ABSTRACT A new type of lithium molten salt electrolytic cell was studied by using multi-physics coupling numerical simulation method and verified by experiment. The distribution of temperature, potential, current density, fluid force and flow field in electrolytic cell was investigated. The results show that the minimum pole distance of the cell is 6 mm, which effectively reduces the pressure drop on the electrolyte to 0.1 V. The mixture of electrolyte and lithium metal can effectively transfer mass through the electrode gap, while the resulting chlorine gas acts as a power source for the entire electrolytic cell, and electric field analysis shows a significant reduction in energy consumption, validating the energy saving potential of the new structure. Pilot tests have determined an energy consumption of 28 KWH/kg of lithium with a current efficiency of 87.5%, a nearly 50% reduction in energy consumption and a more than 30% improvement in current efficiency compared to conventional systems.
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