Multi-walled Carbon Nanotubes Research Articles

Vibro-acoustic characterization of Functionally Graded Multiwalled Carbon Nanotube composite cylindrical panels: An experimental approach

This study experimentally investigates the vibro-acoustic properties of Functionally Graded Multiwalled Carbon Nanotubes (FG-V MWCNT) Glass Fiber Reinforced Polymer composite cylindrical panels, a topic often explored through numerical methods. A novel process methodology is introduced to realize FG-V MWCNT composites, and the results are compared with those of uniformly distributed and conventional composites. Using an in-house developed experimental setup, the natural frequencies, mode shapes, acceleration, and Sound Pressure Levels (SPL) are measured. The FG-V MWCNT composites demonstrate a notable enhancement in fundamental frequency (21.13%) and a reduction in SPL in the lower frequency range compared to conventional composites. The proposed material composition and process methodology show potential for creating lightweight, structurally efficient large airframe components.

Experimental investigation on the mechanical properties of multi-walled carbon nanotubes modified glass fiber-reinforced polymer composites

Experimental investigation on the mechanical properties of multi-walled carbon nanotubes modified glass fiber-reinforced polymer composites

Damage sensing in multi-functional nanocomposite polymer bonded energetics with embedded multi-walled carbon nanotube sensing networks

Abstract This experimental investigation evaluates the strain and damage sensing abilities of multi-walled carbon nanotube (MWCNT) networks embedded in the binder phase of polymer-bonded energetics (PBEs). PBEs are a special class of particulate composite materials that consist of energetic crystals bound by a polymer matrix, wherein the polymer matrix serves to maintain the composite’s shape and form. The structural health monitoring (SHM) approach presented in this work exploits the piezoresistive properties of the distributed MWCNT networks. Major challenges faced during such implementation include the low binder concentrations of PBEs, the presence of conductive/non-conductive particulate phases, the high degree of heterogeneity in the PBE microstructure, and achieving the optimal MWCNT dispersion. In this study, ammonium perchlorate (AP) crystals as the oxidizer, Aluminum grains as the metallic fuel, and Polydimethylsiloxane (PDMS) as the binder are used as the constituents for fabricating PBEs. To study the effect of each constituent on the MWCNT network’s SHM abilities, various materials systems are comprehensively studied: MWCNT/PDMS materials are first evaluated to study the binder’s electromechanical response, followed by AP/MWCNT/PDMS to assess the impact of AP addition, and finally, AP/AL/MWCNT/PDMS to evaluate the impact of adding conductive aluminum grains. Compression samples (ASTM D695) were fabricated and subjected to monotonic compression. Electrical resistance is recorded in conjunction with the mechanical test via an LCR meter. Gauge factors relating to the change in normalized resistance to applied strain are calculated to quantify the electromechanical response. MWCNT dispersions and mechanical failure modes are analyzed via scanning electron microscopy imaging of the fracture surfaces. Correlations between the electrical behavior in response to the mechanical behavior are presented, and possible mechanisms that influence the electromechanical behavior are discussed. The results presented herein demonstrate the successful ability of MWCNT networks as SHM sensors capable of real-time strain and damage assessment of PBEs.

Enhancing Electrochemical Performance of Si@CNT Anode by Integrating SrTiO3 Material for High-Capacity Lithium-Ion Batteries

Silicon (Si) has attracted worldwide attention for its ultrahigh theoretical storage capacity (4200 mA h g−1), low mass density (2.33 g cm−3), low operating potential (0.4 V vs. Li/Li+), abundant reserves, environmentally benign nature, and low cost. It is a promising high-energy-density anode material for next-generation lithium-ion batteries (LIBs), offering a replacement for graphite anodes owing to the escalating energy demands in booming automobile and energy storage applications. Unfortunately, the commercialization of silicon anodes is stringently hindered by large volume expansion during lithiation–delithiation, the unstable and detrimental growth of electrode/electrolyte interface layers, sluggish Li-ion diffusion, poor rate performance, and inherently low ion/electron conductivity. These present major safety challenges lead to quick capacity degradation in LIBs. Herein, we present the synergistic effects of nanostructured silicon and SrTiO3 (STO) for use as anodes in Li-ion batteries. Si and STO nanoparticles were incorporated into a multiwalled carbon nanotube (CNT) matrix using a planetary ball-milling process. The mechanical stress resulting from the expansion of Si was transferred via the CNT matrix to the STO. We discovered that the introduction of STO can improve the electrochemical performance of Si/CNT nanocomposite anodes. Experimental measurements and electrochemical impedance spectroscopy provide evidence for the enhanced mobility of Li-ions facilitated by STO. Hence, incorporating STO into the Si@CNT anode yields promising results, exhibiting a high initial Coulombic efficiency of approximately 85%, a reversible specific capacity of ~800 mA h g−1 after 100 cycles at 100 mA g−1, and a high-rate capability of 1400 mA g−1 with a capacity of 800 mA h g−1. Interestingly, it exhibits a capacity of 350 mAh g−1 after 1000 lithiation and delithiation cycles at a high rate of 600 mA hg−1. This result unveils and sheds light on the design of a scalable method for manufacturing Si anodes for next-generation LIBs.

