Fabry-Perot Cavity Modes Research Articles

Tensile Control of Vibrational Strong Light‐Matter Coupling with Flexible Polyester Films

AbstractPolaritons are generated by strong interaction between photons and matter, with the hybridization fundamentally changing the energy landscape of the system. Future exploitation of polaritons will benefit from implementing low‐cost, flexible, and easily tuneable configurations, as electronics have before. Here, coherent coupling of the carbonyl stretch vibrations of polyester (poly(ethylene terephthalate), PET) films to the optical modes of a Fabry–Perot (FP) cavity is presented, in which the FP cavity is directly formed on flexible, free‐standing, and commercially available PET films. For 2‐µm thick PET films, the carbonyl stretch vibration of the PET overlaps with the half‐wavelength FP cavity mode, leading to the coupling of the two modes, a Rabi splitting above 160 cm−1, and associated anticrossing in angular dispersion measurements. The study demonstrates dynamic control of light‐matter interaction strength by modulating film thickness under tension, finding that a 25% tensile stretch can tune the light‐matter interaction from 20:80 mixing to near‐perfect 50:50 hybridization at normal incidence. These findings are discussed in the context of future foldable/twistable/wearable polaritonic devices.

Ultrathin tunable UWB metasurface absorber design by exciting plasmonic modes in bilayer graphene stack

This work presents a graphene-based ultra-wideband (UWB) tunable metasurface absorber (MSA) consisting of top patterned graphene (Gpat) and bottom continuous graphene (Gcont) separated by a 2 μm thick silicon dioxide (SiO2) substrate. An absorptivity (Af) ≥ 90 % from 0.1 to 14 THz (fractional bandwidth = 197.2 %) has been achieved in three steps: (i) Fabry-Perot cavity mode has been generated near 0.1 THz using bilayer graphene stack, (ii) multiple plasmonic modes have been excited by engraving resonant slots on Gpat and (iii) plasmonic coupling strength has been enhanced between Gpat and Gcont by adjusting SiO2 substrate's thickness. The excited plasmonic modes show high absorption due to the generation of localized surface plasmon polariton (LSPP) waves. The fourfold symmetry in design nullifies the effect of the polarization angle (ϕ). Interestingly, the orthogonal modes' excitation helps to achieve similar Af response under both transverse electric and transverse magnetic polarizations for incidence angle (θ) up to 60°. Further, an effective DC biasing mechanism has been devised to tune the chemical potential (μc) of the interconnected Gcont, which ensures common DC bias between unit cells. A DC voltage from 0 to 10.2 V can vary μc (Bottom) from 0 to 1 eV to provide frequency tunability.

Increasing the Q-factor of Fabry-Perot etalons using focused Bessel beam illumination.

Sensing and filtering applications often require Fabry-Perot (FP) etalons with an Interferometer Transfer Function (ITF) having high visibility, narrow Full Width at Half Maximum (FWHM), and high sensitivity. For the ITF to have these characteristics, the illumination beam must be matched to the modes of the FP cavity. This is challenging when a small illumination element size is needed, as typical focused beams are not matched to the FP cavity modes. Bessel beams are a potential alternative as their structure resembles the FP cavity modes while possessing a focused core. To study the feasibility of using Bessel beam illumination, in this Letter, ITFs of an FP etalon were measured using Bessel and Gaussian illumination beams. A Bessel beam with core size of 28 µm provided an ITF with visibility 3.0 times higher, a FWHM 0.3 times narrower, and a sensitivity 2.2 times higher than a Gaussian beam with waist 32 µm. The results show that Bessel beam illumination can provide ITFs similar to that of collimated beam illumination while also having with a focused core.

Mid-infrared pyroelectric detector with metasurface electrode for broadband enhanced absorption

Pyroelectric photodetectors have continuously been an attractive candidate due to their noncryogenic and easy-to-fabricate specifics. Because the detectivity or resolution of the pyroelectric detector is closely related to the absorptivity to incident radiation, we propose a scheme for a metasurface-based pyroelectric detector (MPPD) by constructing its top electrode with an absorptive metasurface composed of nanogrid-patch units. The resonance modes of Fabry–Perot cavity, magnetic dipole and electric dipole are collectively leveraged for the mid-infrared MPPD with optimal broadband absorption plus three absorptive peaks at 3.13 μm, 3.94 μm and 4.8 μm. The mechanisms and field distributions of these resonance peaks are intensively explored and verified for configuration of the metasurface top electrode with optimized geometries. Finally, our scheme achieves an average absorptivity of 94.2% in the mid-infrared range of 3–5 μm, with its thermal response enhanced by 2.6 times that results in a significantly improved pyroelectric current for the detector.

