Water Transport Model Research Articles

Modeling Nitrogen Recovery and Water Transport in Gas-Permeable Membranes

This study presents a new modeling approach for nitrogen recovery for gas-permeable membrane (GPM) contactors, including both ammonia and water transport dynamics. A distinct feature of the model is its capacity to model water transport across the membrane, which has been overlooked in most publications. Osmotic pressure differences are used to predict the behavior of ammonia and water transport in the GPM. Experiments carried out to develop, test and calibrate the model examined the dynamics of ammonia and water transport through the GPM at various nitrogen concentrations. Specifically, the GPM contactor was tested for nitrogen recovery from high-strength synthetic wastewaters (2.4-10.6 g N/L) at 35°C and at pH 9. The initial volume of the trapping solution (diluted H2SO4) was 10 times lower than that of the synthetic wastewater, aiming to concentrate the recovered nitrogen. The estimated ammonia transport constant (Km) ranged between (1.2 – 2.1)·10-6 m/s and water transport constant Kw between (2.8 – 8.2)·10-10 m/(s bar). Numerical determination of the model parameters revealed high R² values, demonstrating strong agreement with experimental data.

An impedance spectroscopy study to unravel the effect of water on proton and oxygen transport in PEM fuel cells

A recent physics-based model for liquid and gaseous water transport in the cathode catalyst layer (CCL) is incorporated into our 1d ＋ 1d model for the PEM fuel cell impedance. The model includes parametric dependencies of the CCL oxygen diffusivity and proton conductivity on the liquid saturation. Fitting of the 1d ＋ 1d model to experimental impedance spectra of a PEM fuel cell reveals two intriguing effects. Contrary to common belief, the liquid water saturation in the CCL is nearly independent of cell current density due to the growing liquid pressure gradient that drives liquid water removal from the CCL. Further, the “dry” oxygen diffusivity of the catalyst layer increases with cell current density. Apparently, at small current density, electrochemical conversion proceeds primarily in narrow pores, where the Knudsen oxygen diffusivity is low. With growing current density, larger and better connected pores with higher oxygen diffusivity dominate in the current conversion, leading to increase in effective oxygen diffusivity observed in impedance spectroscopy data.

Numerical Modeling of Water Transport in a Microporous Layer-Coated Porous Transport Layer for a Polymer Electrolyte Membrane Water Electrolyzer with an Interdigitated Flow Field for Internal Gas-Liquid Separation

A novel design for interdigitated flow fields in polymer electrolyte membrane electrolyzers has been developed for both ground and space applications. This design separates oxygen and liquid water internally, eliminating the need for water circulators to remove bubbles and external gas-liquid separators with buoyancy. The capillary pressure in the hydrophobic microporous layer (MPL) of the anode porous transport layer facilitates internal separation of oxygen gas and pressurized liquid water. A finite element model (COMSOL Multiphysics) simulates water transport in the MPL, while electrochemical impedance spectra determine the electrochemical kinetic parameters for the model. The model takes into account the oxygen bubble coverage of the cathode, liquid water saturation in the MPL, and the current ratio between liquid water and water vapor at the MPL-cathode layer interface. The vapor from liquid water in the MPL is modeled to mix with oxygen for diffusion. A volumetric water evaporation rate as a linear function of liquid water saturation in the MPL is assumed, where the rate constant is estimated from vapor permeation tests.

Numerical Modeling of Water Transport in a Microporous Layer-Coated Porous Transport Layer for a Polymer Electrolyte Membrane Water Electrolyzer with an Interdigitated Flow Field for Internal Gas-Liquid Separation

A novel design for interdigitated flow fields in polymer electrolyte membrane electrolyzers has been developed for both ground and space applications. This design separates oxygen and liquid water internally, eliminating the need for water circulators to remove bubbles and external gas-liquid separators with buoyancy. The capillary pressure in the hydrophobic microporous layer (MPL) of the anode porous transport layer facilitates internal separation of oxygen gas and pressurized liquid water. A finite element model (COMSOL Multiphysics) simulates water transport in the MPL, while electrochemical impedance spectra determine the electrochemical kinetic parameters for the model. The model takes into account the oxygen bubble coverage of the cathode, liquid water saturation in the MPL, and the current ratio between liquid water and water vapor at the MPL-cathode layer interface. The vapor from liquid water in the MPL is modeled to mix with oxygen for diffusion. A volumetric water evaporation rate as a linear function of liquid water saturation in the MPL is assumed, where the rate constant is estimated from vapor permeation tests.