Synergistic plasma and platinum catalysts interactions in CO2 reforming of propane at room temperature: The role of supports

This study investigates the synergistic impact of plasma and catalyst in a hybrid non-thermal plasma system integrated with 1 wt% Pt catalysts supported on diverse catalyst supports (γ-Al2O3, SBA-15, HZSM-5, CeO2, TiO2, and multi-wall carbon nanotube (CNT)) at ambient conditions in dry reforming of propane (DRP). To optimize the reaction, the impact of in-situ plasma reduction time was investigated over the Pt/Al2O3 catalyst at varying durations before the DRP reaction. The most favorable catalytic performance was observed at a reduction time of 60 min due to having the highest surface area (284 m2/g), which might result in smaller Pt particle size, and the effective reduction of oxidation states to Pt0. A comparison of reduction sources also revealed that the plasma-reduced catalyst outperformed the other, which was attributed to the agglomeration of Pt active sites during the thermal reduction process. The chemo-physical properties of different catalysts directly affected the plasma characteristics and catalytic performance. Pt/Al2O3 exhibited the highest performance, attributed to having the smallest mean Pt particle size (0.94 nm) and highest discharge power (13.97 W), effective capacitance (1.41 nF), and charge transfer (0.34 μC) during DRP reaction, leading to a 13 % and 15 % increase in CO2 and C3H8 conversions, respectively, compared to plasma-only mode. The catalytic performance showed that the synergy of catalysts with higher basic sites and plasma characteristics, along with smaller Pt particle size, resulted in high reactant conversion and syngas selectivity. Binary HRTEM images also indicated the presence of more soft carbon (coke) in the pore channels of the spent Pt/HZSM-5 catalyst than in spent Pt/Al2O3.

Effects of Ni Loadings on the Structure and Morphology of Carbon Nanotubes Using Nickel Doped Iron Oxide Catalysts

AbstractIron oxide and their different doped iron oxide catalyst have been used for decades and are considered as efficient catalysts in several synthesis schemes including synthesis of carbon nanotubes. The iron oxide of the catalyst is abundant in nature, high catalytic activity at low over potentials, stability in basic media and low cost, making it environmentally and economically attractive. Nickel doped iron oxide catalyst have not been reported in the literature. Doping of nickel over iron oxide catalyst, different percentage 1 %, 5 %, 10 % and 20 % were done by impregnation method. The samples were characterized by X‐Ray powder Diffraction (XRD), Fourier‐Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscope (SEM), Energy Dispersive X‐ray (EDX) and Thermo Gravimetric Analysis (TGA). Nickel doped iron oxide was used as catalyst for the synthesis of carbon nanotubes (CNTs) and doping changed the morphology of carbon nanotube (CNTs). FTIR results confirmed the doping and presence of different functional groups. Chemical vapor deposition (CVD) was carried out for the synthesis of multiwall carbon nanotubes (MWCNTs) on nickel doped iron oxide catalyst for different percentage (1 %, 5 %, 10 % and 20 %) separately. CVD assembly was carried in tube furnace and the reaction was checked at two different temperature i.e 700 °C and 750 °C and using methane and compressed natural gas (CNG) as precursors. The catalyst was activated in the furnace at 800 °C for an hour. Methane and argon were used in proportion 2 : 1 inside the furnace. SEM showed formation of CNTs at 750 °C with CNG precursor. Formation of CNTs increased with increasing doping with this CNTs was confirmed by SEM.

Scalable Layered Heterogeneous Hydrogel Fibers with Strain-Induced Crystallization for Tough, Resilient, and Highly Conductive Soft Bioelectronics.

