Modern Sediments Research Articles

Long-lived topography of the Oaxacan Complex (southern Mexico) after the assembly of Pangea: Evidence from apatite fission-track dating

Understanding the exhumation history of ancient orogens is crucial for unraveling the tectonic and climatic forces that shape Earth's landscapes. Relict topography from ancient orogenic belts can persist on the surface for tens of millions of years, providing detritus to surrounding areas even without significant uplift events. This study examines the exhumation history of the Oaxacan Complex in southern Mexico, a Proterozoic peri-Gondwanan continental block located at the periphery of western equatorial Pangea during the l ate Paleozoic. This complex supplied detritus to extensional basins in southern Mexico throughout the Mesozoic and Cenozoic. We reinterpret existing apatite fission track (AFT) data from in situ samples of the Oaxacan Complex and add a set of detrital AFT data from modern sediments of the Peñoles River, which drains the northern Oaxacan Complex. The detrital AFT age distribution is continuous, ranging from ∼180 Ma to ∼50 Ma, without a predominant component age and showing a positive age-elevation correlation, suggesting a slow cooling history of the basement exposed in the drained area. QTQt thermal history modeling of the detrital AFT ages corroborates this slow cooling. Moreover, reinterpretation of in-situ AFT data from the literature confirms that the cooling history of the crustal block exposed in the northern Oaxacan Complex is characterized by a prolonged residence time in the Partial Annealing Zone of the apatite fission-track thermochronometer, spanning at least from the Triassic to the Paleogene. These results suggest that the Oaxacan Complex did not undergo any significant exhumation events after the Late Paleozoic assembly of Pangea, neither during the Triassic–Early Cretaceous rifting associated with Pangea breakup nor during development of the Late Cretaceous–Eocene Mexican Orogen. According to this scenario, we suggest that the post-collision relict topography of the Oaxacan Complex was likely sustained by isostatic rebound and lithological resistance, supplying sediment for tens of millions of years to the Mesozoic and Cenozoic basins of southern Mexico.

Holocene benthic foraminifera ecological succession in the Panamanian Caribbean

Benthic foraminifera assemblages from a 452 cm long sediment core (GAL18) were collected from a mangrove forest on the Caribbean coast of Panama. The core spans the last ∼5200 cal yrs. B.P. Ninety-six benthic species were recorded in the sedimentary sequence. The most frequent and abundant were the calcite hyaline species Ammonia batava, Ammonia tepida, Ammonia ariakensis, Elphidium articulatum, Elphidium cristobalense, and Cribroelphidium galeroense. The second most abundant were four porcelaneous species: Quinqueloculina cf. araucana, Quinqueloculina cf. poeyana, Quinqueloculina neocostata and Quinqueloculina seminulum. There were also scattered species of agglutinant taxa along the core and in modern sediments. Micropaleontological, sedimentological, and geochemical analyses allowed the recognition of four lithologic units that were consistent with four paleoenvironmental scenarios of ecological succession. (I) The Estuarine Zone deposited at ∼5200–3600 cal yrs. B.P. suggests the development of a mangrove ecosystem along a channeled tidal area with estuarine water exchange and dominant species from brackish waters such as Ammonia and Cribroelphidium. Isotopic (δ13Corg, δ15N), geochemical (C/N, Ca/Ti, K/Rd, Fe/Ca), and pollen data also show a polyhaline environment with bio-calcite production and active coastal weathering. (II) The Seaward Zone deposited between ∼3600–1250 cal yrs. B.P., closest to marine waters, with an overall increase in benthic species, like the euhaline Quinqueloculina spp., and other calcareous organisms. (III) The Transition Zone was deposited amid 1250–650 cal yrs. B.P. when the area experienced less frequent flooding by tidal waters, dominated by polyhaline Elphidium and Ammonia spp., and the establishment of a mangrove ecosystem influenced by changing salinity, as the sea level almost reached its modern position. Finally, (IV) the Landward Zone deposited over the last 650 cal yrs. B.P., where the lack of benthic foraminifera and bio-calcite deposits contrast with high amounts of organic carbon and vegetal debris, which supports that the core site was located further inland than in previous intervals. This multiproxy study features subtle but irreversible changes that a fringe mangrove community can experience over time, highlighting the complex relationship between the coastal region and the sea.

