Dating Of Monazite Research Articles

Chemical U–Th–total Pb dating and structural disorder of monazite-(Ce) from granitoids of the Aduiskii massif, Middle Urals

Using the methods of electron probe microanalysis and Raman spectroscopy, the zoning, chemical composition, and disorder in the matrix of accessory monazite extracted from a synplutonic quartz dioritic dyke intruding migmatite, diorite, and fine-granular granite of the Aduiskii massif were studied. It was established that monazite grains contained inner and outer zones. The contributions of chemical and radiation factors to mineral disorder were estimated. The results of chemical U-Th-total Pb dating of mineral are reported. The age 252 ± 4 Ma corresponds to the second maximum of granite formation.

Geochemistry, U-Pb dating, and Lu-Hf isotopes of zircon and monazite of porphyritic granites within the Jiao-Liao-Ji orogenic belt: Implications for petrogenesis and tectonic setting

Abundant porphyritic granites, including Grt-bearing and Bt-bearing porphyritic granites, and flesh-red porphyritic granites, as various scale batholiths are widely distributed within the Jiao-Liao-Ji belt (JLJB), which extends for a distance of at least 1000km, rather than being limited to sporadic outcrops in southern Liaoning and Jilin as stated in previous studies. On the basis of morphology, CL and BSE zoning patterns, and mineral inclusions of dated zircon and monazite grains from samples of various porphyritic granites, the grains exhibit evident magmatic zones with distinct cores and rims and preserve felsic mineral inclusions of Qtz+Kfs+Pl+Qtz±Ap in both domains. The magmatic zircon cores and rims from 18 dated samples yielded two distinct weighted mean age groups, from 1872±9 to 1866±7Ma and 1851±14 to 1842±10Ma, with age peaks at 1869±1.7 and 1848±2.4Ma, respectively. Similarly, the magmatic cores and rims of monazites from 10 dated samples also showed two distinct weighted mean age groups, from 1870±3 to 1864±2Ma and 1851±6 to 1842±12Ma, with age peaks at 1868±0.8 and 1847±1.2Ma, respectively. The numerous U-Pb age data of both zircons and monazites revealed that the JLJB experienced a major episode of granitic magmatism in the Paleoproterozoic with initial emplacement timing of melts at ∼1.87Ga and crystallisation end timing of melts at ∼1.84Ga as represented by the magmatic cores and rims of the zircons and monazites, respectively. A combined study of whole-rock geochemistry and zircon Lu-Hf isotopic analyses revealed that the three types of porphyritic rocks are enriched in HREE, Zr, Nb, Ga, and Y and are depleted in V, Cr, and Ni, and that most have high TFeO/MgO ratios and Zr-saturation temperatures of ∼850°C, which is suggestive of an affinity with A-type granite. Moreover, the dominant εHf(t) values of the magmatic zircons range from −4.8 to +3.3, which is consistent with those of the 2.2–2.1Ga calc-alkaline meta-granites in the JLJB. Considering the high contents of garnet, Al-rich paragneiss enclaves, and ∼1.92Ga inherited metamorphic zircons in the granites, these porphyritic rocks were most likely derived from the partial melting of the 2.2–2.1Ga calc-alkaline meta-granites with abundant involvement of Al-rich pelitic granulites from the basement of the JLJB. As the result of a newly combined study of traditional geothermobarometers and phase equilibria modelling together with geochronological U-Pb dating, a precise clockwise P-T-t path with a subsequent near isothermal decompression process has been well determined in the HP-MP granulite facies metamorphic rocks in the JLJB. Thus, the following sequence of events can be inferred. Abundant ∼2.2–2.1Ga granitic rocks and voluminous Paleoproterozoic sedimentary rocks were subducted to lower crustal depths and underwent a peak HP-MP granulite facies metamorphism at 1950–1900Ma. These granulite facies rocks were exhumed to middle crustal levels and experienced a post-peak MP-LP granulite facies metamorphism at 1875–1840Ma. The retrograde rocks continued to be exhumed to shallow crustal levels at 1830–1800Ma and were finally overprinted by late amphibolite facies retrogression. The numerous magmatic zircons and monazites from the various porphyritic granites record a distinct Paleoproterozoic granitic magmatic event with two evident age peaks of ∼1.87Ga and ∼1.84Ga, which are completely consistent with the post-peak MP-LP granulite facies metamorphism (1875–1840Ma), representing an anorogenic magmatic association formed in an extensional setting possibly resulting from mantle upwelling and lithospheric thinning and resulting in the violent partial melting of ∼2.2–2.1Ga meta-granites along with abundant Al-rich pelitic granulites. Considering these data in combination with previous whole-rock geochemistry and age data, it can be stated that similar porphyritic granites are not only limited to the entire JLJB but are also widely distributed in North and South Korea. Thus, it can be concluded that the ∼1.87–1.84Ga porphyritic granites, together with massive rapakivi granites, Kfs-megacrysts, and porphyritic monzogranites, as products of an anorogenic granitic magmatic event, may have widely formed in both the JLJB and Korean Peninsula in an extensional and thinning tectonic setting.

