Modulus Of Composites Research Articles

Preparation of boron nitride grafted carbon nanotubes for enhancing the tribological performance of poly (ether ether ketone) composite

The impendency demands for the excellent wear resistance materials are blossoming as the increasing possibilities of complex application environments. Poly (ether ether ketone) (PEEK) is regarded as a promising candidate for its outstanding mechanical properties and remarkable thermal stability. Herein, a feasible strategy is proposed to obtain hydroxylated boron nitride (BNO) grafted carbon nanotubes (CNTs). Then, introduce the as- prepared reinforcements into the matrix to fabricate the BNO-CNT/PEEK composites. The incorporation of BNO-CNT significantly increases the nano- hardness and elastic modulus of composites. The interfacial interactions between components promote the synergistic enhancement effects, ultimately increasing the thermal conductivity and tribological performance of composites. The coefficient of friction and wear rate remarkably decline with the introduction of 3 wt% BNO-CNT. Thus, this facile approach demonstrates its potential for improving tribological properties in PEEK composites.

Mechanical property enhancement of flax fibers via supercritical fluid treatment

The desire for lightweight, carbon-negative materials has been increasing in recent years, particularly as the transportation sector reduces its global carbon footprint. Natural fibers, such as flax fiber and their composites, offer a compelling combination of properties including low density, high specific strength, and carbon negativity. However, because of the low modulus and high variability in performance, natural fibers can’t compete with glass fibers as structural reinforcements in polymer composites. In this study, flax technical fibers were treated in supercritical CO2 (scCO2), and the effects of this treatment on the morphology and properties of flax fibers are reported. Treatment in scCO2 successfully resulted in higher fiber modulus and strength by 33% and 40%, respectively. Fiber porosity was reduced by 50% and morphological changes to the fibers were observed. Specifically, fiber lumen collapsed during treatment and micro/mesoporosity was reduced by 27%. Treated flax fibers were used to create 30 vol% unidirectional flax-epoxy composites. ScCO2 treatment raised composite modulus and strength by 33% and 25%, respectively. Because of the dependence between technical fiber size and mechanical properties, the relationship between fiber modulus and fiber size were created and applied to the rule-of-mixtures. This relationship were found to be viable representations of the fiber performance within each composite. Overall, the treatment developed in this study has the potential to significantly improve natural fiber properties, enabling their consideration for use in lightweight, semi-structural composites.

Thermally-assisted magnetization of magnetic composites for enhanced micro actuator performance: a low-cost approach using permanent magnets

A micro actuator based on magnetic composite materials can control its deformation and movement through varying magnetic fields, showcasing significant applications in fields such as soft robotics and biomedicine. However, existing magnetic composite materials still require complex magnetization processes involving sophisticated equipment and demanding external magnetic fields. This paper proposed a low-cost, thermally-assisted magnetization process based on permanent magnets. It was observed that the maximum magnetic induction intensity on the surface of magnetic composites is linearly correlated with the heating temperature. Additionally, magnetically treated materials at elevated temperatures can achieve traditional high-field magnetization effects at lower field strengths. Specifically, we synthesized a magnetic composite with 50%wt NdFeB@PDMS and investigated the conditions of the thermally-assisted magnetization process based on permanent magnets, along with mechanical and magnetic performance characterization methods. Experimental results indicate that below 200 °C, the tensile strength and elastic modulus of the base material increase with rising temperatures, demonstrating a trend of high-temperature hardening. However, when the temperature exceeds 200 °C, the elevated temperature leads to the decomposition of the base material, resulting in a rapid decrease in the tensile strength and elastic modulus of the magnetic composite. Furthermore, high temperatures can disrupt the magnetic domains of the magnetic material, reducing its coercive force and making it more susceptible to external magnetic fields and heat, thereby compromising the stability of the magnetic material. These findings provide new insights into the development of more stable and controllable magnetic composite materials.

