Mobility Of Cr Research Articles

Poly-γ-glutamic acid chelates chromium (III) and copper (II), alleviating their toxicity in cucumber and affecting rhizosphere bacterial community assembly

The accumulation of chromium (Cr) and copper (Cu) in soil during industrialization and modernization poses an extreme threat to crops. Poly-γ-glutamic acid (γ-PGA) has the potential to stabilize heavy metals in soil through chelation because of the numerous carboxyl groups in its side chain. The rhizosphere microbiome contributes to plant detoxification by participating in heavy metal passivation. However, it is still unclear whether γ-PGA can alleviate the toxicity of Cr and Cu to plants and whether this effect is associated with changes in the rhizosphere microbiome assembly. Here, we found that γ-PGA application significantly reduced the content of Cr or Cu in cucumber plants by 67.45%–86.77% and 94.67%-98.21, respectively, and alleviated the oxidative stress of Cr or Cu to plants. Moreover, γ-PGA significantly increased the biomass of cucumber fruits in the plot experiment by 13.5% and 25.3% under Cr and Cu stress, respectively. The content of Cr or Cu in the cucumber fruit was below limits of detection, in contrast to the 31.23 mg/kg Cr or 9.86 mg/kg Cu detected in the no-γ-PGA treatment. γ-PGA effectively chelated Cr and Cu in vitro, and less than 30% of their chelates were degraded in 20 weeks, suggesting the strong stability of these chelates. γ-PGA significantly altered the rhizosphere bacterial community composition of cucumber by enriching phyla Gemmatimonadota, Acidobacteriota and Firmicutes, and genera Gemmatimonas and Stenotrophomonas, which potentially involved in reducing the mobility of Cr and Cu in soils. Furthermore, γ-PGA significantly enriched taxa assigned to plant growth-promoting bacteria (PGPB). Together, our results suggest that γ-PGA can reduce the Cr and Cu contents in cucumber, and this process is strongly associated with the chelation capacity of γ-PGA and its effects on rhizosphere microbiome composition. These results highlight the exciting potential to use γ-PGA for the remediation of heavy metal-contaminated soils.

Microplastic-induced changes in Cd and Cr behavior in the agricultural soil-wheat system: Insights into metal bioavailability and phytotoxicity

Microplastics (MPs) and heavy metals widely coexist in agricultural soils, posing significant risks to soil-plant ecosystems. This study explores the effects of five common MPs—polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polystyrene (PS), and polylactic acid (PLA)—and environmental-simulating microplastics (EMPs), composed based on the composition of local MPs in agricultural soils, on the bioavailability and phytotoxicity of Cd and Cr in soils. Pot experiments demonstrated that MPs, particularly PE and EMPs at a 5 % dosage, markedly decreased soil pH, water-holding capacity, and soil organic carbon content. This decrease in pH led to enhanced Cd and Cr mobility and bioavailability, especially with PE and EMPs increasing Cr bioavailability in 15 cm depth soil by up to 43.9 % and 37.8 %, respectively. In soils with 2.1 mg/kg of Cd and 390 mg/kg of Cr, both 1 % and 5 % doses of MPs inhibited wheat growth while enhancing the uptake and translocation of Cd and Cr in wheat. Notably, PE, PS, PLA, and EMPs exposure significantly elevated levels of oxidative stress markers (SOD, POD, CAT, and MDA) in wheat. These findings highlight the importance of further research on the combined impacts of MPs and heavy metals on soil health and plant safety.

