Binary Systems Research Articles

Impact of the Sr2+-Nd3+ heterovalent isomorphism on the luminescence of orthoborates in Sr3B2O6-NdBO3 system

The phase diagram of the Sr3B2O6-NdBO3 binary system was studied. The intermediate compound Sr3Nd2(BO3)4 can be synthesized over a wide range of compositions, from 27 to 70 mol.% NdBO3, at 1200°C. The maximum luminescence of Nd in this solid solution was measured for the highest content of Sr. The partial substitution of Nd by 3 mol.% Sr in NdBO3 does not significantly affect the presence of concentration quenching. The phase exhibiting the strongest luminescence within the system is neodymium doped Sr3B2O6.

Multidimensional Characterization and Separation of Ultrafine Particles: Insights and Advances by Means of Froth Flotation

Particle systems and their efficient and precise separation are becoming increasingly complex. Therefore, instead of focusing on a single separation feature, a multidimensional approach is needed where more than one particle property is considered. This, however, requires the precise characterization of the particle system, which is especially challenging for fine particles with sizes below 10 µm. This paper discusses the benefits and limitations of different characterization techniques, including optical contour analysis, inverse gas chromatography, flow cytometry, and SEM-based image analysis. The separation of ultrafine particles was investigated for a binary system using froth flotation, where a novel developed flotation apparatus is used. A special focus was placed on the multidimensional evaluation of the separation according to the particle properties of size, shape, and wettability, which was addressed via multivariate Tromp and entropy functions. The results emphasize the intricacy of the flotation process and the complex interaction of the individual particle properties and process parameters. The investigations contribute to the understanding of the characterization of particulate properties as well as the separation behavior of ultrafine particles via froth flotation, especially in the case of a multidimensional approach.

A novel organic-inorganic hybrid hollow polymer capsule with rich amino/imino groups for anionic contaminant removal in wastewater: Synthesis, performance and mechanism

Herein, we developed a new organic-inorganic hybrid polymer adsorbent, termed PECP, by one-step precipitation polycondensation between polyethyene polyamine and hexachlorocyclotriphosphazene. The morphology and microstructure of PECP were investigated by FTIR, SEM, TEM, XPS, XRD and N2 adsorption. Results show PECP owned a hollow capsule structure and lots of amino/imino groups. The adsorption capacity of PECP for anionic dye methyl orange (MO) was up to 1031.9 mg g-1. The adsorption process was very fast. After five cycles, the adsorption capacity of PECP for MO still remained at 89 % of the initial adsorption capacity. Meanwhile, PECP delivered a high adsorption capacity for other anionic contaminants like acid chrome blue K (1003.5 mg g-1), congo red (1152.2 mg g-1) and diclofenac sodium (914.2 mg g-1). In the binary systems contaminated with double dyes, the separation factors of MO for methylene blue, Rhodamine B and crystal violet were up to 450.8, 55.4 and 355.9, respectively. The experimental data unveiled that the MO removal by PECP was very consistent with the pseudo-second-order kinetic model and the Langmuir isotherm model. The removal process was spontaneous and endothermic. FTIR spectroscopy and XPS analysis confirmed the role of electrostatic force and hydrogen bond on the adsorption of MO on PECP.

Observational signature of QPOs with particle motion around non-commutative Schwarzschild black hole surrounded by perfect fluid dark matter

We analyze the orbital and oscillatory motion of test particles in the vicinity of a non-commutative black hole submerged in perfect fluid dark matter and derive analytical solutions for the specific angular momentum and radial profiles of energy. Using the effective potential approach, we discuss the stability of circular orbits. Furthermore, we calculate the innermost stable circular orbits. The effective force acting on particles has also been discussed. We find the expressions for frequencies of radial and latitudinal harmonic oscillations as a function of the black hole mass and the model’s parameters. The key features of quasi-periodic oscillations of test particles near the stable circular orbits in an equatorial plane of the black hole are discussed. Furthermore, Periastron precession has been discussed. We demonstrate that the parameters of the model have a strong influence on particle motion around black holes. By using the observational data of four different X-ray binary systems GRO J1655-40, XTE J1550-564, XTE J1859+226, and GRS 1915+105, within the scope of Monte Carlo Markov Chain, we constrain the involved parameters α and β. It is necessary to mention that our presented investigations through graphical behavior are viable with required physical behavior.