Machine learning–enabled direct ink writing of conductive polymer composites for enhanced performance in thermal management and current protection

This study introduces a novel approach that leverages the synergy of machine learning (ML) and Direct Ink Writing (DIW) to optimize the manufacturing feasibility of conductive polymer composites (CPCs) films. The main research focus centers on precisely fine-tuning the printing parameters to strike the perfect balance between the high loading of dendritic copper fillers and their influences on processing and composite performance properties. This pioneering combination significantly enhances the precision of the final product without resorting to time-consuming procedures. ML algorithms contributed to identifying optimal printing variables such as speed, flow pressure, and filler concentration, which helped in identifying the optimal filler content and its performance capabilities. The resulting films exhibited thermo-resistive behavior with a noticeable resistivity increase by 6-7 orders of magnitude at elevated temperatures, specifically around 100 °C. Furthermore, the study highlights remarkable strain-sensing capabilities, simultaneously showcasing a substantial increase in composite modulus. These discoveries bear substantial significance for the development of exceptionally functional thermal interface materials suitable for use in sensors, current collectors, and energy storage devices. The method presented here offers a promising pathway for advancing the fabrication and performance optimization of conductive polymer composites, opening up diverse applications in emerging technologies.

An intensive exploration of plasticization, tensile, flexural and ecotoxicity of styrene-grafted thermoplastic starch (TPS) composite material

Thermoplastic starch (TPS) is a potential alternative to non-biodegradable plastics. Nevertheless, nice hydrophilicity, poor mechanical property and processability restrain use. Herein, pure corn starch was modified by styrene grafting, then, plasticized by glycerol to prepare TPS composite material. Later, plasticizing behavior, thermal-stability, mechanical property, ecotoxicity, etc. were explored. Main results reveal that styrene was successfully grafted to starch achieving a grafting yield (GY) as 45.58 wt% and grafting converted starch crystalline shape transformation from A to V. Glycerol plasticization furtherly altered crystalline structure and surface wettability. To native species, plasticization induced amorphization; to grafted species, it induced crystalline perfection. Compared to native species grafted starch displayed easier plasticization characteristic and better processability, elevated hydrophobicity and mechanical property. Herein, a glycerol content as 20 wt% is proper. From native to grafted TPS composite material tensile, flexural strengths and modulus were elevated from 8.9, 20.9 and 777–24.2, 56.5 and 1924 MPa. A more important issue is that styrene grafted TPS composite material composting products displayed no-visible ecotoxicity. Where, wheat and mung seeds germination rates and plant fresh and dry masses in systems containing 10 wt% previous TPS composting products are all higher than 90 % those of blank compositing systems, which is in line with EN 13432–2000 standard, non-toxic to environment. It seems via some level styrene grafting possessing nice mechanical property and non-visible ecotoxicity starch material can be prepared, possibly having a potential use in plastic industry in real, which is of great significance and attractive.

Prediction method for elastic modulus of resin-mineral composites considering the effects of pores and interfacial transition zones

Prediction method for elastic modulus of resin-mineral composites considering the effects of pores and interfacial transition zones

Thermorheological complexity in Nylon12‐Cork composites: Role of interfacial compatibilizer

AbstractHerein, we demonstrate how compatibilizers affect the thermorheological properties and morphology of engineering thermoplastic composites based on nylon and cork. Nylon12 was melt‐mixed with cork treated with four distinct compatibilizers with radically different chemical structures and compositions, respectively: (i) Octadecanamide (ODA), (ii) polyethylene‐graft‐maleic anhydride (PE‐g‐MA), (iii) polypropylene‐graft‐maleic anhydride (PP‐g‐MA), and (iv) (3‐aminopropyl)triethoxysilane (APTS). The rheological behavior was assessed using an oscillatory rheometer and the morphology was visualized using a scanning electron microscope. The rheological data were thoroughly analyzed using different formalisms based on empirical, phenomenological, and molecular origin, including the Carreau‐model, time–temperature superposition (TTS), Han plot, and van Gurp–Palmen (vGP) plot. It is observed that rheological data of neat nylon can be treated as themorheologically simple. However, the inclusion of cork makes the composite thermorheologically complex and increases the relaxation time (τ) by >50‐fold when compared to the neat polymer. As compatibilizers, ODA and PP‐g‐MA significantly lower τ, improve internal flow behavior, and demonstrate good cork distribution and dispersion. However, PE‐g‐MA does not affect the τ of composites significantly. The application of APTS as a compatibilizer enhances the interfacial interaction between Nylon12 and cork most significantly, which leads to a notable rise in τ, and the composite's elastic modulus surges by two orders in magnitude compared to neat Nylon. Additionally, the polymer melt flow becomes elastically dominant. Finally, it is observed that the Han plot offers a better insight into the correlation between changes in the thermorheological behavior and the microstructural modifications to the composites.Highlights Utilizing cork particles as a sustainable raw material for engineering thermoplastics. Quantifying compatibilizer's impact on rheological properties of polymer composite. Illustrating how interfacial interaction affects thermorheological complexity in composites. Visualizing morphological change in nylon‐cork composite with interfacial interaction. Producing lightweight engineering polymer composites using cork as a filler.

