cu, Mn, Zn, Ca, Fe, K, Mg, P, S, As, B, Cd, Co, Cr, Hg, Mo, Na, Ni, Pb, and Se from a sandy loam soil amended with source-separated municipal solid waste (SSMSW) compost. Basil (Ocimum basilicum L.) and Swiss chard (Beta vulgaris L.) were amended with 0, 20, 40, and 60% SSMSW compost to soil (by volume) mixture. Soils and compost were sequentially extracted to fractionate Cu, Pb, and Zn into exchangeable (EXCH), iron- and manganese-oxide-bound (FeMnOX), organic-matter (OM), and structurally bound (SB) forms. Overall, in both species, the proportion of Cu, Pb, and Zn levels in different fractions followed the sequence: SB > OM >> FeMnOX > EXCH for Cu; FeMnOX = SB > OM > EXCH for Pb; and FeMnOX > SB = EXCH >> OM for Zn. Application of SSMSW compost increased soil pH and electrical conductivity (EC), and increased the concentration of Cu, Pb, and Zn in all fractions, but not EXCH Pb. Basil yields were greatest in the 20% treatment, but Swiss chard yields were greater in all compost-amended soils relative to the unamended soil. Basil plants in 20 or 40% compost treatments reached flowering earlier than plants from other treatments. Additions of SSMSW compost to soil altered basil essential oil, but basil oil was free of metals. The results from this study suggest that mature SSMSW compost with concentrations of Cu, Pb, Mo, and Zn of 311, 223, 17, and 767 mg/kg, respectively, could be used as a soil conditioner without phytotoxic effects on agricultural crops and without increasing the normal range of Cu, Pb, and Zn in crop tissue. However, the long-term effect of the accumulation of heavy metals in soils needs to be carefully considered.

Source-Separated Municipal Solid Waste Compost Application to Swiss Chard and Basil

Source-Separated Municipal Solid Waste Compost Application to Swiss Chard and Basil

Evaluation of MSW Compost as a Component of Integrated Nutrient Management in Wetland Rice

The potential of municipal solid waste compost (MSWC) was evaluated for rice cultivar, IET- 1444, during the wet seasons of 1997-99. Field experiments were conducted at the Agriculture Experimental Farm of Calcutta University, West Bengal, India using MSWC and cow dung manure (CDM), with or without urea (U), and fertilizers (F). Dry matter accumulation was highest with CDM + U, followed, in a descending order, by MSWC + U and F. Panicle length was largest and thousand–grain-weight were highest for F. Application of CDM alone gave 30% higher grain yield over MSWC but the latter, along with urea, increased grain yield by 49% over MSWC alone. Uptake of N by straw and grain was significantly higher with CDM as compared to MSWC. Percent N recovery was higher when fertilizer in the form of urea was applied with either CDM or MSWC. Uptake of heavy metals (Zn, Cu, and Pb) by straw and grain of rice was lower with the application of MSWC alone than with the other treatments except control. Uptake of Cd was below detection limit. There was no significant variation between the physico-chemical properties of soil due to the application of these treatments. Results indicated that MSWC application to rice was effective and safe to be used as an alternative organic supplement.

Effects of Surface Application of MSW Compost On Cotton Production – Soil Properties, Plant Responses, And Nematode Management

Equipment was modified and/or developed for broadcast and banded applications of municipal solid waste (MSW) compost at selected rates to agricultural land for cotton production. Replicated tests were conducted for four years to determine the effects of compost on soil properties, crop yield, and nematode populations. Soil type in the test field was Faceville loamy sand. Broadcast application of compost significantly reduced soil compaction in the top 30 cm of soil in cotton rows and row-middles compared to no compost application. Banded application did not affect compaction in the row middles. Columbia lance nematode densities decreased in all compost-treated plots during all four years of study. Several plots treated with compost had nematode densities comparable to those found in the plots treated with Temik 15G nematicide. Compost application significantly increased the soil organic matter content and soil nitrogen content at six and 14 weeks after planting. However, the compost did not affect the leaf nitrogen content of the cotton plant during the same sampling periods. In 1996, 1997, and 1998, all rates of added compost significantly increased seed cotton yield. Yield increase was proportional to application rate. There were very few carry-over compost effects from each previous year's treatments on either soil organic matter, soil nitrogen, or seed cotton yield.

The influence of soluble organic matter from municipal solid waste compost on trace metal leaching in calcareous soils

The use of municipal solid waste (MSW) compost as fertilizer may cause increased leaching due to its high content of trace metals and thus pose a threat to groundwater quality. The effect of MSW compost application on trace metal leaching in calcareous soils has been studied in soil column experiments under laboratory conditions using three soils from the study area in the Gaza Strip and Israel. Higher levels of organic matter in solution (TOMS), nitrate, and the trace metals Cu, Ni and Zn were found in the leachates of a sandy soil and, to a lesser extent, a loamy soil, to which MSW compost had been applied at a rate of 65 Mg ha −1 (dry weight basis). Nevertheless, the majority of water-soluble trace metal species from compost accumulated in the topsoil rather than washing out, with the exception of aqueous Ni species. Ni concentrations exceeded the maximum allowable limits for drinking water (in Germany: 50 μg l −1) at peak times in the leachates from sandy soil, while all other trace metals remained far below the corresponding limits. The highest absolute concentrations of trace metals were found for the leaching of Cu from compost-amended sandy soil (100 μg l −1). For Cd, Pb and Hg no evidence of downward movement was found in any assay. Gel filtration studies of the collected soil leachates showed that all trace metals encountered in the leachates existed mostly as organic complexes. In sandy soil most of the water-soluble organic matter added with the compost had leached from the rootzone after a year's equivalent of rainfall, while TOMS mobility was greatly reduced in the loamy soil. The makeup of the TOMS in the sandy soil and its metal-binding capacity was strongly influenced by compost-derived dissolved organic matter (DOM) as observed by FTIR spectrometry. Hence the vertical displacement of trace metals (Cu, Ni, Zn) in these calcareous soils seemed to result primarily from the presence of mobile metal–organic complexes in the soil solution after compost addition. Further studies are required to validate these findings in the field, especially to assess the risk of Cu and Ni leaching in sandy soil.

Microbial Biomass and Activity in a Laterite Soil Amended with Municipal Solid Waste Compost

The dynamics of soil quality indicators, such as microbial biomass‐C, soil respiration, and urease and acid phosphatase activities, in a laterite soil (Typic Haplustalf ) amended with different doses of Calcutta municipal solid waste compost (MSWC) were studied over 120 days of incubation at 30 °C under 60 % soil water holding capacity. The parameters were found to increase with the increase in doses of MSWC. Soil microbial biomass‐C (MBC) and soil respiration activity reached peak values at 30 days of incubation and then gradually decreased up to 120 days of incubation. Urease and acid phosphatase activities showed peak values at 60 and 90 days of incubation, respectively. The increase in soil enzyme activities with the fall in MBC suggested that the release of enzymes was associated with lysis of microbial cells at the end of their life cycle. There was no indication of any detrimental effect on soil quality indicators of application of MSWC to soil.