Diffusion behavior and mechanical properties of the Mg-Er binary system

The Mg-Er binary system, as a new lightweight alloy material system with important research value and prospects for development and application, has attracted much attention from researchers in the field of materials science. Studies have shown that the addition of the rare earth element Er can improve the mechanical strength and heat resistance of magnesium alloys. However, the specific mechanism of the interaction between Mg and Er and its effect on the mechanical properties still need to be studied in depth. A combination of microscopic morphology characterization and nanoindentation experiments were employed to investigate the binary diffusion behavior and mechanical properties of the Mg-Er system between 748 K and 823 K in this research. The results indicate that the growth constant of the diffusion layer increases with temperature, with Mg24Er5 exhibiting a higher growth constant than the sum of Mg2Er and MgEr. Notably, the Mg2Er phase has the lowest growth activation energy (127.81 kJ/mol), which suggests that it is formed first during the initial growth stage due to its relatively low energy barrier. Moreover, the interdiffusion coefficient of Mg24Er5 was found to be the highest. By calculating diffusion activation energy, this sequence of formation (Mg2Er→Mg24Er5→MgEr) is in agreement with the trend of growth activation energy. Additionally, nanoindentation experiments and first-principles calculations were utilized to derive the mechanical properties of the Mg-Er binary system. The investigations unveil that Mg2Er boasts the highest hardness and Young’s modulus. These findings have significant implications for understanding the correlation between structure and properties for the Mg-Er alloy system.

Use of third generation data for the pure elements to model the thermodynamics of binary alloy systems: Part 3 – The theoretical prediction of the Al–Si–Zn system

In a previous paper a method was developed to define Einstein temperatures for metastable phases of the elements and their relation to the so-called lattice stabilities used in the past, and also the variation of the Einstein temperature with composition to account for the composition dependence of the excess entropy. This approach was demonstrated successfully for the Al–Zn system. In this paper this approach is extended to cover the Al–Si and Si–Zn binary systems. The phase diagram for the Al–Si–Zn ternary system was then predicted from the thermodynamic description of the binary subsystems only without any ternary interaction parameters. Agreement with the experimental data is shown to be very good.

Toward Fully Controllable Monomers Sequence: Binary Organocatalyzed Polymerization from Epoxide/Aziridine/Cyclic Anhydride Monomer Mixture.

The sequence of monomers within a polymer chain plays a pivotal role in determining the physicochemical properties of the polymer. In the copolymerization of two or more monomers, the arrangement of monomers within the resulting polymer is primarily dictated by the intrinsic reactivity of the monomers. Precisely controlling the monomer sequence in copolymerization, particularly through the manipulation of catalysts, is a subject of intense interest and poses significant challenges. In this study, we report the catalyst-controlled copolymerization of epoxides, N-tosyl aziridine (TAz), and cyclic anhydrides. To achieve this, a binary catalyst system comprising a Lewis acid, triethylborane, and Brønsted base, t-BuP1, was utilized. This system was utilized to regulate the selectivity between two catalytic reactions: ring-opening alternating copolymerization (ROAC) of epoxides/cyclic anhydrides and ROAC of TAz/cyclic anhydrides. Changing the catalyst ratio made it possible to continuously modulate the resulting poly(ester-amide ester) from ABA-type real block copolymers to gradient, random-like, reversed gradient, and reversed BAB-type block-like copolymers. A range of epoxides and anhydrides was investigated, demonstrating the versatility of this polymerization system. Additionally, density functional theory calculations were conducted to enhance our mechanistic understanding of the process. This synthetic method not only provides a versatile means for producing copolymers with comparable chemical compositions but also facilitates the exploration of the intricate relationship between monomer sequences and the resultant polymer properties, offering valuable insights for advancements in polymer science.