Magnesium geochemistry of authigenic carbonate at marine cold seep

Cold seeps, featured by their extremely methane-rich sedimentary environments, play a significant role in the geological history and are common in marine sediments across the seafloor. Primary dolomite, possibly mediated by microorganisms, can be widely discovered in methane-rich environments. Hence, cold seeps may provide new insights into the ‘dolomite problem’, which has confused geologists for decades. Magnesium isotope geochemistry of seep carbonates contributes to the understanding of the dolomite formation mechanism in marine environments. In this paper, magnesium geochemical characteristics of carbonates in modern sediments are summarized, along with rare researches on magnesium isotopes of seep carbonates. Methane vigorously interacts with sulfate by anaerobic oxidation of methane at cold seeps, producing vast amounts of dissolved sulfide which can significantly promote dolomitization of seep carbonates. Compared with temperature, alkalinity, mineralogy, etc., the competition between rapid carbonate precipitation rates and aqueous ligands may be the main factor of the magnesium fractionation at cold seeps, which is controlled by the kinetic effect. The range of magnesium isotopes of seep carbonates is narrow (from -3.46‰ to -2.36‰), and an upper limit of magnesium content seems to exist. This characteristic may be a good indicator for identifying dolomitization related to anaerobic oxidation of methane. Whereas, mechanisms of magnesium isotope fractionation and dolomitization at cold seeps remain unclear, necessitating more natural samples tested, stimulated calculation and laboratory experiment.

Bayesian statistical analysis reveals spatial heterogeneity in Cyclone Thane deposits from Southeast India

Modern and geological records of storm sedimentary deposits preserved on siliciclastic coastlines are important archives to evaluate the past and current magnitude and impacts of.storms. Examination of modern storm deposits also offers the opportunity to evaluate the similarities and differences between storm and other coastal overwash processes and hazards.We examined the stratigraphy and sedimentary characteristics of the 31st December 2012 Cyclone Thane and underlying coastal units from 14 pits from six sites from the coastal zone of Tamil Nadu Province, southeast India. We analysed the grain size parameters, grain shape, and heavy mineral proportions of each deposit in high resolution and examined the sedimentary structures of each unit. For the first time, we use Bayesian factors to quantitatively evaluate the similarities and differences between the storm sedimentary deposits and other co-located coastal sedimentary deposits. At several sites, the storm deposits differ in several parameters from the underlying coastal deposits, but at some locations, distinguishing between different depositional units cannot be achieved. In comparing the storm deposits from the different sites, mean grain size results in the most coherent pattern with closely located sites having similar mean grain size, and more southerly sites being finer grained. The other measured parameters show a far less coherent pattern with adjacent sites often preserving larger differences than more distal sites attesting to very local hydrodynamic variations during sediment deposition. As with the sedimentary parameters, the sedimentary structures formed during sediment deposition preserved at each site are highly variable. To date, the presence of terminal foresets at the landward edge of washover fans remains the only diagnostic feature of storm deposition, but that this feature is not ubiquitous across all storm deposits. Our findings demonstrate the spatially heterogeneous nature of storm sediment deposition and the challenges of identifying storm deposits in coastal siliciclastic sequences. The use of Bayesian statistical approaches also offers a robust method for evaluating and discriminating between coastal sediment deposits that has many advantages over traditional frequentist approaches. This method can easily be applied to other sedimentary depositional environments.

Recent deep-sea nematodes and agglutinated foraminifera select specific grains and bioclasts from their environments: Ecological implications

The high-latitude regions are known for a diverse array of benthic meiofauna, yet our understanding of these communities remains limited, particularly in the deep ocean. This study aims to assess the variability and adaptation of nematodes and agglutinated foraminifera in the modern sediments of the Southern Pacific Ocean at >3500 m water depth. Seawater and sediment slurry from the first piston cores (i.e., mudline samples) from International Ocean Discovery Program Sites U1539, U1540, U1541, and U1543 were analyzed for Rose Bengal stained nematode and agglutinated benthic foraminifera. During the microscopic study seven nematode specimens belonging to the genus Desmoscolex, with 16–17, 36 or 38 main rings were found. Scanning electron microscopy study suggest that one morphotype with 17 main rings used only coccoliths of the species Calcidiscus leptoporus while the other specimens used fine-grained siliciclastic material on their concretion ring. Besides nematodes, a few benthic agglutinated foraminifera specimens exclusively used a single species of planktic foraminifera (Globoconella inflata) and/or robust coccoliths, in addition to other fine-grained siliciclastic material, for their test construction. These patterns appear to be highly selective. Specimens of the same benthic nematode Desmoscolex genus and agglutinated foraminifera that have diverse grain types show that these specimens can adapt to their environments, choose specific grains as per their preference, and have no relationship with the grain/particle abundance. This study of Desmoscolex and agglutinated foraminifera species suggests low to moderate organic matter flux and increased ventilation in the abyssal depth of the Southern Pacific Ocean.