Late Permian volcanic dykes in the crystalline basement of the Považský Inovec Mts. (Western Carpathians): U–Th–Pb zircon SHRIMP and monazite chemical dating

AbstractThis paper presents geochronological data for the volcanic dykes located in the northern Považský Inovec Mts. The dykes are up to 5 m thick and tens to hundreds of metres long. They comprise variously inclined and oriented lenses, composed of strongly altered grey-green alkali basalts. Their age was variously interpreted and discussed in the past. Dykes were emplaced into the Tatricum metamorphic rocks, mostly consisting of mica schists and gneisses of the Variscan (early Carboniferous) age. Two different methods, zircon SHRIMP and monazite chemical dating, were applied to determine the age of these dykes. U-Pb SHRIMP dating of magmatic zircons yielded the concordia age of 260.2 ± 1.4 Ma. The Th-U-Pb monazite dating of the same dyke gave the CHIME age of 259 ± 3Ma. Both ages confirm the magmatic crystallization at the boundary of the latest Middle Permian to the Late Permian. Dyke emplacement was coeval with development of the Late Paleozoic sedimentary basin known in the northern Považský Inovec Mts. and could be correlated with other pre-Mesozoic Tethyan regions especially in the Southern Alps.

Thermal history of a Late Mesoproterozoic paired metamorphic belt (?) during Rodinia assembly: New insight from medium-pressure granulites from the Aravalli-Delhi Mobile Belt, Northwestern India

In this study, we investigate the possible record of a Late Mesoproterozoic paired metamorphic belt in the Aravalli-Delhi Mobile Belt (ADMB), NW India using a suite of supracrustal and metaigneous granulites from the Pilwa-Chinwali granulite terrain at the north-western margin of the ADMB. Using metamorphic reaction textures, mineral chemistry, metamorphic reaction history, geothermobarometric computations and electron microprobe dating of monazite in 5 samples of pelitic granulite, leptynite gneiss, enderbite and charnockite, we have deduced a medium-pressure granulite facies metamorphism (P between 4.9 and 6.8 kbar, T > 760–815 °C) along a heating-cooling, counterclockwise P-T path between 1.09 and 1.01 Ga. When collated with published metamorphic and chronological constraints and geological settings of the adjoining crustal domains of the ADMB, these findings provide new insights into the developments of two tectonic domains of contrasting thermal gradients at ca. 1.0 Ga, consistent with metamorphic transformations in tectonically thickened middle-lower crustal sections during continental collision to continental subduction and in the root zones of spatially adjacent island arc, as part of the Rodinia supercontinent assembly event.

Geochronological constraints on the trans-Hudsonian tectono-metamorphic evolution of the pre-Athabasca basement within the Wollaston-Mudjatik Transition Zone, Saskatchewan

