Multielemental Composition Research Articles

Determination of the geographical origin of Trachinotus ovatus and Pampus argenteus in China by multi-element and stable isotope analysis

This study aimed to determine whether Trachinotus ovatus and Pampus argenteus could be differentiated by multi-element composition or stable isotope ratio analysis of δ13C and δ15N. The multi-element analysis values of a total of 60 Pampus argenteus samples from three sites and 60 Trachinotus ovatus samples from four sites around China were determined, and the other 60 samples of Pampus argenteus and 51 samples of Trachinotus ovatus were tested by principal component analysis (PCA) to estimate the accuracy of origin identification. The results showed that the cross-validation accuracy rate is 92.2% for the Pampus argenteus and 98.3% for the Trachinotus ovatus. Stable isotope analysis of δ13C and δ15N also can distinguish Trachinotus ovatus from different geographical origins. These results showed that the usefulness of multi-element and stable isotope analysis as indicators for authenticating the geographical origin of two pomfrets in China.

High-entropy transition metal nitride thin films alloyed with Al: Microstructure, phase composition and mechanical properties

Deviation from equimolar composition in high-entropy multielement ceramics offers a possibility of fine-tuning the materials’ properties for targeted application. Here, we present a systematic experimental and theoretical study on the effects of alloying equimolar pentanary (TiHfNbVZr)N and hexanary (TiHfNbVZrTa)N high-entropy nitrides with Al. Although being predicted to be metastable by ab initio density-functional theory calculations, single-phase fcc NaCl-structured solid solution thin films with Al solubility limits as high as x ∼ 0.51–0.61 in (TiHfNbVZr)1-xAlxN and x ∼ 0.45–0.64 in (TiHfNbVZrTa)1-xAlxN are synthesised utilizing a hybrid deposition technique that offers dynamic mixing of film atoms from Al+ subplantation and non-equilibrium growth conditions leading to quenching of the desired film structure. In experimental studies supplemented with density-functional theory calculations, it is demonstrated that Al concentration in alloys with the multielement compositions of high-entropy nitride thin films determine hardness, yield strength, toughness, and ability to deform plastically up to fracture due to different deformation mechanisms arising from the electronic structure and phase compositions.

Evaluation of coffee and coffee waste fractions as mineral sources based on their multi-element composition

ABSTRACT The production and consumption of coffee generates large amounts of waste which, if released into the environment, could cause unacceptable pollution. The search for alternatives for the use of these waste materials, namely coffee silver skin (CSS) and spent coffee grounds (SCG), is of great importance from an environmental and economic point of view. In this context, the present study was conducted to evaluate the use of CSS and SCG as mineral sources in order to strengthen their status as novel foods, which is currently not recognised. With the aim of validating the content of metals and metalloids in CSS and SCG, a comparative study of green and roasted coffee was also conducted. The results of the HR-ICP-MS analyses showed that coffee and coffee by-products contain high levels of macro essential elements: K (2387–35 993 mg/kg), Mg (1263–5298 mg/kg) and Na (82.6–170 mg/kg). Among the essential trace elements, Fe predominated with amounts between 41.8 and 728 mg/kg. The essential elements in the ultra-trace range (Mo, Cr, Co and Se) are found in amounts between 0.02 and 2.42 mg/kg. The content of toxic elements (Pb, As, Cd and Sn) is in the range of 0.01–0.25 mg/kg, which is below the maximum levels set by the EU Commission for these elements in foodstuff. However, the levels of Rb, Ba, Sr, Ti and Al are high, and range from 2.33 to 764 mg/kg. Considering the high content of essential elements in CSSs that are useful for daily human needs, the potential use of CSS should be encouraged. On the other hand, in order to meet the requirements for the use of novel foods, monitoring of potentially toxic elements must be carried out.