Chemical composition of sediment and macrozoobenthos of small urban lakes, the Republic of Karelia, Russia

Assessing the benthic communities in water bodies under increasing anthropogenic pressure seems to be an urgent task of scientific research aimed at short-term and long-term monitoring of water bodies. This study focuses on the chemical composition of modern sediment and the current state of macrozoobenthos of small lakes in the Republic of Karelia (Kitaiskoe and Plotichie) influenced by anthropogenic factors. It was discovered that the lakes of Medvezhyegorsk have a higher concentration of heavy metals (such as lead (Pb), cadmium (Cd), molybdenum (Mo), and antimony (Sb),) compared to the Earth’s crust and natural background levels. The current study established the significant impact of industry and transportation on the movement and build up of pollutants in these lakes. The qualitative and quantitative parameters analysed for the benthic communities in the littoral and profundal zones included the species diversity, the structure of dominant species, and their percentage in the samples. According to the level of macrozoobenthos development, both reservoirs (lakes) were classified as mesotrophic, and according to the values of the chironomid index “K” as moderately polluted. The Pantle–Buck method (saprobic index) showed that the lakes can be classified as polluted (water quality class 4). Macrozoobenthos groups most tolerant to environmental conditions, for example, Chironomidae larvae, prevailed in the studied urban lakes. The economic development of the lakes leads to ecosystem transformation and long-term eutrophication over time affecting the biotic indicators of surface water quality. The results obtained can serve as a basis for complex environmental monitoring of the urbanized territories in the taiga zone.

Imbrication fabric as a diagnostic feature for the genetic classification of gravels deposited by fluid‐gravity versus sediment‐gravity subaerial flows

AbstractGravel transport in subaerial environments occurs through different flows that are conveniently classified as debris flows, debris floods and water flows based on their distinct morpho‐sedimentary dynamics and different implications for geomorphic hazard. Because distinctive features allowing gravelly sedimentary bodies to be ascribed to related genetic process are still a matter of discussion, this study aims to establish whether imbrication fabric represents a sedimentological fingerprint potentially applicable towards a more robust genetic classification of gravels. We analysed the fabric of 1007 imbricated clasts from modern and ancient deposits. Our results highlight statistically significant differences between imbrication fabrics in gravels deposited by different flows. Particles imbricated by water flows are typified by low imbrication angles (median of 35°) and elongated clasts oriented perpendicular to the flow. In contrast, debris‐flow gravels exhibit high imbrication angles (median of 65°) and elongated clasts oriented parallel to the flow. Debris‐flood deposits display elongated clasts both parallel and transverse to the main flow and intermediate values of imbrication angle (median of 47°). We propose that imbrication angles result from the combination of stability‐driven selection—a process acting under tractional transport and promoting the remobilization of high‐angle imbrication fabrics—and shear‐stress‐driven overriding—a mechanism leading to the formation of the higher imbrication angles—with the first dominating in water flows and the latter being effective in mass transport processes. The progressive change in imbrication fabrics from fluid‐gravity to sediment‐gravity flow deposits offers easily quantifiable sedimentological evidence to help in distinguishing genetic processes that contribute to the accumulation of gravels in alluvial and colluvial settings. Analysis of imbrication fabric can add valuable information, particularly as regards the classification of (1) coarse deposits in stratigraphic records and (2) modern debris flood deposits.

Microstructural and mechanical properties of Al-5356 alloy structures fabricated using direct energy deposition (DED): In-pursuit to optimizing deposition parameters

Many industries including aerospace make extensive use of lightweight materials like aluminium alloys because of their extraordinary properties. Wire Arc Additive Manufacturing-Cold Metal Transfer (WAAM-CMT) as a part of modern direct energy deposition technique can be recommended for developing aerospace components of aluminium alloys. However, it is still necessary to investigate the impact of the combined change of developing parameters on some of the crucial qualities including metallurgical and mechanical properties. Therefore, in this part of research work, practically, various process parameters were tried for development of aluminium (Al-5356) alloy walls. Finaly, a specific set of parameters namely wire feed speed, scanning speed and inter layer temperature parameters with two levels of each were selected and with the assistance of these, four walls have been fabricated. Th preliminary analysis showed that low heat input accompanied by higher scanning speed of 60 cm/min and lower wire feed rate of 6 m/min was found to best suitable set of parameters for developing dimensionally stable Al wall with flaw less microstructure. The said set of parameters also showed higher hardness that also accompanied with finer grains, lower percentage towards high angle grain boundary and lower KAM. Even slight variation in these parameters that deal to high heat input can give rise of porosity and misalignment in the wall. Details of microhardness reported high hardness in the bottom part of the wall. However, in a single bead the hardness is higher in the top region, which may be owing to finer grains in the specified region. The above said set of parameters also able to deliver better tensile strength and toughness for Al-5356 alloy. The developed alloy showed improved strength in longitudinal orientation owing to intra layer failure with ductile mode of fracture in contrast to transverse orientation, where the failure mode was reported to mixed (ductile as well as brittle) owing to inter layer fracture.

