Molybdate Inhibitors Research Articles

Corrosion Inhibition of AZ31-xLi (x = 4, 8, 12) magnesium alloys in sodium chloride solutions by aqueous molybdate

Corrosion of lithium-containing AZ31 magnesium alloys AZ31-xLi (x = 4, 8, and 12 wt%) has been examined in 0.05 M NaCl solution with and without 10–150 mM of Na2MoO4 inhibitor. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and dynamic electrochemical impedance spectroscopy (DEIS) measurements were used to correlate the phase composition and microstructure of the alloys with their corrosion propensity and effectiveness of the molybdate inhibitor, giving high inhibition efficiency (>85%) at concentrations higher than ca. 35 mM. Post-corrosion microstructure, Raman, and X-ray photoelectron spectroscopy analyses allowed to provide the inhibition mechanism of AZ31-xLi alloys by molybdate ions.

Enthralling Anodic Protection by Molybdate on High-Entropy Alloy-Based Electrocatalyst for Sustainable Seawater Oxidation.

Efficient and sustainable seawater electrolysis is still limited due to the interference of chloride corrosion at the anode. The designing of suitable electrocatalysts is one of the crucial ways to boost electrocatalytic activity. However, the approach may fall short as achieving high current density often occurs in chlorine evolution reaction (CER)-dominating potential regions. Thereby, apart from developing an OER-active high-entropy alloy-based electrocatalyst, the present study also offers a unique way to protect anode surface under high current density or potential by using MoO4 2- as an effective inhibitor during seawater oxidation. The wide variation of d-band center of high-entropy alloy-based electrocatalyst allows great oxygen evolution reaction (OER) proficiency exhibiting an overpotential of 230mV at current density of 20mA cm-2. Besides, the electrocatalyst demonstrates impressive stability over 500h at high current density of 1 A cm-2 or at a high oxidation potential of 2.0V versus RHE in the presence of a molybdate inhibitor. Theoretical and experimental studies reveal MoO4 2- electrostatically accumulated at anode surface due to higher adsorption ability, thereby creating a protective layer against chlorides without affecting OER.

Exploring mechanism of corrosion inhibition of WE43 and AZ31 alloys by aqueous molybdate in Hank’s solution by multisine impedimetric monitoring

The concept of utilizing multisine dynamic electrochemical impedance spectroscopy to monitor effectiveness of a model molybdate inhibitor for AZ31 and WE43 Mg alloys is proposed. The corrosion kinetics and instantaneous values of inhibition efficiency (IE) of molybdate at concentrations up to 150 mM were examined. The inhibitor provides inhibition in Hank’s solution at concentrations starting from ca. 25 mM, with the IE of about 90%. These data together with results of the surface analysis allowed to propose the mechanism of the corrosion inhibition of AZ31 and WE43 Mg alloys by aqueous molybdate in Hank’s solution.

The Assessment of Pit Chemistry Parameters of 316 Stainless Steel and 304 Stainless Steel by Adding a Molybdate Inhibitor in a Chloride Aggressive Media

In this study, the efficacy of Mo as an alloying element and inhibitor on the pit chemistry parameters of 316 stainless steel (316SS) (2 wt% Mo) and 304 stainless steel (304SS) (0.2 wt% Mo) in chloride and molybdate-bearing solution is investigated. To evaluate pit chemistry parameters, three-step polarization and four-step polarization tests using a pencil electrode were conducted. The results suggested that the presence of molybdate ions increased the pit transition potential and repassivation potential. Moreover, molybdate increases the critical, saturation, and supersaturation concentrations at an equal pit depth. Therefore, the concentration of necessary cations increased to precipitate the salt. A comparison of the pit chemistry characteristics between 316SS and 304SS showed that molybdenum increased the potential necessary for salt removal and facilitated the repassivation process of the individual pit.

An investigation on the effect of molybdenum alloy element and molybdate inhibitor on the stable and metastable pits and its correlation with the pit morphology

BackgroundMolybdenum (Mo) has been introduced as a useful alloying element by increasing the resistance to pitting corrosion of steels. To prove this opinion, the effect of this element on pitting corrosion parameters in corrosive environments can be investigated. In addition, adding a molybdate (MoO42−) inhibitor to the media can answer the question of whether there is a synergistic effect between molybdenum in the alloy and molybdate in the environment to increase corrosion resistance or not. The study holds relevance by suitable select materials based on the presence of corrosion-resistant alloying elements and inhibitors based on the reduction of environmental acidity or the occurrence of polymerization reactions for industries frequently affected by pitting corrosion. MethodsIn this paper, the influence of the molybdenum alloying element and molybdate inhibitor on the metastable and stable pits of 316 SS and 304 SS in chloride and molybdate-bearing media is studied. The evaluation is conducted using potentiodynamic and potentiostatic techniques on a flat sample. The morphology of the pits is observed through scanning electron microscopy in solutions of NaCl and Na2MoO4. FindingsThe results suggest that the presence of molybdate ions in chloride solution leads to an increase in the pitting potential and repassivation potential of both steels. Furthermore, molybdate is suggested to decrease the peak current, radius, and stability product of metastable pits. A comparative analysis between the corrosion behavior of 316 SS and 304 SS suggests that the addition of molybdenum enhances the resistance to pitting corrosion and facilitates the repassivation process. Additionally, adding molybdate in chloride solutions results in smaller stable cavity sizes without altering their appearance.