Nickel, chromium, and cobalt in soils developed on nickel laterites near an abandoned mining area in southern Czech Republic

Geochemical anomalies are gaining importance due to the Europe's renewed prospecting activities for technologically critical metals, such as nickel (Ni) and cobalt (Co). In this context, soils developed on Ni laterites near old open pit mining and exploration works near Křemže in southern Czech Republic were investigated using multi-method approach to assess the distribution, solid speciation, and (bio)availability of the trace metals, with a particular focus on Ni, chromium (Cr), and Co. The total concentrations of metals in the studied soils (Ni: 170–4950 mg/kg, Cr: 56–1190 mg/kg, Co: 14–424 mg/kg) exceeded the median world regulatory guideline values (Ni: 112 mg/kg; Cr: 250 mg/kg; Co: 50 mg/kg) as well as the Czech concentration limits for agricultural soils for most of the samples. The concentration of metals in the soil profiles generally increased as a function of depth with surface horizons in agricultural plots homogenized by ploughing. The effect of a former open pit mine (already closed for ca 80 years) on the vertical distribution of metallic elements has not been demonstrated. The extractable metals were relatively low (extraction efficiency order: water < DTPA < EDTA). The mean EDTA-extractable values corresponded to 4.2 % Nitot, 8.6 % Cotot, and only 0.14 % Crtot. This contrasting metal availability is strictly related to the metal speciation in the solid phase. The primary minerals (olivine, clinopyroxene) are highly weathered to secondary phyllosilicates (lizardite, talc) and Fe oxyhydroxides and Mn oxides, all representing important carriers for Ni. Cobalt was exclusively hosted by Mn oxides, and the less mobile Cr was mainly bound in insoluble phases, likely spinel-family oxides. Despite the relatively low metal availability, elevated concentrations of Ni in the crop biomass (86 mg/kg) collected in the agricultural area suggest a metal uptake from the soil, which should be further investigated in detail.

Effects of nZVI on the migration and availability of Cr(VI) in soils under simulated acid rain leaching conditions

Hexavalent chromium, Cr(VI), is a ubiquitous toxic metal that can be reduced to Cr(III) by nano-zero-valent iron (nZVI). Finding out effects of continuous rainfall leaching on the Cr(VI) release and availability remains a problem, needing to be addressed. Whether the Cr(VI) reduction by nZVI and continuous rainfall leaching lead to localized heterogeneity in soil is unclear. Therefore, two in situ high-resolution (HR) techniques of the diffusive gradients in thin-films (DGT) and planar optode were combined with ex situ sampling experiments here. Results demonstrate that nZVI decreased Cr(VI) leaching by 5.60–8.50 % compared to control soils. DGT-measured concentrations of Cr(VI), CDGT-Cr(VI), ranged from 7.31 to 19.4 μg L-1 in the control soils, increasing with depth while CDGT-Cr(VI) in nZVI-treated soils (2.41–6.18 μg L-1) decreased or remained stable with depth. However, simulated acid-rain leaching increases CDGT-Cr(VI) by 1.61-fold in nZVI-treated soils, negatively affecting the remediation. DGT measurements in bulk soils using disc devices are better at capturing the change of Cr(VI) availability at different conditions, whereas 2D-HR DGT mappings did not characterize significant mobilization of Cr(VI) at the micro-scale. These findings emphasize the importance of monitoring Cr(VI) release and availability in remediated soil under acid-rain leaching conditions for effective environment management.

Highly alkaline electrokinetic extraction: Characteristics of chromium mobilization, conversion and transport in high alkalinity soil

In site chromium (Cr) contaminated soil characterized by high alkalinity and carbonate content, protons are not effectively targeted for Cr(III) mobilization but rather accelerate the reduction of easily transportable Cr(VI) within the acidification electrokinetic (EK) system. As an alternative, the highly alkaline extraction conditions (HAECs) maintained by anolyte regulation are explored owing to the ability to desorb strong binding Cr(VI) and form anionic Cr(III)-hydroxides (Cr(OH)4−, Cr(OH)52−). The results demonstrate that HAECs were more efficient in mobilizing ions in severe alkalinity and electrical conductivity soil compared to organic acid acidifying extraction conditions (OAECs). Simultaneously, a limited amount of soluble Cr(III) was produced; however, its transportation was hindered and more noticeable in the case of Cr(VI), displaying a distinct retention phase within the intermediate soil chamber. The antagonistic interplay between electromigration and electroosmotic flow was considered the main responsible factor. The conversion intensity of Cr(VI) to Cr(III) was inhibited at HAECs. The promising mobilization and low conversion intensity contributed to total Cr removal. At HAECs, enhanced electromigration and electroosmotic flow combined with a favorable oxidation environment may facilitate in situ delivery of oxidants, offering practical implications for the EK detoxification of high alkalinity site soil contaminated with Cr. The practicability of HAECs is likely to be enhanced when the cost-benefit balance of providing a simultaneous energy supply during site treatment is resolved.