Modeling Water Transport in Polymer Electrolyte Membrane Electrolyzers Using a One-Dimensional Transport Model

In this work, we present a water transport model to quantify the movement of water across Nafion® membranes in a proton exchange membrane electrolyzer as a function of varying operating conditions and membrane parameters. This physics-based model is based on the three main water transport mechanisms: diffusion, electro-osmotic drag, and pressure-driven flow. Three sets of equations are obtained to model the movement of water on the cathode side – I. Material balances for hydrogen and water in the flow channel (z-direction), II. Water movement across the membrane in the x-direction, and III. Expressions for variable membrane properties to serve as model inputs. The condensation of water at the cathode is also modeled to understand the respective transport contributions from the vapor and liquid phases. The coupled equation sets are solved numerically with appropriate boundary conditions. An analytical solution is also obtained for the governing differential equation for the mole fraction of water in the vapor phase. This study is perhaps the first effort for a detailed physics-based transport model to predict the water transport in the electrolyzer in one dimension using the actual measured values for the physical parameters of the system. The model results are compared with the experimental data available for water transport, and a good agreement is observed over the wide range of current, temperature and pressure differentials. Further, with the help of this simple transport model, the numerical analysis is performed to delineate the effect of electrolyzer operating conditions on the net water transport across the membrane, water condensation at the cathode, individual contribution of the transport fluxes, and electrolyzer design. Finally, the model is exercised to simulate the dependence of water transport as a function of membrane thickness. This confirms the validity of the current approach of using thin reinforced membranes by electrolyzer fabricators. Figure 1

On the transferability of residence time distributions in two 10-km long river sections with similar hydromorphic units

Quantifying hydrologic exchange fluxes (HEFs) at the stream-groundwater interface and their residence time distributions (RTDs) in the subsurface are important for managing the water quality and ecosystem health in dynamic river corridors. However, field measurements and directly simulating high-spatial resolution HEFs and RTDs can be time-consuming, particularly at watershed-scale. Recent research has proposed the potential application of using hydromorphic units (HUs), which cluster the bathymetry and surface water hydrodynamics attributes, to aid in RTD estimation. However, more pioneering studies have demonstrated that underground structure and large-scale river channel geomorphology are the primary factors controlling the HEFs and RTDs. To address this contradiction, this work evaluates the HEFs and resulting HU-RTD relationships for two 10-km long river sections along the Columbia River, leveraging a one-way coupled three-dimensional transient surface–subsurface water transport modeling framework. Applying such a framework at the two river sections with similar HUs allows for quantitative comparisons of HEFs and RTDs using both statistical tests and machine learning classification models. The comparison reveals that the similarity and transferability of the HU-RTD relationship is very low for the two investigated river sections. This suggests that, creating a general algorithm to estimate RTDs in large-scale river reaches based solely on surface water hydrodynamics and short-distance bathymetry topography data may be nearly impossible.

Three-dimensional mass transfer modeling and phenolic chemistry exploration for ultrasound-assisted and microwave drying of goji berry

Herein, goji berries were pretreated with sodium carbonate (Na2CO3) and then dried via ultrasound-assisted air drying or microwave drying. Water migration and phenolic chemistry of goji berries were studied under drying. A three-dimensional ellipsoid water transport model, accounting for porosity and temperature fluctuations, was established to explore the intricacies of the drying mechanism. Generally, microwave drying promoted interior water transport compared to ultrasound drying. Among all the drying methods, microwave drying at 240 W (MW-240 W) exhibited the highest De (from 7.34 × 10−9 to 9.61 × 10−9 m2/s) and kc (6.78 × 10−4 m/s) values. The goji berries received a considerably high water content gradient between its surface and center within the first 2 s of all the drying treatments. Microwave drying diminished the water content gradient earlier than air drying and ultrasound-assisted air drying treatments. Furthermore, most correlations observed among phenolics, oxidase activity, and cell wall pectin did not align with the established theories, highlighting the highly nonlinear nature of phenolic chemistry during goji berry drying. This study provides a three-dimensional model to study the mass transfer mechanism of goji berries and analyzes the evolution of polyphenols during the drying process.