Eco-Friendly Synthesis of Al2O3 Nanoparticles: Comprehensive Characterization Properties, Mechanics, and Photocatalytic Dye Adsorption Study

Metal and metal oxide nanoparticles are gaining traction in inorganic catalysis and photocatalysis, driving the development of eco-friendly methods. This study introduces an eco-friendly and cost-effective approach for synthesizing Al2O3 nanoparticles (NPs) using extracts derived from the leaves of Calligonum comosum L. The primary objective of this investigation is to assess the photocatalytic efficacy of the synthesized catalyst in addressing organic pollutants. The Al2O3 NPs exhibit a spherical morphology with crystalline arrangements, as evidenced by an average crystallite size of 25.1 nm in the XRD analysis. The band gap energy of the Al2O3 NPs is determined to be 2.86 eV. In terms of mechanical properties, the Al2O3 NPs show significant potential in enhancing both flexural and compressive properties, thereby making them a viable choice for improving the mechanical performance of composites. Notably, the Young’s modulus of the hybrid composite (comprising plant material and Al2O3 NPs) exhibits a remarkable increase of 34.4% in flexion and 78.3% in compression compared to the plant material alone. The catalytic performance of the Al2O3 NPs is evaluated using methylene blue (MB) as a cationic dye and Rose Bengal (RB) as an anionic dye. Impressively, the Al2O3 NPs demonstrate degradation efficiencies of 98.2% for MB and 90.5% for RB. The degradation processes occur under solar light irradiation, with a contact time of 120 m, a maintained pH of 7, and a temperature of 25 °C. This study found that Al2O3 nanoparticles are a promising, cost-effective, and environmentally friendly option for water treatment.

Coupled effect of MWCNTs concentration and induced pore structures on compressive performance and elastic modulus of ultra-high toughness cementitious composites: Experimental and theoretical studies

Due to the superior mechanical properties and electrical conductivity of multi-walled carbon nanotubes (MWCNTs), their integration into cementitious composites can improve compressive strength and self-sensing capabilities. However, balancing high mechanical strength with high conductivity is challenging as high MWCNT dosages can impede strength development. We addressed this by studying the effect of MWCNTs concentration (0–1.1 wt% of cementitious binders) and induced pore structures on the compressive performance and elastic modulus of ultra-high toughness cementitious composites (UHTCC), both experimentally and theoretically. It was found that as the MWCNTs concentration increased, the porosity continued to increase, while the compressive strength fluctuated. Two failure patterns were identified, i.e., quasi-brittle failure and ductile failure. Analysis showed MWCNTs could promote cement binder hydration, increasing matrix density but the strength development was curbed by increased porosity. A balance was achieved at 0.7 wt% MWCNTs. Further investigations using the Eshelby-Mori-Tanaka method discussed how MWCNT concentration, mechanical properties, distribution, porosity, and pore geometry influenced the elastic modulus. Ultimately, we developed a UHTCC-MWCNT composite with 1.1 wt% MWCNTs, which exhibited substantial improvements in compressive strength (44.85 MPa) and conductivity (9.78✕10−3 S/m), showing increases of 22.18 % and 18,132.6 % respectively, compared to the reference group.

Micromechanics modeling of cement concrete considering the interaction among randomly oriented ellipsoidal inhomogeneities

To account for the random orientation of ellipsoidal inhomogeneities, the averaging process over two Euler angles has been widely used in existing micromechanics models. However, the interaction among various inhomogeneity orientations is often overlooked and may also affect the prediction of composite elastic modulus. In this work, to consider the interaction among randomly oriented aggregates and fibers in cement concrete, a micromechanics model, the orientation interaction model (OIM), is proposed. An orientation average model (OAM) is also proposed, and by comparing OIM and OAM predictions, the effect of inhomogeneity orientation interaction on the predicted elastic modulus is shown. In both models, geometries of coarse aggregates and fibers are approximated using ellipsoids with three different semiaxes and cylinders, respectively, and their orientations are described using three Euler angles. Compared with existing random orientation models using two Euler angles, the proposed models can capture the isotropy of composites with randomly oriented asymmetric ellipsoidal inhomogeneities. By comparing the predictions of OIM, OAM, composite sphere models and the Mori-Tanaka method with spherical inhomogeneities, it is found that with the increase of the stiffness contrast between the matrix and inhomogeneities, the effects of the inhomogeneity geometry and orientation interaction become more apparent. The model predictions agree well with the experimental data. By changing the value range of three Euler angles based on the inhomogeneity orientation distribution, both models are also suitable for transversely isotropic and anisotropic composites containing several types of inhomogeneities.

