The increasing application of fiber reinforcement to mitigate desiccation cracks induced by evaporation during backfill curing addresses the dispersion challenge associated with high fiber addition. This study aims to enhance the interfacial strength between fibers and cement-soil mixtures through chemical modification methods (NaOH, HCl, and Silane Coupling Agent). By conducting a single fiber pull-out test and microstructures observation, the outcomes reveal that modified PVA fibers exhibit a notable increase in shear strength and pull-out energy compared to unmodified ones, thereby necessitating a reduced fiber dosage for desiccation crack reduction. Furthermore, this investigation delves into the Digital Image Correlation (DIC) feasibility of employing the Digital Image Correlation (DIC) method to monitor the desiccation crack pattern of cement-soil slurry during the initial hydration stages. The findings indicate that NaOH and HCl treatment notably diminishes stress concentration under drying conditions, consequently reducing crack width and area.