Qualitative analysis of the positron acoustic (PA) waves in a four-component plasma system consisting of static positive ions, mobile cold positron, and Kaniadakis distributed hot positrons and electrons is investigated. Using the reductive perturbation technique, the Korteweg-de Vries (K-dV) equation and the modified KdV equation are derived for the PA waves. Variations of the total energy of the conservative systems corresponding to the KdV and mKdV equations are presented. Applying numerical computations, effect of parameter (κ), number density ratio (μ1) of electrons to ions and number density (μ2) of hot positrons to ions, and speed (U) of the traveling wave are discussed on the positron acoustic solitary wave solutions of the KdV and mKdV equations. Furthermore, it is found that the parameter κ has no effect on the solitary wave solution of the KdV equation, whereas it has significant effect on the solitary wave solution of the modified KdV equation. Considering an external periodic perturbation, the perturbed dynamical systems corresponding to the KdV and mKdV equations are analyzed by employing three dimensional phase portrait analysis, time series analysis, and Poincare section. Chaotic motions of the perturbed PA waves occur through the quasiperiodic route to chaos.