The effects of drying methods and harvest season on piperine, essential oil composition, and multi-elemental composition of black pepper

This study aimed to evaluate the piperine content, essential oil composition, and multi-elemental composition of black pepper samples according to different drying methods and harvest season. Differences in essential oil composition and B, Ca, K, Mg, and S were noted according to sampling campaign, indicating secondary metabolism plant alterations. Mechanical drying resulted in essential oil composition changes due to high temperature exposure during processing. Increases in Fe and Cr contents when employing mechanical dryers with direct heating were also observed, due to direct contact with metallic structures and particulate material from the burning process. The As and Pb contents of several samples were higher than the maximum permissible limits, reaching 0.46 and 0.56 mg kg−1, respectively, thus surpassing legislation safety limitations for human consumption.

High-entropy nanoparticles: Synthesis-structure-property relationships and data-driven discovery.

High-entropy nanoparticles have become a rapidly growing area of research in recent years. Because of their multielemental compositions and unique high-entropy mixing states (i.e., solid-solution) that can lead to tunable activity and enhanced stability, these nanoparticles have received notable attention for catalyst design and exploration. However, this strong potential is also accompanied by grand challenges originating from their vast compositional space and complex atomic structure, which hinder comprehensive exploration and fundamental understanding. Through a multidisciplinary view of synthesis, characterization, catalytic applications, high-throughput screening, and data-driven materials discovery, this review is dedicated to discussing the important progress of high-entropy nanoparticles and unveiling the critical needs for their future development for catalysis, energy, and sustainability applications.

Macro/microelements, nutrients and bioactive components in common and Tartary buckwheat (Fagopyrum spp.) grain and stone-milling fractions

The study aimed to determine variations in macro/microelements, nutrients and bioactive components in grain and stone-milled fractions of common and Tartary buckwheat cultivated over three consecutive years. Whole grain were milled to obtain several fractions: light flour, semolina, three or four bran fractions, and hulls. Dry matter, crude protein, crude fat, macro- and microelements, total antioxidant capacity, rutin and quercetin contents, and compounds with antioxidative potential were determined. Crude protein in buckwheat samples ranged from 2.9% to 35.7%, and crude fat from 0.2% to 10.1%. Bioactive compounds were significantly higher in Tartary buckwheat samples, especially for semolina and bran fractions. The multi-elemental compositions of these buckwheat species were comparable, while the differences between the milling fractions varied considerably for K, P, Mg, S, Fe and Zn. Principal component analysis for 20 parameters derived from 45 samples showed good discrimination for buckwheat whole grain, light flour and hulls for both species, for Tartary buckwheat bran and semolina, and for common buckwheat bran and semolina. The profiles of compounds with antioxidant potential were significantly different between the buckwheat species, as well as for hulls and bran fractions compared with the other fractions. In general, harvest year did not have any significant impact on any of the parameters analysed.

Olive Oil Traceability Studies Using Inorganic and Isotopic Signatures: A Review.

The olive oil industry is subject to significant fraudulent practices that can lead to serious economic implications and even affect consumer health. Therefore, many analytical strategies have been developed for olive oil’s geographic authentication, including multi-elemental and isotopic analyses. In the first part of this review, the range of multi-elemental concentrations recorded in olive oil from the main olive oil-producing countries is discussed. The compiled data from the literature indicates that the concentrations of elements are in comparable ranges overall. They can be classified into three categories, with (1) Rb and Pb well below 1 µg kg−1; (2) elements such as As, B, Mn, Ni, and Sr ranging on average between 10 and 100 µg kg−1; and (3) elements including Cr, Fe, and Ca ranging between 100 to 10,000 µg kg−1. Various sample preparations, detection techniques, and statistical data treatments were reviewed and discussed. Results obtained through the selected analytical approaches have demonstrated a strong correlation between the multi-elemental composition of the oil and that of the soil in which the plant grew. The review next focused on the limits of olive oil authentication using the multi-elemental composition method. Finally, different methods based on isotopic signatures were compiled and critically assessed. Stable isotopes of light elements have provided acceptable segregation of oils from different origins for years already. More recently, the determination of stable isotopes of strontium has proven to be a reliable tool in determining the geographical origin of food products. The ratio 87Sr/86Sr is stable over time and directly related to soil geology; it merits further study and is likely to become part of the standard tool kit for olive oil origin determination, along with a combination of different isotopic approaches and multi-elemental composition.

