The deterioration mechanism of alkali-activated slag-fly ash-steel slag concrete (AAC) under sodium chloride attack and freeze-thaw (SF-T) cycles was investigated through a multi-scale methodology. Results showed that appropriate water glass modulus and higher Na2O dosage increased the compressive strength and salt-frost resistance of AAC. The mass loss in AAC was concentrated in the first 100 SF-T cycles, but PCC increases linearly with the SF-T cycles. The salt-frost resistance of PCC was similar to that of AAC samples Na2O dosage of 5 %. Higher Na2O dosage reduces the amount of unreacted precursor, thus reducing the porosity and improving the pore structure of concrete. However, increasing Na2O dosage has not limited the crack development, and the crack width in AAC was greater than in PCC after SF-T cycles. The porosity and average pore size of the concrete increased after SF-T cycles. Friedel's salt was only present in PCC, and NaCl crystals were observed in AAC.
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