Shaping methods based on sand-resin mixtures have undoubted benefits and accordingly are increas� ingly used in the manufacture of highperformance iron, steel, and nonferrousalloy castings. However, they cannot be unconditionally recommended for lowcarbon steel castings. This is because heat from the molten metal destroys the organic components present in such molds. At low temperatures (150 °C), these mixtures mainly emit water vapor and complex hydrocarbons. At high tem� peratures (700°C), however, the gas emitted consists predominantly of carbon monoxide (84-85%), hydro� gen H2 (3-6%), carbon dioxide CO2 (around 5%), and methane CH4 (around 2%) (1). In the mold cavity, this gas mixture is partially oxidized by oxygen and is diluted by atmospheric nitrogen but retains a high reducing (carburizing) potential. Consequently, on casting low� carbon steel in a mold made of sand-tar mixture, sur� face carburization of the castings occurs as they solidify (2). In casting carbon steel and some alloy steels, this is somewhat compensated by subsequent surface decar� burization in cooling of the castings in the mold and subsequent heat treatment. However, in castings of highchromium alloy steel, the carburized surface layer is retained, since there is practically no decarburization in view of the formation of a protective chromium� oxide film on the casting surface. With increase in carbon content, the corrosion resistance of the highchromium steel falls sharply (3). Therefore, the retention of carburizing layer at the sur� face of such castings significantly impairs their perfor� mance. In the present work, we study the influence of the gas formed at the metal-mold interface on the surface carburization of 10X18H9 Л steel castings, in the case of molds made from mixtures with different binders. We assume here that the destruction products of the organic components in the mixture are transformed to CH4, CO, H2, and CO2 at high temperatures. Corre� spondingly, the basic carburization potential of the gas medium is mainly due to the presence of hydrocarbons (primarily CH4) and carbon monoxide in the gas phase. Accordingly, surface carburization of the cast� ing may be regarded as mainly the result of the reaction of steel with these components of the gas mixture (1) 2CO = (C) + CO 2 ;( 1 )