Vapor Movement Research Articles

Vapour transfer in unsaturated compacted bentonite

Results of an experimental and theoretical investigation of heat and moisture movement in unsaturated MX-80 bentonite are presented. A thermo-hydraulic cell that allows measurement of transient temperatures and facilitates the determination of pseudo-transients of moisture content, dry density and chemical composition has been used to perform thermal gradient tests. Results of a number of tests are presented, and observation of the accumulation of chloride ions near the hot end clearly indicates that there is a cycle of vapour and liquid moisture movement, with vapour moving from hotter to cooler regions, condensing, and then moving as liquid towards the hotter regions. An empirical method is applied to calculate approximate vapour fluxes using measured variations in chloride ion concentration and moisture content with time. The vapour fluxes calculated empirically are found to be lower than those determined by some existing vapour flow theories. Subsequently, an existing vapour flow model is modified to represent the observed vapour fluxes more closely.

An experimental simulation model for coated paper drying

Due to the lack of information regarding the phenomena of mass, heat, and momentum transfer in coated paper drying, substantial research work still needs to be done. A simulation model for coated paper drying is introduced which integrates heat and mass transfer mechanisms. In the model, the coated paper was assumed to have 3 layers (coated layer, wet and dry layers of the base paper), in which the thickness of each layer is a function of drying time and condition. The thickness of the wet layer of the base paper was considered to be a function of water permeability rate that in turn is a function of the moisture diffusion coefficient, time and drying rate. Movement of vapor resulting from evaporation in the middle layer was assumed to be a combination of laminar bulk flow and molecular diffusion. Radiation absorption was used as a diminishing exponential model, which depends on moisture content. Hot air and super heated vapor were used as drying fluids. Functional variables were temperature, drying fluid velocity and delay time. To verify the simulation results two compositions were applied for the coating suspension. The simulation results matched well with experimental outcomes.

Vapor Movement of Aminocyclopyrachlor, Aminopyralid, and Dicamba in the Field

Vapor movement of synthetic auxin herbicides can injure desirable plants outside the treatment zone. Vapor movement of the synthetic auxin herbicides aminocyclopyrachlor and aminocyclopyrachlor methyl was compared with that of the relatively volatile herbicide dicamba and the low volatile herbicide aminopyralid with a soybean bioassay under greenhouse and field conditions. Soybean is very sensitive to these active ingredients. Under greenhouse conditions, 82 (61 to 104) mg ae ha−1of aminocyclopyrachlor, 26 (18 to 33) mg ae ha−1of aminocyclopyrachlor methyl, 82 (69 to 95) mg ae ha−1of aminopyralid, and 61 (47 to 75) mg ae ha−1of dicamba produced an estimated 25% visual soybean phytotoxicity response when soybean was treated POST at the V3 growth stage (GR25[95% confidence interval]). In field studies, aminocyclopyrachlor, aminocyclopyrachlor methyl, and aminopyralid were applied at 70 g ae ha−1and dicamba was applied at 560 g ae ha−1(labeled application rates) to soybean at the V3 growth stage. All herbicides were applied within an enclosed chamber (3 m by 3 m by 1 m) to mitigate movement of spray droplets. The enclosures were removed shortly after spray application and soybean response immediately surrounding the treated area was recorded in each of eight directions approximately 10 d after treatment. On the basis of bioassay responses, relative amount of vapor movement was dicamba > aminocyclopyrachlor methyl > aminopyralid ≈ aminocyclopyrachlor. Vapor movement of aminocyclopyrachlor was very low indicating that the risk of phytotoxic response of sensitive plants due to volatility of aminocyclopyrachlor is negligible.

