Abstract A theoretical investigation has been carried out to explore the modulational instability (MI) of electrostatic waves in a warm multi-ion dusty plasma system containing positive ions, negative ions and positively or negatively charged dust in presence of superthermal electrons. With the help of the standard perturbation technique, it is found that the dynamics of the modulated wave is governed by a damped nonlinear Schrödinger equation (NLSE). Regions of MI of the electrostatic wave are precisely determined and the analytical solutions predict the formation of dissipative bright and dark solitons as well as dissipative first- and second-order rogue wave solutions. It is found that the striking features (viz., instability criteria, amplitude and width of rogue waves, etc.) are significantly modified by the effects of relevant plasma parameters such as degree of the electron superthermality, dust density, etc. The time dependent numerical simulations of the damped NLSE reveal that modulated electrostatic waves exhibit breather like structures. Moreover, phase plane analysis has been performed to study the dynamical behaviors of NLSE by using the theory of dynamical system. It is remarked that outcome of present study may provide physical insight into understanding the generation of several types of nonlinear structures in dusty plasma environments, where superthermal electrons, positive and negative ions are accountable (e.g. Saturn’s magnetosphere, auroral zone, etc.).