Solid–liquid equilibria and non-isothermal crystallization kinetics of n-alkanes binary systems

Solid–liquid equilibria and non-isothermal crystallization kinetics of n-alkanes binary systems

Are lithium-rich giants binaries? A radial velocity variability analysis of 1,400 giants

The existence of low-mass giants with large amounts of lithium (Li) in their surfaces has challenged stellar evolution for decades. One of the possibilities usually discussed in the literature to explain these Li-rich giants involves the interaction with a close binary companion, a scenario that predicts that, when compared against their non-enriched counterparts, Li-rich giants should preferentially be found as part of binary systems. We aim to assemble the largest possible sample of low-mass giants with well-measured Li abundances, to determine with high statistical significance the close binary fractions of Li-rich and Li-normal giants, and thus test the binary interaction scenario for the emergence of Li-rich giants. We developed a method that uses radial velocities (RVs) at three different epochs to quantify the degree of RV variability, which we used as a proxy for the presence of a close binary companion. The method was tested and calibrated against samples of known RV standard stars and known spectroscopic binaries. We then assembled a sample of 1418 giants with available RVs from RAVE, GALAH, and Gaia as well as stellar parameters and Li abundances from GALAH, to which we applied our variability classification. We could determine an evolutionary state for 1030 of these giants. We also compared the results of our RV variability analysis with binarity indicators from the Gaia mission. When applying our methodology to the control samples, we found that the accuracy of the classification is controlled by the precision of the RVs used in the analysis. For the set of RVs available for the giants, this accuracy is 80-85<!PCT!>. Consistent with seismic studies, the resulting sample of giants contains a fraction of Li-rich objects in the red clump (RC) that is twice as large as that in the first ascent red giant branch (RGB). Among RC giants, the fractions of Li-rich objects with a high RV variability and with no RV variability are the same as those for Li-normal objects, but we find some evidence that these fractions may be different for giants in the first-ascent RGB. Analysis of binary indicators in Gaia DR3 shows a smaller fraction of binary giants than our criteria, but no relation can be seen between Li enrichment and binarity either. Our RV variability analysis indicates that there is no preference for Li-rich giants in the RC to be part of binary systems, thus arguing against a binary interaction scenario for the genesis of the bulk of Li-rich giants at that evolutionary stage. On the other hand, Li-rich giants in the RGB appear to have a small but measurable preference for having close companions, something that deserves further scrutiny with more and better data. Additional measurements of the RVs of these giants at a higher RV precision would greatly help in confirming and more robustly quantifying these results.

Experimental study on gas hydrate generation in a thermal-kinetic binary promotion system

ABSTRACT The primary measure for the prevention and control of coal and gas protrusion is gas extraction. However, various factors, such as coal seam conditions, drilling construction, and extraction management, have led to poor gas management. Therefore, the method of transforming gaseous gas into solid hydrate provides a new direction for the prevention and control of coal and gas herniation. In this paper, the factors that influence gas hydrate solidification and its influence law are explored. A thermo-kinetic binary promotion system was constructed by combining thermo-kinetic promoters, and experiments on gas hydrate generation under the thermo-kinetic binary system were carried out. The effects of four thermodynamic accelerators (CP, THF, TBAB, HCFC-141b) compounded with the kinetic accelerator SDS on the gas hydrate generation characteristics were determined. The experimental results show that among the four thermodynamic promoters, THF and SDS have the best synergistic effect, and the optimal mass concentration ratio of the two is 21.2 wt% THF + 8.6 wt% SDS. The gas pressure in the reactor decreased by a maximum of 2.788 MPa within 500 min in this experimental system, and the absorption rate of gas reached 55.41%, which indicates a more pronounced hydration promotion effect.

New algorithm of measuring gravitational wave radiation from rotating binary system

In order to investigate the gravitational wave (GW) radiation, without resorting to the traceless transverse gauge approach to the GW formalism of the linearized general relativity, we formulate the so-called modified linearized general relativity (MLGR). As an application of the MLGR, we construct a novel paradigm of measuring the GW radiation from a binary system of compact objects, to theoretically interpret its phenomenology. To accomplish this, we formulate the mass scalar and mass vector potentials for the merging binary compact objects, from which we construct the mass magnetic field in addition to the mass electric one which also includes the mass vector potential effect. Next, defining the mass Poyinting vector in terms of the mass electric and mass magnetic fields in the MLGR, we find the GW radiation intensity profile possessing a prolate ellipsoid geometry due to the merging binary compact objects source. At a given radial distance from the binary compact objects, the GW radiation intensity on the revolution axis of the binary compact objects is shown to be twice that on the equatorial plane. Moreover, we explicitly obtain the total radiation power of the GW, which has the same characteristic as that of the electromagnetic wave in the rotating charge electric dipole moment. We also find that, in no distorting limit of the merging binary compact objects, the compact objects in the MLGR do not yield the total GW radiation power, consistent with the result of the traceless transverse gauge algorithm in the linearized general relativity.