Water Crossover in Proton Exchange Membrane Water Electrolysis

Water management is critical for high performance of polymer electrolyte membrane water electrolysis (PEMWE). In this work, we investigated the water crossover for 5 cm2 PEMWE single cell by varying the temperature (40–80 °C), current density (0–2 A cm−2 geo), cathode pressure (ambient, 310 kPagauge,inlet), and nitrogen purge rate (50, 100 nccm). Using an advanced gravimetric method, the water crossover to the cathode could be established very accurately and also corrected by the water vapor fraction. Here, we pointed out that the cathode exhaust gas is saturated with water vapor, either from diffusion or by proton drag at low or high current densities, respectively. Very importantly, the water crossover at high current density is controlled by the proton drag and are used to extract the temperature-dependent proton drag coefficient at 1 A cm−2 geo. Our results reveal that the proton drag coefficient increases from 2.5 ± 0.2 at 40 °C to 3.2 ± 0.2 at 80 °C (+28%). Altogether, we have developed a sophisticated gravimetric method to accurately determine the water crossover under PEMWE operating conditions and proposed a model of the temperature-dependent proton drag coefficient. Unravelling the proton drag and diffusion is very important for modeling of water transport in PEMWE.

Renal calcium and magnesium handling during pregnancy: modeling and analysis.

Pregnancy is associated with elevated demand of most nutrients, with many trace elements and minerals critical for the development of fetus. In particular, calcium (Ca2+) and magnesium (Mg2+) are essential for cellular function, and their deficiency can lead to impaired fetal growth. A key contributor to the homeostasis of these ions is the kidney, which in a pregnant rat undergoes major changes in morphology, hemodynamics, and molecular structure. The goal of this study is to unravel the functional implications of these pregnancy-induced changes in renal handling of Ca2+ and Mg2+, two cations that are essential in a healthy pregnancy. To achieve that goal, we developed computational models of electrolyte and water transport along the nephrons of a rat in mid and late pregnancy. Model simulations reveal a substantial increase in the reabsorption of Mg2+ along the proximal tubules and thick ascending limbs. In contrast, the reabsorption of Ca2+ is increased in the proximal tubules but decreased in the thick ascending limbs, due to the lower transepithelial concentration gradient of Ca2+ along the latter. Despite the enhanced transport capacity, the marked increase in glomerular filtration rate results in elevated urinary excretions of Ca2+ and Mg2+ in pregnancy. Furthermore, we conducted simulations of hypocalcemia and hypomagnesemia. We found that hypocalcemia lowers Ca2+ excretion substantially more than Mg2+ excretion, with this effect being more pronounced in virgin rats than in pregnant ones. Conversely, hypomagnesemia reduces the excretion of Mg2+ and Ca2+ to more similar degrees. These differences can be explained by the greater sensitivity of the calcium-sensing receptor (CaSR) to Ca2+ compared with Mg2+.NEW & NOTEWORTHY A growing fetus' demands of minerals, notably calcium and magnesium, necessitate adaptations in pregnancy. In particular, the kidney undergoes major changes in morphology, hemodynamics, and molecular structure. This computational modeling study provides insights into how these pregnancy-induced renal adaptation impact calcium and magnesium transport along different nephron segments. Model simulations indicate that, despite the enhanced transport capacity, the marked increase in glomerular filtration rate results in elevated urinary excretions of calcium and magnesium in pregnancy.

Water, Salt, and Ion Transport and Its Response to Water-Saving Irrigation in the Hetao Irrigation District Based on the SWAT-Salt Model

Soil salinization is one of the main hazards affecting the sustainable development of agriculture in the Hetao Irrigation District (HID) of Inner Mongolia. To grasp the water and salt transport patterns and spatial–temporal distribution characteristics of the HID at the regional scale, the improved Soil and Water Assessment Tool with a salinity module (SWAT-Salt) model was used to establish the distributed water and salt transport model for the watershed in this study. The results demonstrated that the modified model could more accurately represent the process of water and salt changes in the HID. The coefficient of determination (R2) in the simulation of streamflow and discharge salt loading was 0.83 and 0.86, respectively, and the Nash–Sutcliffe efficiency (NSE) was 0.80 and 0.74, respectively. Based on this, different hydrological processes (surface runoff, lateral flow, groundwater, soil seepage) as well as spatial–temporal distribution characteristics of water salinity in groundwater and soil were analyzed in the HID. Differences in groundwater and soil salinity in different land uses and soil types were also compared. Of these, surface runoff and lateral flow salt discharge loading are concentrated in the southwestern portion of the basin, while groundwater salt discharge loading is concentrated in the eastern as well as southwestern portions of the basin. The salt discharge loading from groundwater accounts for about 98.7% of the total salt discharge loading from all hydrological pathways and is the major contributing part of salt discharge from the irrigation area. Soil salinity increases gradually from west to east. Groundwater salinity (2946 mg/L) and soil water electrical conductivity (0.309 dS/m) were minimized in the cropland. Meanwhile, rational allocation of irrigation water can appropriately increase the amount of salt discharge loading. In conclusion, the model could provide a reference for the investigation of soil salinization and water–salt management measures in irrigation areas.

