This paper studies carbon tax policy in inventory games of multi-echelon supply chains. Four structures are considered with regard to the decision-making of supply chain members (decentralized, vertical downward cooperation, vertical upward cooperation, and horizontal cooperation). The purposes are to find the solutions of inventory games at each cooperation scheme, to compare strategies, and to examine the impact of the carbon tax on costs, emissions, and cooperation savings. A coordination mechanism with synchronized cycles is proposed, using cooperative game theory concepts in SC centralization. Closed-form equilibrium values were calculated for the optimal replenishment cycles, costs, and carbon emissions functions. For this intent, an algebraic method was deployed for vertical cooperation games. Though, other games were solved by an exact solution method. The numerical examples examined the impacts of the carbon tax on each structure and compared optimal solutions. Moreover, the impact of inventory and carbon emissions parameters on the cost and carbon emissions savings from cooperation settings were evaluated, indicating that SCs can reduce both costs and carbon emissions through cooperation. Additionally, it was found that the carbon tax can reduce the level of carbon emissions, while simultaneously decreasing coalition costs and emissions savings.