Downstream change of luminescence sensitivity in sedimentary quartz and the rearrangement of optically stimulated luminescence (OSL) components along two large rivers

Recently, it has been proposed that the luminescence sensitivity of quartz grains, i.e. their luminescence response to unit dose, might be used for sediment fingerprinting. Sensitivity is determined both by the origin of quartz grains and the sedimentary processes they underwent. However, a more detailed understanding of the factors influencing sensitivity is essential in order to expand and specify the applicability of the parameter in sediment sourcing and geomorphological studies alike. In the present research, we examined the spatial changes of sensitivity parameters of coarse grain quartz in modern sediments of the largest rivers of the Carpathian Basin, Central Europe, to determine the role of source areas and transportation distance.Based on the luminescence analysis of 39 samples, quartz extracts with a Carpathian origin (catchment of the Tisza River have a significantly higher sensitivity, except the LM-OSL medium component, than those originating from the Alpine domain (catchment of the Danube River). No clear relationship could be identified between natural sensitisation and transportation distance. In terms of the Tisza the observed downstream increase of quartz sensitivity is due to high sensitivity quartz grains supplied by its tributaries. In the meantime, a recurring change was observed along the Danube, which can be attributed mostly to local erosional processes. Consequently, tributaries and erosion can overprint the potential downstream sensitisation of quartz grains in large rivers.Meanwhile, in terms of the Danube on sections where a significant downstream increase was detected in LM-OSL fast component sensitivity, LM-OSL medium component sensitivity systematically decreased. Additionally, during laboratory sensitization, the CW-OSL sensitivity of Danube samples increased considerably, whereas changes were more moderate in the case of Tisza samples. Moreover, in the case of Tisza-related quartz extracts, the 110°C TL sensitivity and the LM-OSL fast and medium components showed a strong correlation, indicating the stability of luminescence processes (trapping and recombination). Whereas, in the case of the Danube both LM-OSL components show a weak correlation with the 110°C TL intensity. All these indicate that Alpine-origin quartz grains are more susceptible to the rearrangement of electron traps and/or recombination centres, which can also be an indicator of sediment sources in Quaternary studies in the region.

A global database of tsunami deposits

AbstractGeomorphic environments play a crucial role in influencing the preservation and characteristics of tsunami deposits. This paper introduces a global database of tsunami deposits, encompassing information on deposit locations, thematic data such as geomorphic environments and proxies and bibliographic details. Additionally, the database features maps incorporating environmental parameters and the precise locations of tsunami deposits. The primary utility of this database lies in assessing progress and identifying gaps in knowledge. It also involves analysing the relationship between environmental parameters and interpreting areas with varying probabilities of tsunami deposit preservation. The files are readily compatible with GIS software and can seamlessly integrate into spatial databases associated with tsunamis or other hazards. This contributes significantly to disaster risk management, enhancing preparedness and response efforts by providing a comprehensive historical dataset on tsunamis. Future applications of the database include the incorporation of modern deposits, boulders and new data from paleotsunami and historical studies. By enhancing data with thematic information, such as dating techniques and creating timelines, the database facilitates a more comprehensive understanding. The correlation between geomorphic environments and proxies aids in selecting sampling sites and identifying suitable proxies for analysis. Encouraging an open‐access approach, this database invites all interested researchers to include and modify additional information. The information compiled for this database serves multiple purposes: (1) assessing the global distribution of tsunami deposits; (2) identifying knowledge gaps in tsunami deposits; (3) guiding the selection of study areas for further research and finally; (4) enabling a meta‐analysis of the information gathered.

