Experimental data on measuring the complex dielectric constant (CDP) of clays with full moistening with distilled water in the frequency range from 1 kHz to 8.5 GHz at temperatures from -15 to +25 °C are presented. The modeling of the dependences of is carried out by a multirelaxation model that takes into account the relaxation of free and bound water, as well as relaxation at the bound water - mineral and bound water - air boundaries. It is shown that at temperatures below -5 °C, a relaxation process appears in the CDP spectrum due to polarization at the bound water - ice or ice - mineral interface. The relationship between the parameters of this relaxation process and the petrophysical characteristics of the rock is found.