Heat and electricity are two fundamental forms of energy widely utilized in our daily lives. Recently, in the study of complex networks, there is growing evidence that they behave significantly different at the micro-nanoscale. Here, we use a small-world network model to investigate the effects of reconnection probability p and decay exponent α on thermal and electrical transport within the network. Our results demonstrate that the electrical transport efficiency increases by nearly one order of magnitude, while the thermal transport efficiency falls off a cliff by three to four orders of magnitude, breaking the traditional rule that shortcuts enhance energy transport in small-world networks. Furthermore, we elucidate that phonon localization is a crucial factor in the weakening of thermal transport efficiency in small-world networks by characterizing the density of states, phonon participation ratio, and nearest-neighbor spacing distribution. These insights will pave new ways for designing thermoelectric materials with high electrical conductance and low thermal conductance.