The Hudsonian Pressure-Temperature-Deformation-time-(P-T-D-t) evolution of the pre-Athabasca crystalline basement (>∼1700Ma) of the Wollaston-Mudjatik Transition Zone (WMTZ) highlights two major tectono-metamorphic events M1-D1 and M2-D2. The ages of these two event have been obtained by in-situ LA-ICPMS U-Th-Pb dating of monazite from Grt-Crd bearing pelitic gneiss and U-Pb analyses performed on zircons from pegmatites, using both exposed basement and drill cores from the Wolly–McClean exploration drilling project. The M1-D1 event, interpreted as the burial of the thinned Hearne margin via southward thrusting to pressures varying from 10 to 6kbar, occurred between ca.1840 and 1813Ma. The M2-D2 event, producing the northeast structural trend of the WMTZ, was formed in a sinistral transpressional tectonic regime during the late stage of the Hudsonian oblique collision between ca. 1813 and 1770Ma. Thermobarometric estimates on the M2–D2 assemblages show that the entire studied area was reequilibrated at about 5kbar and 750–825°C. trans-Hudsonian pegmatites are viewed as the main proto-ore of the uranium-rich Athabasca unconformity-type deposits. Formation, transfer and differentiation of these trans-Hudsonian pegmatites are replaced in this P-T-D-t evolution. During the 1840–1813MaM1-D1 partial melting event, the first batches of melt produced in the deep crust are the most likely enriched in uranium. Then, these melts were transferred upwards to the upper crustal levels owing to the development of crustal scale steeply-dipping D2 shear zones, and finally were differentiated to form uranium-enriched pegmatites between 1813 and 1770Ma. Some monazite and zircon grains within retrogressed migmatites recorded a later event at ca. 1720Ma, interpreted as the terminal cooling event down to 300–400°C responsible for partial retrogression of metamorphic assemblages. This age provides new insights into the timing of the onset of the Athabasca sedimentation that should therefore be at least 1710Ma old or younger.

Petrography, geochemistry, and U–Pb geochronology of pegmatites and aplites associated with the Alvand intrusive complex in the Hamedan region, Sanandaj–Sirjan zone, Zagros orogen (Iran)

The Alvand intrusive complex in the Hamedan area in Iran is in the Sanandaj–Sirjan zone of the Zagros orogen. It consists of a wide range of plutonic rocks, mainly gabbro, diorite, granodiorite, granite, and leucogranites that were intruded by aplitic and pegmatitic dykes. At least three successive magmatic episodes generated an older gabbro–diorite–tonalite assemblage, followed by a voluminous granodiorite–granite association, which was then followed by minor leucocratic granitoids. Aplitic and pegmatitic dykes and bodies have truncated both plutonic rocks of the Alvand intrusive complex and its metamorphic aureole. Chemically they belong to peraluminous LCT (Li-, Cs-, and Ta-bearing) family of pegmatites. Mineralogically, they resemble Muscovite (MS) and Muscovite Rare Element (MSREL) classes of pegmatites. High amounts of some elements, such as Sn (up to 10,000 ppm), Rb (up to 936 ppm), Ba (up to 706 ppm), and LREE (up to 404 ppm) indicate the highly fractionated nature of some of these aplites and pegmatites. U–Pb dating of monazite, zircon, and allanite by LA-ICPMS indicate the following ages: monazite-bearing aplites of Heydareh-e-Poshteshahr and Barfejin areas, southwest of Hamedan, give an age range of 162–172 Ma; zircon in Heydareh-e-Poshteshar gives an average age of ~165 Ma and for allanite-bearing pegmatites of Artiman area, north of Tuyserkan, an age of 154.1 ± 3.7 Ma was determined. These overlap with previously reported ages (ca. 167–153 Ma) for the plutonic rocks of the Alvand complex. Therefore, these data reveal that the Jurassic was a period of magmatism in the Hamedan region and adjacent areas in the Sanandaj–Sirjan zone, which was situated at the southern edge of the central Iranian micro-plate (southern Eurasian plate) at this time. Our results also suggest that advective heating in a continental arc setting has caused melting of fertile supracrustal lithologies, such as meta-pelites. These partial melts were then emplaced at much higher crustal levels, but within a thermally anomalous environment, which, therefore, leads to formation of evolved felsic rocks, such as the studied LCT aplite–pegmatite suite and their parental granitic rocks. This is a new result that indicates the role of syn-subduction crustal partial melting in the region as part of Zagros orogeny.