The effect of inhibiting molybdate used in anodizing-conversion treatment to improve corrosion protection of AA2030 aluminum alloy in different steps

In this article, different treatment baths for corrosion protection of 2030 aluminum alloy in addition to replacing the hexavalent chromium due to the European recommendation were employed. This work is divided into three steps of treatment: first, anodization using molybdate inhibitor without and with phosphoric acid and, then, pre-oxidation with sodium hydroxide. In the last step, we studied the influence of conversion coating with the combination of sodium molybdate and fluoride on the anodic layer formed on aluminum alloy 2030. In order to characterize the formed layers, we use microstructural characterization (SEM, AFM, and nano-indentation), which allows highlighting the surface condition as well as the morphological distribution, and electrochemical techniques such as potentiodynamic polarization and electrochemical impedance spectroscopy which shows that the anodization treatment of the aluminum alloy with phosphoric acid and sodium molybdate offered better corrosion resistance. This resistance increased with the use of pre-oxidation and then reached a maximum value of 99.8% efficiency with the addition of the molybdate conversion coating which causes an increase in the double layer and gave an alternative possibility of chromium VI.

Inhibitive effect of sodium molybdate on corrosion of AZ31 magnesium alloy in chloride solutions

In this work, corrosion inhibition of the AZ31 magnesium alloy was investigated in NaCl solutions containing different amounts of sodium molybdate inhibitor. Electrochemical, hydrogen evolution, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. The results showed that Na2MoO4 inhibitor provides reliable inhibition at high concentrations (150 mM). Surface examination by Raman and XPS spectroscopy confirmed the formation of a protective surface layer of mixed Mo(VI, V, IV) species. Based on these results, the mechanism of corrosion inhibition of the AZ31 alloy by aqueous molybdates was proposed.

Chromate and Molybdate Inhibitors Effects on Corrosion Charateristic of API 5L Grade B in a Brine Water Solution Containing 8 % NaCl

Piping systems at gathering stations in the oil and gas industries often fail due to corrosion attacks from the brine water solution containing 8% NaCl that flows through the system. This solution is highly corrosive on the API 5L grade B steel pipes, thereby shortening its lifespan, with an increase in the frequency of pipe replacements. However, the corrosion resistance of API 5L grade B pipes can be improved by using chromate and molybdate inhibitors. Therefore, the objective of this research is to improve the corrosion resistance of the steel pipes using sodium chromate (Na2CrO4) and sodium molybdate (Na2MoO4) inhibitors with concentrations of 0.2, 0.4, 0.6, 0.8 and 1,0%. This research also aim to determine the optimum concentration of inhibitors to produce minimum corrosion rate, by testing the brine water solution containing 8% NaCl through the potentiodynamic polarization method. The results show that generally, the addition of sodium chromate and sodium molybdate inhibitors to the brine solution causes the steel pipes to be more resistant to corrosion. Furthermore, the sodium chromate inhibitor concentration of 0.6% produces the greatest corrosion potential of – 400 mV with the lowest rate of 0.38 mpy, while sodium molybdate concentration of 0.4% produces the highest corrosion potential of – 385 mV with the lowest rate of 0.34 mpy. The results of SEM observations at 0.4% sodium molybdate concentration showed that the corrosion inhibition/passivation effect of the inhibitor made the steel surface smoother, while the sodium chromate inhibitor at similar percentage failed to reach the optimal concentration to inhibit the corrosion process.

Application of porous organosilica intercalated graphene oxide as the container of molybdate inhibitors for anticorrosive coatings

Porous organosilica intercalated graphene oxide (p-GA) was synthesized via the two-step polymerization method using 1-(2-aminoethyl)-3- aminopropyltrimethoxysilane as monomer. The average pore diameter of p-GA was calculated to be 4.42 nm with the Barret–Joyner–Halenda (BJH) algorithm. Amino and imino groups on the surface of organosilica pore were served as loading sites for molybdate inhibitors(Al2(MoO4)3). The controlled release of inhibitor ions from the molybdate loading p-GA (p-GAMo) occurred during the hydrophilic transformation process of the organosilica pores. The p-GAMo was embedded in polyvinyl butyral (PVB) coating and applied on mild steel. The results show that p-GAMo/PVB coating has active inhibition performance and exhibits high impermeability.

