Lithium-ion batteries play a significant role in modern electronics and electric vehicles. However, current lithium-ion battery chemistries are unable to satisfy the increasingly heightened expectations regarding energy demand and reliability. To boost the overall energy density while ensuring the safety of Li batteries, researchers have focused on developing the battery materials [1]. Silicon has an ultrahigh theoretical capacity and has been regarded as the best choice for next-generation lithium-ion battery anodes, but it also suffers from dramatic expansion during cycling [2]. Hence mitigating volume expansion is one of the main challenges towards developing a successful Si based anodes. Herein, a facile air-controlled electrospray method to directly deposit silicon/graphene (Si/Gr) onto current collectors was described. This method is inspired by an electrospinning process and possesses all the advantages that electrospinning has such as low cost, easy scaling up, and simultaneous solvent evaporation during the spraying process. Cost-effective silicon/graphene (Si/Gr) composite electrodes have been investigated for the multiple benefits of Gr in providing mechanical integrity to buffer the silicon volume expansion while maintaining electronic contact with Si to provide a Li-ion transport pathway and to form a uniform solid electrolyte interface (SEI) layer. Our results revealed a superior battery performance including a capacity of 1000 mAh/g at 2C rates and minor capacity loss during long cycling. The details of synthesis, characterization, and lithium-ion battery results of the hybrid anodes will be presented.