The Sequential Fully Implicit (SFI) method was proposed [12], in the context of a Multiscale Finite Volume (MSFV) formulation, to simulate coupled immiscible multiphase fluid flow in porous media. Later, Lee et al. [15] extended the SFI formulation to the black-oil model, whereby the gas component is allowed to dissolve in the oil phase. Most recently, the SFI approach was extended to fully compositional isothermal displacements by Moncorgé et al. [21]. SFI schemes solve the fully coupled system in two steps: (1) Construct and solve the pressure equation (flow problem). (2) Solve the coupled species transport equations for the phase saturations and phase compositions. In SFI, each outer iteration involves this two-step sequence. Experience indicates that complex interphase mass transfer behaviors often lead to large numbers of SFI outer iterations compared with the Fully Implicit (FI) method. Here, we demonstrate that the convergence difficulties are directly related to the treatment of the coupling between the flow and transport problems, and we propose a new SFI variant based on a nonlinear overall-volume balance equation. The first step consists of forming and solving a nonlinear pressure equation, which is a weighted sum of all the component mass conservation equations. A Newton-based scheme is used to iterate out all the pressure dependent nonlinearities in both the accumulation and flux terms of the overall-volume balance equation. The resulting pressure field is used to compute the Darcy phase velocities and the total-velocity. The second step of the new SFI scheme entails introducing the overall-mass density as a degree-of-freedom, and solving the full set of component conservation equations cast in the natural-variables form (i.e., saturations and phase compositions). During the second step, the pressure and the total-velocity fields are fixed. The SFI scheme with a nonlinear pressure extends the SFI approach of Jenny et al. [12] to multi-component compositional processes with interphase mass transfer. The proposed compositional SFI approach employs an overall balance for the pressure equation; however, unlike existing volume-balance Sequential Implicit (SI) schemes [1,34,32,27,10,9], which use overall compositions, this SFI formulation is well suited for the natural variables (saturations and phase compositions). We analyze the ‘splitting errors’ associated with the compositional SFI scheme, and we show how to control these errors in order to converge to the same solution as the Fully Implicit (FI) method. We then demonstrate that the compositional SFI has convergence properties that are very comparable to those of the FI approach. This robust sequential-implicit solution scheme allows for designing numerical methods and linear solvers that are optimized for the sub-problems of flow and transport. The SFI scheme with a nonlinear pressure formulation is well suited for multiscale formulations, and it promises to replace the widely used FI approach for compositional reservoir simulation.
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