SURFACE ACTIVITY AND PHASE BEHAVIOUR OF POTASSIUM HEPTYLENE DECYL SUCCINATE / WATER BINARY SYSTEM

The surface activity of potassium heptylene decyl succinate (PHDS) at water-air interface was studied. The obtained results showed a very good correlation between the surface activity of PHDS and concentration of surfactant solutions and temperature of the system. The phase behaviour and structure of aggregates in PHDS)/water binary system were investigated. The phase diagram of the PHDS/water binary system was obtained depending on the concentration of components and temperature of the system. It was established that due to the double hydrocarbon chain of the PHDS molecule, the lamellar liquid crystalline phase exists across a wide range of the phase diagram. It was shown that upon the addition of water, the cross-sectional area of the PHDS molecules in lamellar liquid crystals is changed insignificantly. This result was associated with the invariability of the distance of the lipophilic layers of formed lamellar liquid crystals by PHDS molecules. On the basis of video-enhanced microscopic studies, it was established that in two-phase region of the phase diagram, lamellar liquid crystals coexist with water in the form of vesicles.

Binary Catalytic Hydrogen/Deuterium Exchange of Free α-Amino Acids and Derivatives.

The increasing demand for deuterium-labeled amino acids and derivatives has heightened interest in direct hydrogen/deuterium exchange reactions of free amino acids. Existing methods, including biocatalysis and metal catalysis, typically require expensive deuterium sources or excessive use of deuterium reagents and often struggle with site selectivity. In contrast, our pioneering binary catalysis system, employing benzaldehyde and Cs2CO3 in the presence of inexpensive D2O with minimal stoichiometric quantities, facilitates efficient hydrogen/deuterium exchange at the α-position of amino acids without the need for protecting groups in the polar aprotic solvent DMSO. The process is highly compatible with most natural and non-natural α-amino acids and derivatives, even those with potentially reactive functionalities. This advancement not only addresses the cost and efficiency concerns of existing methods but also significantly broadens the applicability and precision of deuterium labeling in biochemical research.

Spin–Orbit Coupling of the Ellipsoidal Secondary in a Binary Asteroid System

In our solar system, spin–orbit coupling is a common phenomenon in binary asteroid systems, where the mutual orbits are no longer invariant due to exchange of angular momentum between translation and rotation. In this work, dynamical structures in phase space are explored for the problem of spin–orbit coupling by taking advantage of analytical and numerical methods. In particular, the technique of Poincaré sections is adopted to reveal numerical structures, which are dependent on the total angular momentum, the Hamiltonian, mass ratio, and asphericity parameter. Analytical study based on perturbative treatments shows that high-order and/or secondary spin–orbit resonances are responsible for numerical structures arising in Poincaré sections. Analytical solutions are applied to (65803) Didymos, (80218) VO123 and (4383) Suruga to reveal their phase-space structures, showing that there is a high possibility for them to locate inside secondary 1:1 spin–orbit resonance.

Observed jet power and radiative efficiency of black hole candidates in the Kerr+PFDM model

In this research, we explore the electromagnetic energy emitted by astrophysical black holes within the Kerr+PFDM (Kerr + perfect fluid dark matter) spacetime, a model comprising rotating black holes surrounded by dark matter. Our investigation focuses on black holes within X-ray binary systems, namely GRS 1915+105, GRO J1655-40, XTE J1550-564, A0620-00, H1743-322, and GRS 1124-683. Our findings indicate that the Kerr+PFDM spacetime can account for the radiative efficiency of these sources as determined through the continuum-fitting method (CFM). Additionally, employing the Blandford–Znajek mechanism, we demonstrate the ability to replicate the observed jet power. By combining the outcomes of both analyses for the selected objects, we establish more rigorous constraints on the spacetime parameters. Notably, our results reveal that, similar to the Kerr spacetime, the Kerr+PFDM spacetime cannot simultaneously account for the observed jet power and radiative efficiency of GRS 1915+105.