Physical and thermomechanical characterization of unidirectional Helicteres isora fiber-reinforced polylactic acid bio-composites

Identifying novel cellulose fiber bio-composites has become a vital initiative in the exploration of sustainable materials due to increased global concern for the environment. This growing focus on eco-friendly materials has gathered significant attention in recent years. The current investigation deals with one such material, Helicteres isora reinforced Polylactic acid composites. Surface chemical treatment of fiber is one of the most effective methods to modify the hydrophilic fiber to increase its compatibility with the polymer matrix. Sodium hydroxide was used as a pre-treatment chemical to remove any impurities from the fiber surface. Pre-treated fibers were treated with Methacryl silane and Potassium permanganate solution to chemically modify the fiber surface. Density, void content and water absorption behavior of the composites were analyzed as per the standard procedure. Tensile and flexural tests were conducted to evaluate the mechanical strength, modulus, and flexibility of the unidirectional composites. Thermogravimetric and differential thermal analyses were performed to investigate the thermal stability, melting behavior and degradation profiles of prepared composites. A study of failure mechanisms and morphology of the fractured surface through photographs and SEM images revealed fiber splitting and delamination as the dominant reasons behind the failure of composites under tensile loading. Silane-treated Helicteres isora fiber-reinforced Polylactic acid composite exhibited lower water absorption and higher tensile strength than its counterparts. Untreated fiber composite showed maximum flexural strength among the tested composites. By collectively evaluating the results of the tests and properties of the composites, silane-treated fiber-reinforced Polylactic acid composites stands out as the most favorable choice.

Material Selection of Natural Fibre Composite Webbing Sling Using Rule of Mixture

Natural fibre composites have grown in popularity as environmental concerns and knowledge about using eco-friendly materials versus synthetic materials. Furthermore, due to their low density and high strength, natural fibres are suitable for use as lightweight composite and reinforcing materials. Webbing slings are commonly used in many industries to lift loads and are typically made of synthetic fibres such as nylon and polyester. This study analysed the physical and mechanical properties, such as density, tensile strength, and Young’s modulus of natural fibre composites. Bananas, pineapple, and jute with polymer matrices such as polypropylene (PP) and epoxy (EP) were used as alternative natural fibre composites for webbing sling application. Furthermore, descriptive statistical analysis was done to summarise the secondary data from the previous study of the physical and mechanical properties of natural fibre and polymer matrix. The rule of mixture (ROM) is used to identify the optimum fibre loading for manufacturing the webbing sling. This study’s volume fractions of fibre were 10%, 30%, and 50%. Using the ROM equation, the results revealed that the higher fibre loading of up to 50% could increase the mechanical properties such as tensile strength and Young’s modulus. Based on the results, pineapple/epoxy composite was the best material to manufacture the webbing sling and complied with the requirements of Product Design Specifications of polyester webbing sling compared to banana and jute composites.

Prediction of Longitudinal Resonance Elastic Modulus of Wood-plastic Composites Based on GM (1, N) Neural Network

Abstract Based on the grey neural network combined prediction model, the prediction model of the mechanical properties of WPC composites was established by taking the orthogonal design test results of the main processing factors of WPC composites as data samples. Taking the main processing factors of WPC as input, grey GM (1, N) prediction of these variables was carried out, and then BP neural network prediction was carried out to predict the mechanical process index of WPC. The results show that the established prediction model can predict the mechanical properties and technological indexes of WPC composites well.