Mineralogy, geochemistry and geochronology of mafic magmatic enclaves and their significance in evolution of Nongpoh granitoids, Meghalaya, NE India

Abstract The Cambrian Nongpoh granitoids, intrusive into the Precambrian gneissic complex and metasediments of the Shillong Group, represent a major phase of granitic magmatism in the Shillong Plateau. The Nongpoh granitoids comprise diorite, granodiorite, porphyritic and grey granites. Porphyritic granite is the dominant lithology exposed in the Nongpoh granitoids, and contains three types of enclaves, viz. xenoliths of gneissic rocks, dark grey porphyry and biotite-rich microgranular enclaves. The mafic magmatic enclaves (MMEs) of various dimensions and shapes, including rounded, ellipsoidal, rectangular, angular to subangular, and stretched bodies, were produced by evolving nature and contrasting kinematics of interacting felsic and mafic magmas. The biotite-rich enclaves are due to the injection of syn-magmatic mafic dykes in felsic magma. The various textural assemblages and sub-linear variations between silica and major oxides, chemical mixing and element diffusion suggest that multistage magma hybridization was the key process during the evolution of the Nongpoh granitoids. The 501 Ma age obtained by chemical (U–Th–Pb) dating of monazite in MME ascertained the age of the magma hybridization event in the Nongpoh granitoids, which is equivalent to the igneous activity at 500 Ma during the amalgamation of Eastern Gondwana.

Geochronology of accessory allanite and monazite in the Barrovian metamorphic sequence of the Central Alps, Switzerland

The formation of accessory allanite, monazite and rutile in amphibolite-facies rocks across the Barrovian sequence of the Central Alps (Switzerland) was investigated with a combination of petrography and geochemistry and related to the known structural and metamorphic evolution of the Lepontine dome. For each of these minerals a specific approach was adopted for geochronology, taking into account internal zoning and U–Th–Pb systematics. In-situ U–Th–Pb dating of allanite and monazite by ion microprobe revealed systematic trends for the ages of main deformation and temperature in the Lepontine dome. Isotope dilution TIMS dating of rutile returns dates in line with this picture, but is complicated by inheritance of pre-Alpine rutile and possible Pb loss during Alpine metamorphism.Allanite is generally a prograde mineral that is aligned along the main foliation of the samples and found also as inclusions in garnet. Prograde allanite formation is further documented by rutile inclusions with formation temperatures significantly lower than the maximum T recorded by the rock mineral assemblage. Allanite ages vary from 31.3±1.1Ma in orthogneisses in the East to 31.7±1.1Ma for a Bündnerschiefer and 28.5±1.3Ma for a metaquartzite in the central area, to 26.8±1.1Ma in the western part of the Lepontine dome. These ages are interpreted to date the main deformation events (nappe stacking and isoclinal deformation of the nappe stack), close to peak pressure conditions.The timing of the thermal peak in the Lepontine dome is recorded in monazite that grew at the expense of allanite and after a main episode of garnet growth at temperatures of ~620°C. Monazite in the central area yields an age of 22.0±0.3Ma, which is indistinguishable from the age of 21.7±0.4Ma from a metapelite in the western part of the Lepontine dome. In the central area some of the classical kyanite‐staurolite-garnet schists directly underlying the metamorphosed Mesozoic sediments contain monazite that records only a pre-Alpine, Variscan metamorphic event of upper greenschist to lower amphibolite-facies conditions dated at ~330Ma.The new age data provide evidence that nappe stacking at prograde amphibolite-facies conditions and refolding of the nappe stack occurred between 32 and 27Ma, only a few million years after eclogite-facies metamorphism in the Adula-Cima Lunga unit. Amphibolite-facies metamorphism lasted for about 10My to ~22Ma, allowing for multiple ductile deformation and recrystallization events. The long lasting amphibolite-facies metamorphism requires fast cooling between 20 and 15Ma in the Central Alps. This fast cooling was not related to an increase in sedimentation rates in the foreland basins, suggesting that tectonic exhumation was responsible for termination of amphibolite-facies metamorphism in the Lepontine dome.

U–Pb dating of metamorphic monazite establishes a Pan-African age for tectonism in the Nallamalai Fold Belt, India

The Nallamalai Fold Belt comprises late Palaeoproterozoic to Mesoproterozoic sedimentary rocks deformed into a fold-and-thrust belt along the eastern side of Peninsular India. The age of thin-skinned thrusting, folding and low- to medium-grade metamorphism in the belt is unclear, with estimates ranging from Palaeoproterozoic to early Palaeozoic. A possible Pan-African age for thrusting has previously been inferred from Rb–Sr dating of muscovite in shear zones from the adjacent Krishna Province (501 – 474 Ma) but these structures are separated from the Nallamalai Fold Belt by a major thrust. Here, we present in situ U–Pb dating of metamorphic monazite within a low-grade metasedimentary rock in the Nallamalai Fold Belt at the Mangampeta barite mine. Our date of 531 ± 7 Ma for the monazite is the first direct evidence that west- to NW-directed nappe stacking, folding and low-grade metamorphism in the fold belt are related to Pan-African incorporation of India into the Gondwana supercontinent.