Predicting the impact of water transport on carbonation-induced corrosion in variably saturated reinforced concrete

A modelling framework for predicting carbonation-induced corrosion in reinforced concrete is presented. The framework constituents include a new model for water transport in cracked concrete, a link between corrosion current density and water saturation, and a theory for characterising concrete carbonation. The theoretical framework is numerically implemented using the finite element method and model predictions are extensively benchmarked against experimental data. The results show that the model is capable of accurately predicting carbonation progress, as well as wetting and drying of cracked and uncracked concrete, revealing a very good agreement with independent experiments from a set of consistent parameters. In addition, insight is gained into the evolution of carbonation penetration and corrosion current density under periodic wetting and drying conditions. Among others, we find that cyclic wetting periods significantly speed up the carbonation progress and that the induced corrosion current density is very sensitive to concrete saturation.

A preliminary model of water and salt transport in a laboratory scale pressure-retarded osmosis (PRO) module

Nowadays, more and more attention is being paid to the production of green energy. Recently, energy from salinity gradients has also attracted interest. One such process that can generate useful work is the pressure-retarded osmosis (PRO), which uses a semi-permeable membrane to separate the feed and pressurized draw solutions. The semi-permeable membrane allows the transport of solvent (water) from the feed solution (diluted low pressure) side to the draw solution (concentrated high pressure) side, and thus, the excess of pressurized water on the draw side can be used to generate power, i.e., by expansion in the turbine. This work presents a preliminary numerical model developed to study the water and NaCl salt transport through the semi-preamble membrane and in the PRO module designed to perform experimental studies. The model was first verified for simple 2D module geometry. It was then used to study the flow through a simplified 3D module, mimicking the real one used in laboratory-scale experiments. The influence of the hydrodynamic pressure and the NaCl draw solution’s mass flow rate in the module on the energy generation efficiency was examined. The maximum power density obtained for half the osmotic pressure of the NaCl draw solution (i.e., for 28 bar) was found to be equal to approximately 4 W/m2. An increase in the flow rate of the draw solution causes a decrease in the thickness of the boundary layer at the membrane, which reduces the effect of the external concentration polarization. This results in an increase in the concentration difference on either side of the membrane, contributing to a non-linear increase in power density depending on this mass flow rate. Increasing the average velocity from 0.02 m/s to 0.1 m/s increases the power density by up to 80%, from approximately 2.6 to 4.7 W/m2.

A hard sphere model for single-file water transport across biological membranes

We use Gürsey’s statistical mechanics of a one-dimensional fluid to find a formula for the Pf/Pd\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$P_\ extrm{f}/P_\ extrm{d}$$\\end{document} ratio in the transport of hard spheres across a membrane through a narrow channel that can accommodate molecular movement only in single file. Pf\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$P_\ extrm{f}$$\\end{document} is the membrane permeability for osmotic flow and Pd\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$P_\ extrm{d}$$\\end{document} the permeability for exchange across the membrane in the absence of osmotic flow. The deviation of the ratio from unity indicates the degree of cooperative transport relative to ordinary diffusion of independent molecules. In contrast to an early idea that Pf/Pd\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$P_\ extrm{f}/P_\ extrm{d}$$\\end{document} must be equal to the number of molecules in the channel, regardless of the physical nature of the interactions among the molecules, we find a functional dependence on the fractional occupancy of the length of the channel by the hard spheres. We also attempt a random walk calculation for Pd\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$P_\ extrm{d}$$\\end{document} individually, which gives a result for Pf\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$P_\ extrm{f}$$\\end{document} as well when combined with the ratio.Graphical The convection/diffusion ratio for hard spheres in single-file transport

The solution-diffusion model for water transport in reverse osmosis: What went wrong?