Spouting behavior of binary mixtures of spherocylindrical and spherical particles in a spouted bed

Gas-solid spouted bed systems involving biomass utilization have received much attention in recent years. In actual biomass industrial processes, some fine inert particles are usually added to assist the fluidization of biomass particles. However, the flow mechanisms of binary particle systems containing biomass particles in spouted beds are still poorly understood so far. In this study, spherocylindrical particles representing biomass particles and spherical particles representing inert particles were used as the objects of study. The macroscopic and microscopic flow characteristics were explored based on CFD-DEM modeling when the volume fractions of spherocylindrical particles in the binary particle mixtures were 25 %, 50 %, 75 % and 100 %, respectively. The results showed that the minimum spouting velocities (Ums) were in the range of 150–173 m/s, but did not show a correlation with the different particle systems. During fluidization in binary particle systems, separation of spherocylindrical and spherical particles occurs. There is no significant correlation between the particle systems with different volume fractions of spherocylindrical particles and particle orientation. As the volume fraction of spherocylindrical particles increases, the average bed height of the particles decreases and the translational kinetic energy of the particles decreases/rotational kinetic energy increases. Furthermore, the wall effect influences the spherocylindrical particle orientation and volume fraction, driving the spherocylindrical particles near the wall surface toward the vertical direction.

Naphthalene Enhances Polycyclic Aromatic Hydrocarbon Biodegradation by Pseudomonas aeruginosa in Soil and Water: Effect and Mechanism

Bioremediation is a promising technique owing to its effectiveness, low cost, and environmental friendliness. Previous studies have focused on the degradation efficiency of polycyclic aromatic hydrocarbons (PAHs) in soil and water. However, the expression of PAH-catabolic genes in organisms involved in the degradation process has been rarely and unsystematically reported. In this study, a PAH-degrading strain—Pseudomonas aeruginosa (PQ249631)—was successfully isolated from coking-contaminated soil and used for PAH degradation in soil and water. Furthermore, the degradation of PAHs (naphthalene, fluorene, phenanthrene, anthracene, and pyrene) was investigated in single, binary, and mixture systems to explore the interaction of substrates. The results showed that when naphthalene was used as a cometabolite carbon source, the removal rates of fluorene, phenanthrene, anthracene, and pyrene increased from 14.33%, 17.25%, 6.61%, and 4.47% to 72.08%, 100.00%, 15.63%, and 6.63%, respectively. In a PAH mixture, the degradation rate of each PAH was higher when naphthalene, rather than glucose, was used as the cometabolite carbon source. Transcriptome analysis revealed significant differential expression of PAH-catabolic genes and ATP-binding cassette transporter-related genes under naphthalene stress. The enhanced degradation of PAHs could be attributed to the augmentation of the PAH metabolic pathway and membrane transportation, facilitating the transfer of PAHs to bacteria. These findings underscore the effectiveness of P. aeruginosa as a PAH degrader and provide molecular insights into enhancing PAH degradation.

In Vitro Spectroscopic Investigation of Losartan and Glipizide Competitive Binding to Glycated Albumin: A Comparative Study.

Understanding the interaction between pharmaceuticals and serum proteins is crucial for optimizing therapeutic strategies, especially in patients with coexisting chronic diseases. The primary goal of this study was to assess the potential changes in binding affinity and competition between glipizide (GLP, a second-generation sulfonylurea hypoglycemic drug) and losartan (LOS, a medication commonly prescribed for hypertension, particularly for patients with concurrent diabetes) with non-glycated (HSA) and glycated (gHSAGLC, gHSAFRC) human serum albumin using multiple spectroscopic techniques (fluorescence, UV-visible absorption, and circular dichroism spectroscopy). The results indicated that FRC is a more effective glycation agent for HSA than GLC, significantly altering the albumin structure and affecting the microenvironment around critical amino acid residues, Trp-214 and Tyr. These modifications reduce the binding affinity of LOS and GLP to gHSAGLC and gHSAFRC, compared to HSA, resulting in less stable drug-protein complexes. The study revealed that LOS and GLP interact nonspecifically with the hydrophobic regions of the albumin surface in both binary (ligand-albumin) and ternary systems (ligand-albumin-ligandconst) and specifically saturate the binding sites within the protein molecule. Furthermore, the presence of an additional drug (GLP in the LOS-albumin complex or LOS in the GLP-albumin complex) complicates the interactions, likely leading to competitive binding or displacement of the initially bound drug in both non-glycated and glycated albumins. Analysis of the CD spectra suggests mutual interactions between GLP and LOS, underscoring the importance of closely monitoring patients co-administered these drugs, to ensure optimal therapeutic efficacy and safety.

