Weakly bound non-valence anions are molecular systems where the excess electron stabilizes in a very diffuse orbital whose size, shape, and binding energy (∼1-100 meV) are governed by the long-range electrostatic potential of the molecule. Its binding energy comes mainly from charge-dipole or charge-multipole interactions or dispersion forces. While highly correlated methods, like coupled cluster methods, are considered to be the state of the art for describing anionic systems, especially when the electron lies in a very diffuse orbital, we consider here the possibility to use DFT-based calculations. In such molecular anions, the outer electron experiences long-range exchange and correlation interactions. We show that DFT can describe long-range bound states provided that a correct asymptotic exchange and correlation potential is used, namely, that from a range-separated hybrid functional. This opens an alternative to the computationally demanding highly correlated method calculations. It is also suggested that the study of weakly bound anions could help in the construction of new DFT potentials to study systems where nonlocal effects are significant.