The characteristics of modern flood deposits in the lower reaches of a small watershed and the significance of paleo-flood identification

The mountainous region of central Shandong Province in eastern China is renowned for its high frequency of rainstorms, which often result in devastating flood disasters and have profoundly affected the evolution of local ancient civilizations. To identify ancient flood disaster events, recognizing sediment signatures via multiple indices is important. Here, we investigated the 2018 flood deposits in the Danhe River Basin and sampled short core DH2, on which the grain size, total organic matter (TOM) content, carbonate content, magnetic susceptibility (MS) and pollen were measured. The fine grain size of the flood sedimentary layer reveals that the flood energy in the alluvial plain area is usually weak. The pollen species and concentration and the tree pollen content in the flood layer are significantly greater than those in the soil layer, suggesting that the flood sediment mainly originates from the mountainous areas in the upper reaches of the river, which provides more forest vegetation information. The MS of flood deposits is lower than that of the soil layer, which is mainly related to the intensity of pedogenesis. The research results indicate that the flood sediments in the downstream floodplain areas of small watersheds are predominantly composed of fine-grained components, with characteristics of high loss on ignition, low magnetic susceptibility, high pollen abundance and diverse species. These findings establish a multi-index identification system for paleoflood sedimentation, which has important reference significance for the study of paleoflood sedimentology and hydrology.

Correlations of chemical weathering indicators with major chemical constituents in sediments to obtain palaeoclimate information from Chaohu Lake, China

The main chemical compositions of 201 surface sediments and 53 deep sediment samples from Chaohu Lake, China, were analysed. Since the surface sediments (0–2 cm depth) in Chaohu Lake are modern sediments, this paper mainly focuses on the deep sediments (50–100 cm depth) in Chaohu Lake. Particle size analysis and magnetization determination of the CH3 and CH4 column sediment samples were carried out. The age determination data of the CH-1 column sediment samples are reported. A systematic study of the rocks and their chemical compositional characteristics in the Chaohu Lake Basin was also carried out. The results of this study show that four positive chemical weathering indicators and one negative chemical weathering indicator are applicable to the study of Chaohu Lake. The mean CIA of the Chaohu Lake sediments was less than 65, indicating that the Chaohu Lake Basin experienced weak chemical weathering and that the palaeoclimate was cold and dry. Vertical variations in the mean grain size and magnetization in the CH3 and CH4 columnar sediments reflect changes in the depositional environment and climate during deposition of the Chaohu Lake sediments. The age data from the CH-1 column sediment samples directly indicate deposition of the deep sediments in Chaohu Lake during the Little Ice Age in eastern China (AD 1380–1880). The Th/U, Sc/Th, Rb/Sr, Na2O/K2O, CaO/MgO and OC/N ratios of the Chaohu sediments reflect palaeoclimate characteristics and the chemical compositions of the source rocks in the Chaohu Lake basin. The correlations of the CIA, CIW, PIA, and CIX with the chemical compositional ratios provide information on the palaeoclimate and the distribution of the chemical compositions. The CIA, CIW, PIA, and CIX were not correlated with Cd, Pb, As, Hg, or P. In contrast, the CIA, CIW, PIA, and CIX were significantly positively correlated with Cr and N. The WIP was inconsistently correlated with the selected chemical components. Therefore, the study of the correlations of chemical weathering indicators with four heavy metals and two eutrophication-related elements is of little significance. The study of the chemical weathering characteristics of deep sediments of inland lakes should be combined with assessment of the geological characteristics of the lake basins, particularly the analysis of the chemical composition of the rocks in the lake basins.

Tin isotope heterogeneity and baseline of the upper continental crust

Stable Sn isotope ratios are emerging as a novel tracer for a wide range of geological processes; however, the Sn isotopic baseline of the upper continental crust (UCC) is not yet well-constrained. Here, we report high-precision Sn isotope data of a wide range of UCC samples, including granites, pegmatites, and sediments, to document the Sn isotopic composition of UCC. Significant variations in δ122/118Sn3161a (per mil deviation in 122Sn/118Sn relative to NIST 3161a) values are revealed for I-type (δ122/118Sn3161a = 0.025 ± 0.026‰ to 0.495 ± 0.046‰, n = 20) and S-type (δ122/118Sn3161a = 0.156 ± 0.018‰ to 0.501 ± 0.075‰, n = 22) granites. More extreme Sn isotope variability is observed for pegmatites, which have δ122/118Sn3161a from 0.256 ± 0.047‰ to 0.930 ± 0.049‰ (n = 13). The δ122/118Sn3161a of I-type granites decrease with decreasing TFe2O3 (total Fe as Fe2O3) and MgO contents and are attributed to the segregation of Fe-bearing minerals. Conversely, the Sn isotope variation of S-type granites appears to reflect source heterogeneity, whereas the Sn isotope variability of pegmatites may reflect fluid activity. In contrast, the loess samples display homogeneous δ122/118Sn3161a values (0.132 ± 0.034‰ to 0.239 ± 0.020‰, n = 20) that show no correlation with the degree of chemical weathering, suggesting that loess is representative of the average Sn isotope composition of UCC. The δ122/118Sn3161a values of modern sediments and sedimentary rocks range from 0.080‰ to 0.490‰ (n = 25) and the Sn isotope variations may be related to chemical weathering or sediment provenance. Based on the lithology-weighted average δ122/118Sn3161a of UCC samples (41 granites and 45 sediments) in this study, the δ122/118Sn3161a value of UCC is estimated to be 0.233 ± 0.099‰, providing a reference point for further investigations. Tin is isotopically lighter in UCC compared to the mantle, owing to magmatic differentiation and crustal evolution processes.