Multidimensional structural coloration from hierarchically designed plasmonic structures

We propose a photonic strategy for multidimensional structural coloration that responds to varying illumination conditions. Both theoretical and experimental results verified that the combination of a metal/dielectric/metal cavity with a one-dimensional (1D) metal grating can increase the degree of freedom of structural coloration. We fabricated Ag/MgF2/Ag cavities coupled to 1D Ag gratings (pitches of 400, 570, and 800 nm) and obtained their photonic band dispersions (i.e., angle-resolved reflectance spectra) to unravel their mode characteristics. The 1D Ag grating and Ag/MgF2/Ag cavity induced surface plasmon polariton (SPP) and Fabry–Perot cavity modes, respectively. Notably, only a cavity mode emerged in the s-polarization and gradually blueshifted with increasing angle, whereas in the p-polarization, both SPP and cavity modes appeared and shifted oppositely with changes in the angle, leading to intricate color patterns at different wavelengths, angles, and polarizations. To further understand the effect of each mode upon structural coloration, we obtained the distribution of electric field intensity using rigorous coupled-wave analysis simulation, which identified multiple photonic bands in the p-polarization as various SPP-mediated hybrid modes.

Solvent Dependence on Cooperative Vibrational Strong Coupling and Cavity Catalysis.

Strong light-matter coupling offers a unique way to control chemical reactions at the molecular level. Here, we compare the solvent effect on an ester solvolysis process under cooperative vibrational strong coupling (VSC). Three reactants, para-nitrophenylacetate, 3-methyl-para-nitrophenylbenzoate, and bis-(2, 4-dinitrophenyl) oxalate are chosen to study the effect of VSC on the solvolysis reaction rates. Two solvents, ethyl acetate and cyclopentanone, are also considered to compare the cavity catalysis by coupling the C=O stretching band of the reactant and the solvent molecules to a Fabry-Perot cavity mode. Interestingly, both solvents enhance the chemical reaction rate of para-nitrophenylacetate and 3-methyl-para-nitrophenylbenzoate under cooperative VSC conditions. However, the resonance effect is observed at different temperatures for different solvents, which is further confirmed by thermodynamic studies. Bis-(2, 4-dinitrophenyl) oxalate doesn't respond to VSC in either of the solvent systems due to poor overlap of reactant and solvent C=O vibrational bands. Cavity detuning and other control experiments suggest that cooperative VSC of the solvent plays a crucial role in modifying the activation free-energy of the reaction. These findings, along with other observations, cement the concept of polaritonic chemistry.

Anti-reflection metallic anode-enhanced performance of organic solar cells via cross coupling between Fabry-Perot cavity modes and microcavity modes.

An effective anti-reflection metallic anode with the structure of glass/dielectric2 /Ag (D1D2M) is demonstrated both in small-molecule (SM) and conjugated polymer (CP) organic solar cells (OSCs). The anti-reflection mechanism is investigated by the finite-difference time-domain numerical calculation method and the experimental method. By tuning the refractive index and the thickness of the D2 layer, the reflection light is confined in the Fabry-Perot (F-P) cavity modes, which effectively enhances the transmittance of the D1D2M anode in the wavelength range of 420 nm-800 nm. Compared with the conventional glass/Ag (D1M) anode, the experimental transmittance of the D1D2M anode is enhanced by 33.24% at a wavelength of 550 nm. By replacing the D1M anode with the D1D2M anode in the OSCs, the F-P cavity modes cross couple with the microcavity modes in the active layers. As a result, the absorption intensity is obviously increasing in a wide angle range (0≤θ≤85∘) in the wavelength ranges of 475 nm-650 nm and 540 nm-720 nm for the SM and CP OSCs, respectively. The short circuit current density and power conversion efficiency of the SM OSC is increased by 25.07% and 27.23%, respectively.