Reverse osmosis (RO) stands as the state-of-the-art desalination technology, owing to its high energy efficiency and low cost. Further improvements in the performance of this technology require a fundamental understanding of transport mechanisms in RO membranes. For decades, the solution-diffusion model has been the prevalent approach to describe water transport mechanism in RO membranes. In this model, water first partitions into the membrane and then diffuses down a concentration gradient of water within the RO membrane. However, recent experimental and theoretical findings pose serious challenges to the fundamental assumptions of this theory. In this perspective, we discuss seven critical flaws in the solution-diffusion model and explain why the model fails to describe water transport in RO membranes. Instead, through our careful analyses, we determine that the pore-flow model, in which a pressure gradient drives water flow through membrane pores or interconnected free volumes, represents the true mechanism for water transport. We conclude by highlighting the need for research efforts to better understand the frictional interactions between water, salt, and membrane and their impact on water transport. Overall, a fundamental understanding of the water transport mechanism will inform the development of next-generation RO desalination membranes.

Modeling water transport in polymer electrolyte membrane electrolyzers using a one-dimensional transport model

In this paper, we present a one-dimensional transport model for water transport across Nafion® membranes in a proton exchange membrane electrolyzer. This physics-based model is based on the three main water transport mechanisms: diffusion, electro-osmotic drag, and pressure-driven flow. A good agreement is obtained between the model predictions using the measured values of the physical parameters as inputs and the previously reported experimental data. Further, with the help of this simple transport model, the numerical analysis is performed to delineate the effect of electrolyzer operating conditions on the net water transport across the membrane, water condensation at the cathode, individual contribution of the transport fluxes, and electrolyzer design. Finally, the model is exercised to simulate the dependence of water transport as a function of membrane thickness. This confirms the validity of the current approach of using thin reinforced membranes by electrolyzer fabricators.

Measuring and modeling of liquid water transport in a carbon paper with the aid of centrifuge experiment

In previous macroscopic average models of proton exchange membrane fuel cells (PEMFCs), liquid water was assumed to be continuous throughout the carbon paper. The transport of disconnected water drops in carbon paper has long been neglected in these models, which tend to underestimate water saturation in carbon paper. This study proposes a two-phase flow model that considers the transport of disconnected water drops to simulate the air-water transport in carbon paper. The proposed model was established based on the relationship between capillary force and liquid water saturation, and this relationship was obtained by conducting centrifuge experiments. In the centrifuge experiment, initially, the water saturation inside the carbon paper sample was one, and the centrifugal acceleration was zero. As the centrifugal acceleration increased, the water saturation decreased owing to the centrifugal force. After twenty seconds, the water saturation no longer decreases because the centrifugal force on the liquid water is balanced by the capillary force. Centrifugal acceleration was used to evaluate the capillary force. When the centrifugal acceleration was 185 ms−2, the saturation of the water drops in the balanced state was 32.0%. As the centrifugal acceleration increases to 739 ms−2, the saturation decreases to 6.5%. According to the experimental results, a function correlating the saturation and centrifugal acceleration, that is, the capillary force, was established. Finally, the results show that the centrifugal acceleration is more than 18.5 times that of the gravitational acceleration, indicating that the effect of gravity on the motion of water drops is negligible.

A modified model predicting the hydraulic properties of variably saturated soil accounting for film and capillary flow

Accurate knowledge of hydraulic properties of unsaturated soil is vital to modelling water and solute transport process and addressing soil salinisation problems. Due to the defect that the van Genuchten (VG) model cannot represent soil water characteristics (SWC) during the drying stage, we have introduced a modified model, which combines capillary flow with film flow models to describe the unsaturated hydraulic conductivity. The capillary SWC is obtained by assuming the specific water capacity function with lognormal distribution. The film SWC is modified using the logarithmic nonlinear expression by introducing a modification coefficient into the Campbell equation, and the film relative hydraulic conductivity (RHC) is obtained based on the logarithmic nonlinear relationship. The calculated modification coefficient values range from 0.99 to 2.49. Finally, the proposed model’s rationality and applicability are validated through root mean square error (RMSE) analysis with measured values and comparison with the VG model. While the calculation RMSEs of SWC in the two models are basically consistent, the RMSEs of RHC in the proposed model are around 1–10 times smaller than those of the VG model, indicating its superiority in calculating the hydraulic conductivities over the entire matric head.