Uranium-lead dating of hydrothermal zircon and monazite from the Sin Quyen Fe-Cu-REE-Au-(U) deposit, northwestern Vietnam

The Sin Quyen deposit in northwestern Vietnam contains economic concentrations of Cu, Au and LREE, and sub-economic concentration of U. In this deposit, massive and banded replacement ores are hosted in Neoproterozoic metapelite. The paragenetic sequence includes sodic alteration (stage I), calcic-potassic alteration and associated Fe-REE-(U) mineralization (stage II), Cu-Au mineralization (stage III), and sulfide-(quartz-carbonate) veins (stage IV). The Sin Quyen deposit experienced an extensive post-ore metamorphic overprint, which makes it difficult to precisely determine the mineralization age. In this study, zircon and monazite U-Pb geochronometers and the Rb-Sr isochron method are used to constrain the timing of mineralization. Zircon grains in the ore are closely intergrown or texturally associated with hydrothermal minerals of stage II (e.g., garnet, allanite, and hedenbergite). They may contain primary fluid inclusions and display irregular zoning in cathodoluminescence (CL) images. Zircon grains are rich in U (688 to 2902 ppm) and poor in Th (0.2 to 2.9 ppm). Their δ18OV-SMOW values range from 11.9 to 14.0‰, higher than those of typical magmatic zircon. These textural and compositional features imply that zircon precipitated from 18O- and U-rich hydrothermal fluids, coeval with the minerals of stage II. Monazite occurs in close association with stage II magnetite and allanite and has low contents of Th (<2700 ppm), indicative of a hydrothermal origin. Hydrothermal zircon and monazite have indistinguishable U-Pb ages of 841 ± 12 and 836 ± 18 Ma, respectively, representing the timing of Fe-REE mineralization. There is no direct isotopic constraint on the timing of the Cu-Au mineralization, but geological observations suggest that the Cu-Au and Fe-REE ores most likely formed within a single evolved hydrothermal process. In the plot of 87Rb/86Sr vs. 87Sr/86Sr, the composition of bulk-ore and biotite separates from ore lie along a reference line for 30 Ma, which is consistent with the timing of metamorphism in the region. The mineralization age of the Sin Quyen deposit falls within the overall age range (740 to 860 Ma) of the regional Neoproterozoic igneous rocks. This temporal linkage, in combination with the magmatic-like sulfur isotopes of sulfide minerals (δ34SV-CDT = −0.8 to 3.1), indicates that the mineralization may have a close genetic association with the Neoproterozoic igneous activity.

Using in situ SHRIMP U-Pb Monazite and Xenotime Geochronology to Determine the Age of Orogenic Gold Mineralization: An Example from the Paulsens Mine, Southern Pilbara Craton

Paulsens is a mesothermal orogenic gold deposit located in the Wyloo Inlier on the southern margin of the Pilbara craton of Western Australia. Gold occurs in quartz-sulfide veins hosted within a folded and faulted gabbro dike, from which baddeleyite yields a U-Pb crystallization age of 2701 ± 11 Ma. Monazite and xenotime in the veins and from hydrothermally altered country rocks yield three distinct U-Pb dates of ca. 2400, 1730, and 1680 Ma. Textural relationships between euhedral xenotime and pyrite with rounded native gold inclusions from within the quartz-sulfide veins show that the primary gold mineralization was synchronous with xenotime crystallization at 2403 ± 5 Ma, and coeval with pervasive alteration of the host rocks, which yield monazite ages of 2398 ± 37 and 2403 ± 38 Ma. Regional-scale hydrothermal events at ca. 1730 and 1680 Ma are linked to the growth of monazite within phyllitic rocks at 1730 ± 28 and 1721 ± 32 Ma, carbonate veining at 1655 ± 37 Ma, and gold remobilization or introduction of new gold at 1680 ± 9 Ma. The ca. 2400 Ma age for mineralization and hydrothermal alteration does not correspond with any known deformation event in the region, indicating a significantly different and more complicated low-temperature tectonothermal evolution for the southern Pilbara region than previously recognized. The in situ secondary ion mass spectrometry dating of monazite and xenotime employed here will lead to better targeting of orogenic gold deposits in the northern Capricorn Orogen, and these techniques can be utilized for orogenic gold exploration worldwide.