The advancement of soft bioelectronics hinges critically on the electromechanical properties of hydrogels. Despite ongoing research into diverse material and structural strategies to enhance these properties, producing hydrogels that are simultaneously tough, resilient, and highly conductive for long-term, dynamic physiological monitoring remains a formidable challenge. Here, a strategy utilizing scalable layered heterogeneous hydrogel fibers (LHHFs) is introduced that enables synergistic electromechanical modulation of hydrogels. High toughness (1.4MJ m-3) and resilience (over 92% recovery from 200% strain) of LHHFs are achieved through a damage-free toughening mechanism that involves dense long-chain entanglements and reversible strain-induced crystallization of sodium polyacrylate. The unique symmetrical layered structure of LHHFs, featuring distinct electrical and mechanical functional layers, facilitates the mixing of multi-walled carbon nanotubes to significantly enhance electrical conductivity (192.7 S m-1) without compromising toughness and resilience. Furthermore, high-performance LHHF capacitive iontronic strain/pressure sensors and epidermal electrodes are developed, capable of accurately and stably capturing biomechanical and bioelectrical signals from the human body under long-term, dynamic conditions. The LHHF offers a promising route for developing hydrogels with uniquely integrated electromechanical attributes, advancing practical wearable healthcare applications.

Multiwalled carbon nanotubes decorated ɛ-MnO2 nanoflowers cathode with oxygen defect for aqueous zinc-ion batteries

As a potential cathode for aqueous zinc-ion batteries, the low electrical conductivity and poor electrochemical kinetics of MnO2 limit its further development and application. Herein, multiwalled carbon nanotubes decorated MnO2 nanoflowers with hexagonal structure (ɛ-MnO2/MWCNTs) were synthesized by one-step co-precipitation method. The ɛ-MnO2/MWCNTs inherit the advantages of highly conductive MWCNTs and nanostructured MnO2, thus showing excellent zinc-ion storage capacity. The ɛ-MnO2/MWCNTs display high invertible capacity of 335.6 mAh/g at 0.2 A/g after 150 cycles, and long-term capacity of 115.7 mAh/g at 2.0 A/g after 4000 cycles. The results of kinetics tests further reveal that the MWCNTs decoration can reduce polarization of MnO2 and accelerate its reaction kinetics. Thanks to these merits, the ɛ-MnO2/MWCNTs hold great potential for high performance eco-friendly batteries cathode material.

Analyzing the Reinforcement of Multiwalled Carbon Nanotubes in Vulcanized Natural Rubber Nanocomposites Using the Lorenz–Park Method

In this study, multiwalled carbon nanotubes (MWCNTs) were incorporated into vulcanized natural rubber (VNR) matrixes to create nanocomposites with improved mechanical, thermal, and electrical properties. The interfacial interaction of the MWCNTs with the VNR matrix was quantitatively evaluated based on the crosslink density value calculated using the Flory–Rehner methodology. Various rheometric parameters were influenced by the addition of the MWCNTs, including minimum torque (ML), maximum torque (MH), and scorch time (tS1). The MWCNTs significantly enhanced the vulcanization of the composites based on the VNR matrix. This study highlights the impact of MWCNTs on crosslink density, improving mechanical properties and reducing swelling in the VNR matrix. We discovered that the MWCNTs and the VNR matrix interact strongly, which improved the mechanical properties of the matrix. The MWCNTs improved the hardness, tensile strength, and abrasion resistance of the VNR/MWCNT nanocomposites. Based on dynamic mechanical analysis, MWCNT incorporation improved stiffness as indicated by a change in storage modulus and glass transition temperatures. The addition of MWCNTs to the VNR/MWCNT nanocomposites significantly improved their electrical properties, reaching a percolation threshold where conductive pathways were formed, enhancing their overall conductivity. Overall, this study demonstrates the versatility and functionality of VNR/MWCNT nanocomposites for a variety of applications, including sensors, electromagnetic shielding, and antistatic blankets.