Sedimentary record of water-sediment regulation and channel shifts in the Yellow River (Huanghe) Delta

Delta are vital habitats for people and biotic communities. Many of the world's large river deltas are shrinking because of relative sea level rise and intensifying human interventions in the basin. Among these, the Yellow River Delta (hereafter YRD) has been enormously impacted by frequent channel avulsions and a Water-Sediment Regulation Scheme (WSRS) through upstream reservoirs since 2002. However, it remains undisclosed how the YRD responses to these human interventions. Here, modern sedimentation and inter-annual to multi-decadal timescales evolution of the YRD were studied using a dataset including 10 sediment cores collected in the subaqueous delta during the 2014 WSRS, satellite images, hydrographic and bathymetric data from 1976 to 2014. Our results show that the sedimentation of the delta can be divided into three stages: 1976–1995, 1996–2001, and 2002–2014. The area of subaerial delta generally increased from 3884 km2 to 4441 km2 during the whole 1976–2014 period except for a net land loss during 1996–2000. >70% of the delta coastline became artificial after 2000. Bathymetric data reveals that the subaqueous delta was seriously eroded after 1996 due to a shortage of sediment supply, with an estimated 2.3 × 108 t/yr and 1.1 × 108 t/yr of sediment respectively transported to the delta's adjacent sea during 1996–2001 and 2002–2014. The deltaic sediment became coarser due to the impact of the WSRS. Radionuclide 7Be uncovers a rapid sediment accumulation of ∼12 cm at the active delta front during the 2014 WSRS. The evolution of the YRD has become complex under the influence of natural and anthropogenic factors. The YRD thus provides an exemplar shift from natural to human-dominated delta. These results are important for the delta management decision making.

The Ballynoe Stratiform Barite Deposit, Silvermines, County Tipperary, Ireland

The Ballynoe barite deposit is a conformable, mineralised horizon of Lower Carboniferous age overlying a diastem and mass faunal extinction demarking the transition from a quiet water environment to one of dynamic sedimentation. The geometry of the barite orebody correlates with the palaeotopography of the footwall, which acted as an important control over the lateral extent, thickness, and nature of the mineralisation. Sedimentary features within the barite horizon suggest that it was precipitated in the form of a cryptocrystalline mud which underwent major diagenetic modification resulting in extensive stylolitisation, recrystallisation, and remobilisation. There is abundant and compelling geological and isotopic evidence for early local exhalation from the presence of a hydrothermal vent fauna consisting of delicately pyritised worm tubes and haematised filaments of apparent microbial origin. The worm tubes are remarkably similar to examples from modern and ancient volcanic-hosted massive sulphide deposits, and the filamentous microfossils have similarities to modern Fe-oxidising bacteria. Strontium in the barite has an 87Sr/86Sr ratio indistinguishable from seawater between 350 and 344 Ma whilst oxygen isotopes from barite and chert suggest a diagenetic origin in equilibrium with such seawater around 60–70 °C. Fluid inclusion studies have shown that, in general, low temperature inclusions are very saline (20%–25%) whilst at higher homogenisation temperatures they are more dilute (9%–12%).