Estimation of shallow groundwater recharge in central Qinghai-Tibet Plateau by combining unsaturated zone simulation and improved water table fluctuation method

Accurate estimation of groundwater recharge (GR) is crucial for sustainable groundwater use, particularly in alpine regions that are sensitive to climate change response. However, quantifying the amount of GR in these areas is challenging due to the absence of measurement data and an unclear understanding of the GR mechanism. In this paper, we proposed a new method (HS-IWTF) for estimating GR in the central Qinghai-Tibet Plateau. The method utilized Hydrus-1D to create an unsaturated zone soil water transport model, which provides a reference value for specific yield (Sy). Additionally, the method incorporated the impact of groundwater potential decline at various freeze–thaw stages to improve recharge estimation. The results showed that HS-IWTF method can be better applied for estimating GR in alpine regions. The simulated recharge of groundwater though vertical infiltration ranged from 191.7 to 217.8 mm/yr, primarily from precipitation infiltration. The total GR ranged from 312.1 to 405.0 mm/yr, with significant recharge contributed by snow and ice thaw and lateral runoff. The HS-IWTF method is more precise and reliable than simulated infiltration and traditional water table fluctuation (WTF) method in reflecting recharge changes at various monitoring sites during each freeze–thaw period. The thawing process period (0.95 mm/d, 11 %) and the complete thawing period (1.07 mm/d, 61 %) contributed more recharge at higher recharge rates due to improved recharge sources and conditions. The air temperature rise promoted the degradation of the cryosphere and raised the ratio of recharge precipitation (GR/PT), particularly in regions with high altitude and proximity to permafrost and glaciers where recharge was significantly high during the freezing period. This study provides valuable information on the measurement of GR in alpine regions and the crucial role of freeze–thaw processes in GR.

Nondestructive measurement of the capillary water absorption coefficient and water transport behaviors of porous building materials by using single-sided NMR

Capillarity has an important effect on the durability of buildings, and the capillary absorption coefficient is a key parameter to describe the strength of material capillarity. Most of the methods currently used to measure the capillary absorption coefficient of materials can damage the sample or are not accurate enough and need to be improved. This paper proposes a method to measure the capillary absorption coefficient of brick, sandstone, mortar and concrete by using a single-sided nuclear magnetic resonance (NMR) technique, which has the advantages of accuracy, nondestructiveness, continuity and rapidity. The relative error of the capillary absorption coefficient obtained from three repetitions of the experiment ranges from 0 to 5.11%, which is in the range of 0.64%∼1.30% compared with that obtained by the partial impregnation method. This method has great potential for application in in situ testing. This paper also analyzed the water transport behaviors in porous building materials based on the variation in NMR signal intensity in the measured materials and established a water transport model. The model is divided into two stages: the first stage is mainly the one-dimensional rise in moisture in the vertical direction. The second stage is mainly the diffusion of moisture in the horizontal direction, which continuously fills each pore space to saturation. Difficulty in removing air leads to a reduced rate of water absorption in the second stage.

Assessment of the Impacts of Rainfall Characteristics and Land Use Pattern on Runoff Accumulation in the Hulu River Basin, China

Climate change causes the river basin water cycle disorders, and rainfall characteristics frequently result in flood disasters. This study aims to simulate and assess the response behavior of basin floods under the influence of rainfall characteristics and land use changes in the Hulu River basin using a 2D hydrological and hydraulic GAST (GPU Accelerated Surface Water Flow and Transport Model). The peak flow rate and water depth during floods were examined by simulating the evolution process of basin floods and related hydraulic elements under the independent effects of various rainfall characteristics or land use and further simulating the response results of basin floods under the combined effects of rainfall characteristics and land use. The seven scenarios were set to quantify the degree of influence that land use and rainfall characteristics have on the basin flood process based on examining changes in land use and rainfall characteristics in the research area. The results from different rainfall characteristics scenarios depicted that as the rainfall return period is shorter, the peak flow rate is higher, and the peak flow rate is lower as the return period is prolonged. Under different rainfall characteristics, the peak flow rate in scenario R8 is 41.30%, 40.00%, and 34.51% higher than the uniform distribution of rainfall, while water depth is decreased by 0.55%, increased by 4.96% and 2.92% as compared to the uniform distribution of rainfall. While under different land use scenarios, it is observed that the change in land use has increased 2.7% in cultivated land and 1.1% in woodland. In addition, the interactive effect of different rainfall characteristics and land use it can be seen that the scenario with the greatest reduction in flood risk due to rainfall characteristics and land use is RL2-4, representing a 12.55% decrease in peak flow and a 37.69% decrease in peak water depth. In this scenario, the rainfall is heavier in the southeast and northwest regions and lighter in the northeast and southwest regions. The land use type is characterized by reforestation and the return of cultivated land to forests. The changes in rainfall distribution and the increase in grassland contribute to the decrease in flood threat. Future research in the erodible parts of the Hulu River basin, planning for water resources, and soil and water conservation can all benefit from the study’s conclusions.