ICP-MS Multi-Elemental Analysis of the Human Meninges Collected from Sudden Death Victims in South-Eastern Poland.

Metals perform many important physiological functions in the human body. The distribution of elements in different tissues is not uniform. Moreover, some structures can be the site of an accumulation of essential or toxic metals, leading to multi-directional intracellular damage. In the nervous system, these disorders are especially dangerous. Metals dyshomeostasis has been linked to a variety of neurological disorders which end up leading to permanent injuries. The multi-elemental composition of the human brain is still the subject of numerous investigations and debates. In this study, for the first time, the meninges, i.e., the dura mater and the arachnoid, were examined for their elemental composition by means of inductively coupled plasma mass spectrometry (ICP-MS). Tissue samples were collected post mortem from those who died suddenly as a result of suicide (n = 20) or as a result of injuries after an accident (n = 20). The interactions between 51 elements in both groups showed mainly weak positive correlations, which dominated the arachnoid mater compared to the dura mater. The study showed differences in the distribution of some elements within the meninges in the studied groups. The significant differences concerned mainly metals from the lanthanide family (Ln), macroelements (Na, K, Ca, Mg), a few micronutrients (Co), and toxic cadmium (Cd). The performed evaluation of the elemental distribution in the human meninges sheds new light on the trace metals metabolism in the central nervous system, although we do not yet fully understand the role of the human meninges.

Heterogeneous Trimetallic Nanoparticles as Catalysts.

The development and application of trimetallic nanoparticles continues to accelerate rapidly as a result of advances in materials design, synthetic control, and reaction characterization. Following the technological successes of multicomponent materials in automotive exhausts and photovoltaics, synergistic effects are now accessible through the careful preparation of multielement particles, presenting exciting opportunities in the field of catalysis. In this review, we explore the methods currently used in the design, synthesis, analysis, and application of trimetallic nanoparticles across both the experimental and computational realms and provide a critical perspective on the emergent field of trimetallic nanocatalysts. Trimetallic nanoparticles are typically supported on high-surface-area metal oxides for catalytic applications, synthesized via preparative conditions that are comparable to those applied for mono- and bimetallic nanoparticles. However, controlled elemental segregation and subsequent characterization remain challenging because of the heterogeneous nature of the systems. The multielement composition exhibits beneficial synergy for important oxidation, dehydrogenation, and hydrogenation reactions; in some cases, this is realized through higher selectivity, while activity improvements are also observed. However, challenges related to identifying and harnessing influential characteristics for maximum productivity remain. Computation provides support for the experimental endeavors, for example in electrocatalysis, and a clear need is identified for the marriage of simulation, with respect to both combinatorial element screening and optimal reaction design, to experiment in order to maximize productivity from this nascent field. Clear challenges remain with respect to identifying, making, and applying trimetallic catalysts efficiently, but the foundations are now visible, and the outlook is strong for this exciting chemical field.

Role of intrinsic physicochemical parameters on multi-element distribution in surface sediment of the Devi River estuary, eastern India

Multi-element composition including rare earth elements (REE) of surface sediment from the Devi river estuary, eastern coast of India, have been analysed in order to study the weathering characteristics and provenance of sediment along with their behaviour under different physicochemical conditions. These sediments with dominantly felsic provenance have undergone low to moderate chemical alterations. Bulk chemical composition is mainly represented by SiO2, Al2O3, Fe2O3 and K2O. Concentrations of Ba, Nb, Pb, Rb, Th and Zr are above their respective upper crustal abundances. High LREE/HREE ratio, negative Eu anomalies, and (La/Yb)n and (Tb/Yb)n values confirm that sediments are dominantly derived from the Eastern Ghat Group of rocks. Upper estuary sediments show negative Eu anomalies which is similar to that of the source. However, positive Eu anomaly is mostly observed in lower estuary. Contrasting Eu anomalies between upper- and lower-estuarine sediments are uncharacteristic of previously studied major global estuaries. Strong negative correlation between Mn and Eu suggests control of redox conditions over distribution of Eu. Concentration of REEs, Sc, Fe, Mo, V, Zn, Zr, Nb, U, Ti, Na and P increases up to 20 ppt salinity, and followed by declining trend towards mouth. This is mostly due to removal through flocculation of colloidal particles from water column during fresh- and saline-water interaction. This could be the first report about coagulation-based behaviour of Mo in estuarine environment. There is gradual decline in concentration of Cr, Co, Ni, Cu, Rb, Sr, Sb, Cs, Ba, Pb, Al, Mn, Mg, Ca and K with increase in salinity which is attributed to saline induced desorption of elements from sediments. The SiO2 content shows increasing trend towards mouth. Findings of this study highlight the importance of intrinsic physicochemical parameters, mainly salinity and redox condition, on governing geochemical behaviour of different elements including REE in mangrove dominated estuarine sediment.