Inhibition of Q235 Carbon Steel by Calcium Lignosulfonate and Sodium Molybdate in Carbonated Concrete Pore Solution.

The inhibition effect and mechanism of a compound calcium lignosulfonate (CLS) and sodium molybdate inhibitors for Q235 carbon steel in simulated carbonated concrete pore solution (pH 11.5) with 0.02 mol/L NaCl are studied using electrochemical and surface analysis techniques. The results show that in carbonated simulated concrete pore (SCP) solution CLS and Na2MoO4 show a synergistic inhibition effect. The compound inhibitor can be defined as mix-type inhibitor. With 400 ppm CLS plus 600 ppm Na2MoO4, the pitting potential moves positively about 200 mV, and the inhibition efficiency reaches 92.67%. After 24 h immersion, the IE% further increases up to 99.2%. The surface analysis results show that Na2MoO4 could promote stability of the passive film, and the insoluble molybdenum compounds and CaO/Ca(OH)2, together with adsorbed CLS, deposit on the steel surface, forming a complex film. The compounded film effectively inhibits corrosion of the steel.

Inhibitive Effect of Molybdate Ions on the Electrochemical Behavior of Steel Rebar in Simulated Concrete Pore Solution

Several compounds tested as corrosion inhibitors have proven to possess good effectiveness in protection of steel rebar in concrete. However, most of them are considered as pollutant compounds, which limits their use. The aim of this work is to investigate the inhibitive effect of sodium molybdate, which is considered as a nonpollutant compound, against pitting corrosion of steel rebar in simulated concrete pore solution. Corrosion behaviors of steel in different solutions were studied by means of corrosion potential, potentiodynamic polarization, and electrochemical impedance spectroscopy. The results indicate that the addition of sodium molybdate to the chlorinated solution decreases significantly the corrosion rate of steel. Due to its passivating character, the sodium molybdate inhibitor promotes the formation of a stable passive layer on the surface of steel, acting as a physical barrier against chloride ions, on one hand, and consolidating the passivation mechanism of steel, on the other. The optimal inhibition rate is given by the concentration of molybdate ions, corresponding to a [MoO4 2−]/[Cl−] that is equal to 0.5.

Factors Affecting MoO4(2-) Inhibitor Release from Zn2Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings.

Zn2Al/-layered double hydroxide (LDH) with intercalated MoO4(2-) was investigated as a potential source of soluble molybdate inhibitor in anticorrosion coatings for hot dip galvanized steel (HDG). The effect of solution pH, soluble chlorides, and carbonates on the release kinetics of the interleaved MoO4(2-) ions from the LDH powder immersed in solutions containing different anions was studied by X-ray diffraction, in situ attenuated total reflectance infrared (ATR-IR) spectroscopy, and inductively coupled plasma atomic emission spectroscopy (ICP-AES). The effect of the solution composition on the total release and the release kinetics was demonstrated. Less than 30% of the total amount of the intercalated MoO4(2-) was released after 24 h of the immersion in neutral 0.005-0.5 M NaCl and 0.1 M NaNO3 solutions whereas the complete release of MoO4(2-) was observed after 1 h in 0.1 M NaHCO3 or Na2SO4 and in alkaline solutions. The in situ ATR-IR experiments and quantification of the released soluble species by ICP-AES demonstrated the release by an anion exchange in neutral solutions and by the dissolution of Zn2Al/-LDH in alkaline solutions. The anion exchange kinetics with monovalent anions was described by the reaction order n = 0.35 ± 0.05 suggesting the diffusion control; for divalent anions, n = 0.70 ± 0.06 suggested the control by a surface reaction. Dissolution of Zn from coated HDG with and without Zn2Al/-MoO4(2-) fillers, leaching of MoO4(2-) from the coating, and the electrochemical impedance spectroscopy response of the coated systems were measured during the immersion in 0.5 M NaCl solutions with and without 0.1 M NaHCO3. Without carbonates, the release of soluble MoO4(2-) was delayed for 24 h with no inhibiting effect whereas with 0.1 M NaHCO3 the immediate release was accompanied by the immediate and strong inhibiting effect on Zn dissolution. The concept of controlling the inhibition performance of LDH hybrid coatings by means of the environment composition is discussed.

Research on Corrosion Behavior of A3 Steel in Compound Sodium Molybadate Inhibitor Solution

The corrosion behavior of A3 in sodium molybdate inhibitor solution was tested by the static coupon method and the electrochemical workstation method. The results at diffident temperatures and in different concentration inhibitor show that the temperature had a important influence on A3 corrosion when the addition concentration below 500mg/L. The corrosion rate of A3 change less when temperature change from 20.5°C to 61.5°C.

