Relating soil moisture content to soil suction, the soil–water characteristic curve (SWCC) represents an essential feature in unsaturated soil mechanics that enables estimation of different unsaturated soil property functions and modeling of the macro-scale soil behavior. However, depending on the soil and processes under consideration, proper hydraulic characterization of a soil through direct laboratory measurements can be difficult, time-consuming, and involve many uncertainties. In the case of uniformly graded sands, there is a highly nonlinear and steep shape of the SWCC, with only a few kPa of soil suction separating saturated and residual soil moisture conditions, which makes measurements for determinations of SWCC especially challenging. This study encompasses an investigation of the sandy type of soil’s behavior and presents some preliminary results and experiences on the determination of SWCC through the use of physical slope model tests. The 30 cm deep slope, inclined at 35 degrees and instrumented with soil moisture and pore water pressure sensors, was exposed to series of rainfall intensities, ranging from 37 up to 300 mm/h. The results indicated that the data on hydraulic response in monitored points are not only useful for the determination of SWCC, but that the approach is useful for investigation of hydraulic hysteresis phenomena, as well as its effects on soil moisture and pore water pressure conditions, which also affects the stability conditions of a slope. In particular, the best-fit parameters of the van Genuchten model suggested air entry values of 1.6 and 1.1 kPa for the drying and the wetting curves of the SWCC, respectively, with the two branches shifted by about 1 kPa of soil suction.