Impact of thermal soil treatment on heavy metal mobility in the context of waste management.

Thermal soil treatment is a well-established remediation method to remove organic contaminants from soils in waste management. The co-contamination with heavy metals raises the question if thermal soil treatment affects heavy metal mobility in soils. In this study, four contaminated soils and a reference sample were subjected to thermal treatment at 105°C, 300°C and 500°C for 7 day. Thermogravimetry and differential scanning calorimetry were used to understand the reactions, and resulting gases were identified by Fourier-transformed infrared spectroscopy. Treated and untreated samples were characterised by X-ray diffraction (XRD) and electron microprobe analysis and subjected to pH-dependent leaching tests, untreated samples additionally by X-ray-fluorescence (XRF) and inductively coupled plasma mass spectroscopy (ICP-MS). Leachates were analysed using ICP-MS and ion chromatography. Maximum available concentrations were used for hydrogeochemical modelling using LeachXS/Orchestra to predict leaching control mechanisms. Leaching experiments show that thermal treatment tends to decrease the mobility at alkaline pH of Pb, Zn, Cd, As and Cu, but to increase the mobility of Cr. In the acidic to neutral pH range, no clear trend is visible. Hydrogeochemical modelling suggests that adsorption processes play a key role in controlling leaching. It is suggested that the formation of minerals with a more negatively charged surface during thermal treatment are one reason why cations such as Pb2+, Zn2+, Cd2+ and Cu2+ are less mobile after treatment. Future research should focus on a more comprehensive mineralogical investigation of a larger number of samples, using higher resolution techniques such as nanoscale secondary ion mass spectrometry to identify surface phases formed during thermal treatment and/or leaching.

Heavy metal content of mountainous agricultural soils and ecological risk assessment in Gadabay district, Azerbaijan

Objective: The objective of this study was to i) investigate the distribution characteristics of heavy metals, ii) examine their relationships with basic soil properties, and iii) characterize their potential sources and ecological risks. Material and Methods: A total of 85 samples were collected from the surface horizon (0-15 cm) of Chernozem soil in a representative agricultural area located in the Lesser Caucasus Mountains (Gadabay district), and heavy metal contents and basic soil properties were determined. Results: The mean of the heavy metals followed a decreasing order: Mn&amp;gt;Zn&amp;gt;Cu&amp;gt;Cr&amp;gt;Ni&amp;gt;Co&amp;gt;Pb&amp;gt;As&amp;gt;Se&amp;gt;Cd and some heavy metals (As, Cd, Se) exhibited a fragmented distribution. Co, Cr, Mn, Se and Zn contents were higher than the background concentration, while others (As, Cd, Co, Cu, Pb and Zn) exceeded the maximum permissible concentration. Conclusion: The spatial distribution of heavy metals was characterized by their typical and element-specific distribution. The noted variability was likely related to geologic features (soil mineralogy), mining history and agricultural practices. Notably, the presence of limestone and clay minerals contributed to the association of Cd, Cu and Se and Mn and Pb, respectively. Sand content influenced the mobility of Cr and Cu. The relations between pH and Cr, Ni and Se was the indication of the influence of the parent material on the distribution of these metals.