Corrosion of steel in lithium bromide solution containing inhibitor

The corrosion behaviour of carbon steel in 55% lithium bromide solution containing a complex organophosphonate–molybdate inhibitor has been studied using weight loss tests, electrochemical measurements, SEM and X-ray photoelectron spectroscopy. The results showed that the species provides an excellent inhibition performance in 55% lithium bromide solution. When its concentration reached 0·8 kg m−3 in 55% lithium bromide+0·07 mol dm−3 lithium hydroxide at 240°C, the carbon steel’s corrosion rate decreased to 25·02 μm/year, and the anodic passivation region and the passive current density of carbon steel were ∼700 mV and 1 μA cm−2 respectively. At the same time, the capacitance value of electric double layer decreased, and the charge transfer resistance increased. The compact compound film formed on the surface of carbon steel in the inhibited LiBr solution was mainly composed of iron oxide and molybdenum oxide.

Effect of Corrosion Inhibition on the Stress Corrosion Cracking of UNS S31603 Austenitic Stainless Steel

Brine recirculation pumps are essential components used for circulation of brine in multi-stage flashing chambers desalination plants. Failure of these pumps would result in shutdown of the desalination plants. The rotating parts of these pumps (shaft and impeller) are usually made out of stainless steels or Duplex stainless steels. The pressure parts (casings) are usually made out of Ni-resist ductile irons (NDI). In recent years there have been a number of cases in which NDI casing materials failed by stress corrosion cracking (SCC) especially in the Arabian Gulf region. This makes re-evaluation and further studies on the performance of these materials of paramount importance due to process-related economic and reliability considerations. As possible substitutes to NDI casing materials, the authors of this research have recently published material demonstrating the superiority of the SCC resistance of the super DSS, UNS S32750, over the ASS, UNS S31603, in hot brine environment. Economically, the idea of using chemical corrosion inhibitors to enhance the SCC resistance of the ASS, UNS S31603, is appealing, non famous and worth looking at. In this work the effect of corrosion inhibition on the corrosion resistance and SCC of the ASS, UNS S31603, in hot brine environment, is investigated. Brine water was injected with typical treat rate of 350 ppm of passivating type commercially available Molybdate corrosion inhibitor. Theoretically the corrosion inhibitor was proposed to improve the corrosion resistance of ASS, UNS S31603, in brine solution. Electrochemical polarization measurements and SCC tests were used to evaluate the performance of the metal under inhibited and uninhibited environments. Results have shown that treating the brine with this particular type of inhibitor under this particular treat rate and test conditions increased the pitting tendency of the ASS, UNS S31603. Results from both SCC tests and electrochemical measurements are in agreement and both role out the possibility of enhancing corrosion resistance and SCC of ASS UNS S31603 using Molybdate inhibitor.

Acid phosphatase activity in Coxiella burnetii: a possible virulence factor.

High-speed supernatant fluids derived from sonicated Coxiella burnetii contained considerable acid phosphatase activity when assayed by using 4-methylumbelliferylphosphate; they also contained a factor that blocked superoxide anion production by human neutrophils stimulated with formyl-Met-Leu-Phe. The pH optimum of the enzyme was approximately 5.0. The level of phosphatase activity detected in several isolates of C. burnetii implicated in acute (Nine Mile) and chronic (S Q217, PRS Q177, K Q154) Q fever was 25 to 60 times greater than that reported in other microorganisms, including Leishmania and Legionella spp. The enzyme was found in rickettsiae grown in different hosts (L929 cells and embryonated eggs) and, in the case of L929 cells, for both short periods (less than a month) and the long term (years). Cytochemical techniques coupled with electron microscopy localized the phosphatase activity to the periplasmic gap in the parasite. Ion-exchange chromatography revealed a major species of the enzyme and showed that the enzyme of the parasite was distinct from that of the host cell (L929 fibroblasts); its apparent molecular weight was 74,000. Phosphatase inhibitors (i.e., molybdate heteropolyanions) had differential effects on the phosphatases of the parasite and host cell. C. burnetii supernatant fluid inhibited superoxide anion production by formyl-Met-Leu-Phe-stimulated human neutrophils; molybdate inhibitors reversed the inhibition. Treatment of C. burnetii-infected L929 cells with one of the molybdate compounds (complex B') significantly reduced the level of infection and did not affect the viability or growth of the host cell. These data suggest that the acid phosphatase of the parasite may be a major virulence determinant, allowing the agent to avoid being killed during uptake by phagocytes and subsequently in the phagolysosome.

An xps investigation of dichromate and molybdate inhibitors on aluminum

Etude par spectrometrie photoelectronique RX de la composition chimique de ces deux inhibiteurs sur differentes surfaces d'aluminium. Les resultats sont bases sur l'immersion d'echantillons d'aluminium dans des solutions de chlore auxquelles on a ajoute chacun des inhibiteurs