UV/thermal dual-cured MWCNTs composites for pipeline rehabilitation: Mechanical properties and damage analysis

Deformation and damage in underground pipelines remain challenging to monitor over the long term due to sensor degradation caused by corrosive substances present in the pipelines. This study investigates the potential of incorporating multi-walled carbon nanotubes (MWCNTs) into ultraviolet-cured-in-place pipe (UV-CIPP) material, a widely adopted trenchless repair technique, to enhance performance and enable deformation monitoring. A UV/thermal dual-curing strategy is introduced to mitigate the significant reduction in light transmittance caused by the inclusion of MWCNTs in the composite material. The addition of MWCNTs led to a 94.86 % reduction in light transmittance through glass fibers. However, this issue was effectively resolved through the incorporation of thermal curing, allowing for the production of ultra-high-strength composites using only three layers of fibers within a short curing time. Under optimal conditions (0.2 wt% MWCNTs with the impregnation layer on top), the flexural strength and modulus reached 442.75 MPa and 15.58 GPa, respectively, marking improvements of 14.01 % and 45.2 % over the base material. Additionally, the hardness on the composite's backside increased by 10.95 % compared to the front, indicating enhanced reinforcement. The tensile strength of braided glass fibers improved by 42.31 % and 197.54 % with the addition of 0.2 wt% and 1.0 wt% MWCNTs, respectively. Failure modes varied based on the location of the sensing layer, but all specimens eventually failed due to resin cracking, delamination of the MWCNTs-impregnated layer, and fiber fractures. The UV/thermal dual-cured composite material developed for pipeline rehabilitation in this study exhibits ultra-high strength and shows significant potential for multifunctional sensing applications.

Enhanced Mechanical Properties of Ni3Al Composites Reinforced with Single-Walled and Multi-Walled Carbon Nanotubes: An Atomistic Modeling Study

In this study, the mechanical properties of a Ni3Al matrix composite reinforced with single-walled carbon nanotubes (SWCNTs) and multi-walled carbon nanotubes (MWCNTs) were investigated using atomistic modeling. The analysis focused on the behavior of the composite under uniaxial tensile strain across a range of temperatures (100–900[Formula: see text]K). The results demonstrated that the incorporation of any type of carbon nanotubes (CNTs) significantly enhanced Young’s modulus, yield strength, and tensile strength of the Ni3Al matrix. Notably, the reinforcement with MWCNTs resulted in superior mechanical properties compared to SWCNTs. Additionally, an increase in temperature led to a reduction in Young’s modulus for all composite samples. Among the tested configurations, the composite reinforced with MWCNTs exhibited the highest tensile modulus and yield strength, outperforming both the SWCNT-reinforced composite and the unreinforced Ni3Al crystal. These findings underscore the potential of MWCNTs as effective reinforcements in improving the mechanical performance of Ni3Al-based composites, especially at elevated temperatures.

Novel Eco‐Friendly Electrode: Copper Nanoparticle‐Doped MWCNTs for Green Electro‐Organic Synthesis of 1,2,3‐Triazoles With ChCl/Urea as a Solvent and Cocatalyst

ABSTRACTMeticulous electrode design is pivotal in advancing greener and more sustainable electro‐organic synthesis practices. In this research, our team designed and synthesized a copper‐doped electrode on multiwalled carbon nanotubes (MWCNTs) and characterized it using Fourier transform infrared spectroscopy (FT‐IR), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDS), thermogravimetric analysis (TGA), Brunauer–Emmett–Teller (BET) analysis, X‐ray diffraction (XRD) analysis, X‐ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV) analysis. Subsequently, this electrode was utilized as a catalyst at the electrode surface, serving as a cathode in electro‐oxidation reactions in the presence of phenylacetylene, sodium azide (NaN3), and benzyl halide for the production of 1,2,3‐triazole derivatives under ambient temperature, within a 30‐min reaction time, and at atmospheric pressure, achieving an efficiency level ranging from good to excellent, specifically between 88% and 96%. The synthesized 1,2,3‐triazole derivatives were identified using proton nuclear magnetic resonance (1H NMR) spectroscopy, CHN elemental analysis, and melting point. In this paper, choline chloride/urea deep eutectic solvents (DES) serve multiple roles in the reaction mechanism. They function as solvents and co‐catalysts, generate weak bases, and provide numerous advantages in green chemistry. These advantages include low toxicity, reduced environmental risks, improved atom economy, and non‐volatility, making them safer alternatives to traditional organic solvents.

