The global energy crisis and environmental degradation have prompted ports to strive for green transformation. Intermodal transport, as a green and efficient form of organization in the transport sector, currently has a lot of room for development. How can the competitiveness of intermodal transport be enhanced while realizing the green sustainability of ports? This study objectively evaluates the competitiveness of international container intermodal competitiveness of hub ports and analyzes the characteristics of 16 Chinese ports from 2011 to 2020. The obstacle degree model (ODM) and the panel Tobit model considering random effects are utilized to explore the complex multidimensional elements affecting the competitiveness of intermodal transport in ports. In addressing the imbalanced characteristics of intermodal transport in ports, a variety of augmentation pathways are devised using the dynamic multi-time period fuzzy-sets qualitative comparative analysis (fsQCA) method. The results found that: (1) The competitiveness of intermodal transport in ports shows a “three echelons” structure, requiring the implementation of appropriate augmentation strategies. (2) Elements affecting the competitiveness of intermodal transport in ports are multidimensional, underscoring the significance of holistically considering internal and external elements. (3) The key to enhancing the competitiveness of intermodal transport in ports lies in striking a balance between economic development and prudent attention to multiple dimensions to ensure sustainability. This study enriches the empirical research on intermodal transport in ports. It provides valuable references for ports seeking new avenues of growth and for governments with effective management practices.