Unpacking the complexity of longitudinal movement and recruitment patterns of facultative amphidromous fish

Longitudinal movement plays fundamental role in habitat colonization and population establishment of many riverine fish species. Movement patterns of amphidromous fish species at fine-scales that would allow characterizing the direction of movement and factors associated with the establishment of specific life-history strategies (resident or amphidromous) in rivers are still poorly understood. We assess fine-scale longitudinal movement variability patterns of facultative amphidromous fish species Galaxias maculatus in order to unfold its life-history variation and associated recruitment habitats. Specifically, we analyzed multi-elemental composition along core to edge transects in ear-bones (otoliths) of each fish using recursive partitions that divides the transect along signal discontinuities. Fine-scale movement assessment in five free-flowing river systems allowed us to identify movement direction and potential recruitment habitats. As such, resident recruitment of G. maculatus in freshwater (71%) and estuarine (24%) habitats was more frequent than amphidromous recruitment (5%), and was linked to availability of slow-flowing lotic or lentic habitats that produce or retain small-bodied prey consumed by their larvae. We postulate that life-history variation and successful recruitment of facultative amphidromous fish such as G. maculatus in river systems is driven by availability of suitable recruitment habitats and natural hydrologic connectivity that allows fish movement to these habitats.

The Effect of Cultivation Practices on Agronomic Performance, Elemental Composition and Isotopic Signature of Spring Oat (Avena sativa L.).

The present study investigated the effects of cultivation practices on grain (oats) yield and yield components, such as straw yield, harvest index, thousand kernel weight, and plant lodging. In addition, multi-element composition and isotopic signature (δ13C, δ15N) of the oat grains were studied. The spring oat cultivar ‘Noni’ was grown in a long-term field experiment during 2015–2020, using three management practices: control without organic amendment, incorporation of manure every third year and incorporation of crop residues/cover crop in the rotation. Synthetic nitrogen (N) (0, 55, 110 and 165 kg/ha) was applied during oat development in each system. Multi-element analysis of mature grains from two consecutive years (2016 and 2017) was performed using EDXRF spectroscopy, while stable isotope ratios of carbon (C) and nitrogen (N) were obtained using an elemental analyzer coupled to an isotope ratio mass spectrometer (EA/IRMS). The results show how cultivation practices affect yield components and isotopic and elemental signatures. Increasing the N rate improved both the oat grain and straw yields and increased susceptibility to lodging. The results show how the elemental content (Si, Ca, Zn, Fe, Ti, Br and Rb) in the oat grains were influenced by intensification, and a noticeable decrease in elemental content at higher N rates was the result of a dilution effect of increased dry matter production. The mean δ15N values in oat grains ranged from 2.5‰ to 6.4‰ and decreased with increasing N rate, while δ13C values ranged from −29.9‰ to –28.9‰. Based on the δ15N values, it was possible to detect the addition of synthetic N above an N rate of 55 kg/ha, although it was impossible to differentiate between different management practices using stable isotopes.

Clay and Soil Organic Matter Drive Wood Multi-Elemental Composition of a Tropical Tree Species: Implications for Timber Tracing

Clay and Soil Organic Matter Drive Wood Multi-Elemental Composition of a Tropical Tree Species: Implications for Timber Tracing

Greening Ultrasound-Assisted Extraction for Sorghum Flour Multielemental Determination by Microwave-Induced Plasma Optical Emission Spectrometry.