Enhanced reduction of Cr(VI) in UV/EKR system by organic acids: Focus on Cr(VI) desorption and Fe(III) catalysis

Reducing highly toxic and mobile Cr(VI) to environmentally less hazardous Cr(III) is vital research for remediating Cr-contaminated soil. In this study, a UV/EKR system, which combined electrokinetic remediation (EKR) technology with ultraviolet (UV) photoreduction, was employed to investigate the enhanced reduction of Cr(VI) in actual contaminated soil by oxalic, malic, and tartaric acids. The results demonstrated that the introduction of UV radiation resulted in the removal of 99.49% of Cr(VI) from the anolyte and further enhanced the removal efficiency of high-concentration Cr(VI) in the near-anode soil layer by 14.83% compared to traditional EKR. Among the three acids, malic acid exhibited superior performance, as it alleviated the clogging caused by precipitates, provided more photocatalyst Fe(III), and reduced the retention of the reduction product Cr(III) in the soil. This resulted in the removal rates of 90.38%, 83.82%, and 27.14% of water-soluble, weakly bound, and strongly bound Cr(VI), respectively in the near-anode soil layer. Therefore, the combination of organic acids and the UV/EKR technique shows high compatibility, offering a promising solution to the poor reduction efficiency of Cr(VI) in actual soil in the field of EKR. This approach provides new insights for the in-situ remediation of Cr-contaminated soil.

Modulation of sunflower growth via regulation of antioxidants, oil content and gas exchange by arbuscular mycorrhizal fungi and quantum dot biochar under chromium stress

Chromium (Cr) toxicity significantly threatens sunflower growth and productivity by interfering with enzymatic activity and generating reactive oxygen species (ROS). Zinc quantum dot biochar (ZQDB) and arbuscular mycorrhizal fungi (AMF) have become popular to resolve this issue. AMF can facilitate root growth, while biochar tends to minimize Cr mobility in soil. The current study aimed to explore AMF and ZQDB combined effects on sunflower plants in response to Cr toxicity. Four treatments were applied, i.e. NoAMF + NoZQDB, AMF + 0.40%ZQDB, AMF + 0.80%ZQDB, and AMF + 1.20%ZQDB, under different stress levels of Cr, i.e. no Cr (control), 150 and 200 mg Cr/kg soil. Results showed that AMF + 1.20%ZQDB was the treatment that caused the greatest improvement in plant height, stem diameter, head diameter, number of leaves per plant, achenes per head, 1000 achenes weight, achene yield, biological yield, transpiration rate, stomatal conductance, chlorophyll content and oleic acid, relative to the condition NoAMF + No ZQDB at 200 mg Cr/kg soil. A significant decline in peroxidase (POD), superoxide dismutase (SOD), and catalase (CAT) while improvement in ascorbate peroxidase (APx), oil content, and protein content further supported the effectiveness of AMF + 1.20%ZQDB against Cr toxicity. Our results suggest that the treatment AMF + 1.20%ZQDB can efficiently alleviate Cr stress in sunflowers.

Content and Mobility Metals in Oligotrophic Peat Soils of the Cryolithozone of Western Siberia

The ongoing climatic changes have the greatest impact on natural ecosystems in high-latitude areas, as warming climate, as well as increasing anthropogenic load associated with the development of Arctic zone, contribute to the degradation of frozen peatlands and an increase in the thickness of seasonally thawed layer of soil. The relevance of studying peat oligotrophic soils (Cryic Histosols) of the northern territories of Western Siberia is associated with the fact that their degradation enriches natural waters by organomineral substances, which containing a large number of chemical elements, including heavy metals, contributing to changes in the hydrogeochemical properties of natural waters of the North. The article describes the main properties of peats sampled from different horizons of soil profiles laid down at key areas covering the territory of YNAO from north to south and from west to east. The chemical composition of soils was analyzed at the IPA SB RAS using standard methods. The concentrations of gross and mobile forms of metals (Fe, Ca, K, Na, Mg, Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn) were investigated by optical atomic emission spectrometry and flame atomic absorption spectrometry, respectively. It has been determined that a characteristic feature of the distribution of concentrations of chemical elements in peat oligotrophic soils of the northern part of Western Siberia is the presence of two maxima within the soil profile. The first is confined to the upper horizons showing signs of degradation, while the second is confined to the upper part of the permafrost. Statistical analysis using principal component method showed that low ash content, pH and C/N ratio are associated with high mobility of K, Cu, Zn and Mg. The mobility of Fe, Mn, Pb, Cd, and Cr is associated with an increase in ash content, pH, and Ntotal in the upper part of permafrost organogenic rocks.