Approaches for representing hydro-mechanical coupling between sub-surface excavations and argillaceous porous media at the ventilation experiment, Mont Terri

At the Mont Terri Underground Research Laboratory (Switzerland), a field-scale investigation has been conducted in order to investigate the hydro-mechanical and chemical perturbations induced in the argillaceous formation by forced ventilation through a tunnel. This experiment has been selected to be used for processing model development and validation in the international project DECOVALEX-2011. The conceptual and mathematical representation of the engineered void, which itself forms a major part of the experiment and is not simply a boundary condition, is the subject of this paper. A variety of approaches have been examined by the contributors to DECOVALEX and a summary of their findings is presented here. Two major aspects are discussed. Firstly, the approaches for the treatment of the surface condition at the porous media/tunnel interface are examined, with two equivalent but differing formulations successfully demonstrated. Secondly, approaches for representing the tunnel with associated air and water vapour movement, when coupled with the hydro-mechanical (HM) representation of the porous medium, are also examined. It is clearly demonstrated that, for the experimental conditions of the ventilation experiment (VE) that abstracted physical and empirical models of the tunnel, can be used successfully to represent the hydraulic behaviour of the tunnel and the hydraulic interaction between the tunnel and the surrounding rock mass.

A novel approach to sterile pharmaceutical freeze-drying

A novel approach has been developed that enables sterile pharmaceutical products to be freeze-dried in the open laboratory without specialist facilities. The product is filled into vials, semi-stoppered and sealed inside one, followed by a second, sterilization pouch under class 100 conditions. The product is then freeze-dried in the laboratory where the vials are shelf-stoppered before being returned to class 100, unwrapped and crimped. The sterilization pouches increased the resistance to water vapor movement during sublimation, thereby increasing the sublimation time and product temperature. Ovine immunoglobulins were double wrapped and lyophilized (as above) adjusting the primary drying time and shelf temperature for increased product temperature and, therefore, prevention of collapse. Ovine immunoglobulin G formulations freeze-dried to ≤1.1% residual moisture with no effect on protein aggregation or biological activity. The process was simulated with tryptone soya broth and no growth of contaminating microbial cells was observed after incubation at 35 °C for 2 weeks. Although increasing lyophilization time, this approach offers significant plant and validation cost savings when sterile freeze-drying small numbers of vials thereby making the manufacture of treatments for neglected and orphan diseases more viable economically.

Estimation of CO2 diffusion coefficient at 0–10 cm depth in undisturbed and tilled soils

Diffusion coefficients (D) of CO2 at 0–10 cm layers in undisturbed and tilled soil conditions were estimated using the Penman (Penman HL. 1940. Gas and vapor movement in soil, 1. The diffusion of vapours through porous solids. J Agric Sci. 30:437–463), Millington–Quirk (Millington RJ, Quirk JP. 1960. Transport in porous media. In: Van Baren FA, editor. Transactions of the 7th International Congress of Soil Science. Vol. 1. Amsterdam: Elsevier. p. 97–106), Ridgwell et al. (Ridgwell AJ, Marshall SJ, Gregson K. 1999. Consumption of atmospheric methane by soils: A process-based model. Global Biogeochem Cy. 13:59–70), Troeh et al. (Troeh FR, Jabro JD, Kirkham D. 1982. Gaseous diffusion equations for porous materials. Geoderma. 27:239–258) and Moldrup et al. (Moldrup P, Kruse CW, Rolston DE, Yamaguchi T. 1996. Modeling diffusion and reaction in soils: III. Predicting gas diffusivity from the Campbell soil–water retention model. Soil Sci. 161:366–375) models. Soil bulk density and volumetric soil water content (θv) at 0–10 cm were measured on 14 April, 2 June and 12 July 2005 at 0–10 cm depth in no-till (NT) and conventional till (CT) malt barley and undisturbed soil grass–alfalfa (UGA) systems. Air-filled porosity (ε) was calculated from total soil porosity and θv measurements. Both soil air porosity and estimated CO2 diffusivity at the 0–10 cm depth were significantly affected by tillage. Results of CO2 diffusion coefficients in the soil followed trends similar to those for soil ε data. The CT tended to have significantly greater estimated soil CO2 diffusion coefficients than the NT and UGA treatments. The relationship between D/D 0, and air-filled porosity was well described by a power (R 2 = 0.985) function. The model is useful for predicting CO2 gas-diffusion coefficients in undisturbed and tilled soils at various ranges of ε where actual gas D measurements are time-consuming, costly and infeasible.

