This study investigates the fracture toughness of alkali-activated granulated blast-furnace slag (GBFS)-based geopolymer concrete (GPC), non-activated slag cement concrete, and ordinary Portland cement (OPC) concrete in acidic, alkaline, and chloride solutions over six months. A total of 580 centrally straight-notched Brazilian disc (CSNBD) specimens were cast to assess pure mode-I (0°), pure mode-II (28.7°), and mixed-mode (15° and 45°) fractures under these conditions. Microstructural analyses (SEM) were performed to evaluate microstructural changes after six months of exposure. Results showed that GPC exhibited the lowest initial fracture toughness but the smallest reduction (7 %-11 % depending on the mode) across all environments, with slag cement concrete and OPC experiencing reductions of 11 %-14 % and 14 %-21 %, respectively, in acidic conditions. In alkaline environments, GPC showed a 3 %-6 % decrease in fracture toughness, while OPC and slag cement concrete showed reductions of 6 %-13 %. The gradient boosting regressor accurately predicted the failure load of CSNBD specimens, achieving an R² score of 0.948. Finally, SHAP sensitivity analysis identified concrete type, exposure time, and environment as critical input features, consistent with experimental results.
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