A multi-scale assessment of the impact of salinity on the desorption of chromate from hematite: Sea level rise implications

The solubility and transport of Cr(VI) is primarily controlled by adsorption-desorption reactions at the surfaces of soil minerals such as iron oxides. Environmental properties such as pH, ionic strength, and ion competition are expected to affect the mobility and fate of Cr(VI). Sea level rise (SLR), and consequent seawater intrusion, is creating a new biogeochemical soil environment at coastal margins, potentially impacting Cr(VI) retention at contaminated sites. We employed in-situ ATR-FTIR spectroscopy and DFT calculations to investigate at the molecular level the adsorption of Cr(VI) on the hematite surface and its desorption by sulfate, as a function of pH and ionic strength. We further used a batch experiment to assess Cr(VI) desorption at varying artificial seawater (ASW) concentrations. IR results demonstrate the complexity of Cr(VI) adsorption, showing a combination of monodentate inner-sphere complexation at high pH and dichromate outer-sphere (∼75%) at low pH. The Cr(VI)-complexes exhibited desorption induced by increasing pH values (58% of desorption) and sulfate competition (∼40% desorption). ASW desorbed ∼20% more Cr(VI), even at just 1% concentration. Our findings provide insight into Cr(VI)-adsorption complexation that controls the retention and remobilization of Cr(VI) on Fe-oxide minerals. The results point to an elevated risk of Cr(VI) mobilization in contaminated soils affected by SLR.

Interaction between chromite and Mn(II/IV) under anoxic, oxic and anoxic-oxic conditions: Dissolution, oxidation and pH dependence

Chromite oxidative dissolution has been recognized as an important process leading to elevated Cr(VI) in soil and groundwater. Under natural conditions, direct oxidation of Cr(III) by O2 is very unfavorable, and a critical determinant of Cr(VI) generation in soil and groundwater is the interaction between chromite and Mn(II) or Mn(III/IV) oxides. Here, the effects of Mn(II) or Mn(IV) on the oxidative dissolution of chromite were investigated at pH values of 5, 7 and 9 during anoxic, oxic and anoxic-oxic processes. The results showed that the direct oxidation of Cr(III) by O2 was slow in aqueous-phase system, while the Mn oxides in chromite could oxidize dissolved Cr(III). The added Mn(II) can be catalytically oxidized to MnOOH on the chromite surface only under alkaline oxidation conditions, and the catalytic efficiency is slow, which has less effect on chromite oxidative dissolution. Compared with the direct oxidation of O2 and catalytic oxidation of Mn(II), the synthesized biogenic Mn oxides drove the oxidative dissolution of chromite to release more Cr(VI) and were the main threat to the long-term stability of chromite in the environment. Overall, both acidic and alkaline environments are favorable to the catalytic oxidation of chromite by O2, Mn(II) and δ-MnO2, while neutral conditions are favorable to the long-term stability of chromite. These above processes may occur in soils and sediments with redox fluctuations (e.g., rice paddies, river floodplains, wetlands, and peatlands), and the presence of Mn(II) and Mn(III/IV) may play an important role in the oxidation and mobilization of Cr(III), leading to elevated Cr(VI) levels in soils and groundwater.