Strong Coupling of Tamm Plasmons and Fabry-Perot Modes in a One-Dimensional Photonic Crystal Heterostructure

The coupling between multiple modes in subwavelength scale has attracted a lot of attention due to the interesting physics favored by the enhancement of light-matter interaction. In this contribution, we propose a planar hybrid plasmonic-photonic crystal structure, which enables the tunable coupling between Tamm plasmon-polariton and Fabry-Perot cavity modes. Then, a strong coupling can be achieved through evoking the Tamm-mode dependence of the top-layer thickness of the hybrid structure, which is indicated by an anticrossing with a spectrum splitting of 9.298 meV. The effect enables the spatial confinement of polaritons and the formation of hybrid one-dimensional plasmon-polariton modes. In order to account for the splitting of the orthogonally polarized resonances, a detailed investigation on the TE-TM splitting is also performed through the angular-dependence analysis. We note that the value of the TE-TM splitting strongly depends on the thicknesses of dielectric layer and the distance between two distributed Bragg reflector (DBR) stacks. We show that the cavity modes are extremely sensitive to the distance between the DBR stacks and propose using this feature for strain sensing. Thus, our structure may not only offer a platform for study of interesting physics (e.g., spin optronics), but may also provide a route for high-accuracy strain sensors.

Inherent Promotion of Ionic Conductivity via Collective Vibrational Strong Coupling of Water with the Vacuum Electromagnetic Field.

Hydrogen bonding interactions among water molecules play a critical role in chemical reactivity, dynamic proton mobility, static dielectric behavior, and the thermodynamic properties of water. In this study, we demonstrate the modification of ionic conductivity of water through hybridization with a vacuum electromagnetic field by strongly coupling the O─H stretching mode of H2O to a Fabry-Perot cavity mode. The hybridization generates collective vibro-polaritonic states, thereby enhancing the proton conductivity by an order of magnitude at resonance. In addition, the dielectric constants increase at resonance in the coupled state. The findings presented herein reveal how a vacuum electromagnetic environment can be engineered to control the ground-state properties of water.

Cavity catalysis: modifying linear free-energy relationship under cooperative vibrational strong coupling.

Here, we used an unconventional idea of cooperative vibrational strong coupling of solute and solvent molecules to enhance the rate of an esterification reaction. Different derivatives of p-nitrophenyl benzoate (solute) and isopropyl acetate (solvent) are cooperatively coupled to an infrared Fabry–Perot cavity mode. The apparent rates are increased by more than six times at the ON resonance condition, and the rate enhancement follows the lineshape of the vibrational envelope. Very interestingly, a strongly coupled system doesn't obey the Hammett relations. Thermodynamics suggests that the reaction mechanism remains intact for cavity and non-cavity conditions. Temperature-dependent experiments show an entropy-driven process for the coupled molecules. Vacuum field coupling decreases the free energy of activation by 2–5 kJ mol−1, supporting a catalysis process. The non-linear rate enhancement can be due to the reshuffling of the energy distribution between the substituents and the reaction center across the aromatic ring. These findings underline the non-equilibrium behavior of cavity catalysis.

Sub-bandgap light absorption enhancement in germanium films through Berreman mode weak coupling to a microcavity mode

light absorption is a substantial problem that profoundly influences a wide range of disciplines. Whereas it is fundamentally restricted by the bandgap energy of the involved materials. Herein, we study the sub-bandgap light absorption in germanium films via Berreman mode (BE) and its enhancement through weak coupling to Fabry-Perot cavity mode. This enhancement is performed by integrating the semiconductor film into a microcavity structure and tune its resonance frequency to match the epsilon-near-zero (ENZ) wavelength of the film material in a planar multilayer structure. We ascertained that our approach of electric field confinement in the semiconductor layer could perform significant light absorption at large incidence angles. That provides a novel, general, and simple method to enhance the optical and optoelectronic responses of any ENZ material, especially semiconductors below their bandgap energies.