Alpine metamorphism of low-grade schists from the Slavonian Mountains (Croatia): new P-T and geochronological constraints

ABSTRACTLow-grade schists from the Slavonian Mountains (Tisia Mega-Unit, Mt Papuk, Croatia), previously assigned to Precambrian to Lower Palaeozoic metamorphism, have been subjected to geochemical investigations, P-T modelling, and in situ age dating of monazite. The studied fine-grained metasediments consist of chlorite (5–15 vol.%), K white-mica (40–55 vol.%), quartz (20–35 vol.%), feldspar (albite 15–20 vol.%), opaques (<2 vol.%), and accessory minerals. According to their whole-rock geochemistry, the detritus of the former sediments came from upper crustal felsic rocks as they occur, for instance, at Mt Papuk. The schists show a complex microtectonic fabric, including well-developed schistosity systems. P-T pseudosections in the system MnNCKFMASHTO, constructed for typical schists of the study area, resulted in peak P-T conditions of 445–465 °C and 4.6–6.0 kbar for a sample from Kutjevo (eastern part of the study area) and 450–460 °C and 5.2–6.0 for a Vranovo sample (western part). Electron microprobe (EMP) dating of monazite in the schists gave a weighted average age of 109.0 ± 13.1 Ma (2σ) eventually with three subgroups of ages at 225 ± 63 (two analyses), 114 ± 24 and 83 ± 22 Ma. We conclude that the metamorphism of the studied schists at depths of c. 20 km is due to an Alpine collisional event.

Using monazite geochronology to test the plume model for carbonatites: The example of Gifford Creek Carbonatite Complex, Australia

Carbonatites are carbonate-dominated igneous rocks derived by low-degree partial melting of metasomatized mantle, although the geodynamic processes responsible for their emplacement into the crust are disputed. Current models favor either reactivation of lithospheric structures in response to plate movements, or the impingement of mantle plumes. Geochronology provides a means of testing these models, but constraining the age of carbonatites and related metasomatic events is rarely straightforward. We use in situ U-Th-Pb analysis of monazite by SHRIMP to constrain the emplacement age and hydrothermal history of the rare earth element-bearing Gifford Creek Carbonatite Complex in Western Australia, which has been linked to plume magmatism at ca. 1075Ma. Monazite in carbonatites and related metasomatic rocks (fenites) from the carbonatite complex dates the initial emplacement of the carbonatite at 1361±10Ma (n=22, MSWD=0.91). The complex was subjected to multiple stages of magmatic/hydrothermal overprinting from ca. 1300Ma to 900Ma during later regional tectonothermal events. Carbonatite emplacement at ca. 1360Ma appears to be an isolated igneous event in the region, and occurred about 300 million years before intrusion of the ca. 1075Ma Warakurna large igneous province, thus precluding a genetic connection. The Gifford Creek Carbonatite Complex occurs within a major crustal suture, and probably formed in response to reactivation of this suture during plate reorganization. Our study demonstrates the veracity of monazite geochronology in determining the magmatic and hydrothermal histories of a carbonatite complex, critical for evaluating competing geodynamic models for carbonatites. The approach involving in situ SHRIMP U-Th-Pb dating of monazite from a wide spectrum of rocks in a carbonatite complex is best suited to establishing the intrusive age and hydrothermal history of carbonatites.

Results of chemical dating of monazite from the Talnakh economic intrusion (Russia)

Economic copper, nickel, and platinum-group element (PGE) deposits are associated with the Talnakh ultramafic–mafic intrusion of the Noril’sk Province in the northwestern part of the Siberian Platform. The results of the chemical Th–U–Pb dating of monazite from the ore-bearing melanotroctolites of the Talnakh intrusion are presented. The isotope-geochemical features of monazite are compared with zircon, sulfides, and baddeleyite.