Chromium speciation and mobility in contaminated coastal urban soils affected by water salinity and redox conditions

Chromium (Cr) is a redox-sensitive element in contaminated coastal urban soils. Sea level rise (SLR) with subsequent soil inundation may facilitate Cr transformation and mobilization through alterations in local redox conditions and porewater ion composition. We investigated the impact of water salinity and redox conditions on Cr chemistry in these environments. Synchrotron-based X-ray spectroscopy and wet chemical analyses revealed that the soils contained very high levels of Cr (up to 4320 mg kg-1) and that chromite (∼52%) and Fe-Cr hydroxide coprecipitates (∼44%) were the predominant Cr species. The abundance of these two components resulted in low Cr mobility under non-flooded conditions. Chromium(II) was identified in the soils, potentially derived from the waste parent material. Seawater and anoxic conditions resulted in lower Cr release compared to freshwater and aerobic conditions. Up to three to eight times more Cr was released under aerobic conditions versus anaerobic conditions in the freshwater versus saltwater, respectively, with total dissolved Cr values remaining below 0.02 mg L-1. The decrease in Cr release was likely due to Cr reduction by Fe(II) and sulfide. This work provides important information on how salinity and redox fluctuations impact Cr cycling which is likely to occur during SLR.

Chromium Isotope Behavior During Serpentinite Dehydration in Oceanic Subduction Zones

AbstractFluids released through the dehydration of serpentinite can be rich in Cl−, which enables the significant mobility of Cr in subduction zones. However, the Cr isotope behavior accompanying the mobility of Cr during serpentinite dehydration is still poorly constrained. Here, we report high‐precision Cr isotope data for a unique suite of serpentinites that represent metamorphic products at different depths in oceanic subduction zones. Low‐grade serpentinites affected by significant Cr loss during serpentinization exhibit remarkably higher δ53Cr, while samples with Cr contents &gt;∼1,800 ppm typically preserve mantle‐like δ53Cr. Antigorite serpentinites have an average δ53Cr value of −0.17‰ ± 0.19‰ (n = 12, 2SD), which is statistically lower than those of low‐grade serpentinite (−0.05‰ ± 0.30‰, n = 80, 2SD) and higher‐grade chlorite harzburgite (−0.10‰ ± 0.27‰, n = 22, 2SD). This suggests that resolvable Cr isotope fractionation occurs during serpentinite dehydration, which is explained by the variability of Cr isotope behavior in the presence of Cl‐bearing fluids at different dehydration stages. No obvious Cr isotope fractionation was found during chlorite harzburgite dehydration, probably related to the limited Cr mobility in a Cl‐poor fluid. Other processes, such as melt extraction, external fluid influx and retrograde metamorphism, have negligible effects on the Cr isotope systematics of meta‐serpentinites. Fluids released by serpentinite dehydration may have a great effect on the Cr isotope heterogeneity of mantle wedge peridotites and arc magmas.

Application of high-resolution techniques in the assessment of the mobility of Cr, Mo, and W at the sediment-water interface of Nansi Lake, China.

There are few studies on the simultaneous behavior of chromium (Cr), molybdenum (Mo), and tungsten (W) belonging to group VIB of the periodic table. Herein, based on high-resolution dialysis (HR-Peeper) and diffusive gradients in thin films (DGT) technology, the vertical distribution characteristics of DGT-labile and soluble Cr, Mo, and W in two lakes of Nansi Lake (Weishan Lake and Dushan Lake) were analyzed. In addition, the net diffusion fluxes and R-value (CDGT/Csol) were used to evaluate the mobility and release risk of metals at the sediment-water interface. The results showed that the DGT-labile concentrations of the three metal elements (Cr, Mo, and W) in Weishan Lake were higher than those in Dushan Lake, both in overlying water and sediment. This is mainly due to the dredging of the Dushan Lake area, which can permanently remove the polluted sediment in the lake. Meanwhile, the exogenous input is relatively high near the tourist area of Weishan Island. The net diffusion fluxes indicate that the W has a potential release risk of diffusion to the overlying water in Dushan Lake. The release of Cr, Mo, and W is thought to be related to the reductive dissolution of Fe/Mn (hydr)oxides based on Pearson correlation coefficients. The R-values of Cr and W indicate that Cr and W belong to the partial continuity case. The R-value of Mo was lower than the minimum value, meaning that Mo belongs to the single diffusion type and it is difficult for Mo sediments to supply pore water.

