This work is part of a series of articles under the general title The structural design of the blast furnace wall from efficient materials [1–3]. In part 1, Problem statement and calculation prerequisites, typical multilayer enclosing structures of a blast furnace are considered. The layers that make up these structures are described. The main attention is paid to the lining layer. The process of iron smelting and temperature conditions in the characteristic layers of the internal environment of the furnace is briefly described. Based on the theory of A.V. Lykov, the initial equations describing the interrelated transfer of heat and mass in a solid are analyzed in relation to the task – an adequate description of the processes for the purpose of further rational design of the multilayer enclosing structure of the blast furnace. A priori the enclosing structure is considered from a mathematical point of view as the unlimited plate. In part 2, Solving boundary value problems of heat transfer, boundary value problems of heat transfer in individual layers of a structure with different boundary conditions are considered, their solutions, which are basic when developing a mathematical model of a non-stationary heat transfer process in a multi-layer enclosing structure, are given. Part 3 presents a mathematical model of the heat transfer process in the enclosing structure and an algorithm for its implementation. The proposed mathematical model makes it possible to solve a large number of problems. Part 4 presents a number of examples of calculating the heat transfer process in a multilayer blast furnace enclosing structure. The results obtained correlate with the results obtained by other authors, this makes it possible to conclude that the new mathematical model is suitable for solving the problem of rational design of the enclosing structure, as well as to simulate situations that occur at any time interval of operation of the blast furnace enclosure.