Sorghum is the fourth most important cereal produced in Argentina and the fifth worldwide. It has good agronomic characteristics and could be developed in arid areas, allowing a wide geographic distribution. Its starch content, higher than 70%, makes it possible to obtain a good yield of flours. Nutritionally, it should be noted that the grain does not have the protein fraction called prolamins, which makes it suitable for consumption by people with celiac disease. The multielemental composition constitutes an important indicator of the nutritional profile of the grains and allows, together with other parameters, to select the most suitable varieties for human consumption. In its determination, the preanalytical stage is decisive to obtain a reliable result. Organic samples are a challenge for sample introduction systems that use plasma-based techniques. As an alternative to conventional pretreatment with a microwave-assisted digestion (MWAD), a greener, quick, and simple treatment is proposed, using ultrasound-assisted extraction (UAE) in diluted acid media. The UAE method accelerates analysis times, improves performance and productivity, and was applied to sorghum samples cultivated in the province of La Pampa (Argentina). Microwave-induced plasma optical emission spectrometry (MIP OES) was employed for the determination of Cu, K, Mg, Mn, P, and Zn. The detection limits found ranged from 0.6 (Cu) to 89 (P) mg kg−1, and the precision expressed by the relative standard deviation (RSD) was ≤7.7% (Zn). For validation, a maize reference material (NCS ZC 73010) was evaluated. The principal component analysis revealed three different groupings related to the sorghum varieties' mineral profile.

Multi-Elemental Composition Data Handled by Chemometrics for the Discrimination of High-Value Italian Pecorino Cheeses.

The multi-elemental composition of three typical Italian Pecorino cheeses, Protected Designation of Origin (PDO) Pecorino Romano (PR), PDO Pecorino Sardo (PS) and Pecorino di Farindola (PF), was determined by Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES). The ICP-OES method here developed allowed the accurate and precise determination of eight major elements (Ba, Ca, Fe, K, Mg, Na, P, and Zn). The ICP-OES data acquired from 17 PR, 20 PS, and 16 PF samples were processed by unsupervised (Principal Component Analysis, PCA) and supervised (Partial Least Square-Discriminant Analysis, PLS-DA) multivariate methods. PCA revealed a relatively high variability of the multi-elemental composition within the samples of a given variety, and a fairly good separation of the Pecorino cheeses according to the geographical origin. Concerning the supervised classification, PLS-DA has allowed obtaining excellent results, both in calibration (in cross-validation) and in validation (on the external test set). In fact, the model led to a cross-validated total accuracy of 93.3% and a predictive accuracy of 91.3%, corresponding to 2 (over 23) misclassified test samples, indicating the adequacy of the model in discriminating Pecorino cheese in accordance with its origin.

Support vector machine and PCA for the exploratory analysis of Salvia officinalis samples treated with growth regulators based in the agronomic parameters and multielement composition

The objective of this work was to evaluate the influence of different growth regulators on the mineral and total phenolic contents of Salvia officinalis. The samples received the applications of salicylic acid (AS); gibberellic acid (GA3); abscisic acid (ABA) and solution without regulators (control). The exploratory evaluation of the samples was carried out through the Principal Component Analysis (PCA). In addition, has been used supervised learning methods with support vector machine (SVM) algorithms to classify the samples. The phenolic and total flavonoid contents were higher in the plants treated with the regulators. The element found in the highest concentration in Salvia officinalis was N. Plants sprayed with ABA showed higher concentrations of N, K, and Mn; Fe and Al were higher with ABA and gibberellin application, while the application of AS provided the highest accumulation of P. The application of plant regulators improves the nutraceutical properties of Salvia officinalis.

Multi-Element Composition of Diatom Chaetoceros spp. from Natural Phytoplankton Assemblages of the Russian Arctic Seas.