Description of non-ideal effects in composite membranes by a new theoretical approach

In present study, a theoretical model is introduced to calculate the gas permeability of mixed matrix membranes (MMMs) containing porous fillers. This model is based on analogy of gas permeation in MMMs with tensile modulus in composites. The representative parameters of MMM morphologies such as polymer chains tightening around the filler (β<1), unselective channel formation (β>1) and polymer chains penetrating into filler pores (0≤α≤1) which leads to the filler pore blocking are all included in the model. Furthermore, the interphase thickness (t) which is a critical parameter of MMMs participates in calculation equation along with the other parameters. To validate the proposed model, an experimental study with poly(vinylidene fluoride) (PVDF)/poly(methyl methacrylate) (PMMA) blend as polymer matrix and zeolite 4A and NH2-MOF-199 as fillers is performed. The obtained gas permeability data of constructed MMMs and some of the literature data are employed to be fitted with the proposed model. The details of the existence morphologies of MMMs can be described by earning the mentioned parameters ranges. Therefore, by this model, by having a measure of t, the gas permeation of MMM can be achieved accompany with details of the related morphologies. All the theoretical investigations are done utilizing one equation which contains all parameters simultaneously.

Non-covalent interaction induces controlled reinforcement of thermoplastic elastomer composites homologously incorporated with hydrophobized cellulose nanocrystals

Surface hydrophobization of cellulose nanocrystal (CNC) is developed through Pickering emulsion method and esterification-grafting, consequentially enhancing its thermal properties and hydrophobicity, and tensile modulus in thermoplastic elastomer composites. n-Tetradecenylsuccinic anhydride (TDSA) provides a high level of compatibility owing to the structural homology by non-covalent interactions between CNC-graft-TDSA and poly(styrene)-block-poly(isoprene)-block-poly(styrene) (SIS). Theoretical calculations supports the molecular-level insight on how the nanofiller and SIS interacts. Density functional theory calculations and the energy decomposition analysis reveal the stabilization free energy of −2.59 kcal mol−1 gained through hydrophobic and OH–π interactions, which is assigned as the key component for the superior mechanical properties. At the filler contents of 0.6–2.5 vol %, the moduli of the TPE nanocomposites gradually strengthen while retaining thermoplasticity, without sacrificing the ultimate tensile characteristics of SIS, although it is below the calculated φc of 5.9 vol % (critical percolation threshold) for filler-filler interactions. Origin of the controlled boost in filler-matrix binding is rationalized by pronounced hydrophobic interactions in isoprene-rich rubbery phase (86 wt % in SIS). Interestingly, at 5.1 vol % near to filler-filler interactions, even though reinforcements in storage/initial modulus, and toughness increase by up to 14/4.0-, and 1.2-fold, the tensile stress at break only decreases by 27 %.

Optimising Recycling Processes for Polyimine-Based Vitrimer Carbon Fibre-Reinforced Composites: A Comparative Study on Reinforcement Recovery and Material Properties.

We investigated the recycling process of carbon fibre-reinforced polyimine vitrimer composites and compared composites made from virgin and recycled fibres. The vitrimer matrix consisted of a two-component polyimine-type vitrimer system, and as reinforcing materials, we used nonwoven felt and unidirectional carbon fibre. Various diethylenetriamine (DETA) and xylene solvent ratios were examined to find the optimal dissolution conditions. The 20:80 DETA-xylene ratio provided efficient dissolution, and the elevated temperature (80 °C) significantly accelerated the process. Scaling up to larger composite structures was demonstrated. Scanning electron microscopy (SEM) confirmed effective matrix removal, with minimal residue on carbon fibre surfaces and good adhesion in recycled composites. The recycled nonwoven composite exhibited a decreased glass transition temperature due to the residual solvents in the matrix, while the UD composite showed a slight increase. Dynamic mechanical analysis on the recycled composite showed an increased storage modulus for nonwoven composites at room temperature and greater resistance to deformation at elevated temperatures for the UD composites. Interlaminar shear tests indicated slightly reduced adhesion strength in the reprocessed composites. Overall, this study demonstrates the feasibility of recycling vitrimer composites, emphasising the need for further optimisation to ensure environmental and economic sustainability while mitigating residual solvent and matrix effects.

A Constitutive Law Modeling the Mixed Hardening Behavior of Particle-Reinforced Composites

Abstract A homogenized elasto-plastic constitutive law (including both constitutive equations and inversed constitutive equations) is proposed in an incremental form for the particle-reinforced composites based on the flow theory of plasticity and the asymptotic homogenization method. The constitutive law can be used to predict the mixed hardening behavior of particle-reinforced composites under arbitrary loading conditions if the uniaxial tension test curve of matrix materials is known. It is found that the constitutive law of particle-reinforced composites is similar in form to the law of matrix materials. There is a simple proportional relationship between the yield stress, the plastic modulus, and the deviatoric back stress of particle-reinforced composites and the corresponding parameters of matrix materials, which is equal to the ratio of the shear modulus of composites to the shear modulus of matrix materials. The tangent modulus of particle-reinforced composites can be calculated using a simple arithmetic formula according to the tangent modulus of matrix materials. A numerical algorithm is suggested.