Graphene-based dual-band near-perfect absorption in Rabi splitting between topological edge and Fabry–Perot cavity modes

We propose a graphene embedded one-dimensional (1D) topological photonic crystal heterostructure, where the coupling occurs between the topological edge mode (TEM) and the Fabry–Perot cavity mode (CM). It is shown that the coupling leads to the hybridization between TEM and CM, with a Rabi splitting. Based on finite element method, a dual-band near-perfect absorption is found in the Rabi splitting region in near-infrared range. The resonant wavelengths of the two absorption peaks are 1537 and 1579 nm, respectively. And the two absorption peaks can be modulated by the thickness of the defect layer, the coupling distance between TEM and CM, Fermi energy of graphene, and incident angle of light (under TE and TM polarization). In particular, when the Fermi energy of graphene slightly increases over 0.4 eV, the imaginary part of permittivity of graphene is near 0, so does the dual-band absorption. Theoretically, the TEM-CM coupling can be analyzed by the classic oscillator model. The controllable two absorption bands may achieve potential applications in active optoelectronic devices at communication wavelengths, such as optical switches, sensors and modulators.

Design of ultra-broadband absorption enhancement in plasmonic absorber by interaction resonance of multi-plasmon modes and Fabry-Perot mode

This paper shows a strategy to realize ultra-broadband absorption of multi-spectral coverage. A vertical cascaded plasmonic absorber constructed by multilayer helical metallic nanostructure wrapped in a pyramid-shaped dielectric jacket is presented and investigated by numerical simulations. By premeditated planning of the scale proportions of the spirals and the dimension size of the pyramid-shaped dielectric, more than 90% of absorption is realized in 189-3896 nm, an ultra-wide spectral range that basically covers the bands of near-ultraviolet, visible light, and near-infrared. The excitation mechanism of electromagnetic resonance and the formation process of light trapping are both included in the investigation through the analysis of electromagnetic field distribution. The localized surface plasmon mode in the metallic nano-spiral and the Fabry-Perot cavity mode with the gap plasmon resonance in the dielectric gap cooperatively make a significant contribution to reduce the reflection and form the ultra-broadband absorption. The simulation results show that the proposed absorber is basically insensitive to the incident angle and polarization angle, which basically keeps more than 90% absorption within the incident angle of ± 80 °. Such a specific implementation idea can also be applied to the terahertz region by modifying the geometrical size of the structure. This presented design implies new viability to develop the broadband photodetectors, solar cells, and thermal emitters.

Graphene-based low-threshold and tunable optical bistability in one-dimensional photonic crystal Fano resonance heterostructure at optical communication band.

In this paper, the one-dimensional photonic crystal Fano resonance heterostructure is used to achieve low-threshold and tunable graphene-based optical bistability of the transmitted and reflected light beam at optical communication band. The low-threshold of optical bistability (OB) originates from the local field enhancement owing to the Fano resonance excited by topological edge states mode and Fabry-Perot cavity mode. The study found that it is feasible to continuously adjust the hysteresis behavior and optical bistable thresholds by altering the Fermi energy of the left and right graphene respectively. Furthermore, the OB can also be controlled by changing the number of graphene layers or the angle of incident beam, which makes this structure a feasible object of experimental research at optical communication band in the future.

Symmetric Ge2Sb2Te5 based metamaterial absorber induced dynamic wide-gamut structural color

Plasmonic color has played a critical role for its applications in color printing and display owing to the advantages of high-resolution and durability. Recently, increasing attempts have been performed to actualize dynamic structural color. Here theoretically proposed is the generation of wide color gamut in symmetric Ge2Sb2Te5 (GST) based metamaterial absorber. By introducing a periodic metallic nanodisk array on top of the composite structure, the color variation arises from GST transition between amorphous phase and crystalline phase can be enhanced significantly. Due to the interplay of the localized/propagating surface plasmons, Fabry–Perot cavity mode and Wood’s anomaly with different resonant frequencies, both hue and saturation of the structural color can be tuned accordingly through adjusting the structural geometry of the nanodisks. It is demonstrated that up to 74% and 94% of the sRGB and CMY(K) space can be obtained with this phase-change metamaterial display. This finding paves the way toward the development of practical platform for color printing and display applications.

Enhanced Biophotocurrent Generation in Living Photosynthetic Optical Resonator.