Thermal study of MHD hybrid nano fluids confined between two parallel sheets: Shape factors analysis

This article discusses the heat and air transfer characteristics of stable magnetohydrodynamic nanofluid flow between two interconnected sheets under the influence of a magnetic field. The nanofluid is a mixture of equal proportions of ethylene glycol and water. This study examined hybrid nanoparticles containing multi-walled carbon nanotubes (MWCNT) and silver (Ag). This research presents, for the first time, a new method for solving nonlinear equations using HPM Python and AGM Python. In addition, the symbolic solution to HPM and AGM has been attained by employing SymPy and SciPy libraries in Python. The results are presented graphically by comparing them with the fourth-order Runge-Kutta number. The final results reflect a high level of agreement between the analytical and numerical methods on the one hand and HPM Python and AGM Python on the other hand. This examination also investigates the effect of various parameters, including magnetic properties, viscosity coefficients, thermophoretic parameters, Brownian parameters, and nanofluid parameters such as velocity, temperature, and concentration. The results prove that velocity and concentration increase as the magnetic field decreases, whereas the temperature displays an opposite trend. As the Schmidt number increases, both the Nusselt number and concentration decrease. The relationship between concentration and temperature with respect to the Prandtl number indicates that when the Prandtl number decreases, the temperature increases while the concentration declines. It is important to note that the employment of hybrid nanofluids leads to an increase in velocity, temperature, and concentration.

Photothermal superhydrophobic coating for concrete: Highly effective anti/deicing performance and corrosion resistance

Superhydrophobic concrete is an effective method to prevent corrosion of internal steel bar. However, existing superhydrophobic concrete is difficult to remove the ice on the superhydrophobic concrete surface. Here, we overcame this problem by developing a photothermal superhydrophobic coating for concrete, which obtained from polydimethylsiloxane (PDMS), multi-walled carbon nanotubes (MWCNT) and further superhydrophobicity. This photothermal superhydrophobic coating showed the excellent superhydrophobicity, self-cleaning property, anti-fouling property, and the long anti-icing time. In addition, the ice on the coating would rapidly melt into the water which easily rolled off the surface under the irradiation of infrared light. This coating not only had the good chemical durability and mechanical durability, but also had the corrosion resistance performance. This work will enrich superhydrophobic concrete technology and promote the application of superhydrophobic concrete in practical building.

Novel carboxylic-MWCNTs photoresist for fabricating sub-diffraction polymer nanowires via STED lithography

A novel composite photoresist, derived from acrylates and carboxylic-functionalized multi-walled carbon nanotubes (MWNTs-COOH), has been developed for the fabrication of sub-diffraction-sized polymer nanowires using STED-inspired lithography. The MWNTs-COOH dispersed in highly cross-linking acrylate monomers benefits to a reduced inhibition laser power for improving lithography. With the MWNTs-COOH, the inhibition laser power is decreased from 5 mW to 3 mW, while the achievable minimum feature size is increased from 121 nm to 48 nm. This innovative approach holds significant promise for the development of sub-diffraction MWCNTs/polymer composite-based devices in the fields of Micro-Electro-Mechanical Systems (MEMS) and Nano-Electro-Mechanical Systems (NEMS).

Defect identification of nano-cementitious composites, using statistical analysis of thermal images

Carbon-based nanomaterials have diverse applications, including in electronics, energy storage, and environmental remediation. Current research aims to enhance the multifunctionality of construction materials by integrating cement with carbon-based nanomaterials known for their high thermal and electrical conductivity. However, nano-cementitious composites may develop internal defects due to the agglomeration of nanomaterials during fabrication. This study aims to utilize the heat characteristics of nano-cementitious composites for detecting internal defect. Test specimens were prepared by incorporating 1 wt% Multi-Walled Carbon Nanotubes (MWCNTs) into the cement paste. Internal defect sizes were defined from 5 % to 25 % of the specimen's area and were positioned in the center of the specimen. A heat generation test was conducted to capture thermal images and temperature data. Quantitative analysis followed, examining the correlation between defect size and temperature through statistical analysis of the thermal images, using skewness to assess this correlation. The results of the skewness analysis indicated a linear correlation with defect size. A parametric study was conducted to analyze the impact of the number of pixel data on skewness, and it was derived that at least 1500 pixel data are required. Consequently, this study concludes that internal defects in nano-cementitious composites can be detected and their sizes can be inferred through the linear relationship between defect size and skewness.