Petrologically controlled oxygen isotopic classification of cogenetic magmatic and metamorphic sapphire from Quaternary volcanic fields in the Eifel, Germany

Gem sapphire is commonly retrieved from primary and secondary deposits associated with alkali basaltic fields, but its source rocks are rarely preserved. The Eifel (Rhenish Massif, western Germany), although not producing gem sapphire, shares many petrologic and geochemical similarities with such fields worldwide. Due to the young age of volcanic deposits and active quarrying, sapphire-bearing rocks are readily accessible, along with detrital sapphire from modern sediments. Here, oxygen isotope and trace element compositions are reported for 223 sapphire grains, and rutile and zircon inclusions in sapphire were dated indicating crystallization synchronous with Paleogene–Quaternary volcanism. Endmembers in δ18O range are sapphires from syenites representing mantle-derived differentiated melts with minor crustal contamination (~4–6‰) and contact metamorphic mica schists (>10‰) as purely crustal source rocks. Intermediate values between ~6 and 10‰ require variable degrees of mantle-crust hybridization. Lower crustal granulite sources are dismissed based on their oxygen isotopic compositions being lower than most sapphire crystals. Diffusion modelling of sharp oxygen isotopic zonation in compositionally zoned crystals precludes crystal residence at >900 °C over the lifetime of evolved magma reservoirs in the Eifel (c. 50 ka). This argues against direct mantle or lower crustal sapphire origins. Instead, low temperature residence is consistent with sharp δ18O gradients, coexisting andalusite, and fluid inclusion barometry. Hence, Eifel sapphire crystallization is attributed to contact metamorphic aureoles around upper crustal (5–7 km) magma bodies where phonolite, trachyte, and carbonatite melts differentiated from mafic parental magmas, and reacted with metasedimentary wall rocks.

Mechanical transport revealed by optical textures of heavy minerals in aeolian sand: A case study in the Badain Jaran Desert, Northwestern China

Determining whether and to what extent the relative abundance of heavy minerals in original detrital assemblage has been modified by mechanical transport is beneficial for understanding regional historical climate changes and acquiring modern sediment provenance information. Utilizing the frequency of surface mechanical optical textures of heavy minerals may be an effective approach to address this question. However, the connection between the frequency surface mechanical optical textures of heavy minerals and the variations in the relative abundance of these minerals remains uncertain. In this study, 12 modern aeolian sand samples were collected from the Badain Jaran Desert in hyper arid region of northwestern China, characterized by weak weathering to analyze their relative contents of five major heavy minerals. Then, 3796 transparent heavy mineral grains were photographed under the parallel light of a polarizing microscope, and the frequency of 13 surface mechanical optical textures were calculated. The results reveal that the variations in the relative abundance of heavy minerals are substantially influenced by mechanical transport. The decrease in the relative abundance of heavy minerals with weak mechanical stability primarily attributed to mechanical collision. Conversely, the variations in the relative abundance of heavy minerals with strong mechanical stability are primarily influenced by mechanical abrasion. Therefore, mechanical transport impact on the relative abundance of heavy minerals in regions with weak chemical weathering. Establishing heavy mineral characteristic indices for provenance studies using the relative abundance of mechanically unstable minerals may not directly indicate transport distance but rather the strength of wind forces, which have significant potential in palaeo wind regime studies. This study expands the research field of sediment surface micromorphology and has potential applications in inferring past climate changes and determining modern sediment provenance.

GEOCHEMICAL AND SANITARY-CHEMICAL CHARACTERISTICS OF WATER SPRINGS OF BOGORODSKY AND LOSIN-PETROVSKY DISTRICTS OF THE MOSCOW REGION

This paper is the results of evaluated of water parameters (COD, pH, electrical conductivity), the content of major ions (Ca2+, Mg2+, Na+, K+, NH4 +, HCO3–, Cl–, SO4 2–, NO3 –) and microelements (Co, Ni, Cu, Zn, Cd, Pb, Sr, Ba, Mn) for 12 springs in the Bogorodsky and Losino-Petrovsky districts of the Moscow region. The waters are slightly acidic-near-neutral (pH 5.5–7.5) with the mineralization from 0.07 to 0.5 g/l, the total hardness is 0.63–5.7 mg- eq/l, the composition of the water is variable. Spring waters are divided into four groups: Cl-SO4-HCO3-(Mg)-Ca; (SO4)-HCO3-Cl-Na-Ca; (Cl)-HCO3-Ca; and mixed composition. Based on the thermodynamic calculation using the Visual-MINTEQ, it was found that the predominant dissolved forms of Ba, Sr, Mn, Zn, Cd, Ni, Co in the waters in the waters of the surveyed springs are free ions. For Cu and Pb, the factors for the formation of migration forms are the predominant anions of water, as well as the presence of organic matter in water. COD values and nitrogen compaund in the waters of individual springs are indicate that the formation of the composition of spring waters is associated with the infiltration of atmospheric precipitation through the modern sediments subject to antropogenic press. The values of other sanitary-chemical indicators (mineralization, pH, total hardness, chlorides, sulfates, mag- nesium, sodium, manganese), the content of standardized microelements are lower than their maximum permissible concentrations in drinking water.