Bioenergy from photosynthetic living organisms is a potential solution for energy‐harvesting and bioelectricity‐generation issues. With the emerging interest in biophotovoltaics, extracting electricity from photosynthetic organisms remains challenging because of the low electron‐transition rate and photon collection efficiency due to membrane shielding. In this study, the concept of “photosynthetic resonator” to amplify biological nanoelectricity through the confinement of living microalgae (Chlorella sp.) in an optical micro/nanocavity is demonstrated. Strong energy coupling between the Fabry–Perot cavity mode and photosynthetic resonance offers the potential of exploiting optical resonators to amplify photocurrent generation as well as energy harvesting. Biomimetic models and living photosynthesis are explored in which the power is increased by almost 600% and 200%, respectively. Systematic studies of photosystem fluorescence and photocurrent are simultaneously carried out. Finally, an optofluidic‐based photosynthetic device is developed. It is envisaged that the key innovations proposed in this study can provide comprehensive insights in biological‐energy sciences, suggesting a new avenue to amplify electrochemical signals using an optical cavity. Promising applications include photocatalysis, photoelectrochemistry, biofuel devices, and sustainable optoelectronics.

Spin-wave coupling to electromagnetic cavity fields in dysposium ferrite

Coupling of spin-waves with electromagnetic cavity field is demonstrated in an antiferromagnet, dysprosium ferrite (DyFeO3). By measuring transmission at 0.2-0.35 THz and sweeping sample temperature, magnon-photon coupling signatures were found at crossings of spin-wave resonances with Fabry-Perot cavity modes formed in samples. The obtained spectra are explained in terms of classical electrodynamics and a microscopic model.

Broadband continuous single-mode tuning of a short-cavity quantum-cascade VECSEL

Changing the length of a laser cavity is a simple technique for continuously tuning the wavelength of a laser but is rarely used for broad fractional tuning, with a notable exception of the vertical-cavity surface-emitting laser (VCSEL)1,2. This is because, to avoid mode hopping, the cavity must be kept optically short to ensure a large free spectral range compared to the gain bandwidth of the amplifying material. Terahertz quantum-cascade lasers are ideal candidates for such a short cavity scheme as they demonstrate exceptional gain bandwidths (up to octave spanning)3 and can be integrated with broadband amplifying metasurfaces4. We present such a quantum-cascade metasurface-based vertical-external-cavity surface-emitting laser (VECSEL) that exhibits over 20% continuous fractional tuning of a single laser mode. Such tuning is possible because the metasurface has subwavelength thickness, which allows lasing on low-order Fabry–Perot cavity modes. Good beam quality and high output power are simultaneously obtained. Terahertz quantum-cascade lasers with over 20% continuous fractional tuning of a single laser mode are now possible thanks to metasurfaces.

Cost-Effective Realization of Multimode Exciton-Polaritons in Single-Crystalline Microplates of a Layered Metal-Organic Framework.

We report the observation of multimode exciton-polaritons in single-crystalline microplates of a two-dimensional (2D) layered metal-organic framework (MOF), which can be synthesized through a facile solvothermal approach, thereby eliminating all fabrication complexities usually involved in the construction of polariton cavities. With a combination of experiments and theoretical modeling, we have found that the exciton-polaritons are formed at room temperature as a result of a strong coupling between Fabry-Perot cavity modes formed inherently by two parallel surfaces of a microplate and Frenkel excitons provided by the 2D layers of dye molecular linkers in the MOF. Flexibility in rational selection of dye linkers for synthesizing such MOFs renders a large-scale, low-cost production of solid-state, micro-exciton-polaritonic devices operating in the visible and near-infrared range. Our work introduces MOFs as a new class of potential materials to explore polariton-related quantum phenomena in a cost-effective manner.

Detection of ultracold molecules using an optical cavity

We theoretically study non-destructive detection of ultracold molecules, using a Fabry-Perot cavity. Specifically, we consider vacuum Rabi splitting where we demonstrate the use of collective strong coupling for detection of molecules with many participating energy levels. We also consider electromagnetically induced transparency and transient response of light for the molecules interacting with a Fabry-Perot cavity mode, as a mean for non-destructive detection. We identify the parameters that are required for the detection of molecules in the cavity electromagnetically induced transparency configuration. The theoretical analysis for these processes is parametrized with realistic values of both, the molecule and the cavity. For each process, we quantify the state occupancy of the molecules interacting with the cavity and determine to what extent the population does not change during a detection cycle.