Analysis of thermal comfort characteristics of moisture management finished knitted fabrics made from different yarns

In recent years, the studies of thermal characteristics have gained importance since it is directly related to clothing comfort. One of the ways of achieving clothing comfort is through moisture management of textiles. Moisture management refers to the controlled movement of water vapor and perspiration from the surface of the skin to the atmosphere through the fabric. The aim of this research is to study the thermal comfort characteristics of selected knitted fabrics by analyzing the thermal behavior of moisture management finished (MMF) fabrics, in order to find the suitability of the product for different climatic conditions. The knitted fabrics made from yarns of micro-denier polyester filament, spun polyester, polyester/cotton, filament polyester, and 100% cotton were used for the study. Thermal characteristics such as thermal conductivity, thermal resistance, thermal absorptivity, relative water vapor permeability, and water vapor resistance were analyzed for the MMF fabrics. The test results indicated that the knitted fabrics produced from different nature of yarns have greater influence on thermal characteristics, when they were converted into fabrics. The MMF treatment have significant effect on thermal behavior of micro-denier polyester knitted fabrics with respect to thermal conductivity, thermal absorptivity, water vapor permeability, and water vapor resistance. Among the five fabrics, it was observed that micro-denier polyester fabrics gives faster heat transfer, quicker evaporation of sweat from the skin through the fabric, and also cooler feeling at initial touch.

Non-isothermal moisture movement in unsaturated kaolin: An experimental and theoretical investigation

Abstract Non isothermal moisture movement in unsaturated kaolin is investigated in a series of experiments. Vapour transfer is then empirically quantified, and its theoretical representation considered. A thermo-hydraulic cell is used to apply thermal and hydraulic gradients to confined specimens in a number of thermal gradient, thermal-hydraulic gradient, and isothermal-hydraulic tests. Transient measurements of the thermal regime are made, and end of test measurement of moisture content, porosity, and chemical composition from a number of identical tests run for different durations allow pseudo transient variations of these parameters to be established. In each of the tests, where a thermal gradient is applied, the accumulation of chloride ions in the hottest regions indicates a cyclic movement of vapour and liquid moisture. Estimated vapour fluxes are determined by consideration of overall moisture and conservative ion movements in the sealed thermal gradient tests. These vapour fluxes are then compared to those predicted by an established vapour flow theory, and a modification to this theory is proposed based on a variable enhancement factor.

Evaporation from soils under thermal boundary conditions: Experimental and modeling investigation to compare equilibrium‐ and nonequilibrium‐based approaches

In the shallow subsurface immediately below the land‐atmosphere interface, it is widely recognized that the movement of water vapor is closely coupled to thermal processes. However, their mutual interactions are rarely considered in most soil water modeling efforts or in practical applications where it becomes necessary to understand the spatial and temporal distribution of soil moisture. The validation of numerical models that are designed to capture these processes is difficult due to the scarcity of field or laboratory data with accurately known hydraulic and thermal parameters of soils, limiting the testing and refinement of heat and water transfer theories. The goal of this paper is to perform controlled experiments under transient conditions of soil moisture and temperature and use this data to test existing theories and develop appropriate numerical models. Water vapor flow under varying temperature gradients was implemented on the basis of a concept that allows nonequilibrium liquid/gas phase change with gas phase vapor diffusion. To validate this new approach, we developed a long column apparatus equipped with a network of sensors and generated data under well‐controlled thermal boundary conditions at the soil surface. The nonequilibrium approach yielded good agreement with the experimental results, validating the hypothesis that transport in the gas phase is better suited to be modeled with nonequilibrium liquid/gas phase change for highly transient field conditions where the thermal conditions at the land‐atmosphere interface are constantly changing.

Water and heat transport in boreal soils: Implications for soil response to climate change

Soil water content strongly affects permafrost dynamics by changing the soil thermal properties. However, the movement of liquid water, which plays an important role in the heat transport of temperate soils, has been under-represented in boreal studies. Two different heat transport models with and without convective heat transport were compared to measurements of soil temperatures in four boreal sites with different stand ages and drainage classes. Overall, soil temperatures during the growing season tended to be over-estimated by 2–4 °C when movement of liquid water and water vapor was not represented in the model. The role of heat transport in water has broad implications for site responses to warming and suggests reduced vulnerability of permafrost to thaw at drier sites. This result is consistent with field observations of faster thaw in response to warming in wet sites compared to drier sites over the past 30 years in Canadian boreal forests. These results highlight that representation of water flow in heat transport models is important to simulate future soil thermal or permafrost dynamics under a changing climate.