Geochronological constraints on magmatism and polyphase deformation and metamorphism in the southern Omineca Belt, British Columbia

The Omineca Belt between Nelson and Creston in southeastern British Columbia was affected by overlapping pulses of Mesozoic magmatism, metamorphism, and deformation. U–Pb geochronological data from zircon and monazite were collected by laser ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS) to constrain the timing of these events. The Porcupine Creek stock (162.3 ± 1.3 Ma) intruded across folds and fabrics associated with the earliest phase of regional deformation and metamorphism (D1M1), restricting it to the Early–Middle Jurassic. The Jurassic structures are overprinted northwards by Early Cretaceous deformation and metamorphism (D2M2). The Baldy pluton (117.8 ± 1.2 Ma) crosscuts the regional 144–134 Ma M2 isograds, yet was pervasively affected by the D2 deformation, indicating that D2 deformation outlasted M2 metamorphism but had ceased by 111 Ma, the age of an undeformed pluton. Monazite dates from a kyanite-bearing rock in the contact aureole of the Middle Jurassic Wall stock overlap with the age of the intrusion (167 Ma), indicating a contact rather than regional origin for the kyanite. In the southeast part of the study area, three samples from the regional sillimanite zone contain monazite intergrown with sillimanite that yield dates between 80 and 69 Ma, indicating an episode of Late Cretaceous (M3) Barrovian metamorphism and deformation (D3). To the north of this domain, in an area characterized by the older D2M2 deformation, a sillimanite zone schist contains two main monazite age populations, suggestive of overlapping effects of Early Cretaceous and Late Cretaceous metamorphic episodes.

Three stages of geological evolution of granites from the Uralian part of the basement of the West Siberian platform

Granites, especially those that were decompressed as a result of processes of secondary transformations and tectonic movements, hold the greatest potential in the search for oil-bearing rocks in basements of sedimentary basins. Owing to the chemical dating of monazites from collision granites of the East Shebur area, the isochrone age of 274.5 ± 21 Ma was obtained. Zircons (SHRIMP-II) yield a concordant age of 277.5 ± 2 Ma (MSWD = 0.77). The Rb–Sr isochrone age of granites (247.4 ± 9.1 Ma) coincides with the emplacement time of the West Siberian rift system. This age records the process of intruding East Shebur granites into the upper crust level during riftogenesis and the extension of the study area. The younger age datings (231 Ma, 60 Ma (U–Pb); 220 Ma (K–Ar)) record the stages of tectonomagmatic activation, recorded in the basement of the Western Siberia oil-bearing areas.

Discrepancy between U-Pb zircon and monazite dates in granitoids from the Ryoke Belt (Iwakuni-Yanai area, SW Japan)

Discrepancy between U-Pb zircon and monazite dates in granitoids from the Ryoke Belt (Iwakuni-Yanai area, SW Japan)

Ediacaran (∼620 Ma) high-grade regional metamorphism in the northern Arabian Nubian Shield: U-Th-Pb monazite ages of the Elat schist

Ediacaran times witnessed a hemisphere-scale orogenesis, forming the extensive Pan-African mountain ranges and resulting in the final assembly of the Gondwana supercontinent. The Elat metamorphic association (S Israel), located at the northernmost tip of the Arabian Nubian Shield (ANS), comprises amphibolite-facies pelitic and psammitic schists and orthogneisses and was presumably shaped by Ediacaran East African orogenesis. However, the timing, number and duration of metamorphic events in Elat and elsewhere in the ANS are inconclusive and a major emphasis was previously given to pre-Ediacaran island-arc related tectonics. Here U-Th-Pb dating of monazite, a precise chronometer of metamorphic mineral growth, is systematically applied to the Elat schist and unveils the tectono-metamorphic evolution of the Elat association.In-situ analysis of metamorphic monazites by LASS-ICPMS (Laser-Ablation Split-Stream Inductively Coupled Plasma Mass Spectrometry) yields two concordant age clusters at ∼710 and 620Ma, recording two regional metamorphic events. The corresponding REE patterns of the dated monazite grains indicate that garnet porphyroblast growth took place only during the younger event (M2). Likewise, the regional south-dipping penetrative foliation (S2), common to the Elat schist and the surrounding orthogneisses, formed during the Ediacaran event (M2). The peak M2 staurolite-garnet-sillimanite assemblage was overprinted by retrograde andalusite and cordierite during decompression, followed by the intrusion of andesitic dykes that were immediately metamorphosed at greenschist-facies conditions. This metamorphic P-T-d-t path corresponds to the collision of the already accreted arc terranes of the ANS with the Saharan Metacraton, as also suggested by the large geochronological database of 610–580Ma post collisional granitoid batholiths throughout NE Africa and Arabia. The Cryogenian M1 metamorphism therefore records arc-arc collision during major convergence forming the proto-ANS to the south.