Tin Oxide Nanoparticles via Solar Vapor Deposition for Hexavalent Chromium Remediation.

Tin oxide nanoparticles optimized to capture low concentrations of hexavalent chromium from water were developed through a facile, scalable, and low-cost one-step solar vapor deposition methodology. Considering the preservation of high electron donation capacity as the key to support the reduction of mobile Cr(VI) into insoluble forms, the growth of SnO nanoparticles was favored by the co-evaporation of SnO2 with Fe powders at various mass ratios. Characterization techniques indicated that the percentage and the stability of SnO is proportional to the Fe content in the target with a requirement of at least 50% wt to inhibit the formation of a passive SnO2 surface layer. The produced particles were evaluated regarding their efficiency to capture Cr(VI) under conditions similar to water treatment for drinking purposes (pH 7). It was revealed that passivation-free SnO nanoparticles deliver significant improvement in the adsorption capacity corresponding to the residual concentration of 25 μg/L, reaching a value of 1.74 mg/g for the sample prepared with 50% wt Fe in the target. The increase of water acidity was found responsible for the activation of more reduction sites on the particle surface, as reflected through the elevation of efficiency by more than 20% at pH 6.

Effect of TiAlNbCrSi Alloy Microstructure Produced by Mould Casting (MC) or Electron Beam Powder Bed Fusion (EB-PBF) on Scale Grown Under Dry Air and Steam

TiAl parts fabricated with additive manufacturing have begun to find applications in car and aviation industry. Optimization of their properties concentrates on introduction of new alloying additions improving the TiAl ductility and oxidation resistance. Their effect on the mechanical properties was worked out quite well, but the knowledge how they affect the oxidation processes is still limited. Therefore the present experiment was aimed at investigation of scale grown over mould cast (MC) and electron beam powder bed fusion (EB-PBF) Ti–48Al–2Nb–0.7Cr–0.3Si (at. pct) alloys. It was conducted at 650 °C for 1000 hours both in dry air and steam covering early stages of this process. The scale microstructure, chemical and phase composition was examined with the transmission electron microscopy (TEM). Applied treatment caused development of three-layer scale, i.e. with major portions of R-TiO2 + α-Al2O3/R-TiO2/α-Al2O3. The one formed during dry-air oxidation of the EB-PBF alloy was most compact. Steam oxidizing changed morphology of rutile present at its surface from rod/plate-like into whiskers. The Si turned out to be especially active during scale growth diffusing up to its surface. The presence of steam further increased mobility of both Si and Cr rising their presence in the upper part of the scale. The Nb was found to accumulate within the substrate area adjoining to the scale. Refinement of EB-PBF microstructure as compared with the MC alloy resulted in promoting reaction at the scale/substrate front contributing significantly to development of thicker oxide coating and nitrides bearing oxidation affected zone.