Ageing tests study on wood-based sandwich panels

Composite lightweight wood panels are being increasingly used in construction in Spain. Their growing use should be accompanied by necessary guarantees based on studies of their properties. As it is prescriptive and in addition to others tests, in the present work is examinated the durability of these panels when exposed to the climatic conditions, a characteristic of great importance for wood products, according to Guide ETAG 016, the current standard defining the ageing tests to be used. However, due to the use class of this material, there are indications that the testing outlined in this Guide is inappropriate for assessing the ageing of wood-based sandwich panels. Alternative tests are here proposed that recreate rather better the real conditions under which these products are used. Covering the samples in a waterproof sheeting permeable to the outward movement of water vapour, which is in fact used in the installation, provided the best procedure for testing these panels.

Critical heat stress evaluation of clothing ensembles with different levels of porosity

A common metric of assessing the evaporative cooling potential of protective clothing is to assess the rate of diffusion of water vapour through the fabric. Another mechanism that supports evaporative cooling is convective transfer. Prototype porous coveralls were constructed to promote convective air flow with 0.0024 mm (0.06 inch) holes representing nominal openings of 0, 1, 2, 5, 10 and 20% of the garment surface area (called P00, P01, P02, P05, P10 and P20). The purpose of this study was to evaluate the ability of these porous coverall configurations to support evaporative cooling. The assessment measures were critical wet bulb globe temperature (WBGT) and apparent evaporative resistance via a progressive heat stress protocol. There was a progressive increase in critical WBGT with increases in convective permeability for P00, Saratoga™ Hammer, P01, work clothes and P02. There was no further increase for P05, P10 and P20. A similar pattern was found for diffusive permeability, with the exception of Saratoga™ Hammer, which suggested that the convective permeability could explain evaporative cooling better than diffusive permeability. Statement of Relevance: Protective clothing often interferes with evaporative cooling and thus increases the level of heat stress. While increased diffusion of water vapour is associated with lower evaporative resistances, the convective movement of water vapour is a dominant mechanism and better explains the role of the clothing in heat stress.

Vapor Movement of Synthetic Auxin Herbicides: Aminocyclopyrachlor, Aminocyclopyrachlor-Methyl Ester, Dicamba, and Aminopyralid

Aminocyclopyrachlor, a newly discovered synthetic auxin herbicide, and its methyl ester, appear to control a number of perennial broadleaf weeds. The potential volatility of this new herbicide and its methyl ester were determined under laboratory conditions and were also compared to dicamba and aminopyralid with the use of enclosed chamber and open-air plant bioassays. Bioassays consisting of visual estimates of epinastic responses and kidney bean and soybean leaf-width measurements were developed to measure vapor release from glass and plastic. Vapor release of aminocyclopyrachlor from glass surfaces was undetectable under laboratory conditions, and no phytotoxic responses were observed when plants were exposed to vapors emanating from various surfaces. Results were similar to those of aminopyralid, indicating the risk of plant injury from vapor movement of aminocyclopyrachlor and aminopyralid was very low. When combined with 1% methylated seed oil, vapor release of aminocyclopyrachlor-methyl ester reached 86% 192 h after application to glass surfaces. Phytotoxic responses of plants exposed to vapors emanating from various surfaces treated with aminocyclopyrachlor-methyl ester were similar to responses to dicamba under enclosed incubation conditions, but were less in outdoor, open-air environments. Studies are needed to understand better the risk of injury to nontarget plants due to vapor movement of aminocyclopyrachlor-methyl ester under field applications.

A Transient Model for Fuel Cell Cathode-Water Propagation Behavior inside a Cathode after a Step Potential

Most of the voltage losses of proton exchange membrane fuel cells (PEMFC) are due to the sluggish kinetics of oxygen reduction on the cathode and the low oxygen diffusion rate inside the flooded cathode. To simulate the transient flooding in the cathode of a PEMFC, a transient model was developed. This model includes the material conservation of oxygen, vapor, water inside the gas diffusion layer (GDL) and micro-porous layer (MPL), and the electrode kinetics in the cathode catalyst layer (CL). The variation of hydrophobicity of each layer generated a wicking effect that moves water from one layer to the other. Since the GDL, MPL, and CL are made of composite materials with different hydrophilic and hydrophobic properties, a linear function of saturation was used to calculate the wetting contact angle of these composite materials. The balance among capillary force, gas/liquid pressure, and velocity of water in each layer was considered. Therefore, the dynamic behavior of PEMFC, with saturation transportation taken into account, was obtained in this study. A step change of the cell voltage was used to illustrate the transient phenomena of output current, water movement, and diffusion of oxygen and water vapor across the entire cathode.