Improving geochronological framework of the Pan-African orogeny in Cameroon: New SIMS zircon and monazite U-Pb age constraints

High-precision geochronological framework is crucial to understanding of the evolution of orogenesis. As part of the Pan-African North Equatorial Fold Belt, the Neoproterozoic Fold Belt of Cameroon (NFBC) involved polyphase deformation (D1 to D4 phases), metamorphism (up to granulite facies) and widespread crustal anatexis and magmatism. While a general geochronological framework has been established, controversy still exists on the temporal evolution of the metamorphic and magmatic events associated with polyphase deformation, in particular, the accurate age and geodynamic manifestations underlining the end of the orogeny are yet to be well constrained. We conduct in this work integrated analyses of SIMS U-Pb zircon and monazite dating and in-situ zircon Hf-O isotopes on the orthogneiss, leucosome and granite samples from Wum and Yaoundé of southwestern Cameroon in order to provide further constraints on temporal evolution of the NFBC. Our high-precision SIMS U-Pb age data demonstrate that the magmatic protoliths of orthogneisses from Wum and Yaoundé were emplaced synchronously at ca. 620Ma. They were generated by partial melting of the thickened Paleoproterozoic crustal basement rocks with zircon Hf TDMc model age of ca. 1.9–2.0Ga. Metamorphic zircons and two generations of monazites from an in-situ leucosome within the granulitic paragneiss of the Yaoundé Group yield indistinguishable ages of ca. 610Ma. These new results, in combination with previous isotopic data, suggest that the Yaoundé Group supracrustal rocks with zircon Hf TDMc model age of ca. 1.7Ga experienced a very rapid evolution from sedimentation at <626Ma, burial to deformation and granulite facies metamorphism at ca. 610Ma. The deformed two-mica granite and undeformed biotite granite in Wum were precisely dated at 561±3Ma and 557±4Ma, respectively. They both were derived from similar supracrustal sources with zircon Hf TDMc model age of ca. 2.56–2.40Ga. On the basis of our new SIMS U-Pb ages, along with existing dates from the literature, an improved geochronological framework is proposed for the NFBC, with ages of ≥620Ma, ca. 620–600Ma, ca. 590–580Ma, and ca. 580–560Ma for the D1, D2, D3, and D4 phase events, respectively.

Early Paleozoic granulite-facies metamorphism and anatexis in the northern West Qinling orogen: Monazite and zircon U-Pb geochronological constraints

In the northern West Qinling orogen (WQO), granulite-facies metamorphic rocks are recognized within the Qinling Complex. These rocks are composed of amphibole-bearing two-pyroxene granulite and garnet-sillimanite gneiss with widespread migmatitization. We investigate three granulite-facies samples and one leucosome sample from the Qinling Complex, which are suitable for U-Pb analyses of zircon and monazite. SHRIMP and LA-ICPMS U-Pb age dating of zircon and monazite from two pelitic granulites provides weighted mean ages of 430±4 Ma (MSWD=0.88) and 433±4 Ma (MSWD=0.27), respectively. Based on the petrographic characteristics and zircon CL imagery, we postulated a ca. 430 Ma metamorphic timing for the pelitic granulites. LA-ICPMS zircon U-Pb data from an amphibole two-pyroxene granulite sample reports two weighted mean age groups: 424±3 Ma (MSWD=0.45) and 402±3 Ma (MSWD=1.4), which were interpreted as granulite-facies metamorphic and retrograde ages, respectively. LA-ICPMS U-Pb dating of zircons from the leucosome sample yields a weighted mean age of 426±2 Ma (MSWD=0.3), which is interpreted as the crystallization age of the leucosome. These data indicate that the West QOB experienced early Paleozoic granulite-facies metamorphism and anatexis similar to the East QOB. However, it remains unclear whether the early Paleozoic granulite facies metamorphism resulted from an arc setting created by the northward subduction of the Shangdan ocean or from a continental collisional orogenic event.