Characterization of Camphene- and Fenchol-Based Hydrophobic Eutectic Solvents and Their Application in Aldehyde Extraction.

Binary terpenoid-based eutectic systems consisting of the natural substances camphene (CA), fenchol (FE), thymol (TH), menthol (ME), dodecanoic acid (DA), and 1-dodecanol (DO) are synthesized and screened for their Solid-Liquid Equilibrium (SLE) and eutectic compositions. Out of nine eutectic systems, 13 solvent compositions at eutectic points and next to them, in addition to the reference solvent, TH:ME, are synthesized and applied for the solvent extraction of the aromatic aldehydes vanillin (VAN), syringaldehyde (SYR), and p-hydroxybenzaldehyde (HYD) from an acidic aqueous model solution. The extraction efficiency is determined from aldehyde concentrations measured by High-Performance Liquid Chromatography (HPLC), taking into consideration mutual solubility measured by Karl Fischer titration (KF) and a Total Organic Carbon-analysis (TOC). Physicochemical properties, such as the density, viscosity, and stability of the solvents, are evaluated and discussed. Additionally, 1H-NMR measurements are performed to verify hydrogen bonding present in some of the solvents. The results show that all synthesized eutectic systems have a strong hydrophobic character with a maximum water saturation of ≤2.21 vol.% and solvent losses of ≤0.12 vol.% per extraction step. The hydrophobic eutectic solvents based on CA exhibit lower viscosities, lower mutual solubility, and lower extraction efficiency for the aromatic aldehydes when compared with FE-based solvents. The highest extraction efficiencies for VAN (>95%) and for SYR (>93%) at an extraction efficiency of 92.61% for HYD are achieved by the reference solvent TH:ME (50:50 mol.%). With an extraction efficiency of 93.08%, HYD is most preferably extracted by the FE-DO-solvent (80:20 mol.%), where the extraction efficiencies for VAN and SYR reach their maximum at 93.37% and 90.75%, respectively. The drawbacks of the high viscosities of 34.741 mPas of the TH:ME solvent and 31.801 mPas of the FE-DO solvent can be overcome by the CA-TH solvent, which has a viscosity of 3.436 mPas, while exhibiting extraction efficiencies of 71.92% for HYD, >95% for VAN, and >93% for SYR, respectively.

A Dynamic Mechanical Analysis on the Compatibilization Effect of Two Different Polymer Waste-Based Compatibilizers in the Fifty/Fifty Polypropylene/Polyamide 6 Blend.

This study aims to examine the 50/50 polypropylene/polyamide 6 (iPP/PA6) system molded under confined flow conditions, both in its original state and after being modified by two different interfacial agents. This study provides two main insights. Firstly, it focuses on a polymer blend close to phase inversion. Secondly, it investigates the impact of using two different types of interfacial agents (derived from polymer waste) to enhance the compatibility between iPP and PA6. Dynamic Mechanical Analysis (DMA) has been employed to achieve these objectives. It is important to note that the investigation of the 50/50 iPP/PA6 system is a crucial focus predicted in previous studies, where a series of mechanical properties were evaluated using Box-Wilson design of experiments (DOEs) over the whole compositional range on the iPP/PA6 binary system. Thus, two interfacial modifiers, namely succinic anhydride (SA)-grafted atactic polypropylene with terminal, side, and bridge SA grafts (aPP-SASA) and succinyl-fluoresceine (SF) with bridge succinic anhydride grafting atactic polypropylene (aPP-SFSA), were employed. The authors obtained and characterized these agents. The quantity of these agents used in the blend was identified as a critical coordinate in prior studies conducted by the authors. The processing method used, compression molding under confined conditions, was chosen to minimize any orientation effect on the emerging morphology. All characterization procedures were performed on samples processed by contour machining to retain the blend morphologies as they emerged from the processing stage. Results from WAXS and SAXS synchrotron tests concluded there were no changes in the crystal morphology of the iPP or the PA6 in the blends nor any co-crystallization process throughout the compositional range. These findings, and the long period fits on the PP crystalline phase for the fifty/fifty blends we are discussing, will support the present DMA study. Finally, the efficiency of these interfacial modifiers has been concluded, even in this unfavorable scenario.