Modelling and simulation of flow boiling heat transfer

PurposeThe purpose of this paper is to describe the development and application of a numerical model for analysis of flow boiling phenomena and heat transfer.Design/methodology/approachFor flow boiling processes, the fluid and vapour flow regimes in connection with the conjugate heat and mass transfer problem for specimen quenching through the entire boiling curve is modelled. Vaporisation and recondensation, the vapour fraction distribution and vapour movement with respect to the liquid are considered in the calculation of the two‐phase flow and heat transfer process. The derived flow boiling model is based on a mixture model and bubble crowding model approach for two‐phase flow. In addition to the conventional mixture model formulation, here special model implementations have been incorporated that describe: the vapour formation at the superheated solid‐liquid interface, the recondensation process of vapour at the subcooled vapour‐liquid interface, the mass transfer rate in the different boiling phases and the microconvection effect in the nucleate boiling phase resulting from bubble growth and detachment.FindingsThe model prediction results are compared with experimental data for quenching of a circular cylinder, showing good agreement in boiling state and heat transfer coefficient distribution. Simulation and experiments lead to a better understanding of the interaction of incident flow in the boiling state and the resulting heat transfer.Research limitations/implicationsFluid temperatures in the range of 300‐353 K and specimen wall temperatures up to 1,000 K are considered.Practical implicationsFlow boiling is an efficient heat transfer process occurring in several technical applications. Application background of the model development is in quenching of complex metallic specimen geometries in liquids subject to fast changing heat fluxes.Originality/valueA general model for the complex two‐phase boiling heat transfer at high wall temperatures and fast flow conditions that can be used in engineering applications does not yet exist. The results provide detailed information describing the non‐uniform phase change during the complete quenching process from film boiling to pure convection.

Effect of Moisture Management Finish on Comfort Characteristics of Microdenier Polyester Knitted Fabrics

Moisture management can be defined as the controlled movement of water vapor and liquid water (perspiration) from the surface of the skin to the atmosphere through the fabric. Wetting, wicking, and moisture vapor transmission (MVT) properties are the critical aspects for evaluating the comfort performance of textiles. In this study, the effect of stitch length and knit structure on comfort characteristics of moisture management finished knitted fabric that includes wicking, wetting, water absorbency, MVT, and air permeability have been analyzed.

Effects of meteorological models on the solution of the surface energy balance and soil temperature variations in bare soils

summary A complete evaluation of the soil thermal regime can be obtained by evaluating the movement of liquid water, water vapor, and thermal energy in the subsurface. Such an evaluation requires the simultaneous solution of the system of equations for the surface water and energy balance, and subsurface heat transport and water flow. When only daily climatic data is available, one needs not only to estimate diurnal cycles of climatic data, but to calculate the continuous values of various components in the energy balance equation, using different parameterization methods. The objective of this study is to quantify the impact of the choice of different estimation and parameterization methods, referred together to as meteorological models in this paper, on soil temperature predictions in bare soils. A variety of widely accepted meteorological models were tested on the dataset collected at a proposed low-level radioactive-waste disposal site in the Chihuahua Desert in West Texas. As the soil surface was kept bare during the study, no vegetation effects were evaluated. A coupled liquid water, water vapor, and heat transport model, implemented in the HYDRUS-1D program, was used to simulate diurnal and seasonal soil temperature changes in the engineered cover installed at the site. The modified version of HYDRUS provides a flexible means for using various types of information and different models to evaluate surface mass and energy balance. Different meteorological models were compared in terms of their prediction errors for soil temperatures at seven observation depths. The results obtained indicate that although many available meteorological models can be used to solve the energy balance equation at the soil–atmosphere interface in coupled water, vapor, and heat transport models, their impact on overall simulation results varies. For example, using daily average climatic data led to greater prediction errors, while relatively simple meteorological models may significantly improve soil temperature predictions. On the other hand, while models for the albedo and soil emissivity had little impact on soil temperature predictions, the choice of the atmospheric emissivity models had a greater impact. A comparison of all the different models indicates that the error introduced at the soil atmosphere interface propagates to deeper layers. Therefore, attention needs to be paid not only to the precise determination of the soil hydraulic and thermal properties, but also to the selection of proper meteorological models for the components involved in the surface energy balance calculations.