Robust mussel-inspired LBL carbon nanotube-based superhydrophobic polyurethane sponge for efficient oil–water separation utilizing photothermal effect

Superhydrophobic materials possessing efficient and rapid oil–water separation capabilities, as well as robustness, have emerged as the epicenter of global attention. Conventional three-dimensional adsorbent materials often succumb to impaired performance under extreme environmental conditions, rendering it arduous to ensure the efficacy of oil–water separation, and confining the application scenarios. In this study, polyurethane sponges (PUs) co-modified with stearic acid (SA), polydimethylsiloxane (PDMS), and multi-walled carbon nanotubes (MWCNTs), designated as SA-PDMS/MWCNTs@PU (SPMPU), were successfully synthesized via layer-by-layer (LBL) self-assembly and liquid-phase deposition. The SPMPU sponge exhibits an overall separation efficiency of not less than 90 %. It boasts a stable adsorption capacity, formidable mechanical properties, and commendable reusability. SPMPU sponges maintain unparalleled stability in extreme environments, such as strong acids and alkalis, and in the photothermal effect experiment, the SPMPU sponge can attain a temperature of 101.5 °C within 2 min, with rapid reaction kinetics, high efficiency, and unwavering stability. Through the photothermal effect-assisted oil–water separation, a reliable solution is furnished for the current oil–water separation endeavors. The SPMPU sponge preparation is uncomplicated, economical, and yields stable performance, holding significant potential for application in marine oil spills and industrial oil–water separation scenarios.

Implications of nanomaterials reinforcement along with sub-zero temperature cooling on microstructure and mechanical properties of friction stir processed Al7075 alloy

Al 7075 surface composites (SCs) successfully fabricated with additive three different nano-scale particles multi-walled carbon nanotubes (MWCNTs), graphene (GNP), and titanium dioxide (TiO2) by friction stir processing (FSP). The consecutive two-pass FSP was executed under a controlled cooling environment at −20 °C with methanol pumped beneath the workpiece in a specially designed fixture. All of the SCs exhibited homogenous dispersion of filler nanoparticles in their microstructures. The grain size of SCs was remarkably reduced from that of the substrate. The enhancement in hardness and strength was ascribed fundamentally to the grain refinement and Zener (pinning) effect expedited by coolant circulation. The effect of second phase matrix on grain evolution and precipitate-intermetallics formed after FSP was characterized by scanning electron microscope (SEM) and XRD pattern. It has been recorded that there is around 95–110% increase in hardness values in SCs. The wear rate is also dropped in SCs owing to enhanced hardness and the formation of lubricating coating in the case of carbonaceous composites.

Xerogel synthesis from carbon materials and glue inspired by Japanese-solid-calligraphy ink

Abstract Japanese-solid-calligraphy ink is a xerogel made by mixing soot and glue followed by molding and drying. Herein, we prepare xerogels from glue and 1 or 2 carbon materials (fullerene C60, multiwalled and single-walled carbon nanotubes, nanodiamonds, graphite, graphene, and carbon nanohorns) and characterize their surface morphology, indentation hardness, surface resistivity, and other physical properties. Our ecofriendly and simple synthesis does not require special equipment and affords xerogels holding promise as electrode materials.

Flow injection analysis of hydroquinone using amperometric sensor modified with nanomaterials

Modified carbon paste electrodes (CPE) have been widely used in diverse applications, such as environmental, food, and pharmaceutical analysis, among other applications. In this work, the development of an amperometric sensor modified with functionalized multi-walled carbon nanotubes (CNT) and HY-type zeolite (ZEO) is reported for the analysis of hydroquinone (HQ) in pharmaceuticals. Practical and theoretical studies were carried out regarding the modifiers used. No chemical bond was observed between the modifiers and the analyte, such as HQ and CNT. It is likely that dynamic interactions governed by surface adsorption phenomena, rather than covalent bonding, are occurring. Furthermore, the contribution of modifiers to the improvement of the analytical peak current was elucidated through characterization studies, such as electrochemical impedance spectroscopy. These experiments revealed a 147-fold decrease in charge transfer resistance when CPE was modified with ZEO and CNT, which is likely due to an enhancement in electron transfer. A sample rate of 100 injections per hour, and the limit of quantification (LQ) of 8.99 x 10-7 mol/L were achieved during the oxidation of HQ using amperometry in association with flow injection analysis (FIA). The sensitivity of the proposed sensor was of 0.0186 mol/L cm−2. Determinations of pharmaceutical samples were in good agreement with results obtained by High Performance Liquid Chromatography.