Simple SummaryDespite the long history of studying the elemental composition of phytoplankton and its individual ecological and systematic groups or specific algae species, the global dataset is far from completed. Our original research aims to study the elemental composition of a certain taxonomic group of marine diatoms, whose representatives make a significant contribution to primary production in the Arctic Ocean. The data on the chemical composition of diatom microalgae are discussed concerning their role in the global biogeochemical circulation of elements in the ocean. In particular, the obtained data make a prominent input to the study of the multi-element composition of marine diatom species, namely Chaetoceros spp., inhabiting the shelf seas of the Arctic Ocean. These data may be used as a basis for the cultivation of marine diatom strains for obtaining commercially promising producers of biogenic silica or valuable biological products that can be used as raw materials in the production of feed and nutrition for agriculture and aquaculture.Data on the elemental composition of the diatom Chaetoceros spp. from natural phytoplankton communities of Arctic marine ecosystems are presented for the first time. Samples were collected during the 69th cruise (22 August–26 September 2017) of the R/V Akademik Mstislav Keldysh in the Kara, Laptev, and East Siberian Seas. The multi-element composition of the diatom microalgae was studied by ICP-AES and ICP-MS methods. The contents of major (Na, Mg, Al, Si, P, S, K and Ca), trace (Li, Be, B, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Mo, Ag, Cd, Sn, Sb, Cs, Ba, Hg, Tl, Pb, Bi, Th and U) and rare earth (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) elements varied greatly, which was probably associated with the peculiarities of the functional state and mineral nutrition of phytoplankton in the autumn period. Biogenic silicon was the dominant component of the chemical composition of Chaetoceros spp., averaging 19.10 ± 0.58% of dry weight (DW). Other significant macronutrients were alkaline (Na and K) and alkaline earth (Ca and Mg) metals as well as biogenic (S and P) and essential (Al and Fe) elements. Their total contents varied from 1.26 to 2.72% DW, averaging 2.07 ± 0.43% DW. The Al:Si ratio for natural assemblages of Chaetoceros spp. of the shelf seas of the Arctic Ocean was 5.8 × 10−3. The total concentrations of trace and rare earth elements on average were 654.42 ± 120.07 and 4.14 ± 1.37 μg g−1 DW, respectively. We summarize the scarce data on the average chemical composition of marine and oceanic phytoplankton and discuss the limitations and approaches of such studies. We conclude on the lack of data and the need for further targeted studies on this issue.

Multi-elemental composition, nutrients and total phenolics in seeds of Phaseolus vulgaris L. breeding material

Multi-elemental composition, nutrients and total phenolics in seeds of Phaseolus vulgaris L. breeding material

Pigment compositions in Siberian early Upper Paleolithic complexes

Pigment compositions in Siberian early Upper Paleolithic complexes

The Multi-Elemental Composition of the Aqueous Humor of Patients Undergoing Cataract Surgery, Suffering from Coexisting Diabetes, Hypertension, or Diabetic Retinopathy.

The aim of the study was the multi-elemental analysis of aqueous humor (AH) collected from patients undergoing cataract surgery. The study included: 16 patients with age-related macular degeneration AMD (99 controls), 10 patients with retinopathy (105 controls), 61 patients with hypertension (54 controls), and 33 patients with coexisting diabetes (82 controls). The control groups were recruited from patients with a lack of co-existing disease characterizing the specified studied group. The measurements were performed by the use of inductively coupled plasma optical emission spectrometry (ICP-OES). The statistical analysis was carried out using non-parametric testing (Mann–Whitney U). The level of significance was set at p = 0.05. The data obtained revealed substantial variations in elemental composition between the test groups in comparison to the controls. However, the significant variations concerned only a few elements. The phosphorous (P) level and the ratio of P/Ca were significant in retinopathy and diabetes, whereas cobalt (0.091 ± 0.107 mg/L vs. 0.031 ± 0.075 mg/L; p = 0.004) was significant in AMD. In co-existing hypertension, the levels of tin (0.293 ± 0.409 mg/L vs. 0.152 ± 0.3 mg/L; p = 0.031), titanium (0.096 ± 0.059 mg/L vs. 0.152 ± 0.192 mg/L; p = 0.045), and ruthenium (0.035 ± 0.109 mg/L vs. 0.002 ± 0.007 mg/L; p = 0.006) varied in comparison to the controls. The study revealed inter-elemental interactions. The correlation matrices demonstrated the domination of the positive correlations, whereas negative correlations mainly concerned sodium.