Water and Vapor Movement with Condensation and Evaporation in a Sandy Column

The diffusion of warm, humid air into an initially cold, dry, sandy column was analyzed to study the movement of water vapor and liquid water under nonisothermal and low water content conditions. The analysis was performed using the HYDRUS‐1D code. While the water retention curve of sand was measured experimentally, the unsaturated hydraulic conductivity function was inversely estimated from the observed water content profiles in the column. The estimated unsaturated hydraulic conductivity function displayed a shape that reflected distinct processes of capillary pore water flow and film flow at high and low water contents, respectively. Four components of the total water flux, including thermal and isothermal liquid water and water vapor fluxes, were evaluated using the calibrated soil hydraulic properties. Evaporation and condensation rates were calculated based on water mass balance. Water vapor entered the soil column at the hot surface and condensed at the cold bottom. Subsequently, liquid water moved upward and evaporated at the moisture front in the middle of the column where the relative humidity decreased below unity. Liquid water and water vapor then circulated between the bottom and the moisture front, accompanied by condensation and evaporation processes. The impact of the enhancement factor in the thermal vapor diffusion term could not be clearly identified from available experimental water content profiles. Increases in liquid water flow and the evaporation rate could be compensated for by increases in vapor flow and the condensation rate. Additional data would be needed to fully evaluate the effect of the enhancement factor.

Condensation Damage Behind Self-Adhering Membrane Flashing and Interior Furnishings on Exterior Residential Walls

Abstract This paper will present case studies of condensation damage behind self-adhering membranes installed around windows and other penetrations in exterior walls, as well as case studies of condensation damage behind large interior furnishings installed on the interior surfaces of exterior walls, and in unventilated spaces in Minnesota. The self-adhering membranes that are often used to integrate water-resistive barriers with residential doors and windows can, under certain conditions, lead to condensation and subsequent damage. While wider membranes help prevent inward movement of liquid water to the sheathing and stud framing, they also inhibit outward movement of interior water vapor. By increasing the distance that outward moving vapor must travel, wide membrane flashings trap moisture that can condense in cold climates and cause deterioration of degradable materials. In cold climate regions, condensation damage can also occur in exterior walls behind furnishings such as large mirrors and large cabinets. These interior decorations act as thermal reflectors and prevent interior heat from migrating into the exterior walls. When moisture behind these thermal reflectors is cooled below the dew point, condensation and related deterioration of the wall framing can occur. This paper discusses suggestions for the width of applied self-adhered membranes in cold climate regions and recommends locations for thermally reflecting interior furnishings.

Diurnal soil water dynamics in the shallow vadose zone (field site of China University of Geosciences, China)

Because of the relatively low soil moisture in arid or semi-arid regions, water vapour movement often predominates in the vadose zone and affects the partitioning of energy among various land surface fluxes. In an outdoor sand bunker experiment, the soil water content at 10 and 30 cm depth were measured at hourly intervals for 2.5 days during October 2004. It was found that the soil moisture reached the daily maximum value (5.9–6.1% at 10 cm and 11.9–13.1% at 30 cm) and minimum value (4.4–4.5% at 10 cm and 10.4–10.8% at 30 cm) at midday (0–1 p.m. for 10 cm and 2–3 p.m. for 30 cm) and before dawn (2–3 a.m. for 10 cm and 4–5 a.m. for 30 cm), respectively. The modified HYDRUS-1D code, which refers to the coupled water, water vapour and heat transport in soil, was used to simulate the moisture and water vapour flow in the soil. The numerical analyses provided insight into the diurnal movement of liquid water and water vapour driven by the gradients of pressure heads and temperatures in the subsurface zone. The simulated temperature and water content were in good agreement with the measured values. The spatial–temporal distribution of liquid water flux, water vapour flux and soil temperature showed a detailed diurnal pattern of soil water dynamics in relatively coarse sand.