Bismuth incorporated glassy systems with composition xBi2O3-(1-x) [0.3BaO-0.3P2O5-0.4TeO2] (where x = 0.10, 0.15, 0.20, and 0.25) are synthesized by melt quenching technique. The glassy systems are examined for their structural, and surface morphological properties using XRD, SEM, and EDX analysis. A study of photocatalytic activity for the degradation of common organic dyes like Rhodamine B (RhB) dye under visible light is also carried out. From UV-vis absorbance data, the calculated optical band gap energy values declined from (2.99-2.56) eV, whereas the Urbach energy and refractive index values increased from (0.35 -0.52) eV, and (2.39 - 2.52), respectively with the rise of Bi2O3 content(x). Additionally, the fundamental processes of electrical conductivity have been studied within the framework of Jonscher's universal power law and the Almond-West formalism. The Mott and Greaves model asserts that the small polaron hopping model underlies DC conductivity; as Bi2O3 content increases, DC conductivity rises, but hopping distance (Rhop) and hopping energy (Whop) drop dramatically. The electrical conductivity study reveals the semi-conducting nature of the as-prepared samples. In our present study, we are focusing on the structural, optical, and electrical transportation properties, additionally, we investigated this class of glassy materials as a promising candidate for photocatalytic dye degradation. Our study reveals that RhB dye can degrade up to 75% within 340 min of visible light illumination. Moreover, the test demonstrates the production of superoxide radicals by the CB-electrons and hydroxyl radicals by the VB holes enables efficient photocatalytic dye degradation.
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