Gridless inductive output tubes (IOTs) offer compact size and high-power amplification at sub-GHz frequencies. Minimizing cavity dimensions in the interest of compactness leads to smaller gaps, which may cause multipactor discharge under high-power operating conditions. The uncontrolled electron growth resulting from multipactor breakdown can lead to undesired effects including surface damage and system failure. This paper performs a parallel-plate multipactor analysis for a high-Q, L-shaped, aluminum, 431 MHz cavity designed for a gridless IOT to be operated in the MW-power regime. The cavity gap is 27 mm, and diameter is 339 mm. Multipactor susceptibility regions are calculated for non-zero emission energy, half-cycle, and non-half-cycle multipactor using a semi-analytic approach and a standard aluminum secondary electron yield (SEY) curve. The analytical results are validated with particle-in-cell simulation in CST Studio. Simulation results show a voltage range of 6.4–19 kV, compared to the analytically calculated values of 8.2 and 18.3 kV for the lower and upper bounds, respectively. Fluorocarbon coating as a means to reduce secondary electron emission is simulated, which shows 46% reduction in peak particle population with an 11.2 nm PTFE coating, with further reduction as coating thickness increases. The results show that the L-shaped cavity is a suitable choice for this IOT design as it does not exhibit single-surface multipactor and will not develop two-surface multipactor at full-power operation.