Combined cadmium and chromium isotopes record a collapse of bioproductivity across the Cretaceous—Paleogene boundary in the Danish basin

Cadmium (Cd) isotope signatures (δ114Cd) deduced from modern and ancient marine deposits are often used as a proxy for bioproductivity and for micronutrient cycling, whereas chromium (Cr) isotope signatures (δ53Cr) are used as a potential proxy for oxygenation. The Cretaceous—Paleogene (K/Pg) boundary records one of Earth's five big mass extinctions, which contains geochemical fingerprints of the Chixculub asteroid impact and is coeval with the Deccan Trap volcanism. Here we present for the first time a combined record of Cd and Cr isotopes from the Danish Basin to interrogate the effects on bioproductivity across the K/Pg boundary. The δ114Cd values range between −0.28‰ and 0.27‰ defining an average of 0.05‰ ± 0.24 (2σ, n = 87). Authigenic δ53Cr values range between 0.06‰ and 1.06‰ and define an average of 0.59‰ ± 0.51 (2σ, n = 81). An abrupt jump, across the K/Pg boundary layer, from consistently positively fractionated Cd and Cr isotope signatures recorded in Late Maastrichtian white chalks towards less positively fractionated δ114Cd values and heterogeneous δ53Cr values in the Early Danian carbonates, likely indicates a decrease in surface water bioproductivity. This decrease is accompanied by redox fluctuations in the water column as a consequence of environmental changes either related to the Chixculub impact event and/or to the Deccan volcanic eruptions coeval with this boundary. Assuming an efficient removal of Cd and Cr through consumption and/or adsorption by primary producers, or by incorporation into the skeleton/shells of calcifiers, and using the fractionation factor of Cd into carbonates, we reconstruct surface water conditions during the Late Masstrichtian—Early Danian that are compatible with those of modern oceans, with δ114Cd varying from 0.17 to 0.72‰. Overall, the combined Cr-Cd isotope fluctuations over the K/Pg boundary are consistent with a scenario characterized by climate-induced changes of nutrient availability and concomitant responses of primary production levels, ultimately related to the asteroid impact and to the proceeding volcanic activities that influenced the ocean's chemistry. We anticipate our results to point for further studies of other stratigraphic sections worldwide to reveal an extensive Cd-Cr record for the Cretaceous—Paleogene boundary and its corresponding collapse of bioproductivity and decreasing ocean oxygenation.

Extracting paleo-weathering signals from authigenic phases in lake sediments: A case-study of Lake Baikal

Authigenic phases in lake sediments hold the potential to record changes in the isotope compositions of past lake water, potentially yielding valuable information on secular changes in continental weathering patterns and rates, including over past glacial cycles.Here, different leaching approaches are investigated with the aim of extracting Sr, Nd, Pb, and Be hosted in authigenic Fe-Mn (oxy)hydroxide sediment phases for precise isotope measurements. Elemental Al/Mn, Ca/Mn, and P/Mn ratios obtained via a mild reductive leach agree well with the composition of marine authigenic Fe-Mn phases. For core top sediments, leached Sr isotope compositions obtained with this leach agree well with the composition of lake water. The Be and Nd isotope compositions of core top leachates are consistent with the spatial variability observed in the water column. Due to high concentrations in Fe-Mn phases, leachate compositions are dominated by authigenic Be, Sr, Nd, and Pb, even in cases when as much as 40% of leached phases (by mass) are non-authigenic. These lines of evidence suggest that the mild reductive leach successfully extracts the modern lake isotope composition from modern sediments in terms of the isotope systems investigated. We further show that the leaching method is also reliable for older sediments (<340 ka): leached paleo-Sr isotope compositions are consistent between the current and previous interglacial periods, as well as for glacial periods. This suggests that reconstructed water isotope compositions are not affected by early diagenetic processes, instead reflecting environmental factors around the lake that determine the composition of weathering fluxes. Although more difficult to assess for Be, Nd, and Pb due to the heterogeneity of modern lake water, the data we present indicate the overall robustness of the leaching approach.These promising results open up lakes as archives for paleo-weathering reconstructions. Given that marine reconstructions face some important limitations (e.g., integration of basin-wide changes in weathering processes, long residence times for Sr, etc.Fe), lake records provide an avenue to improve our understanding of changes in regional weathering processes over glacial-interglacial timescales. The mild reductive leach used here may also be useful for meteoric Be studies in marine shelf settings, to prevent leaching of terrestrial sedimentary Fe-Mn oxy(hydroxide) phases.