Soil, water and plants contamination by total chrome and chrome VI

AbstractThe chrome (Cr) is a metal utilized in various industrial sectors and its investigation in the environment is necessary, for the Cr (III) contain aessential micronutrients in the human nourishment and the Cr (VI), on the other hand, is toxic. In the present work soil contamination with Cr was realized in drainagelysimetersset in concentrations of 0, 200, 400, 600, 800 and 1000 mg kg−1 of total Cr, with the intuition to determine the total Cr and Cr (VI) flux in leached water, in soil and in plants of lettuce (Lactuca sativa L.). In the lysimeters were cultivated four plants, in three cultivation circles. In the end of the cultivations was observed, that the total applied Cr leached in the soil, evidencing the Cr mobility in latossoil with simulant characteristics to the ones utilized in this paper. The Cr (VI) concentrations in the soil increased soon after the treatment applications, but tend to decrees in the time elapse, the same tendences were observed for the total Cr concentrations in the leached water. The Cr absorption by plants was related to the Cr disponibility in the soil, for the soil concentration and the plants decreased with time passing. The Cr mobility in the soil possibilitated the groundwater contamination presenting risks to the water quality and, consequently to public health.

Water Management Impacts on Chromium Behavior and Uptake by Rice in Paddy Soil with High Geological Background Values.

Chromium (Cr) is an expression toxic metal and is seriously released into the soil environment due to its extensive use and mining. Basalt is an important Cr reservoir in the terrestrial environment. Cr in paddy soil can be enriched by chemical weathering. Therefore, basalt-derived paddy soils contain extremely high concentrations of Cr and can enter the human body through the food chain. However, the water management conditions' effect on the transformation of Cr in basalt-derived paddy soil with high geological background values was less recognized. In this study, a pot experiment was conducted to investigate the effects of different water management treatments on the migration and transformation of Cr in a soil-rice system at different rice growth stages. Two water management treatments of continuous flooding (CF) and alternative wet and dry (AWD) and four different rice growth stages were set up. The results showed that AWD treatment significantly reduced the biomass of rice and promoted the absorption of Cr in rice plants. During the four growth periods, the root, stem and leaf of rice increased from 11.24-16.11 mg kg-1, 0.66-1.56 mg kg-1 and 0.48-2.29 mg kg-1 to 12.43-22.60 mg kg-1, 0.98-3.31 mg kg-1 and 0.58-2.86 mg kg-1, respectively. The Cr concentration in roots, stems and leaves of AWD treatment was 40%, 89% and 25% higher than CF treatment in the filling stage, respectively. The AWD treatment also facilitated the potential bioactive fractions conversion to the bioavailable fraction, compared with the CF treatment. In addition, the enrichment of iron-reducing bacteria and sulfate-reducing bacteria with AWD treatment also provided electron iron for the mobilization of Cr, thus affecting the migration and transformation of Cr in the soil. We speculated that the reason for this phenomenon may be the bioavailability of Cr was affected by the biogeochemical cycle of iron under the influence of alternating redox. This indicates that AWD treatment may bring certain environmental risks in contaminated paddy soil with high geological background, and it is necessary to be aware of this risk when using water-saving irrigation to plant rice.

High-resolution imaging of O2 dynamics and metal solubilization in the rhizosphere of the hyperaccumulator Leersia hexandra Swartz

The mobilization of trace metals in the rhizosphere can be affected by the redox potential, which is closely related to the O2 dynamics. This study examined the distributions of O2 and trace metals in the rhizosphere of the subaquatic hyperaccumulator Leersia hexandra Swartz under chromium (Cr) stress using planar optodes and the diffusive gradients in thin films technique coupled with laser ablation inductively coupled plasma mass spectrometry. The O2 concentrations and oxidized areas in the rhizosphere significantly increased with increases in the light intensity, air humidity, and atmospheric CO2 concentrations (p < 0.05). The O2 concentration first increased with increasing ambient temperatures, then decreased when the temperature increased from 25 to 32 ℃. The O2 concentration in the rhizosphere was significantly decreased under Cr stress (p < 0.05), with a prolonged response time to the altered ambient temperature. Cr stress led to decreased mobilities of As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Sb, V, W, and Zn in the rhizosphere, which were negatively correlated with the concentrations of O2. These results provide new insights into the role of changes in the O2 concentration induced by the roots of hyperaccumulator plants in controlling the mobility of trace metals in soils.