Study of Mechanical and Surface Properties of Multi-Walled Carbon Nanotube Grafted Flax Fiber and Its Composites

ABSTRACT The modification method of grafting multi-walled carbon nanotubes (MWCNT, abbreviated as CNT in this paper) on the surface of flax fibers was investigated, i.e. CNT were grafted onto the surface of flax fibers by silane coupling agent under the action of ultrasonic waves to form covalent bonding. The tensile strength of CNT grafted flax fiber is 22% higher than that of untreated flax fiber monofilament. The tensile strength of FFRP composites after CNT grafting treatment increased by 14.2%; however, the tensile modulus of single fiber and composites did not show a significant increase, the interfacial shear strength of the fiber-resin is 38.3% higher than that of untreated filament. The improvement of the contact angle after grafting was investigated by observing the surface morphology, and the surface of flax filament was characterized by scanning electron microscopy and atomic force microscopy. Also the elemental changes of the flax single fiber surface before and after the treatment were analyzed using X-ray photoelectron spectroscopy. The results showed that the tensile strength of flax single fibers, its composites, and interfacial shear strength of fiber-matrix was improved after CNT grafting treatment but the increase of modulus was not obvious.

Model prediction of unidirectional fiber-reinforced composites under finite deformation

The intuitive knowledge is that the mechanical modulus of unidirectional fiber-reinforced composites (UD-FRPs) decreases with higher fiber orientation angles. However, numerical results in this work and experimental results in previous literature indicate that the mechanical response of UD-FRPs has a U-shaped dependence on fiber orientation angle. To explain this phenomenon, we develop an anisotropic model to capture the mechanical behavior of UD-FRPs. The strain energy is decomposed into four components: matrix, fiber, fiber-matrix normal, and shear interactions. Each component can be determined by matching the mechanical responses of unit cells with 0°, 45°, and 90° off-axis. The results obtained from the presented model match well with the numerical response of unit cells with 15°, 30°, 60°, and 75° off-axis. With an increasing fiber orientation angle, the matrix part remains unchanged, the fiber component decreases, but the fiber-matrix normal component increases, and the fiber-matrix shear component increases and then decreases. The change in strain energy contributions explains the mechanism of the U-shaped dependence of the mechanical response on fiber orientation angle.

Physical, rheological and micro characteristics of ARA/Nano-TiO2 composite modified asphalt before and after short-term aging

This paper aims to investigate the composite application of nanomaterials and natural asphalt in order to enhance the road performance of asphalt pavement. The objective is to develop high-performance modified asphalt that improves the durability, reliability, and load resistance of asphalt roads while reducing resource waste and environmental pollution. The composite modified asphalt was prepared by adding different blends of Albanian natural rock asphalt (ARA) and 1% of nano titanium dioxide (Nano-TiO2), and the basic properties and rheological properties of the asphalt before and after aging were tested by using basic performance tests and temperature scanning tests. Subsequently, the microscopic morphological characteristics of the asphalt were observed by scanning electron microscope and atomic force microscope, and the number of bee structures, the area share of bee structures, root mean square roughness Rq, and arithmetic mean roughness Ra were used as microscopic quantitative indexes. The results indicate that the complex modulus and rutting coefficient of ARA/Nano-TiO2 composite-modified asphalt increase with an increase in ARA dosage when the dosage of Nano-TiO2 is 1%. The asphalt modified with Nano-TiO2 composite blended with 15% ARA exhibits higher residual needle penetration, composite modulus ratio, rutting coefficient ratio and lower softening point increment compared to 70# asphalt. The bitumen modified with titanium dioxide nanocomposite blended with 15% ARA exhibits higher Rq and Ra and a more stable phase structure before and after aging. 15% of ARA/Nano-TiO2 composite-modified asphalt has higher Rq and Ra before and after aging, and its phase structure is more stable. The results show that ARA/Nano-TiO2 composite-modified asphalt has better high-temperature deformation resistance and aging resistance than 70# and that 15% ARA is recommended as the optimum amount of composite-modified asphalt.